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At least 1,549 records · Page 86

Engineering-Scale Test of a Water-Lean Solvent for Post-Combustion Capture

EPRI, Pacific Northwest National Laboratory, RTI International, and their project collaborators developed an engineering-scale test of a new water-lean solvent, N-(2-ethoxyethyl)-3-morpholinopropan-1-amine (EEMPA or 2-EEMPA) as a post-combustion CO 2 capture solvent for power plant applications. This test was conducted using the Pilot Solvent Test Unit at the National Carbon Capture Center. The primary objective of this test was to collect long-term data operating EEMPA with both coal- and natural gas-representative flue gases at the approximately 0.5 MW e -equivalent scale (5–10 metric tons CO 2 /day captured). This report details the activities preparing for that test, data collected during the test campaign, and analyses and interpretations of that data.

20 FOSSIL-FUELED POWER PLANTS↗

Technoeconomic Assessment of Phosphoric Acid and Rare Earth Element Recovery from Phosphoric Acid Sludge

Sustainability faces many challenges, including the availability of materials necessary for technological advancement. Rare earth elements (REEs), for example, are key materials for several manufacturing industries that can unlock renewable energy and sustainable development. In this study, a decanter centrifuge has been employed to successfully separated phosphoric acid and REE-containing particles from phosphoric acid sludge with concentrations ranging from 1000 to 2200 ppm REEs. Operating efficiently with up to 35 wt.% solids, the centrifuge was demonstrated to achieve approximately 95% phosphoric acid recovery and 90% REE recovery in a single pass, eliminating the need for additional processing steps. This breakthrough supports a proposed rare earth oxide (REO) recovery process integrating phosphoric acid (PA), elemental phosphorus (P4), and REO into two potential pathways: PA-REO and PA-P4-REO. These processes aim to reintroduce recovered phosphoric acid into the main product to significantly increase output and revenue. Post-separation, phosphorus-rich particles can be converted to P4, while REE-containing solids undergo further treatment including acid leaching, extraction/stripping, precipitation, and calcination to produce a marketable REO material. Technoeconomic analysis indicates promising profitability, with the PA-REO process showing a delta net present value (ΔNPV) of USD 441.8 million over a 12-year period and expected return within a year of construction, while the PA-P4-REO process yields a ΔNPV of USD 178.7 million over a 12-year return period. Both pathways offer robust financial prospects and demonstrate the feasibility of commercial-scale REO recovery from phosphoric acid sludge, offering an economically feasible approach to produce REEs for future sustainable development challenges related to sustainability.

36 MATERIALS SCIENCE↗

Apollo 13 Mission Report

The Apollo 13 mission, planned as a lunar landing in the Fra Mauro area, was aborted because of an abrupt loss of service module cryogenic oxygen associated with a fire in one of the two tanks at approximately 56 hours. The lunar module provided the necessary support to sustain a minimum operational condition for a safe return to earth. A circumlunar profile was executed as the most efficient means of earth return, with the lunar module providing power and life support until transfer to the command module just prior to entry. Although the mission was unsuccessful as planned, a lunar flyby and several scientific experiments were completed.

Source record↗

Space shuttle three main engine return to launch site abort

A Return-to-Launch-Site (RTLS) abort with three Space Shuttle Main Engines (SSME) operational was examined. The results are trajectories and main engine cutoff conditions that are approximately the same as for a two SSME case. Requiring the three SSME solution to match the two SSME abort eliminates additional crew training and is accomplished with negligible software impact.

Carter, J. F.↗

Test particle propagation in magnetostatic turbulence. 2: The local approximation method

An approximation method for statistical mechanics is presented and applied to a class of problems which contains a test particle propagation problem. All of the available basic equations used in statistical mechanics are cast in the form of a single equation which is integrodifferential in time and which is then used as the starting point for the construction of the local approximation method. Simplification of the integrodifferential equation is achieved through approximation to the Laplace transform of its kernel. The approximation is valid near the origin in the Laplace space and is based on the assumption of small Laplace variable. No other small parameter is necessary for the construction of this approximation method. The n'th level of approximation is constructed formally, and the first five levels of approximation are calculated explicitly. It is shown that each level of approximation is governed by an inhomogeneous partial differential equation in time with time independent operator coefficients. The order in time of these partial differential equations is found to increase as n does. At n = 0 the most local first order partial differential equation which governs the Markovian limit is regained.

Klimas, A. J.↗

Navigation simulator for the Space Tug vehicle

A general simulation program (GSP) for state estimation of a nonlinear space vehicle flight navigation system is developed and used as a basis for evaluating the performance of a Space Tug navigation system. An explanation of the iterative guidance mode (IGM) guidance law, derivation of the dynamics, coordinate frames and state estimation routines are given in order to clarify the assumptions and approximations made. A number of simulation and analytical studies are used to demonstrate the operation of the Tug system. Included in the simulation studies are (1) initial offset vector parameter study; (2) propagation time vs accuracy; (3) measurement noise parametric study and (4) reduction in computational burden of an on-board implementable scheme. From the results of these studies, conclusions and recommendations concerning future areas of practical and theoretical work are presented.

Colburn, B. K.↗

Observed variability of aircraft noise footprint measurements

A description is presented of some measurements which illustrate the variability of the experimentally developed ground noise footprints for a series of landing approach operations of a turbojet aircraft and a turbine powered helicopter. Measurements on the recently developed NASA Remotely Operated Multiple Array Acoustic Range are considered. The information presented is related to a turbojet fighter aircraft and a turbine powered helicopter performing landing approach operations along a 3 deg approach path. Each vehicle was acquired on radar tracking approximately 10 kilometers from the touchdown point and entered the test area at an altitude of about 470 m. The measured variations in meteorological quantities for the two time periods during which these tests were conducted are presented in graphs. Other graphs show the ground noise contour for the turbojet aircraft and the turbine helicopter.

Maglieri, D. J.↗

Effects of supply conditions on film thickness in lubricated Hertzian contacts

A generalization of the hydrodynamic expression for Hertzian contacts is described and various methods for calculating the thickness of the oil film winter steady-state, isothermal conditions are given. This is important for engineering applications such as gears and bearings because these results are closer to real operating conditions. Theories of lubrication are discussed, and the mathematics involved are presented using approximately 30 equations and 13 figures. For lubricated, linear, elliptical or point Hertzian contacts it is demonstrated how to calculate the thickness of the oil film at the center of the contact for steady-state isothermal conditions.

Dalmaz, G.↗

DIAL with heterodyne detection including speckle noise: Aircraft/shuttle measurements of O3, H2O, and NH3 with pulsed tunable CO2lasers

A parametric analysis of DIAL sensitivity with heterodyne detection is presented and comparisons with direct detection are discussed. Examples are given for monitoring vertical distributions of O3, H2O, and NH3 using a ground-, aircraft-, or shuttle-based pulsed tunable CO2 laser DIAL system. Results indicate that maximum sensitivity at minimum laser energy per measurement requires multiple pulse operation with the energy per pulse selected so that the measured photon rate is approximately equal to the detector IF bandwidth. Measurement sensitivities can be maximized and interference effects minimized by fine adjustment of measurement frequencies using the tunability of high pressure lasers. The use of rare isotope lasers minimizes loss due to CO2 atmospheric absorption.

Brockman, P.↗

High speed computerized data acquisition of photovoltaic V-I characteristics

The voltage current (V-I) characteristics of the photovoltaic array were studied under actual environmental conditions. A method of data acquisition was devised that uses a capacitor charge technique to obtain the V-I characteristic and a computerized data system to display, record and process the data. The capacitor charge technique uses an array shorting transistor and a capacitor bank to sweep the array operating voltage and current from short circuit to open circuit in a specified time (approximately 125 ms). The computerized data system is synchronized with this transition and repetitively samples the array voltage and current during the transition and records the ambient conditions. This data is then normalized by the computer to standard conditions (100 mW/sq cm, 28 C) and is available in tabular and graphic form for both the voltage current and voltage power characteristics. The capacitor charge technique is described.

Delombard, R.↗

A digital imaging photometry system for cometary data acquisition

This report describes a digital imaging photometry system developed in the Space Science Laboratory at the Marshall Space Flight center. The photometric system used for cometary data acquisition is based on an intensified secondary electron conduction (ISEC) vidicon coupled to a versatile data acquisition system which allows real-time interactive operation. Field tests on the Orion and Rosette nebulas indicate a limiting magnitude of approximately m sub v = 14 over the 40 arcmin field-of-view. Observations were conducted of Comet Giacobini-Zinner in August 1985. The resulting data are discussed in relation to the capabilities of the digital analysis system. The development program concluded on August 31, 1985.

Clifton, K. S.↗

Galerkin approximation for inverse problems for nonautonomous nonlinear distributed systems

An abstract framework and convergence theory is developed for Galerkin approximation for inverse problems involving the identification of nonautonomous nonlinear distributed parameter systems. A set of relatively easily verified conditions is provided which are sufficient to guarantee the existence of optimal solutions and their approximation by a sequence of solutions to a sequence of approximating finite dimensional identification problems. The approach is based on the theory of monotone operators in Banach spaces and is applicable to a reasonably broad class of nonlinear distributed systems. Operator theoretic and variational techniques are used to establish a fundamental convergence result. An example involving evolution systems with dynamics described by nonstationary quasilinear elliptic operators along with some applications are presented and discussed.

Banks, H. T.↗

Electrodeposition and codeposition under low gravity/nonconvecting conditions

An experimental electrodeposition system was developed for modeling the behavior of inert particles codepositing in an electroplating matrix under low-gravity conditions. The device consists of a Co-electrodeposition cell operating in a convectionless mode (cathode over anode) and containing polystyrene particles with density approximating that of the electroplating solution. Data were obtained in shielded cells at 1 g, and the experiment was duplicated at 0.01 g on a KC-135 flight. No difference was found between convection-free bench experiments and the 0.01 g KC-135 experiments with 0.0900 M CuSO4. Codeposition experiments using 11.8-micron matched-density polystyrene spheres in 1 M CoSO4 have revealed that a noticeable particle gradient is created as the solution density mismatches in the vicinity of the cathode; gentle stirring was required to maintain a homogeneous particle suspension. Cr3C2 dust, which readily disperses at 1 g, tended to coagulate into spherical globules at 0.01 g, when stirred.

Riley, Clyde↗

Observational results of microwave temperature profile measurements from the airborne Antarctic ozone experiment

The Microwave Temperature Profiler, MTP, is installed on NASA's ER-2 aircraft. MTP measures profiles of air temperature versus altitude. Temperatures are obtained every 13.7 seconds for 15 altitudes in an altitude region that is approximately 5 km thick (at high flight levels). MTP is a passive microwave radiometer, operating at the frequencies 57.3 and 58.8 GHz. Thermal emission from oxygen molecules provides the signal that is converted to air temperature. MTP is unique in that it is the only airborne instrument of its kind. The MTP instrument was used during the Airborne Antarctic Ozone Experiment, AAOE, to enable potential vorticity to be measured along the flight track. Other uses for the MTP data have become apparent. The most intriguing unexpected use is the detection and characterization of mountain waves that were encountered during flights over the Palmer Peninsula. Mountain waves that propagate into the polar vortex may have implications for the formation of the ozone hole. Upward excursions of air parcels lead to a brief cooling. This can begin the process of cloud formation. It is important to determine how much additional formation of polar stratospheric cloud (PSC) material is possible by the passage of air parcels through a mountain wave pattern that endures for long periods. Other mountain wave effects have been suggested, such as a speeding up of the vortex, and a consequent cooling of large air volumes (which in turn might add to PSC production).

Gary, Bruce L.↗

Microanalysis of extended-test xenon hollow cathodes

Four hollow cathode electron sources were analyzed via boroscopy, scanning electron microscopy, energy dispersive x ray analysis, and x ray diffraction analysis. These techniques were used to develop a preliminary understanding of the chemistry of the devices that arise from contamination due to inadequate feed-system integrity and improper insert activation. Two hollow cathodes were operated in an ion thruster simulator at an emission current of 23.0 A for approximately 500 hrs. The two tests differed in propellant-feed systems, discharge power supplies, and activation procedures. Tungsten deposition and barium tungstate formation on the internal cathode surfaces occurred during the first test, which were believed to result from oxygen contamination of the propellant feed-system. Consequently, the test facility was upgraded to reduce contamination, and the test was repeated. The second hollow cathode was found to have experienced significantly less tungsten deposition. A second pair of cathodes examined were the discharge and the neutralizer hollow cathodes used in a life-test of a 30-cm ring-cusp ion thruster at a 5.5 kW power level. The cathodes' test history was documented and the post-test microanalyses are described. The most significant change resulting from the life-test was substantial tungsten deposition on the internal cathode surfaces, as well as removal of material from the insert surface. In addition, barium tungstate and molybdate were found on insert surfaces. As a result of the cathode examinations, procedures and approaches were proposed for improved discharge ignition and cathode longevity.

Verhey, Timothy R.↗

The design and evolution of the beta two-stage-to-orbit horizontal takeoff and landing launch system

The Beta launch system was originally conceived in 1986 as a horizontal takeoff and landing, fully reusable, two-stage-to-orbit, manned launch vehicle to replace the Shuttle. It was to be capable of delivering a 50,000 lb. payload to low polar orbit. The booster propulsion system consisted of JP fueled turbojets and LH fueled ramjets mounted in pods in an over/under arrangement, and a single LOX/LH fueled SSME rocket. The second stage orbiter, which staged at Mach 8, was powered by an SSME rocket. A major goal was to develop a vehicle design consistent with near term technology. The vehicle design was completed with a GLOW of approximately 2,000,000 lbs. All design goals were met. Since then, interest has shifted to the 10,000 lbs. to low polar orbit payload class. The original Beta was down-sized to meet this payload class. The GLOW of the down-sized vehicle was approximately 1,000,000 lbs. The booster was converted to exclusively air-breathing operation. Because the booster depends on conventional air-breathing propulsion only, the staging Mach number was reduced to 5.5. The orbiter remains an SSME rocket-powered stage.

Burkardt, Leo A.↗

Flight validation of a pulsed smoke flow visualization system

A flow visualization scheme, designed to measure vortex fluid dynamics on research aircraft, was validated in flight. Strake vortex trajectories and axial core velocities were determined using pulsed smoke, high-speed video images, and semiautomated image edge detection hardware and software. Smoke was pulsed by using a fast-acting three-way valve. After being redesigned because of repeatedly jamming in flight, the valve shuttle operated flawlessly during the last two tests. A 25-percent scale, Gothic strake was used to generate vortex over the wing of a GA-7 Cougar and was operated at a local angle of attack of 22 degrees and Reynolds number of approximately 7.8 x 10(exp 5)/ft. Maximum axial velocities measured in the vortex core were between 1.75 and 1.95 times the freestream velocity. Analysis of the pulsed smoke system's affect on forebody vortices indicates that the system may reorient the forebody vortex system; however, blowing momentum coefficients normally used will have no appreciable affect on the leading-edge extension vortex system. It is recommended that a similar pulsed smoke system be installed on the F/A-18 High Angle Research Vehicle and that this approach be used to analyze vortex core dynamics during the remainder of its high-angle-of-attack research flights.

Ward, Donald T.↗