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Thermoelectric materials development

A systematic search for advanced thermoelectric materials was initiated at JPL several years ago to evaluate candidate materials which includes consideration of the following property attributes: (1) semiconducting properties; (2) large Seebeck coefficient; (3) high carrier mobility and high electrical conductivity; (4) low lattice thermal conductivity; and (5) chemical stability and low vapor pressure. Through this candidate screening process, JPL identified several families of materials as promising candidates for improved thermoelectric materials including the skutterudite family. As part of an ongoing effort to develop skutterudite materials with lower thermal conductivity values, several solid solutions and filled skutterudite materials were investigated under the effort sponsored by DOE. The efforts have primarily focused on: (1) study of existence and properties of solid solutions between the binary compounds CoSb3 and IrSb3, and RuSb2Te, and (2) CeFe(4-x)Sb12 based filled compositions. For the solid solutions, the lattice thermal conductivity reduction was expected to be reduced by the introduction of the Te and Ru atoms while in the case of CeFe(4-x)Ru(x)Sb12 based filled compositions. For the solid solutions, the lattice thermal conductivity reduction was expected to be reduced by the introduction of the Te and Ru atoms while in the case of CeFe(4-x)Ru(x)Sb12 filled compositions, the reduction would be caused by the rattling of Ce atoms located in the empty voids of the skutterudite structure and the substitution of Fe for Ru. The details of the sample preparation and characterization of their thermoelectric properties are reported in this report.

Fleurial, J. P.↗

Resonance Scattering of Fe XVII X-ray and EUV Lines

Over the years a number of calculations have been carried out to derive intensities of various X-ray and EUV lines in Fe XVII to compare with observed spectra. The predicted intensities have not agreed with solar observations, particularly for the line at 1.5.02 Angstroms; resonance scattering has been suggested as the source for much of the disagreement. The atomic data calculated earlier used seven configurations having n=3 orbitals and the scattering calculations were carried out only for incident energies above the threshold of the highest fine-structure level. These calculations have now been extended to thirteen configurations having n=4 orbitals and the scattering calculations are carried out below as well as above the threshold of the highest fine structure level. These improved calculations of Fe XVII change the intensity ratios compared to those obtained earlier, bringing the optically thin F(15.02)/F(16.78) ratio and several other ratios closer to the observed values. However, some disagreement with the solar observations still persists, even thought the agreement of the presently calculated optically thin F(15.02)/F(15.26) ratio with the experimental results of Brown et al. (1998) and Laming et al. (2000) has improved. Some of the remaining discrepancy is still thought to be the effect of opacity, which is consistent with expected physical conditions for solar sources. EUV intensity ratios are also calculated and compared with observations. Level populations and intensity ratios are calculated, as a function of column density of Fe XVII, in the slab and cylindrical geometries. As found previously, the predicted intensities for the resonance lines at 15.02 and 15.26 Angstroms exhibit initial increases in flux relative to the forbidden line at 17.10 Angstroms and the resonance line at 16.78 Angstroms as optical thickness increases. The same behavior is predicted for the lines at 12.262 and 12.122 Angstroms. Predicted intensities for some of the allowed EUV lines are also affected by opacity.

Bhatia, A. K.↗

A New Paradigm for Quality Metrics

SMA metrics have been traditionally represented as either leading and lagging indicators. Traditional ways of viewing these metrics and trending the data is via graphs which reflect one attribute in each graph. The KSC Independent Assessment Team developed a non-traditional method for expressing variation as a ratio (the deviation between the Expected and Actual). This method allows different measures to be plotted on the same graph for trending and comparison to provide a holistic view across a particular theme or discipline. Since all measurements are a ratio of variation and dimensionless, this variation-based metrics approach can be used a new analytical tool which is complimentary to existing value-added metrics tools.

Dimensionless↗

GCR Transport in the Brain: Assessment of Self-Shielding, Columnar Damage, and Nuclear Reactions on Cell Inactivation Rates

Radiation shield design is driven by the need to limit radiation risks while optimizing risk reduction with launch mass/expense penalties. Both limitation and optimization objectives require the development of accurate and complete means for evaluating the effectiveness of various shield materials and body-self shielding. For galactic cosmic rays (GCR), biophysical response models indicate that track structure effects lead to substantially different assessments of shielding effectiveness relative to assessments based on LET-dependent quality factors. Methods for assessing risk to the central nervous system (CNS) from heavy ions are poorly understood at this time. High-energy and charge (HZE) ion can produce tissue events resulting in damage to clusters of cells in a columnar fashion, especially for stopping heavy ions. Grahn (1973) and Todd (1986) have discussed a microlesion concept or model of stochastic tissue events in analyzing damage from HZE's. Some tissues, including the CNS, maybe sensitive to microlesion's or stochastic tissue events in a manner not illuminated by either conventional dosimetry or fluence-based risk factors. HZE ions may also produce important lateral damage to adjacent cells. Fluences of high-energy proton and alpha particles in the GCR are many times higher than HZE ions. Behind spacecraft and body self-shielding the ratio of protons, alpha particles, and neutrons to HZE ions increases several-fold from free-space values. Models of GCR damage behind shielding have placed large concern on the role of target fragments produced from tissue atoms. The self-shielding of the brain reduces the number of heavy ions reaching the interior regions by a large amount and the remaining light particle environment (protons, neutrons, deuterons. and alpha particles) may be the greatest concern. Tracks of high-energy proton produce nuclear reactions in tissue, which can deposit doses of more than 1 Gv within 5 - 10 cell layers. Information on rates of cell killing from GCR, including patterns of cell killing from single particle tracks. can provide useful information on expected differences between proton and HZE tracks and clinical experiences with photon irradiation. To model effects on cells in the brain, it is important that transport models accurately describe changes in the GCR due to interactions in the cranium and proximate tissues. We describe calculations of the attenuated GCR particle fluxes at three dose-points in the brain and associated patterns of cell killing using biophysical models. The effects of the brain self-shielding and bone-tissue interface of the skull in modulating the GCR environment are considered. For each brain dose-point, the mass distribution in the surrounding 4(pi) solid angle is characterized using the CAM model to trace 512 rays. The CAM model describes the self-shielding by converting the tissue distribution to mass-equivalent aluminum, and nominal values of spacecraft shielding is considered. Particle transport is performed with the proton, neutron, and heavy-ion transport code HZETRN with the nuclear fragmentation model QMSFRG. The distribution of cells killed along the path of individual GCR ions is modeled using in vitro cell inactivation data for cells with varying sensitivity. Monte Carlo simulations of arrays of inactivated cells are considered for protons and heavy ions and used to describe the absolute number of cell killing events of various magnitude in the brain from the GCR. Included are simulations of positions of inactivated cells from stopping heavy ions and nuclear stars produced by high-energy ions most importantly, protons and neutrons.

Shavers, M. R.↗

On the breakup of tectonic plates by polar wandering

The observed boundary system of the major tectonic plates on the surface of the earth lends fresh support to the hypothesis of polar wandering. A dynamic model of the outer shell of the earth under the influence of polar shift is developed. The analysis falls into two parts: (1) deriving equations for stresses caused by polar shifting; and (2) deducing the pattern according to which the fracture of the shell can be expected. For stress analysis, the theory of plates and shells is the dominant feature of this model. In order to determine the fracture pattern, the existence of a mathematical theorem of plasticity is recalled: it says that the plastic flow begins to occur when a function in terms of the differences of the three principal stresses surpasses a certain critical value. By introducing the figures for the geophysical constants, this model generates stresses which could produce an initial break in the lithosphere.

Liu, H. S.↗

Aerodynamic measurements concerned with a turret model

An experimental investigation was carried out in the 14 by 14 ft Ames transonic wind tunnel on a turret model. The aerodynamic parameters measured were steady and unsteady pressures (static and total fluid pressures), local mean velocities, and local mean densities at selected locations along the optical beam path for the azimuth look angles of 90, 120, and 150 degrees from the turret. The test stream Mach numbers considered are 0.55, 0.65 and 0.75, and the Reynolds number per meter is in the range of 10 million. The results indicate that severe optical degradation can be expected at aft look azimuth, angles, this degradation in optical performance increases as the azimuth angle is increased. The ratio of rms static pressure to the local mean static pressure peaks in the range of 0.07 to 0.12 and the ratio of rms total pressure to the local mean total pressure peaks in the range of 0.02 to 0.04. These values depend on the Mach number and the aft look azimuth angle. The scale lengths obtained from correlation considerations are also presented.

Raman, K. R.↗

CO 4.6 micron emission lines from the IRC +10216 inner envelope

Results are presented of an investigation of gas in the inner envelope of IRC +10216 at a scale size (approximately 2 arcsec) never observed previously. Observations were made at the 4.6-micrometer fundamental vibration-rotation band of CO, employing an annular observing aperture to isolate radiation resonantly scattered from the extended molecular envelope. In addition to the expected emission up to the expansion velocity of the envelope, both CO and 13CO show evidence of high-velocity features in the blue wing of the line, beyond the 15 km/s expansion velocity. A mass loss rate for the inner envelope of approximately 5-7 x 10 to the -5 solar mass per year is derived (lower than the values derived for the extended envelope from millimeter CO data).

Sahai, R.↗

High-speed quiet tunnels

The adverse effect of wind-tunnel noise on boundary-layer transition is considered, and the development of Pilot Quiet Tunnels exhibiting low noise levels in upstream regions of the test rhombus to high values of the stream unit Reynolds number is covered. Advances in quiet nozzle and tunnel designs are discussed, including a new Mach-8 nozzle and modifications to an existing conical nozzle in one of the helium tunnels at NASA Langley. Attention is focused on the final engineering design of a large-scale high-speed low-disturbance tunnel expected to accommodate nozzles of various lengths with Mach numbers ranging from 2 to 6.

Beckwith, Ivan E.↗

Prediction modeling of physiological responses and human performance in the heat with application to space operations

This institute has developed a comprehensive USARIEM heat strain model for predicting physiological responses and soldier performance in the heat which has been programmed for use by hand-held calculators, personal computers, and incorporated into the development of a heat strain decision aid. This model deals directly with five major inputs: the clothing worn, the physical work intensity, the state of heat acclimation, the ambient environment (air temperature, relative humidity, wind speed, and solar load), and the accepted heat casualty level. In addition to predicting rectal temperature, heart rate, and sweat loss given the above inputs, our model predicts the expected physical work/rest cycle, the maximum safe physical work time, the estimated recovery time from maximal physical work, and the drinking water requirements associated with each of these situations. This model provides heat injury risk management guidance based on thermal strain predictions from the user specified environmental conditions, soldier characteristics, clothing worn, and the physical work intensity. If heat transfer values for space operations' clothing are known, NASA can use this prediction model to help avoid undue heat strain in astronauts during space flight.

Pandolf, Kent B.↗

Highlights of Part I: Propagation Through Mars Environment: Propagation through Mars Environment - Part 1

We recommend using the dayside Martian ionosphere as a reflector for global communication, because it has a stable density peak and usable critical frequency. This is very crucial for the future Mars ground to ground communication. The dayside ionosphere has been well modeled as a Chapman layer. We suggest performing the Martian nightside ionosphere modeling study. Because the nightside ionosphere has very little measurements available, we propose to drop a digital ionosound instrument into the Mars surface for data collection. Even though the Martian tropospheric radio refractivity had a small value, it still can cause ray bending and multipath effects. We recommend performing an accurate calculation on excess phase and group delays (range and time delays). Other effects, such as range rate errors, appearance angle deviation, defocusing loss on Mars, etc. should be estimated. Ice depolarization effects due to Martian clouds on radio waves are unknown yet, but they are expected to be small, because of lower optical depth and the thinner layer of cloud. Total Martian atmospheric gaseous attenuation is expected to be less than 1 dB on microwaves and, because the Martian atmosphere had very low concentration in uncondensed H2O and O2. An accurate calculation for zenith opacity requires the information about scale heights of H2O and O2 distribution. An accurate water vapor altitude profile at Mars is not available et. Under the normal condition, CO2 and N2 gases ddo not have electric or magnetic dipoles and do not absorb electromagnetic energy from the waves. However, they may generate the dipoles through a collision and interact with waves under a high density condition and absorb electromagnetic waves in the infrared and visible band. Dust storm is the most dominant factor on the radio wave attenuation. Large Martian dust storms can cause at least 3 dB or higher loss to Ka band wave. For a normal dust storm, the attenuation is about 1 dB. The attenuation much depends on dust mass loading, dust size distribution, etc. Most large dust storms occur in the southern hemisphere during later spring and early summer when the southern hemisphere becomes suddenly hot.

Ho, Christian↗

Measurement of the Heat Capacity of He-II Under a Heat Current Near the Lambda Transition

We present preliminary measurements of the heat capacity of superfluid helium-4 under an applied heat current near the lambda transition. The calorimeter is a standard cylindrical thermal conductivity cell with a 0.6 mm gap between two copper endplates. The sidewall is made of stainless steel. A heat current density in the range of 1 to 4 microW/sq cm is applied through the helium sample while a pulse method is used to measure the heat capacity. Temperature changes are recorded with high-resolution thermometers (HRTs) located on the top and bottom endplates. Corrections are made to the readings of the HRTs to account for the Kapitza boundary resistance and the anomalous Kapitza boundary resistance. After the corrections, both the top and the bottom HRTs. give the same heat capacity values. The heat capacity is found to be much larger than the prediction of recent theories. We also plotted our data on a scaled plot to test the prediction of scaling by the theories. The result and its interpretation will be presented. The cell height was deliberately made to be thin to reduce the effects of gravity. Nonetheless, gravity is expected to have significant effects on the heat capacity data in the temperature range of our measurement. A space experiment would remove this unwanted gravity effect and allow the true physics to be examined. Moreover, in the absence of gravity, a deeper cell can be used allowing HRTs to be mounted on to the sidewall providing direct measurements of the helium temperature, unaffected by the anomalous Kapitza boundary resistance.

Harter, Alexa W.↗

An Estimate of the Likelihood for a Climatically Significant Volcanic Eruption Within the Present Decade (2000-2009)

Since 1750, the number of cataclysmic volcanic eruptions (i.e., those having a volcanic explosivity index, or VEI, equal to 4 or larger) per decade is found to span 2-11, with 96% located in the tropics and extra-tropical Northern Hemisphere, A two-point moving average of the time series has higher values since the 1860s than before, measuring 8.00 in the 1910s (the highest value) and measuring 6.50 in the 1980s, the highest since the 18 1 0s' peak. On the basis of the usual behavior of the first difference of the two-point moving averages, one infers that the two-point moving average for the 1990s will measure about 6.50 +/- 1.00, implying that about 7 +/- 4 cataclysmic volcanic eruptions should be expected during the present decade (2000-2009). Because cataclysmic volcanic eruptions (especially, those having VEI equal to 5 or larger) nearly always have been associated with episodes of short-term global cooling, the occurrence of even one could ameliorate the effects of global warming. Poisson probability distributions reveal that the probability of one or more VEI equal to 4 or larger events occurring within the next ten years is >99%, while it is about 49% for VEI equal to 5 or larger events and 18% for VEI equal to 6 or larger events. Hence, the likelihood that a, climatically significant volcanic eruption will occur within the next 10 years appears reasonably high.

Wilson, Robert M.↗

Velocity Characteristics of Evaporated Plasma using Hinode/EIS

This paper presents a detailed study of chromospheric evaporation using the EUV Imaging Spectrometer (EIS) onboard Hinode in conjunction with HXR observat,ions from RHESSI. The advanced capabilities of EIS were used to measure Doppler shifts in 15 emission lines covering the temperature range T=0.05-16 MK during the impulsive phase of a C-class flare on 2007 December 14. Blueshifts indicative of the evaporated material were observed in six emission lines from Fe XIV-XXIV (2-16 MK). Upflow velocity was found to scale with temperature as v(sub up) (kilometers per second) approximately equal to 5-17 T (MK). Although the hottest emission lines, Fe XXIII and Fe XXIV, exhibited upflows of greater than 200 kilometers per second, their line profiles were found to be dominated by a stationary component in stark contrast to the predictions of the standard flare model. Emission from O VI-Fe XIII lines (0.5-1.5 MK) was found to be redshifted by v(sub down) (kilometers per second) approximately equal to 60-17 T (MK) and was interpreted as the downward-moving 'plug' characteristic of explosive evaporation. These downflows occur at temperatures significantly higher than previously expected. Both upflows and downflows were spatially and temporally correlated with HXR emission observed by RHESSI that provided the properties of the electron beam deemed to be the driver of the evaporation. The energy contained in the electron beam was found to be greater than or equal to 10(sup 11) ergs per square centimeter per second consistent with the value required to drive explosive chromospheric evaporation from hydrodynamic simulations.

Milligan, Ryan O.↗

The Trajectory, Orbit and Preliminary Fall Data of the JUNE BOOTID Superbolide of July 23, 2008

The results of the atmospheric trajectory, radiant, orbit and preliminary fall data calculations of an extremely bright slow-moving fireball are presented. The fireball had a -20.7 maximum absolute magnitude and the spectacular long-persistence dust trail (Fig 1 and 2) was observed in a widespread region of Tajikistan twenty eight minutes after sunset, precisely at 14h 45m 25s UT on July 23, 2008. The bolide was first recorded at a height of 38.2 km, and attained its maximum brightness at a height of 35.0 km and finished at a height of 19.6 km. These values are very much in line with other well-known fireballs producing meteorites. The first break-up must have occurred under an aerodynamic pressure Pdyn of about 1.5 MPa, similar to those derived from the study of atmospheric break-ups of previously reported meteorite-dropping bolides. Our trajectory, and dynamic results suggest that one might well expect to find meteorites on the ground in this case. The heliocentric orbit of the meteoroid determined from the observations is very similar to the mean orbit of the June Bootid meteor shower, whose parental comet is 7P/Pons-Winnecke (Lindblad et al. 2003). If the parent was indeed a comet, this has implications for the internal structure of comets, and for the survivability of cometary meteorites.

Konovalova, N. A.↗

Envisioning the Future Role of an Exploration Clinical Decision Support System

The Exploration Medical Capability Element of the NASA Human Research Program seeks to fuse new and existing technologies with practical mission goals into feasible and fiscally realizable human missions to the Moon and Mars. Expected communication delays with Earth-based medical experts will require unprecedented crew self-reliance to rapidly identify and treat anticipated and unforeseen medical conditions using constrained onboard resources with limited crew clinical skill. During this session, the current status of this project will be presented. We will discuss how current modes of decision support (e.g., alerts of critical values, reminders of overdue preventive health tasks, guided clinical workflows, advice for drug prescribing, critiques of existing health care orders, and suggestions for various active care issues) can be tailored to exploration crew needs.

human-system integration↗

Airport Pricing Strategies

Conventional economic wisdom suggests that congestion pricing would be an appropriate response to cope with the growing congestion levels currently experienced at many airports. Several characteristics of aviation markets, however, may make naive congestion prices equal to the value of marginal travel delays a non-optimal response. This paper has developed a model of airport pricing that captures a number of these features. The model in particular reflects that airlines typically have market power and are engaged in oligopolistic competition at different sub-markets; that part of external travel delays that aircraft impose are internal to an operator and hence should not be accounted for in congestion tolls. We presented an analytical treatment for a simple bi-nodal symmetric network, which through the use of 'hyper-networks' would be readily applicable to dynamic problems (in discrete time) such as peak - off-peak differences, and some numerical exercises for the same symmetric network, which was only designed to illustrate the possible comparative static impacts of tolling, in addition to marginal equilibrium conditions as could be derived for the general model specification. Some main conclusions are that second-best optimal tolls are typically lower than what would be suggested by congestion costs alone and may even be negative, and that the toll as derived by Brueckner (2002) may not lead to an increase in total welfare. While Brueckner (2002) has made clear that congestion tolls on airports may be smaller than expected when congestion costs among aircraft are internal for a firm, our analysis adds to this that a further downward adjustment may be in order due to market power. The presence of market power (which causes prices to exceed marginal costs) may cause the pure congestion toll to be suboptimal, because the resulting decrease in demand is too high (the pure congestion tall does not take into account the decrease in consumer surplus). The various downward adjustments in welfare maximizing tolls may well cause the optimal values of these to be negative. Insofar as subsidization is considered unacceptable for whichever reason, our results warn that the most efficient among the non-negative tolls may actually be a zero toll; the pure congestion toll may actually decrease welfare compared to the base case. The model in this paper contains a few simplifying assumptions that may be relaxed in future work. Load factors and aircraft capacity are fixed in this model for simplicity. In a more advanced version of this model, load factors and aircraft capacity can be endogenized. This makes the derivation of the optimality conditions far more complicated, but it should be feasible in a numerical experiment. One can also add a fourth layer to the model, describing the airport's optimization problem. For example, the airport can maximize profits under a cost recovery constraint. The model then deals with interactions between four types of agents. No distinction is made between peak and off-peak traffic in this paper. Finally, the results of the numerical exercise in this paper need to be checked against an asymmetric equilibrium.

Pels, Eric↗

Infrared upconversion for astronomical applications

The performance of an upconversion system is examined for observation of astronomical sources in the low to middle infrared spectral range. Theoretical values for the performance parameters of an upconversion system for astronomical observations are evaluated in view of the conversion efficiencies, spectral resolution, field of view, minimum detectable source brightness and source flux. Experimental results of blackbody measurements and molecular absorption spectrum measurements using a lithium niobate upconverter with an argon-ion laser as the pump are presented. Estimates of the expected optimum sensitivity of an upconversion device which may be built with the presently available components are given.

Abbas, M. M.↗

Intercomparison of the Nimbus 7 SBUV/TOMS total ozone data sets with Dobson and M83 results

Two years of SBUV/TOMS (Solar Backscattered Ultraviolet/Total Ozone Mapping Spectrometer) data spanning the period November 1978 to October 1980 have been processed and compared with ground-based ozone measurements made at 62 Dobson spectrophotometer and 18 M83 filter photometer ozone stations. Results show that the satellite ozone values are consistently smaller than those measured by the stations; most of this difference is probably due to an error in the currently accepted ozone absorption cross sections at ultraviolet wavelengths. Dobson-derived ozone amounts agree extremely well with those derived from each of the satellite instruments. Long-term stability of the ozone derived by the two instruments is expected to be better than 0.5 percent per year.

Bhartia, P. K.↗