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At least 1,549 records · Page 86

Using Thermoelectric Converters for Loop Heat Pipe Operating Temperature Control

This paper describes an experimental study to investigate the effectiveness of using thermoelectric converters (TECs) to control the loop heat pipe (LHP) operating temperature. Tests were conducted on an LHP having two evaporators and two condensers. Each evaporator has its own integral compensation chamber (CC). One side of the TEC is attached to the CC, and the other side is connected to the evaporator through a copper thermal strap. A bi-polar power supply is used to provide the power for the operation of each TEC. The bipolar supply will automatic change the direction of the current to the TEC depending on whether the CC requires heating or cooling in order to maintain its temperature at the desired set point. When cooling the CC, the heat pumped by the TEC plus the power needed to operate the TEC is dissipated to the evaporator, and is ultimately transmitted to the condenser. When heating the CC, the TEC can draw heat from the evaporator to supplement the required control heater power. Test results showed that the TEC could control the LHP operating temperature within h1K of the set point temperature. The control heater power required for TEC operation was also much less than that of using electrical heaters.

Ku, Jentung↗

Thermal Interface Evaluation of Heat Transfer from a Pumped Loop to Titanium-Water Thermosyphons

Titanium-water thermosyphons are being considered for use in the heat rejection system for lunar outpost fission surface power. Key to their use is heat transfer between a closed loop heat source and the heat pipe evaporators. This work describes laboratory testing of several interfaces that were evaluated for their thermal performance characteristics, in the temperature range of 350 to 400 K, utilizing a water closed loop heat source and multiple thermosyphon evaporator geometries. A gas gap calorimeter was used to measure heat flow at steady state. Thermocouples in the closed loop heat source and on the evaporator were used to measure thermal conductance. The interfaces were in two generic categories, those immersed in the water closed loop heat source and those clamped to the water closed loop heat source with differing thermal conductive agents. In general, immersed evaporators showed better overall performance than their clamped counterparts. Selected clamped evaporator geometries offered promise.

Jaworske, Donald A.↗

Venting of a Water/Inhibited Propylene Glycol Mixture in a Vacuum Environment-Characterization and Representative Test Results

A planned use of the Orion space vehicle involves its residence at the International Space Station for six months at a time. One concept of operations involves temporarily venting portions of the idle Orion active thermal control system (ATCS) during the docked phase, preventing freezing. The venting would have to be reasonably complete with few, if any, completely filled pockets of frozen liquid. Even if pockets of frozen liquid did not damage the hardware during the freezing process, they could prevent the system from filling completely prior to its reactivation. The venting of single component systems in a space environment has been performed numerous times and is well understood. Local nucleation occurs at warm, relatively massive parts of the system, which creates vapor and forces the bulk liquid out of the system. The remnants of the liquid will freeze, then evaporate over time through local heating. Because the Orion ATCS working fluid is a 50/50 mixture of water and inhibited propylene glycol, its boiling behavior was expected to differ from that of a pure fluid. It was thought that the relatively high vapor pressure water might evaporate preferentially, leaving behind a mixture enriched with the low vapor pressure propylene glycol, which would be vaporization ]resistant. Owing to this concern, a test was developed to compare the evaporation behavior of pure water, a 50/50 mixture of water and inhibited propylene glycol, and inhibited propylene glycol. The test was performed using room temperature fluids in an instrumented thin walled stainless steel vertical tube. The 1 in x 0.035 in wall tube was instrumented with surface thermocouples and encased in closed cell polyurethane foam. Reticulated polyurethane foam was placed inside the tube to reduce the convection currents. A vacuum system connected to the top of the tube set the pressure boundary condition. Tests were run for the three fluids at back pressures ranging from 1 to 18 torr. During each test, the mass of the test article was measured as it changed over time, as was its temperature and backpressure. The tests were successful. Somewhat surprisingly, the results showed that the evaporation behavior of the three fluids had more similarities than differences. The 50/50 mixture evaporated similarly to the pure water - albeit at a slower rate. The test results indicate that our extensive space - based experience with venting of single component fluids can be applied to the problem of Orion ATCS venting as long as the appropriate puts, takes, and caveats are applied.

Ungar, Eugene K.↗

A Thermal Analysis of a Hot-Wire Probe for Icing Applications

This paper presents a steady-state thermal model of a hot-wire instrument applicable to atmospheric measurement of water content in clouds. In this application, the power required to maintain the wire at a given temperature is used to deduce the water content of the cloud. The model considers electrical resistive heating, axial conduction, convection to the flow, radiation to the surroundings, as well as energy loss due to the heating, melting, and evaporation of impinging liquid and or ice. All of these parameters can be varied axially along the wire. The model further introduces a parameter called the evaporation potential which locally gauges the maximum fraction of incoming water that evaporates. The primary outputs of the model are the steady-state power required to maintain a spatially-average constant temperature as well as the variation of that temperature and other parameters along the wire. The model is used to understand the sensitivity of the hot-wire performance to various flow and boundary conditions including a detailed comparison of dry air and wet (i.e. cloud-on) conditions. The steady-state power values are compared to experimental results from a Science Engineering Associates (SEA) Multi-Element probe, a commonly used water-content measurement instrument. The model results show good agreement with experiment for both dry and cloud-on conditions with liquid water content. For ice, the experimental measurements under read the actual water content due to incomplete evaporation and splashing. Model results, which account for incomplete evaporation, are still higher than experimental results where the discrepancy is attributed to splashing mass-loss which is not accounted in the model.

Thermal Analysis↗

Molecular Composition Analysis of Distant Targets

This document is the Final Report for NASA Innovative Advanced Concepts (NIAC) Phase I Grant 15-NIAC16A-0145, titled Molecular Composition Analysis of Distant Targets. The research was focused on developing a system concept for probing the molecular composition of cold solar system targets, such as Asteroids, Comets, Planets and Moons from a distant vantage, for example from a spacecraft that is orbiting the target (Hughes et al., 2015). The orbiting spacecraft is equipped with a high-power laser, which is run by electricity from photovoltaic panels. The laser is directed at a spot on the target. Materials on the surface of the target are heated by the laser beam, and begin to melt and then evaporate, forming a plume of asteroid molecules in front of the heated spot. The heated spot glows, producing blackbody illumination that is visible from the spacecraft, via a path through the evaporated plume. As the blackbody radiation from the heated spot passes through the plume of evaporated material, molecules in the plume absorb radiation in a manner that is specific to the rotational and vibrational characteristics of the specific molecules. A spectrometer aboard the spacecraft is used to observe absorption lines in the blackbody signal. The pattern of absorption can be used to estimate the molecular composition of materials in the plume, which originated on the target. Focusing on a single spot produces a borehole, and shallow subsurface profiling of the targets bulk composition is possible. At the beginning of the Phase I research, the estimated Technology Readiness Level (TRL) of the system was TRL-1. During the Phase I research, an end-to-end theoretical model of the sensor system was developed from first principles. The model includes laser energy and optical propagation, target heating, melting and evaporation of target material, plume density, thermal radiation from the heated spot, molecular cross section of likely asteroid materials, and estimation of the absorption profile at a distant spectrometer. Results obtained by executing simulations based on the model provide compelling evidence that the concept of remote laser evaporative molecular absorption spectroscopy is feasible. In this document, technical details of the model are presented, and results of simulations are described that indicate the utility of the proposed sensor system. Additionally, an asteroid rendezvous mission is analyzed, with a survey of system requirements to accomplish molecular composition analysis of the asteroid. Based on positive theoretical results obtained during Phase I, the estimated TRL of the system is now TRL-2. This document also describes potential future research and experimentation that could push the system to TRL-4 within 2 years. Steps required for construction of a laboratory prototype are described. An experiment to test predictions of the theory is described, based on the laboratory prototype setup.

asteroid↗

Land Surfaces at the Tipping-Point for Water and Energy Balance Coupling

The surface water and energy balances can be coupled or uncoupled depending on whether the evaporation regime is water-limited or energy-limited. As the landscape loses soil moisture during drydowns, a transition between the regimes may occur, which signifies a nonlinear change in water-energy-carbon coupling. Regions that switch often between these two regimes, that is, are dominated by neither regime, are particularly vulnerable to climate variability and change. To robustly identify these tipping points, we identify drydown events based on global soil moisture data sets from remote sensing. The event identification does not rely on precipitation information and is robust with respect to measurement noise. Then, the soil moisture thresholds delineating the evaporation regime transitions are determined by Sequential Monte Carlo Sampling and a two-stage parametrization strategy. Based on the estimated soil moisture thresholds across the globe, we estimate observation-based water availability indices which quantify the nonlinear controls of soil moisture on evaporation. This framework is tested and applied globally using Soil Moisture Active Passive soil moisture retrievals. Combined with a new tippling-point metric that describes the frequency of evaporation regime transitions, we identify regions that switch often between different evaporation regimes at the global scale. Given unit shifts in soil moisture, these regions will experience the most change in how their surface water and energy are coupled.

Jianzhi Dong↗

Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333

The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion adsorption chemicals, solid-liquid separation methods, and achievable decontamination factors. Results of the radionuclide removal testing indicate that the radionuclides, including Tc-99, can be removed with inorganic sorbents and precipitating agents. Evaporation test results indicate that the simulant can be evaporated to fairly high concentration prior to formation of appreciable solids, but corrosion has not yet been examined.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Apparatus for diffusion-gap thermal desalination

A thermal distillation apparatus including evaporation surfaces that are wetted with a solution, and from which at least some of the volatile solvent contained in the solution evaporates, condensers having an external surface in close proximity to, but not touching, a corresponding one of the one or more evaporation surfaces, and on which vapors of the solvent condense, releasing thermal energy that heats a flow of the solution moving upward within the condensers, spacers that prevent contact between the evaporating surfaces and the condensers, wherein spaces between the evaporating surfaces and the condensers are filled with a gaseous mixture composed of solvent vapor and one or more non-condensable gases, and except for diffusion of the solvent vapor relative to the non-condensable gases, the gaseous mixture is stationary.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hot Gravitons and Gravitational Waves From Kerr Black Holes in the Early Universe

Any abundance of black holes that was present in the early universe will evolve as matter, making up an increasingly large fraction of the total energy density as space expands. This motivates us to consider scenarios in which the early universe included an era that was dominated by low-mass ($M < 5\times 10^8$ g) black holes which evaporate prior to primordial nucleosynthesis. In significant regions of parameter space, these black holes will become gravitationally bound within binary systems, and undergo mergers before evaporating. Such mergers result in three potentially observable signatures. First, any black holes that have undergone one or more mergers will possess substantial angular momentum, causing their Hawking evaporation to produce significant quantities of high-energy gravitons. These products of Hawking evaporation are predicted to constitute a background of hot ($\sim$eV-keV) gravitons today, with an energy density corresponding to $\Delta N_{\rm eff} \sim 0.01-0.03$. Second, these mergers will produce a stochastic background of high-frequency gravitational waves. And third, the energy density of these gravitational waves can be as large as $\Delta N_{\rm eff} \sim 0.3$, depending on the length of time between the mergers and evaporation. These signals are each potentially within the reach of future measurements.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Plastic shrinkage of mortars with shrinkage reducing admixture and lightweight aggregates studied by neutron tomography

Water transport in fresh, highly permeable concrete and rapid water evaporation from the concrete surface during the first few hours after placement are the key parameters influencing plastic shrinkage cracking. In this work, neutron tomography was used to determine both the water loss from the concrete surface due to evaporation and the redistribution of fluid that occurs in fresh mortars exposed to external drying. In addition to the reference mortar with a water to cement ratio (w/c) of 0.30, a mortar with the addition of pre-wetted lightweight aggregates (LWA) and a mortar with a shrinkage reducing admixture (SRA) were tested. The addition of SRA reduced the evaporation rate from the mortar at the initial stages of drying and reduced the total water loss. The pre-wetted LWA released a large part of the absorbed water as a consequence of capillary pressure developing in the fresh mortar due to evaporation.

36 MATERIALS SCIENCE↗

Investigating Phase-Change-Induced Flow in Gas Diffusion Layers in Fuel Cells with X-ray Computed Tomography

The performance of polymer-electrolyte fuel cells is heavily dependent on proper management of liquid water. One particular reason is that liquid water can collect in the gas diffusion layers (GDLs) blocking the reactant flow to the catalyst layer. This results in increased mass-transport losses. At higher temperatures, evaporation of water becomes a dominant water-removal mechanism and specifically phase-change-induced (PCI) flow is present due to thermal gradients. This study used synchrotron based micro X-ray computed tomography (CT) to visualize and quantify the water distribution within gas diffusion layers subject to a thermal gradient. Plotting saturation as a function of through-plane distance quantitatively shows water redistribution, where water evaporates at hotter locations and condenses in colder locations. The morphology of the 2 GDLs on the micro-scale, as well as evaporating water clusters, are resolved, indicating that the GDL voids are slightly prolate, whereas water clusters are oblate. From the mean radii of water distributions and visual inspection, it is observed that larger water clusters evaporate faster than smaller ones.

25 ENERGY STORAGE↗

A novel hybrid dual-temperature absorption refrigeration system: Thermodynamic, economic, and environmental analysis

The applications of multi-evaporator and low temperature refrigeration systems are growing rapidly, highlighting the necessity of developing new configurations that can be economically and environmentally attractive. In this study, a hybrid dual-evaporator absorption refrigeration system for refrigerating and freezing applications is proposed and evaluated from thermodynamic, economic, and environmental viewpoints. In the proposed system, two compressors were employed between the evaporators and absorbers to increase the absorbers pressure to a higher level. The detailed parametric study results demonstrated that only employing a compressor between the higher temperature evaporator and absorber is beneficial improving the coefficient of performance (COP) significantly. However, the economic results showed that the compressor should be implemented carefully because in most design and operating conditions, the required capital and operating costs outweigh the COP improvement. Under specified design conditions, integrating the second compressor with a pressure ratio of 2.5 significantly increased the COP from 0.404 to 0.624 while it caused an increase in the unit production cost of cooling (UPCC) from $\$0.211$/ton-hr to $\$0.228$/ton-hr. The use of flue gas as a heat input was found to have excellent potential to improve the economic and environmental performance of the system. A detailed comparison with a dual-temperature transcritical carbon dioxide refrigeration cycle from the literature demonstrated that, under similar conditions, the system of this study has a substantially lower UPCC than the system in the literature ($\$0.211$/ton-hr and $\$0.110$/ton-hr for the steam and waste heat driven systems against $\$0.457$/ton-hr). Altogether, the proposed system (with and without the compressor) of this study showed an excellent potential for dual-temperature refrigeration applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A conservative, interface-resolved, compressible framework for the modeling and simulation of liquid/gas phase change

This paper presents a method for simulating evaporation in a compressible, interface-resolved framework appropriate for modeling problems of engineering interest. In order to achieve robustness and broad applicability, the method has been designed to discretely enforce consistent mass and thermal energy transport at the phase interface, to globally conserve mass, momentum, and energy, and to be capable of modeling compressible and incompressible systems. Verification is performed via the Sod-shock test, one-dimensional heat conduction, evaporation from a planar interface, and evaporation of three-dimensional droplets. Convergence with increasing mesh resolution is demonstrated in all tested configurations, and conservation is maintained near machine precision for a translating droplet. Conservation and accurate phase change rates are preserved at the low numerical resolutions commonly encountered in engineering calculations. Following verification, the method is validated by comparison to an empirical correlation for evaporating droplets in high temperature crossflow, and the presentation concludes with the simulation of an iso-octane spray at conditions representative of gasoline direct injection. In conclusion, successful verification, validation, and demonstrated practical utility suggest the method to be an accurate, efficient, and robust approach for the study of phase change in engineering systems.

97 MATHEMATICS AND COMPUTING↗

Influence of surface relaxation on solute atoms positioning within atom probe tomography reconstructions

Highlights: • APT measurement of Al/Cu alloy is simulated with a combined electrostatics and molecular dynamics (MD) approach. • Results show segregation of dilute Cu at [111] poles in correspondence to experimental measurements. • No temperature is involved. The effect originates in both disparate evaporation field and bond-energies in the alloy. While thermal or field-induced surface migration has been invoked often in past literature to rationalize the experimental observations of solute and impurity atoms segregation to specific poles and zones lines in atom probe tomography (APT) reconstructions, it does not satisfactorily explain all experimental results. Using a combined finite-element and molecular dynamics simulation approach that models the field evaporation process from mechanically relaxed emitter structures, we show that an additional mechanism, athermal relaxation, can also drive significant solute migration. The mechanism is illustrated for Cu in solid solution in Al, which exhibits segregation of Cu to 111 poles and along [110] zone lines in reconstructed APT data. The higher bonding energy of Cu atoms on the surface, confirmed using density-functional theory calculations, causes longer retention on the surface and preferential evaporation of neighboring Al atoms with subsequent athermal relaxation of Cu into higher-neighbor-count sites left vacant by evaporating Al neighbors. This in turn results in barrier-free long-range migration of the Cu atoms by a series of relaxation events that follow the receding terrace ledges towards high-neighbor count poles and zone lines. This mechanism fundamentally limits spatial resolution in the limit of zero temperature.

36 MATERIALS SCIENCE↗

Three‐Moment Representation of Rain in a Bulk Microphysics Model

Abstract A bulk three‐moment representation for rain microphysics is developed and implemented in the Predicted Particle Properties (P3) microphysics scheme. In addition, a new parameterization for rain self‐collection and collisional breakup (RSCB) is presented using a lookup table approach, based on the Spectral‐Bin Model (SBM). To quantify the impacts of sedimentation, evaporation, and RSCB on drop size distributions (DSDs), a rain shaft model is applied to a wide range of atmospheric scenarios (i.e., initial conditions and regimes) and compared against results from the SBM. DSD shapes are mainly determined by both sedimentation and evaporation, except in heavy rain where the impact of RSCB on DSD shape becomes more important than evaporation. The new parameterization for RSCB has a considerable impact on the mean drop size, improving the agreement between P3 and SBM. Only 4% of the original two‐moment rainshaft simulations have mean drop sizes and rain rates within ±20% of the SBM results, but this increases to more than 95% agreement when the three‐moment rain representation is used together with the new parameterization for RSCB. Generally, the improvement is more significant for heavy rain than for light drizzle. Remaining differences between bin and bulk model are attributable to treatments of evaporation, and the restriction to gamma DSDs in P3.

precipitation↗

Estimating Future Surface Water Availability Through an Integrated Climate‐Hydrology‐Management Modeling Framework at a Basin Scale Under CMIP6 Scenarios

Abstract Climate change and increasing water demand due to population growth pose serious threats to surface water availability. The biggest challenge in addressing these threats is the gap between climate science and water management practices. Local water planning often lacks the integration of climate change information, especially with regard to its impacts on surface water storage and evaporation as well as the associated uncertainties. Using Texas as an example, state and regional water planning relies on the use of reservoir “Firm Yield” (FY)—an important metric that quantifies surface water availability. However, this existing planning methodology does not account for the impacts of climate change on future inflows and on reservoir evaporation. To bridge this knowledge gap, an integrated climate‐hydrology‐management (CHM) modeling framework was developed, which is generally applicable to river basins with geographical, hydrological, and water right settings similar to those in Texas. The framework leverages the advantages of two modeling approaches—the Distributed Hydrology Soil Vegetation Model (DHSVM) and Water Availability Modeling (WAM). Additionally, the Double Bias Correction Constructed Analogues method is utilized to downscale and incorporate Coupled Model Intercomparison Project Phase 6 GCMs. Finally, the DHSVM simulated naturalized streamflow and reservoir evaporation rate are input to WAM to simulate reservoir FY. A new term—“Ratio of Firm Yield” (RFY)—is created to compare how much FY changes under different climate scenarios. The results indicate that climate change has a significant impact on surface water availability by increasing reservoir evaporation, altering the seasonal pattern of naturalized streamflow, and reducing FY.

54 ENVIRONMENTAL SCIENCES↗

In situ measurements of plasma properties during gas-condensation of Cu nanoparticles

Since the mean, standard deviation, and modality of nanoparticle size distributions can vary greatly between similar input conditions (e.g., power and gas flow rate), plasma diagnostics were carried out in situ using a double-sided, planar Langmuir probe to determine the effect the plasma has on the heating of clusters and their final size distributions. The formation of Cu nanoparticles was analyzed using cluster-plasma physics, which relates the processes of condensation and evaporation to internal plasma properties (e.g., electron temperature and density). Monitoring these plasma properties while depositing Cu nanoparticles with different size distributions revealed a negative correlation between average particle size and electron temperature. Furthermore, the modality of the size distributions also correlated with the modality of the electron energy distributions. It was found that the maximum cluster temperature reached during plasma heating and the material's evaporation point regulates the growth process inside the plasma. In the case of Cu, size distributions with average sizes of 8.2, 17.3, and 24.9 nm in diameter were monitored with the Langmuir probe, and from the measurements made, the cluster temperatures for each deposition were calculated to be 1028, 1009, and 863 K. These values are then compared with the onset evaporation temperature of particles of this size, which was estimated to be 1059, 1068, and 1071 K. Thus, when the cluster temperature is too close to the evaporation temperature, less particle growth occurs, resulting in the formation of smaller particles.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Gauss-bonnet black holes and possibilities for their experimental search

Corollaries of gravity models with second-order curvature corrections in the form of a Gauss-Bonnet term and possibilities (or impossibilities) for their experimental search or observations are discussed. The full version of the four-dimensional Schwarzschild-Gauss-Bonnet black hole solution and the constraint on the possible minimal black hole mass following from this model are considered. Using our solution as a model for the final stages of Hawking evaporation of black holes with a low initial mass (up to 10{sup 15} g) whose lifetime is comparable to that of our Universe, we have revealed differences in the patterns of evaporation: we have obtained high values of the emitted energy and showed the impossibility of an experimental search for primordial black holes by their evaporation products. Scenarios for the evaporation of Gauss-Bonnet black holes in multidimensional gravity models and possibilities for their experimental search are also discussed.

79 ASTRONOMY AND ASTROPHYSICS↗