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At least 1,549 records · Page 86
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Revealing Mesoscale Ionomer Membrane Structure by Tender Resonant X-ray Scattering

Nafion, a perfluorosulfonic acid ionomer, has been well-studied for decades due to its key role as an ion-conductive membrane in electrochemical energy conversion and storage applications. When hydrated, this membrane phase separates into a complex hierarchical nanostructure with hydrophilic domains that facilitate ion transport. Hard X-ray scattering has been a powerful technique in understanding Nafion due to its capabilities in capturing the ionomer’s nanophase separated structure, which gives rise to contrast between polymer and water domains. More recently, resonant X-ray scattering, which tunes to elemental absorption edges to provide specificity on constituent elements, has been explored to highlight key interactions related to the sulfonic acid groups within its structure. Here, in this work, we study the Nafion nanostructure by combining hard X-ray scattering and tender resonant X-ray scattering (TReXS) at the sulfur K-edge to reveal a mesoscopic feature corresponding to a correlation length of approximately 40 nm that has been challenging to resolve with hard X-ray studies. Additionally, we study the effect of the dispersion solvent composition that plays a key role in the formation of this mesoscale feature. Notably, TReXS can attain high contrast to decipher this mesoscale morphology even for dry polymer membranes under a vacuum, which typically have reduced contrast for hard X-rays. We find that the correlation length of this mesoscale feature decreases with increasing water fraction in the dispersion, which is the opposite trend exhibited by the smaller intercrystalline feature in the same membranes. This study showcases the utility of TReXS to uncover multiscale morphological details in functional polymers that are not always revealed by other methods like hard X-ray scattering. We illustrate this with Nafion, which is a relevant ion-conducting polymer for electrochemical technologies.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Colloidal Clusters and Networks Formed by Oppositely Charged Nanoparticles with Varying Stiffnesses

Colloidal clusters and gels are ubiquitous in science and technology. Particle softness has a strong effect on interparticle interactions; however, our understanding of the role of this factor in the formation of colloidal clusters and gels is only beginning to evolve. Here, we report the results of experimental and simulation studies of the impact of particle softness on the assembly of clusters and networks from mixtures of oppositely charged polymer nanoparticles (NPs). Experiments were performed below or above the polymer glass transition temperature, at which the interaction potential and adhesive forces between the NPs were significantly varied. Hard NPs assembled in fractal clusters that subsequently organized in a kinetically arrested colloidal gel, while soft NPs formed dense precipitating aggregates, due to the NP deformation and the decreased interparticle distance. Importantly, interactions of hard and soft NPs led to the formation of discrete precipitating NP aggregates at a relatively low volume fraction of soft NPs. A phenomenological model was developed for interactions of oppositely charged NPs with varying softnesses. Furthermore, the experimental results were in agreement with molecular dynamics simulations based on the model. This work provides insight on interparticle interactions before, during, and after the formation of hard–hard, hard–soft, and soft–soft contacts and has impact for numerous applications of reversible colloidal gels, including their use as inks for additive manufacturing.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Energy loss of a heavy fermion in a collisional QED plasma

We compute the energy loss of heavy fermions moving in a plasma, taking into account the modification of the photon collective modes induced by collisions using a Bhatnagar-Gross–Krook collisional kernel. We include contributions from both hard and soft scatterings of the heavy fermion using a collisionally modified hard-thermal-loop resummed propagator. Using this method, one does not need to introduce a separation scale between hard- and soft-momentum exchanges. To place our calculation in context, we review other theoretical approaches to computing the collisional energy loss of fermions and discuss the systematics and results obtained in each approach compared to using a resummed propagator for both hard and soft momentum exchanges. Our final results indicate that self-consistently including the effect of collisions in the self-energies of the resummed propagator results in an increased energy loss compared to using collisionless hard-thermal-loop propagators. The effect becomes larger as the magnitude of the coupling constant and the velocity of the fermion increase. Published by the American Physical Society 2024

Astronomy & Astrophysics↗
DOE OSTI2025

Sign Problem in Tensor-Network Contraction

We investigate how the computational difficulty of contracting tensor networks depends on the sign structure of the tensor entries. Using results from computational complexity, we observe that the approximate contraction of tensor networks with only positive entries has lower computational complexity as compared to tensor networks with general real or complex entries. This raises the question of how this transition in computational complexity manifests itself in the hardness of different tensor-network-contraction schemes. We pursue this question by studying random tensor networks with varying bias toward positive entries. First, we consider contraction via Monte Carlo sampling and find that the transition from hard to easy occurs when the tensor entries become predominantly positive; this can be understood as a tensor-network manifestation of the well-known negative-sign problem in quantum Monte Carlo. Second, we analyze the commonly used contraction based on boundary tensor networks. The performance of this scheme is governed by the number of correlations in contiguous parts of the tensor network (which by analogy can be thought of as entanglement). Remarkably, we find that the transition from hard to easy—i.e., from a volume-law to a boundary-law scaling of entanglement—already occurs for a slight bias of the tensor entries toward a positive mean, scaling inversely with the bond dimension D , and thus the problem becomes easy the earlier the larger D occurs. This is in contrast both to expectations and to the behavior found in Monte Carlo contraction, where the hardness at fixed bias increases with the bond dimension. To provide insight into this early breakdown of computational hardness and the accompanying entanglement transition, we construct an effective classical statistical-mechanical model that predicts a transition at a bias of the tensor entries of 1 / D , confirming our observations. We conclude by investigating the computational difficulty of computing expectation values of tensor-network wave functions (projected entangled-pair states, PEPSs) and find that in this setting, the complexity of entanglement-based contraction always remains low. We explain this by providing a local transformation that maps PEPS expectation values to a positive-valued tensor network. This not only provides insight into the origin of the observed boundary-law entanglement scaling but also suggests new approaches toward PEPS contraction based on positive decompositions. Published by the American Physical Society 2025

Chen, Jielun (ORCID:0000000178411545)↗
DOE OSTI2023

Probing gluon saturation via diffractive jets in ultra-peripheral nucleus-nucleus collisions

Abstract We argue that semi-inclusive photo-production of a pair of hard jets via coherent diffraction in nucleus-nucleus ultra-peripheral collisions at high energy is a golden channel to study gluon saturation. The dominant contribution is the diffractive production of three jets in an asymmetric configuration. Two of the jets are hard and propagate at nearly central pseudo-rapidities. The third jet is semi-hard, with transverse momentum comparable to the nuclear saturation momentum, and is well separated in pseudo-rapidity from the hard dijets. The emission of the semi-hard jet allows for strong scattering, thus avoiding the “higher-twist” suppression of the exclusive dijet production due to colour transparency. We compute the trijet cross-section using the diffractive TMD factorisation which emerges from the CGC effective theory at high energy. The cross-section is controlled by gluon saturation, which leaves its imprints on the structure of the final state, notably on the rapidity distribution.

Physics↗
DOE OSTI2022

Microhardness Distribution of Long Magnesium Block Processed through Powder Metallurgy

Powder metallurgy is a popular method of making raw powders into specific shaped samples. However, the pressure distribution and the microhardness difference within the sample are nonnegligible and unclear when the sample is long or exceeds a specific size. In this study, the long magnesium blocks, with a ratio of about 2.8 between the sample height and the sample side length, are successfully synthesized under three uniaxial and two biaxial conditions. Then, the sample hardness values on the outer surface and the center plane are tested to study the microhardness distribution. The modified analytical expression indicates that the normal pressure exponentially decreases along the compression direction, which is consistent with the hardness distribution trend. Because higher pressure leads to a more compact arrangement of the powders, more metal bonds are formed after sintering. During the first pressing, the sidewall pressure makes the surface hardness higher. The secondary reverse compression mainly improves the bottom and core hardness due to the re-orientation and re-location of the powders. The obtained relationship between the applied pressure and the hardness distribution is instructive in predicting and improving the sample quality.

Wang, Jiaying↗
NASA NTRS1973

High temperature, low-cycle fatigue of copper-base alloys in argon. Part 1: Preliminary results for 12 alloys at 1000 F (538 C)

Short-term tensile evaluations at room temperature and 538 C and low-cycle fatigue evaluations at 538 C are presented for the following materials: Zirconium copper-annealed, Zirconium copper-1/4 hard, Zirconium copper-1/2 hard, Tellurium copper-1/2 hard, Chromium copper-SA and aged, OFHC copper-hard, OFHC copper-1/4 hard, OFHC copper-annealed, Silver-as drawn, Zr-Cr-Mg copper-SA, CW and aged, Electroformed copper-30-35 ksi, and Co-Be-Zr- copper-SA, aged. A total of 50 tensile tests and 76 low-cycle fatigue tests were performed using a strain rate of 0.2 percent per second.

Conway, J. B.↗
NASA NTRS1974

OSO-7 observations of solar X-rays in the energy range 10-100 keV

Data on 123 hard X-ray bursts observed by the satellite OSO-7 between Oct. 10, 1971 and June 6, 1972 are described and evaluated. Typical duration of a burst is 100 sec. Average spectral indices lie between 3.5 and 5.5 for two-thirds of the 123 bursts, with a median of 4.6. In some events a soft-hard-soft pattern is observed, but there are numerous examples in which the spectrum softens continuously throughout the burst. The mean shape of the hard X-ray time profile as measured by the full width at half maximum does not depend on burst amplitude; nor does the spectral hardness correlate with the flux. The distribution of burst peak fluxes and the observation of large soft X-ray bursts without accompanying hard X rays suggest the existence of a distinct class of solar flares which emit only soft X rays. No center-to-limb variation was found in the frequency of occurrence of bursts or in the fraction with a nonthermal component. Estimates of the energy in the form of nonthermal electrons and in the flare plasma derived from these data indicate that the total amounts in each are comparable.

Datlowe, D. W.↗
NASA NTRS1975

The role of electron concentration in softening and hardening of ternary molybdenum alloys

An investigation was conducted to determine softening and hardening behavior in ternary Mo alloys and to correlate these effects with electron concentration. Results showed that the hardness behavior of ternary Mo alloys could be correlated with results anticipated from binary data based upon expressions involving the number of s + d electrons contributed by the solute elements. It was further shown that combining alloying elements at concentrations that produce the maximum amount of softening in Mo does not result in additive softening in ternary Mo alloys. Once a critical electron concentration is exceeded, only alloy hardening is observed. A comparison of hardness behavior with literature data on Hall coefficient and magnetic susceptibility for W-Re alloys showed that hardness minima occur at Re concentrations where minima are observed for the physical property measurements. These observations, and the correlation of hardness with electron concentration, support the hypothesis that alloy softening in Group VI metals is an intrinsic characteristic of these metals and that electron concentration plays the dominant role in controlling hardness.

Stephens, J. R.↗
NASA NTRS1979

Wear of aluminum and hypoeutectic aluminum-silicon alloys in boundary-lubricated pin-on disk sliding

The friction and wear of pure aluminum and a number of hypoeutectic aluminum-silicon alloys (with 3 to 12 wt %Si) were studied with a pin-on-disk apparatus. The contacts were lubricated with mineral oil and sliding was in the boundary-lubrication regime at 2.6 cm/sec. Surfaces were analyzed with photomicrographs, scanning electron microscopy, X-ray dispersive analysis, and diamond pyramid hardness measurements. There were two wear regimes for the alloys - high and low - whereas pure aluminum exhibited a high wear rate throughout the test period. Wear rate decreased and the transition stress from high to low wear increased with increasing hardness. There was no correlation between friction coefficient and hardness. A least squares curve fit indicated a wear-rate dependence greater than the inverse first power of hardness. The lower wear rates of the alloys may be due to the composites of silicon platelets in aluminum resulting in increased hardness and thus impairing the shear of the aluminum.

Ferrante, J.↗
NASA NTRS1979

HEAO-1 observations of dwarf novae

Results are reported for X-ray observations of about 20 dwarf novae in optical outburst with the A-2 experiment aboard HEAO 1. It is shown that only U Gem was detected as an X-ray source during optical outburst and that X-ray emission was observed from SS Cyg, EX Hya, and AY Lyr during optical quiescence. The results obtained indicate that: (1) the soft and hard X-ray emission from U Gem and SS Cyg is linked to the optical state of the system; (2) both U Gem and SS Cyg have one soft and one hard X-ray spectral component; (3) the ratio of soft to hard X-ray energy flux from both U Gem and SS Cyg during outburst is about 10; (4) X-ray emission of the strength and temperature seen from SS Cyg and U Gem is not common among dwarf novae; (5) the hard X-ray flux from SS Cyg and EX Hya probably originates in a hot optically thin plasma; and (6) the variability of the hard X-ray flux from SS Cyg and EX Hya suggests a cooling time scale that would limit the characteristic size of the emission region to a value comparable to the dimensions of a white dwarf.

Mason, K.↗
NASA NTRS1982

Effects of environment on microhardness of magnesium oxide

Micro-Vickers hardness measurements of magnesium oxide single crystals were conducted in various environments. These environments included air, nitrogen gas, water, mineral oil with or without various additives, and aqueous solutions with various pH values. Indentations were made on the (100) plane with the diagonals of the indentation in the (100) direction. The results indicate that a sulfur containing additve in mineral oil increased hardness, a chlorine containing additive in mineral oil decreased hardness, and aqueous solutions of hydrogen chloride decreased hardness. Other environments were found to have little effect on hardness. Mechanically polished surfaces showed larger indentation creep than did as-cleaved surfaces.

Ishigaki, H.↗
NASA NTRS1983

The XPS depth profiling and tribological characterization of ion-plated gold on various metals

Friction properties were measured with a gold film; the graded interface between gold and nickel substrate; and the nickel substrate. All sliding was conducted against hard silicon carbide pins in two processes. In the adhesive process, friction arises primarily from adhesion between sliding surfaces. In the abrasion process, friction occurs as a result of the hard pin sliding against the film, indenting into it, and plowing a series of grooves. Copper and 440 C stainless steel substrates were also used. Results indicate that the friction related to both adhesion and abrasion is influenced by coating depth. The trends in friction behavior as a function of film depth are, however, just the opposite. The graded interface exhibited the highest adhesion and friction, while the graded interface resulted in the lowest abrasion and friction. The coefficient of friction due to abrasion is inversely related to the hardness. The greater the hardness of the surface, the lower is the abrasion and friction. The microhardness in the graded interface exhibited the highest hardness due to an alloy hardening effect. Almost no graded interface between the vapor-deposited gold film and the substrates was detected.

Miyoshi, K.↗
NASA NTRS1993

The Neupert effect - What can it tell us about the impulsive and gradual phases of solar flares?

A study aimed at determining the fractions of impulsive and gradual flares that show the Neupert effect (the correlation observed in many flares between the time-integrated microwave and hard X-ray emissions and the soft X-ray emission light curve) and the implications that can be drawn about the different flare types is presented. The study is based on hard X-ray data from the Hard X-ray Burst Spectrometer on the Solar Maximum Mission and soft X-ray data from the GOES detector. It is concluded that the comparison of the soft X-ray time-derivative and the hard X-ray profile provides a simple and effective way of comparing the timing of the hard X-ray emission and the heating of the plasma.

Dennis, Brian R.↗
NASA NTRS1993

Comparative study of x ray and microwave emissions during solar flares

The work supported by the grant consisted of two projects. The first project involved making detailed case studies of two flares using SMM data in conjunction with ground based observations. The first flare occurred at 1454 UT on June 20, 1989 and involved the eruption of a prominence near the limb. In the study we used data from many wavelength regimes including the radio, H-alpha, hard X-rays, and soft X-rays. We used a full gyrosynchrotron code to model the apparent presence of a 1.4 GHz source early in the flare that was in the form of a large coronal loop. The model results lead us to conclude that the initial acceleration occurs in small, dense loops which also produced the flare's hard X-ray emission. We also found evidence that a source at 1.4 GHz later in the event was due to second harmonic plasma emission. This source was adjacent to a leg of the prominence and comes from a dense column of material in the magnetic structure supporting the prominence. Finally, we investigated a source of microwaves and soft X-rays, occurring approximately 10 min after the hard X-ray peak, and calculate a lower limit for the density of the source. The second flare that was studied occurred at 2156 UT on June 20, 1989 and was observed with the VLA and the Owens Valley Radio Observatory (OVRO) Frequency Agile Array. We have developed a gyrosynchrotron model of the sources at flare peak using a new gyrosynchrotron approximation which is valid at very low harmonics of the gyrofrequency. We found that the accelerated particle densities of the sources decreased much more with radius from the source center than had been supposed in previous work, while the magnetic field varied less. We also used the available data to analyze a highly polarized source which appeared late in the flare. The second project involved compiling a statistical base for the relative timing of the hard X-ray peak, the turbulent and blue-shift velocities inferred from soft X-ray line emissions observed by SMM and the microwave peak as determined from ground-based observations. This timing was then used to aid the testing of newly developed global models for flares that incorporate the global magnetic topology as well as the electron dynamics that are responsible for the hard X-rays and microwaves.

Winglee, Robert M.↗
NASA NTRS1996

New observational facts about particle acceleration and transport during solar flares

Extensive hard X-ray (HXR)/gamma-ray (GR) observations of solar flares, performed during solar cycles 21 and 22 have led to important new discoveries. These data, combined with observations obtained in other parts of the electromagnetic spectrum (soft X-ray, Hard X-ray, optical, and radio) largley contributed to get a better understanding and to develop new ideas on particle acceleration and transport during solar flares. This review presents new observational facts relevant to hard X-ray/gamma-ray producing flares. Among these are the frequent presence of sub-second time structure in the hard X-ray emission, the variability in hard X-ray and radio spatial distributions during a flare and from flare to flare, the evidence for strong gamma-ray line emission from the Corona and the existence of extended phases of the gamma-ray emission lasting for several hours after the flare onset. This ensemble of observations indicates that particle acceleration takes place at different sites in a complex and dynamic magnetic field environment.

Trottel, G.↗
NASA NTRS1995

Testing Solar Flare Models with BATSE

We propose to use high-sensitivity Burst and Transient Source Experiment (BATSE) hard X-ray observations to test the thick-target and electric field acceleration models of solar flares. We will compare the predictions made by these models with hard X-ray spectral observations obtained with BATSE and simultaneous soft X-ray Ca XIX emission observed with the Yohkoh Bragg Crystal Spectrometer (BCS). The increased sensitivities of the BATSE and BCS (relative to previous detectors) permits a renewed study of the relationship between heating and dynamical motions during the crucial rise phase of flares. With these observations, we will: (1) investigate the ability of the thick-target model to explain the temporal evolution of hard X-ray emission relative to the soft X-ray blueshift during the earliest stages of the impulsive phase; and (2) search for evidence of electric-field acceleration as implied by temporal correlations between hard X-ray spectral breaks and the Ca XIX blueshift. The proposed study will utilize hard X-ray lightcurve and spectral measurements in the 10-100 keV energy range obtained with the BATSE Large Area Detectors (LAD). The DISCLA and CONT data will be the primary data products used in this analysis.

Zarro, Dominic M.↗
NASA NTRS1961

Landing Characteristics of a Lenticular-Shaped Reentry Vehicle

An experimental investigation was made of the landing characteristics of a 1/9-scale dynamic model of a lenticular-shaped reentry vehicle having extendible tail panels for control after reentry and for landing control (flare-out). The landing tests were made by catapulting a free model onto a hard-surface runway and onto water. A "belly-landing" technique in which the vehicle was caused to skid and rock on its curved undersurface (heat shield), converting sinking speed into angular energy, was investigated on a hard-surface runway. Landings were made in calm water and in waves both with and without auxiliary landing devices. Landing motions and acceleration data were obtained over a range of landing attitudes and initial sinking speeds during hard-surface landings and for several wave conditions during water landings. A few vertical landings (parachute letdown) were made in calm water. The hard-surface landing characteristics were good. Maximum landing accelerations on a hard surface were 5g and 18 radians per sq second over a range of landing conditions. Horizontal landings on water resulted in large violent rebounds and some diving in waves. Extreme attitude changes during rebound at initial impact made the attitude of subsequent impact random. Maximum accelerations for water landings were approximately 21g and 145 radians per sq second in waves 7 feet high. Various auxiliary water-landing devices produced no practical improvement in behavior. Reduction of horizontal speed and positive control of impact attitude did improve performance in calm water. During vertical landings in calm water maximum accelerations of 15g and 110 radians per sq second were measured for a contact attitude of -45 deg and a vertical velocity of 70 feet per second.

Blanchard, Ulysse J.↗