Kondo lattice and antiferromagnetic behavior in quaternary CeTAl 4 Si 2 (T = Rh, Ir) single crystals
Here, we have explored in detail the anisotropic magnetic properties of CeRhAl 4 Si 2 and CeIrAl 4 Si 2 , which undergo two antiferromagnetic transitions, at T N1 = 12.6 and 15.5 K, followed by a second transition at T N2 = 9.4 and 13.8 K, respectively, with the [001]-axis as the relatively easy axis of magnetization. The electrical resistivity at ambient and applied pressure provides evidence of Kondo interaction in both compounds, further supported by a reduced value of the entropy associated with the magnetic ordering. The Sommerfeld coefficient γ is inferred to be 195.6 and 49.4 mJ/(mol K 2 ) for CeRhAl 4 Si 2 and CeIrAl 4 Si 2 , respectively, classifying these materials as moderate heavy-fermion compounds. The crystal electric field energy levels are derived from the peak seen in the Schottky heat capacity. Furthermore, we have also performed electronic structure calculations by using the local spin density approximation + U [LSDA+U] approach, which provide physical insights on the observed magnetic behavior of these two compounds.