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NASA NTRS2003

Development of Numerical Codes for Modeling Electromagnetic Behavior at High Frequencies Near Large Objects

A study into the problem of determining electromagnetic solutions at high frequencies for problems involving complex geometries, large sizes and multiple sources (e.g. antennas) has been initiated. Typical applications include the behavior of antennas (and radiators) installed on complex conducting structures (e.g. ships, aircrafts, etc..) with strong interactions between antennas, the radiation patterns, and electromagnetic signals is of great interest for electromagnetic compatibility control. This includes the overall performance evaluation and control of all on-board radiating systems, electromagnetic interference, and personnel radiation hazards. Electromagnetic computational capability exists at NASA LaRC, and many of the codes developed are based on the Moment Method (MM). However, the MM is computationally intensive, and this places a limit on the size of objects and structures that can be modeled. Here, two approaches are proposed: (i) a current-based hybrid scheme that combines the MM with Physical optics, and (ii) an Alternating Direction Implicit-Finite Difference Time Domain (ADI-FDTD) method. The essence of a hybrid technique is to split the overall scattering surface(s) into two regions: (a) a MM zone (MMZ) which can be used over any part of the given geometry, but is most essential over irregular and "non-smooth" geometries, and (b) a PO sub-region (POSR). Currents induced on the scattering and reflecting surfaces can then be computed in two ways depending on whether the region belonged to the MMZ or was part of the POSR. For the MMZ, the current calculations proceed in terms of basis functions with undetermined coefficients (as in the usual MM method), and the answer obtained by solving a system of linear equations. Over the POSR, conduction is obtained as a superposition of two contributions: (i) currents due to the incident magnetic field, and (ii) currents produced by the mutual induction from conduction within the MMZ. This effectively leads to a reduction in the size of linear equations from N to N - Npo with N being the total number of segments for the entire surface and Npo the number of segments over the POSR. The scheme would be appropriate for relatively large, flat surfaces, and at high frequencies. The ADI-FDTD scheme provides for both transient and steady state analyses. The restrictive Courant-Friedrich-Levy (CFL) condition on the time-step is removed, and so large time steps can be chosen even though the spatial grids are small. This report includes the problem definition, a detailed discussion of both the numerical techniques, and numerical implementations for simple surface geometries. Numerical solutions have been derived for a few simple situations.

Joshi, R. P.↗
NASA NTRS1994

Cross section parameterizations for cosmic-ray nuclei. II. Double nucleon removal

Parameterizations of double nucleon removal from the electromagnetic and strong interactions of cosmic rays with nuclei are presented. These parameterizations are an extension of previous single nucleon removal parameterizations and combined they represent the dominant part of the electromagnetic dissociation encountered by a cosmic ray on its traversal through matter. Such parameterizations should be very useful in studying cosmic-ray transport through the interstellar medium, the Earth's atmosphere, spacecraft walls, and extraterrestrial matter.

NASA Discipline Radiation Health↗
NASA NTRS2004

Modeling Compressibility Effects in High-Speed Turbulent Flows

Man has strived to make objects fly faster, first from subsonic to supersonic and then to hypersonic speeds. Spacecraft and high-speed missiles routinely fly at hypersonic Mach numbers, M greater than 5. In defense applications, aircraft reach hypersonic speeds at high altitude and so may civilian aircraft in the future. Hypersonic flight, while presenting opportunities, has formidable challenges that have spurred vigorous research and development, mainly by NASA and the Air Force in the USA. Although NASP, the premier hypersonic concept of the eighties and early nineties, did not lead to flight demonstration, much basic research and technology development was possible. There is renewed interest in supersonic and hypersonic flight with the HyTech program of the Air Force and the Hyper-X program at NASA being examples of current thrusts in the field. At high-subsonic to supersonic speeds, fluid compressibility becomes increasingly important in the turbulent boundary layers and shear layers associated with the flow around aerospace vehicles. Changes in thermodynamic variables: density, temperature and pressure, interact strongly with the underlying vortical, turbulent flow. The ensuing changes to the flow may be qualitative such as shocks which have no incompressible counterpart, or quantitative such as the reduction of skin friction with Mach number, large heat transfer rates due to viscous heating, and the dramatic reduction of fuel/oxidant mixing at high convective Mach number. The peculiarities of compressible turbulence, so-called compressibility effects, have been reviewed by Fernholz and Finley. Predictions of aerodynamic performance in high-speed applications require accurate computational modeling of these "compressibility effects" on turbulence. During the course of the project we have made fundamental advances in modeling the pressure-strain correlation and developed a code to evaluate alternate turbulence models in the compressible shear layer.

Sarkar, S.↗
NASA NTRS1986

The effects of bone on proton NMR relaxation times of surrounding liquids

Preliminary attempts by our group at UCSF to assess fat content of vertebral marrow in the lumbar spine using relaxation time information demonstrated that the presence of trabecular bone affects relaxation times. The objective of this work was a thorough study of the effects of bone on NMR relaxation characteristics of surrounding liquids. Trabecular bone from autopsy specimens was ground up and sifted into a series of powders with graded densities ranging from 0.3 gm/cc to 0.8 gm/cc. Each powder was placed first in n-saline and then in cottonseed oil. With spectroscopy, spin-lattice relaxation times (T1) and effective spin-spin relaxation times (T2*) were measured for each liquid in each bone powder. As bone density and surface to volume ratio increased, T1 decreased faster for saline than for oil. T2* decreased significantly for both water and oil as the surface to volume ratio increased. It was concluded that effects of water on T1 could be explained by a surface interaction at the bone/liquid interface, which restricted rotational and translational motion of nearby molecules. The T1s of oil were not affected since oil molecules are nonpolar, do not participate in significant intermolecular hydrogen bonding, and therefore would not be expected to interact strongly with the bone surface. Effects on T2* could be explained by local magnetic field inhomogeneities created by discontinuous magnetic susceptibility near the bone surface. These preliminary results suggest that water in contact with trabecular bone in vivo will exhibit shortened relaxation times.

NASA Discipline Musculoskeletal↗
NASA NTRS2004

Laboratory Infrared Spectra of Polycyclic Aromatic Nitrogen Heterocycles: Quinoline, and Phenanthridine in Solid Argon and H2O

Polycyclic aromatic hydrocarbons (PAHs) are common throughout the universe. Their detection and identification are based on telescopic infrared (IR) spectra compared with laboratory data. Polycyclic Aromatic Nitrogen Heterocycles (PANHs) are heterocyclic aromatics i.e., PAHs with carbon atoms replaced by a nitrogen atom. These molecules should be present in the interstellar medium, but have received relatively little attention. We present mid-IR spectra of two PANHs, quinoline (C9H7N), and phenanthridine (C13H9N) isolated in solid argon and frozen in solid H2O at 12 K, conditions yielding data directly comparable to astronomical observations. In contrast to simple PAHs, that do not interact strongly with solid H2O, the nitrogen atoms in PANHs are potentially capable of hydrogen bonding with H2O. Whereas the IR spectrum of phenanthridine in H2O is similar to that of the same compound isolated in an argon matrix, quinoline absorptions shift up to 16 cm(sup -1) (0.072 mm) between argon and H2O. Thus, astronomers will not always be able to rely on IR band positions of matrix isolated PANHs to correctly interpret the absorptions of PANHs frozen in H2O ice grains. Furthermore, our data suggest that relative band areas also vary, so determining column densities to better than a factor of 3 will require knowledge of the matrix in which the PANH is embedded and laboratory studies of relevant samples.

Bernstein, M. P.↗
NASA NTRS2005

Nucleobases in Space: Laboratory Studies of Polycyclic Aromatic Nitrogen Heterocycles

Polycyclic Aromatic Nitrogen Heterocycles (PANHs) are heterocyclic aromatics Le., PAHs with carbon atoms replaced by a nitrogen atom. These molecules have been detected in meteorite extracts, and in general these nitrogen heterocycles are of astrobiological interest since this class of molecules include nucleobases, basic components of our nucleic acids. These compounds are predicted to be present in the interstellar medium and in Titan tholin, but have received relatively little attention. We will present spectra and reactions of PANHs, frozen in solid H2O at 12 K, conditions germane to astronomical observations. In contrast to simple PAHs, that do not interact strongly with solid H2O, the nitrogen atoms in PANHs are potentially capable of hydrogen bonding with H20 changing their spectra, complicating their remote detection on the surfaces of icy bodies. Moreover, we have studied the photo-chemistry of these interesting compounds under astrophysical conditions and will use our lab studies to assess a potential interstellar heritage of these compounds in carbonaceous chondrites.

Elsila, Jamie↗
NASA NTRS1995

Coupled Monte Carlo Probability Density Function/ SPRAY/CFD Code Developed for Modeling Gas-Turbine Combustor Flows

The success of any solution methodology for studying gas-turbine combustor flows depends a great deal on how well it can model various complex, rate-controlling processes associated with turbulent transport, mixing, chemical kinetics, evaporation and spreading rates of the spray, convective and radiative heat transfer, and other phenomena. These phenomena often strongly interact with each other at disparate time and length scales. In particular, turbulence plays an important role in determining the rates of mass and heat transfer, chemical reactions, and evaporation in many practical combustion devices. Turbulence manifests its influence in a diffusion flame in several forms depending on how turbulence interacts with various flame scales. These forms range from the so-called wrinkled, or stretched, flamelets regime, to the distributed combustion regime. Conventional turbulence closure models have difficulty in treating highly nonlinear reaction rates. A solution procedure based on the joint composition probability density function (PDF) approach holds the promise of modeling various important combustion phenomena relevant to practical combustion devices such as extinction, blowoff limits, and emissions predictions because it can handle the nonlinear chemical reaction rates without any approximation. In this approach, mean and turbulence gas-phase velocity fields are determined from a standard turbulence model; the joint composition field of species and enthalpy are determined from the solution of a modeled PDF transport equation; and a Lagrangian-based dilute spray model is used for the liquid-phase representation with appropriate consideration of the exchanges of mass, momentum, and energy between the two phases. The PDF transport equation is solved by a Monte Carlo method, and existing state-of-the-art numerical representations are used to solve the mean gasphase velocity and turbulence fields together with the liquid-phase equations. The joint composition PDF approach was extended in our previous work to the study of compressible reacting flows. The application of this method to several supersonic diffusion flames associated with scramjet combustor flow fields provided favorable comparisons with the available experimental data. A further extension of this approach to spray flames, three-dimensional computations, and parallel computing was reported in a recent paper. The recently developed PDF/SPRAY/computational fluid dynamics (CFD) module combines the novelty of the joint composition PDF approach with the ability to run on parallel architectures. This algorithm was implemented on the NASA Lewis Research Center's Cray T3D, a massively parallel computer with an aggregate of 64 processor elements. The calculation procedure was applied to predict the flow properties of both open and confined swirl-stabilized spray flames.

Source record↗
NASA NTRS1998

EUPDF: Eulerian Monte Carlo Probability Density Function Solver for Applications With Parallel Computing, Unstructured Grids, and Sprays

The success of any solution methodology used in the study of gas-turbine combustor flows depends a great deal on how well it can model the various complex and rate controlling processes associated with the spray's turbulent transport, mixing, chemical kinetics, evaporation, and spreading rates, as well as convective and radiative heat transfer and other phenomena. The phenomena to be modeled, which are controlled by these processes, often strongly interact with each other at different times and locations. In particular, turbulence plays an important role in determining the rates of mass and heat transfer, chemical reactions, and evaporation in many practical combustion devices. The influence of turbulence in a diffusion flame manifests itself in several forms, ranging from the so-called wrinkled, or stretched, flamelets regime to the distributed combustion regime, depending upon how turbulence interacts with various flame scales. Conventional turbulence models have difficulty treating highly nonlinear reaction rates. A solution procedure based on the composition joint probability density function (PDF) approach holds the promise of modeling various important combustion phenomena relevant to practical combustion devices (such as extinction, blowoff limits, and emissions predictions) because it can account for nonlinear chemical reaction rates without making approximations. In an attempt to advance the state-of-the-art in multidimensional numerical methods, we at the NASA Lewis Research Center extended our previous work on the PDF method to unstructured grids, parallel computing, and sprays. EUPDF, which was developed by M.S. Raju of Nyma, Inc., was designed to be massively parallel and could easily be coupled with any existing gas-phase and/or spray solvers. EUPDF can use an unstructured mesh with mixed triangular, quadrilateral, and/or tetrahedral elements. The application of the PDF method showed favorable results when applied to several supersonic-diffusion flames and spray flames. The EUPDF source code will be available with the National Combustion Code (NCC) as a complete package.

Raju, M. S.↗
NASA NTRS2003

Creep Resistance of ZrO2 Ceramic Improved by the Addition of a Small Amount of Er2O3

Zirconia (ZrO2) has great technological importance in structural, electrical, and chemical applications. It is the crucial component for state-of-the art thermal barrier coatings and an enabling component as a solid electrolyte for solid-oxide fuel cell systems. Pure ZrO2 is of limited use for industrial applications because of the phase transformations that occur. Upon the addition of stabilizers, cubic (c-ZrO2) and tetragonal (t-ZrO2) forms can be preserved. It is the stabilized and partially stabilized forms of zirconia that function as thermal barrier coatings, solid electrolytes, and oxygen sensors and that have numerous applications in the electrochemical industry. The cubic form of ZrO2 is typically stabilized through Y2O3 additions. However, Y2O3-stabilized zirconia is susceptible to deformation at high temperatures (greater than 900 C) because of the large number of slip systems and the high oxygen diffusion rates, which result in high creep rates at high temperatures. Successful use of ZrO2 at high temperatures requires that new dopant additives be found that will retain or enhance the desirable properties of cubic ZrO2 and yet produce a material with lower creep rates. At the NASA Glenn Research Center, erbium oxide (Er2O3) was identified as a promising dopant for improving the creep resistance of. ZrO2. The selection of Er2O3 was based on the strong interactions of point defects and dislocations. Single crystals of 5 mol% Er2O3- doped ZrO2 rods (4 mm in diameter) and monofilaments (200 to 300 mm in diameter and 30 cm long) were grown using the laser-heated float zone technique, and their creep behavior was measured as a function of temperature. The addition of 5 mol% Er2O3 to single-crystal ZrO2 improved its creep resistance at high temperatures by 2 to 3 orders of magnitude over state-of-the-art Y2O3-doped crystals. Detailed microstructural characterization of ZrO2-Er2O3 single crystals has identified new mechanisms for improving the creep resistance of this class of materials. Adding Er2O3 to ZrO2 results in microstructure of stable and metastable tetragonal precipitates that with thermal treatment evolve to a tweed structure of nanosize tetragonal lamellae. The superior high-temperature creep resistance of Er2O3-doped ZrO2 is attributed to nanoscale precipitation hardening. Doping with Er2O3 will significantly increase the upper-use temperature limit of ZrO2. Potential applications include using Er2O3-doped ZrO2 as a high-temperature fiber for structural applications and adding Er2O3 to reduce the sintering rates of ZrO2 thermal barrier coatings. This work was conducted at Dpto. de F sica de la Materia Condensada, Universidad de Sevilla, Spain, and at NASA Glenn.

Martinez-Fernandez, Julian↗
NASA NTRS2004

Hydrodynamics in a Degenerate, Strongly Attractive Fermi Gas

In summary, we use all-optical methods with evaporative cooling near a Feshbach resonance to produce a strongly interacting degenerate Fermi gas. We observe hydrodynamic behavior in the expansion dynamics. At low temperatures, collisions may not explain the expansion dynamics. We observe hydrodynamics in the trapped gas. Our observations include collisionally-damped excitation spectra at high temperature which were not discussed above. In addition, we observe weakly damped breathing modes at low temperature. The observed temperature dependence of the damping time and hydrodynamic frequency are not consistent with collisional dynamics nor with collisionless mean field interactions. These observations constitute the first evidence for superfluid hydrodynamics in a Fermi gas.

Thomas, John E.↗
NASA NTRS2004

Accurate Calculation of Oscillator Strengths for CI II Lines Using Non-orthogonal Wavefunctions

Non-orthogonal orbitals technique in the multiconfiguration Hartree-Fock approach is used to calculate oscillator strengths and transition probabilities for allowed and intercombination lines in Cl II. The relativistic corrections are included through the Breit-Pauli Hamiltonian. The Cl II wave functions show strong term dependence. The non-orthogonal orbitals are used to describe the term dependence of radial functions. Large sets of spectroscopic and correlation functions are chosen to describe adequately strong interactions in the 3s(sup 2)3p(sup 3)nl (sup 3)Po, (sup 1)Po and (sup 3)Do Rydberg series and to properly account for the important correlation and relaxation effects. The length and velocity forms of oscillator strength show good agreement for most transitions. The calculated radiative lifetime for the 3s3p(sup 5) (sup 3)Po state is in good agreement with experiment.

Tayal, S. S.↗
NASA NTRS2010

LES/RANS Simulation of a Supersonic Reacting Wall Jet

This work presents results from large-eddy / Reynolds-averaged Navier-Stokes (LES/RANS) simulations of the well-known Burrows-Kurkov supersonic reacting wall-jet experiment. Generally good agreement with experimental mole fraction, stagnation temperature, and Pitot pressure profiles is obtained for non-reactive mixing of the hydrogen jet with a non-vitiated air stream. A lifted flame, stabilized between 10 and 22 cm downstream of the hydrogen jet, is formed for hydrogen injected into a vitiated air stream. Flame stabilization occurs closer to the hydrogen injection location when a three-dimensional combustor geometry (with boundary layer development resolved on all walls) is considered. Volumetric expansion of the reactive shear layer is accompanied by the formation of large eddies which interact strongly with the reaction zone. Time averaged predictions of the reaction zone structure show an under-prediction of the peak water concentration and stagnation temperature, relative to experimental data and to results from a Reynolds-averaged Navier-Stokes calculation. If the experimental data can be considered as being accurate, this result indicates that the present LES/RANS method does not correctly capture the cascade of turbulence scales that should be resolvable on the present mesh. Instead, energy is concentrated in the very largest scales, which provide an over-mixing effect that excessively cools and strains the flame. Predictions improve with the use of a low-dissipation version of the baseline piecewise parabolic advection scheme, which captures the formation of smaller-scale structures superimposed on larger structures of the order of the shear-layer width.

Edwards, Jack R.↗
NASA NTRS2010

Reduction of Unsteady Forcing in a Vaned, Contra-Rotating Transonic Turbine Configuration

HPT blade unsteadiness in the presence of a downstream vane consistent with contra-rotation is characterized by strong interaction at the first harmonic of downstream vane passing. E An existing stage-and-one-half transonic turbine rig design was used as a baseline to investigate means of reducing such a blade-vane interaction. E Methods assessed included: Aerodynamic shaping of HPT blades 3D stacking of the downstream vane Steady pressure-side blowing E Of the methods assessed, a combination of vane bowing and steady pressure-side blowing produced the most favorable result. E Transonic turbine experiments are planned to assess predictive accuracy for the baseline turbine and any design improvements.

Clark, John↗
NASA NTRS2010

Gravitational-Wave Astronomy

Einstein's General Theory of Relativity is our best classical description of gravity, and informs modern astronomy and astrophysics at all scales: stellar, galactic, and cosmological. Among its surprising predictions is the existence of gravitational waves -- ripples in space-time that carry energy and momentum away from strongly interacting gravitating sources. In my talk, I will give an overview of the properties of this radiation, recent breakthroughs in computational physics allowing us to calculate the waveforms from galactic mergers, and the prospect of direct observation with interferometric detectors such as LIGO and LISA.

Kelly, Bernard J.↗
NASA NTRS2011

Fluids and their Effect on Measurements on Lunar Soil Particle size Distribution

From the late 1960s until now, lunar soil particle size distributions have typically been determined by sieving sometimes dry, and at other times with fluids such as water or Freon. Laser diffraction instruments allow rapid assessment of particle size distribution, and eventually may replace sieve measurements. However, when measuring lunar soils with laser diffraction instruments, care must be taken in choosing a carrier fluid that is compatible with lunar material. Distilled water is the fluid of choice for laser diffraction measurements of substances when there is no concern about adverse effects of water on the material being measured. When we began our analyses of lunar soils using laser diffraction, our first measurements were made with distilled water. Although the medians that we measured were comparable to earlier sieve data, the means tended to be significantly larger than expected. The effect of water vapor on lunar soil has been studied extensively. The particles interact strongly with water vapor, and subsequent adsorptions of nitrogen showed that the specific surface area increased as much as threefold after exposure to moisture. It was observed that significant porosity had been generated by this exposure to water vapor. The possibility of other physical changes in the surfaces of the grains was not studied.

Cooper, B. L.↗
NASA NTRS2011

Large-Amplitude Transmitter-Associated and Lightning-Associated Whistler Waves in the Earth's Inner Plasmasphere at L less than 2

We report observations of very large amplitude whistler mode waves in the Earth fs nightside inner radiation belt enabled by the STEREO Time Domain Sampler. Amplitudes range from 30.110 mV/m (zero ]peak), 2 to 3 orders of magnitude larger than previously observed in this region. Measurements from the peak electric field detector (TDSMax) indicate that these large ]amplitude waves are prevalent throughout the plasmasphere. A detailed examination of high time resolution electric field waveforms is undertaken on a subset of these whistlers at L < 2, associated with pump waves from lightning flashes and the naval transmitter NPM in Hawaii, that become unstable after propagation through the ionosphere and grow to large amplitudes. Many of the waveforms undergo periodic polarization reversals near the lower hybrid and NPM naval transmitter frequencies. The reversals may be related to finite plasma temperature and gradients in density induced by ion cyclotron heating of the plasma at 200 Hz, the modulation frequency of the continuous ]mode NPM naval transmitter signal. Test particle simulations using the amplitudes and durations of the waves observed herein suggest that they can interact strongly with high ]energy (>100 keV) electrons on a time scale of <1 s and thus may be an important previously unaccounted for source of energization or pitch ]angle scattering in the inner radiation belt.

Breneman, A.↗
NASA NTRS2010

Ultraviolet+Infrared Star Formation Rates: Hickson Compact Groups with Swift and SPitzer

We present Swift UVOT ultraviolet (UV; 1600-3000 A) data with complete three-band UV photometry for a sample of 41 galaxies in 11 nearby (<4500 km/s) Hickson Compact Groups (HCGs) of galaxies. We use UVOT uvw2-band (2000A) photometry to estimate the dust-unobscured component, SFR(sub uv), of the total star formation rate, SFR(sub TOTAL). We use Spitzer MIPS 24 micron photometry to estimate SFR(sub IR), the component of SFR(sub TOTAL) that suffers dust extinction in the UV and is re-emitted in the IR. By combining the two components, we obtain SFR(sub TOTAL) estimates for all HCG galaxies. We obtain total stellar mass, M(sub *) estimates by means of Two Micron All Sky Survey K(sub s)-band luminosities, and use them to calculate specific star formation rates, SSFR is identical with SFR(sub TOTAL)/ M (sub *). SSFR values show a clear and significant bimodality, with a gap between low (approximately <3.2 x 10(exp -11) / yr) and high-SSFR (approximately > 1.2 x lO)exp -10)/yr) systems. We compare this bimodality to the previously discovered bimodality in alpha-IRAC, the MIR activity index from a power-law fit to the Spitzer IRAC 4.5-8 micron data for these galaxies. We find that all galaxies with alpha-IRAC <= 0 (> 0) are in the high- (low-) SSFR locus, as expected if high levels of star-forming activity power MIR emission from polycyclic aromatic hydrocarbon molecules and a hot dust continuum. Consistent with this finding, all elliptical/SO galaxies are in the low-SSFR locus, while 22 out of 24 spirals / irregulars are in the high-SSFR locus, with two borderline cases. We further divide our sample into three subsamples (I, II, and III) according to decreasing H I richness of the parent galaxy group to which a galaxy belongs. Consistent with the SSFR and alpha-IRAC bimodality, 12 out of 15 type I (11 out of 12 type III) galaxies are in the high- (low-) SSFR locus, while type II galaxies span almost the full range of SSFR values. We use the Spitzer Infrared Nearby Galaxy Survey (SINGS) to construct a comparison subsample of galaxies that (1) match HCG galaxies in J-band total galaxy luminosity and (2) are not strongly interacting and largely isolated. This selection eliminates mostly low-luminosity dwarfs and galaxies with some degree of peculiarity, providing a substantially improved, quiescent control sample. Unlike HCG galaxies, galaxies in the comparison SINGS subsample are continuously distributed both in SSFR and alpha-IRAC, although they show ranges in SFR(sub TOTAL) values, morphologies and stellar masses similar to those for HCG systems. We test the SSFR bimodality against a number of uncertainties, and find that these can only lead to its further enhancement. Excluding galaxies belonging to HCGs with three giant galaxies (triplets) leaves both the SSFR and the alpha-IRAC bimodality completely unaffected. We interpret these results as further evidence that an environment characterized by high galaxy number densities and low galaxy velocity dispersions, such as the one found in compact groups, plays a key role in accelerating galaxy evolution by enhancing star formation processes in galaxies and favoring a fast transition to quiescence.

Tzanavaris, P.↗
NASA NTRS2012

In Situ Carbon and Sulfur Isotope Analysis of Archean Organic Matter and Pyrite

Stable isotopic compositions of biologically important elements (e.g., C and S) in sedimentary rocks are valuable biosignatures to the extent that they indicate the presence and variable expression of microbial metabolisms in space and time. Strong interactions between the carbon and sulfur cycles (e.g., via organic matter remineralization during microbial sulfate reduction) make coordinated, in situ C and S isotope analysis by secondary ion mass spectrometry (SIMS) a particularly powerful tool. In rocks ranging in age from 2.7-2.5 Ga, expansions in the ranges of delta C-13 of organic matter and delta S-34 of pyrite likely reflect the increasing influence of oxygenic photosynthesis in the surface ocean (as well as methane and sulfur metabolisms in deeper waters), whereas the large range of mass independent sulfur isotope fractionation (Delta S-33) suggests that the atmosphere remained anoxic until approx 2.4 Gyr ago. We report in situ delta C-13 measurements of organic matter in the approx 2.7-2.6 Ga Carawine Dolomite, Marra Mamba Iron Formation, and Jeerinah, Wittenoom, and Tumbiana Formations, as well as the approx 2.5 Ga Mount McRae Shale. We also report in situ delta S-24 and Delta S-33 measurements of pyrite associated with organic matter in a subset of these samples. In a single square cm sample of the Tumbiana Formation with bulk delta C-13(sub org) of -49.7% (VPDB), two distinct kerogen types have delta C-13 values, measured in situ, consistent with oxygenic photosynthesis (-33%) and methane metabolism (-52%). In a sample from the ABDP-9 core, radiobitumen associated with a uraniferous mineral grain is C-13-enriched by 8% (-26.8%0) relative to average in situ kerogen (-34.9%0) and similar in delta C-13 to solvent extractable hydrocarbons from the Mount McRae Shale (avg delta C-13 = -27.1 %). Average reproducibility for delta C-13 was 0.4% (2 SD) using a 6 micron spot and 0.8% using a 3 micron spot. In situ sulfur isotope analyses of 33 authigenic pyrite grains in 3 samples of the ABDP-9 core using a 10 micron spot (2 SD reproducibility = 0.4% for delta S-34 and -0.1% for Delta S-33) show a range of 28.1 % in delta S-34 (-10.3 to 17.8%) and 13.3%0 in Delta S-33 (-3.8 to 9.5%), whereas the range from 132 bulk analyses across 84 m of core is 19.4% for delta S-34 and 11.5% for Delta S-33. Coordinated, in situ carbon and sulfur isotope analyses in one ABDP-9 sample are shown. In situ values from this kerogen-pyrite association are within 0.1% of the bulk value in the case of delta C-13 and higher by several permil in the case of delta S-34 and Delta S-33. Coordinated in situ carbon and sulfur isotope analyses in rocks deposited during key intervals of environmental change (e.g., the Great Oxidation Event) can refine our understanding of the mode and tempo of change. In Earth's oldest sedimentary rocks, and in extraterrestrial samples, these coordinated in situ analyses may reveal biosignatures in the form of isotopic correlations at the scale of individual microorganisms and their microhabitats.

Williford, K. H.↗