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At least 1,549 records · Page 86

Tension-compression asymmetry in superelasticity of SrNi 2 P 2 single crystals and the influence of low temperatures

ThCr 2 Si 2 -type intermetallic compounds are known to exhibit superelasticity associated with structural transitions through lattice collapse and expansion. These transitions occur via the formation and breaking of Si-type bonds, respectively, under uniaxial loading along the [0 0 1] direction. Unlike most ThCr 2 Si 2 -type intermetallic compounds, which have either an uncollapsed tetragonal structure or a collapsed tetragonal structure, SrNi 2 P 2 possesses a third type of collapsed structured: a one-third orthorhombic structure, for which one expects the occurrence of unique structural transitions and superelastic behavior. In this study, uniaxial compression and tension tests were conducted on micron-sized SrNi 2 P 2 single crystalline columns at room temperature, 200 K, and 100 K, to investigate the influence of loading direction and temperature on the superelasticity of SrNi 2 P 2 . Experimental data and density functional theory calculations revealed the presence of tension-compression asymmetry in the structural transitions and superelasticity, as well as an asymmetry in their temperature dependence, due to the opposite superelastic process associated with compression (forming P-P bonds) and tension (breaking P-P bonds). Additionally, following thermodynamics, the observations suggest that this asymmetric superelasticity could lead to an opposite elastocaloric effect between compression and tension, which could be beneficial potentially in obtaining large temperature changes compared to conventional superelastic solids that show the same elastocaloric effect regardless of loading direction. Furthermore, these results provide an important fundamental insight into the structural transitions, superelasticity processes, and potential elastocaloric effects in SrNi 2 P 2 .

36 MATERIALS SCIENCE↗

Effects of forward velocity on noise for a J85 turbojet engine with multitube suppressor from wind tunnel and flight tests

Flight tests and wind tunnel noise tests using a J85 engine with some representative jet exhaust noise suppressors are reported. Capabilities and limitations of the two types of experimental methods are evaluated with emphasis on investigation of forward velocity effects. The suppressor arrangement was a 104-elliptical-tube nozzle configuration, with or without an acoustically lined shroud. The suppressor noise levels are found not reduced as much by forward velocity as expected for unsuppressed jets. The directivity and forward velocity effects appear more similar to predicted trends for internally generated noise than for unsuppressed jet noise.

Stone, J. R.↗

Thrust vectoring for lateral-directional stability

The advantages and disadvantages of using thrust vectoring for lateral-directional control and the effects of reducing the tail size of a single-engine aircraft were investigated. The aerodynamic characteristics of the F-16 aircraft were generated by using the Aerodynamic Preliminary Analysis System II panel code. The resulting lateral-directional linear perturbation analysis of a modified F-16 aircraft with various tail sizes and yaw vectoring was performed at several speeds and altitudes to determine the stability and control trends for the aircraft compared to these trends for a baseline aircraft. A study of the paddle-type turning vane thrust vectoring control system as used on the National Aeronautics and Space Administration F/A-18 High Alpha Research Vehicle is also presented.

Peron, Lee R.↗

Microgravity effects of sea urchin fertilization and development

Gravity has been a pervasive influence on all living systems and there is convincing evidence to suggest that it alters fertilization and embryogenesis in several developmental systems. Notwithstanding the global importance of gravity on development, it has only been recently possible to begin to design experiments which might directly investigate the specific effects of this vector. The goal of this research program is to explore and understand the effects of gravity on fertilization and early development using sea urchins as a model system. Sea urchin development has several advantages for this project including the feasibility of maintaining and manipulating these cells during spaceflight, the high percentage of normal fertilization and early development, and the abundant knowledge about molecular, biochemical, and cellular events during embryogenesis which permits detailed insights into the mechanism by which gravity might interfere with development. Furthermore, skeletal calcium is deposited into the embryonic spicules within a day of fertilization permitting studies of the effects of gravity on bone calcium deposition.

Steffen, S.↗

Discontinuous Aligned Carbon Fiber Intermediates for Automotive and Related Applications

This work focused on preferentially aligning discontinuous carbon fibers in wet-laid or air-laid processes. It is well known that aligned fibers provides higher directional strength and stiffness. Discontinuous fibers further allow higher degree of draw and formability as the gaps in the fibers allow for higher material movement. The current processes are limited in their ability to align carbon fibers during processing. The aligned fibers have several benefits - (a) in applications where chopped fibers can replace continuous fibers for targeted strength and stiffness metrics, but at a substantially reduced cost; (b) they can tolerate deeper draws than continuous fiber composites in thermo-stamping and compression molding processes; (c) they can be tailored for pultrusion and unidirectional applications. Although pultrusion is primarily a process that adopts continuous fibers, stitch bonded entangled discontinuous fibers can provide unique intermediates. This is analogous to natural coir fibers which get aligned and entangled to produce ropes/rods for example, (d) they can be processed in cross-ply and multi-directional formats, like composite laminates. In this work Neenah Paper partnered with IACMI, UT and ORNL to evaluate structure-process-property relationships with Zoltek carbon fiber. A few process parameters such as machine speed, weight basis, fiber length, effect of fiber sizing, direction of mat lay-up etc. were investigated. The produced mats were converted to thermoplastic composite laminates using polyamide 6 (PA6, nylon) resin. The specific objective of this project is to produce a wet-laid nonwoven carbon fiber mat with a high degree of unidirectional fiber alignment, using discontinuous carbon fibers. The report provides details about the processing, characterization, and lower-upper bound properties.

36 MATERIALS SCIENCE↗

Achieving Diesel-Like Efficiency in a High Stroke-to-Bore Ratio DISI Engine under Stoichiometric Operation

This work explores pathways to achieve diesel-like, high-efficiency combustion with stoichiometric 3-way catalyst compatible spark ignition (SI). A high stroke-to-bore engine design (1.5:1) with cooled exhaust gas recirculation (EGR) and high compression ratio (r c ) was used to improve engine efficiency by up to 30% compared with a production turbocharged gasoline direct injection spark ignition engine. To achieve efficiency improvements, engine experiments were coupled with computational fluid dynamics simulations to guide and explain experimental trends between the original engine and the high stroke-to-bore ratio design (1.5:1). The effects of EGR and late intake valve closing (IVC) and fuel characteristics are investigated through their effects on knock mitigation. Direct injection of 91 RON E10 gasoline, 99 RON E0 gasoline, and liquified petroleum gas (i.e., propane/autogas) were evaluated with geometric rc ranging from 13.3:1 to 16.8:1. Finally, engine experiments demonstrated 47% gross thermal efficiency, and 45% net thermal efficiency at stoichiometric engine operation, at up to 17 bar IMEP and 2000 r/min with 16.8:1 rc.

42 ENGINEERING↗

Micropolar deep material network

This study extends the Deep Material Network (DMN), a physics-informed machine learning framework, to predict the homogenized mechanical response of composite materials with micropolar (Cosserat-type) constitutive behavior. This extension incorporates microstructure-dependent size effects, enabling accurate, efficient, and size-aware predictions for composites with complex internal architectures. While traditional, direct numerical simulation micropolar models effectively capture size effects by introducing extra local degrees of freedom, they bring significant computational challenges, particularly for multiscale analyses relevant to engineering applications. The micropolar DMN developed in this paper achieves high accuracy while significantly reducing computation time compared to micropolar direct numerical simulations. This advancement enables multiscale analyses and parameter studies that were previously impractical, such as high-cycle fatigue simulations and comprehensive investigations of internal length scale effects notably in size-dependent plastic response and the optimization of lattice structures. By uniting microstructure-sensitive modeling, physics-driven learning, and scalable surrogate modeling, the micropolar DMN paves the way for accelerated material design, large-scale parametric studies, and the reliable incorporation of size-dependent effects across a wide range of engineering applications, including optimization and next-generation composite design.

36 MATERIALS SCIENCE↗

An Analysis of Potentially Implementing Standardized Canisters in the U.S. Commercial Waste Management System

This analytical study focuses on loading standardized transportation, aging, and disposal canisters (STADs) at commercial reactor sites and subsequent transportation, e.g., to a consolidated interim storage facility (CISF). Specifically, the amount of spent nuclear fuel (SNF) available to load into STADs with varying deployment dates is explored, and the scenarios are compared with a scenario in which STADs are never loaded at reactor sites. Two key findings are that about half of the U.S. inventory of commercial SNF could be captured in STADs if they were fully deployed by 2035 and that the percentage of SNF available to load into STADs decreases as STAD deployment is delayed.In additional scenarios, the effects of shipping STADs directly from at-reactor spent fuel pools (SFPs) to a CISF are analyzed for a STAD full deployment year of 2035. A key finding from the analysis is that the dry storage of SNF in STADs at reactor sites can be minimized by direct shipment to a CISF from reactor site SFPs. Furthermore, minimizing dry storage at reactor sites means maximizing the receipt rate for STADs at a CISF, and there is likely a more optimal point between the two scenarios for an overall cost-effective operation of waste management systems.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Radiation model predictions and validation using LDEF satellite data

Predictions and comparisons with the radiation dose measurements on Long Duration Exposure Facility (LDEF) by thermoluminescent dosimeters were made to evaluate the accuracy of models currently used in defining the ionizing radiation environment for low Earth orbit missions. The calculations include a detailed simulation of the radiation exposure (altitude and solar cycle variations, directional dependence) and shielding effects (three-dimensional LDEF geometry model) so that differences in the predicted and observed doses can be attributed to environment model uncertainties. The LDEF dose data are utilized to assess the accuracy of models describing the trapped proton flux, the trapped proton directionality, and the trapped electron flux.

Armstrong, T. W.↗

Potential Applications of Satellite Based Low Frequency Microwave Measurements of Snow and Ice

In this presentation we will examine some potential applications of low frequency microwave radar and radiometer data to remote sensing of snow and ice conditions over land. We focus on the following low frequency bands; L-band (1.28 GHz), S-band (2.69 GHz), and C-band (5.0 GHz). To predict the effect of snow cover on microwave emission, we need to characterize the dielectric properties of the snow in terms of important physical parameters such as snow density, temperature, and wetness. For the case of dry snow, we use an empirical mixing formula which gives the effective complex permittivity of snow as a function of density, temperature, and frequency. For wet snow, we use another mixing formula which gives the effective complex permittivity as a function of snow wetness. With dry snow, the loss at low microwave frequencies is very small so the corresponding penetration depths are very large (eg., 100 m). Clearly seasonal snow covers are far too thin to have a direct scattering or emission effect on these low frequency bands. There are, however, indirect effects introduced because of altered reflection at the snow/soil boundary, and an extra reflecting interface at the snow/air boundary. For C-band, layers of snow with different densities can have an impact if the number of layers grows sufficiently large. (eg., many meters of snow pack with cm-scale density layering.) Wet snow poses a more difficult problem. Liquid water is much more effective than ice at scattering and absorbing L-band radiation, so even a small amount of wetness will greatly reduce penetration. For example, with a snow wetness of 1 percent (volume fraction), and a density of 300 kg/cu. m, the penetration depths for L-band, S-band, and C-band are about 1.6 m, 0.3 m, and 0.15 m respectively. Very wet snow has more than 10 percent liquid water, and the corresponding L-band penetration is less than 0.2 m. Because the penetration distance is a strong function of frequency, it may be possible to identify a particular class of snow where the wetness is a few percent, and the depth is around one meter by looking at the frequency gradient.

West, Richard D.↗

Effects of vertical fins near the nose of the fuselage on the directional and damping-in-yaw stability derivatives of an airplane model under steady-state and oscillatory conditions

A wind-tunnel investigation has been made at low speed to determine the effects of vertical fins placed ahead of the vertical tail on the directional stability and damping-in-yaw characteristics of a swept-wing model under steady-state oscillatory conditions. Various sizes of fins were used above and below the fuselage center line. The vertical-tail size also was varied.

STABILITY, DIRECTIONAL - STATIC↗

On the Equilibrium Electrostatic Potential and Light-Induced Charge Redistribution in Halide Perovskite Structures

Lead halide perovskites are semiconductor materials which are employed as nonintentionally doped absorbers inserted between two selective carrier transport layers (SCTL), realizing a p-i-n or n-i-p heterojunction. In our study, we have developed and investigated a lateral device, based on methylammonium lead iodide (MAPbI3) in which the p-i-n heterojunction develops in the horizontal direction. Our research suggests that the effective doping level in the MAPbI3 film should be very low, below 1012 cm-3. Along the vertical direction, this doping level is not enough to screen the electric field of the buried heterojunction with the SCTL. The perovskite work function is therefore affected by the work function of the SCTL underneath. From drift-diffusion simulations, we show that intrinsic perovskite-SCTL structures develop mV range surface photovoltages (SPVs) under continuous illumination. However, perovskite-SCTL structures can develop SPVs of hundreds of mV, as confirmed by our measurements. We therefore analyzed the compatibility between low doping and low defect densities in the perovskite layer and such high SPV values using numerical modeling. It is shown that these high SPV values could originate from electronic processes due to large band offsets in the buried perovskite-SCTL heterojunctions, or at the SCTL-transparent conductive oxide (TCO) buried heterojunction. However, such electronic processes can hardly explain the long SPV persistence after switching off the illumination.

defects↗

On the elastic properties of fiber composite laminates with statistically dispersed ply orientations

Structural application of advanced composite filamentary materials requires lamination of the basic orthotropic plies into angle-ply laminates. The resulting elastic and strength properties depend on the pattern of orientation and are influenced by inevitable errors and inaccuracy in placement of the angle plies. Reviewed is the effect on elastic properties of orientation dispersion. The conventional constitutive relations are recast in a homologous form to account for orientation dispersion by addition of a single parameter. Graphical results are presented to show the behavior of the most important advanced composite materials. The results are directly useful for estimating effects of manufacturing inaccuracy and for design of partially oriented reinforced structures.

Robinson, E. Y.↗

The effect of bromination of carbon fibers on the coefficient of thermal expansion of graphite fiber-epoxy composites

To examine the effect of bromination of carbon fibers on the coefficient of thermal expansion (CTE) of carbon fiber epoxy composites, several pristine and brominated carbon fiber-epoxy composite samples were subjected to thermomechanical analysis. The CTE's of these samples were measured in the uniaxial and transverse directions. The CTE was dominated by the fibers in the uniaxial direction, while it was dominated by the matrix in the transverse directions. Bromination had no effect on the CTE of any of the composites. In addition, the CTE of fiber tow was measured in the absence of a polymer matrix, using an extension probe. The results from this technique were inconclusive.

Jaworske, D. A.↗

Multi-Scale Analysis of Effective Mechanical Properties of 3D Woven Composite Materials

This work aims to compute and analyze the mechanical properties of 3D woven composite materials that share the same yarn structure but differ in their matrix porosity and fiber volume fraction. Assuming linear elastic behavior, the software PuMA, developed at NASA, was used to characterize the different composites from their constituents' data averaging their elastic properties in three main directions to obtain their effective orthotropic mechanical properties. This was performed in three steps: firstly, the different phases (yarns/matrix) were analyzed as anisotropic materials separately at the micro-scale; then, the results from these analyses were homogenized and used to obtain the anisotropic elasticity tensor at the meso-scale for the different woven materials; and finally, assuming orthotropic mechanical behavior for the unit cell the mechanical properties were obtained at the macro-scale. The 3D woven composite materials selected for this study are made of phenolic resin with porosity values between 0 and 0.6, and resin infiltrated carbon fiber with volume fractions between 0.5 and 0.9 for the yarns. Results from PuMA were validated with external FEA simulations for the non-porous 3D woven material with a fiber volume fraction of 0.9 in the yarns. Results will be included in the final paper after completing the study detailed in Section II.

Sergio Fraile Izquierdo↗

Anions Enhance Rare Earth Adsorption at Negatively Charged Surfaces

Anions are expected to be repelled from negatively charged surfaces. At aqueous interfaces, however, ion-specific effects can dominate over direct electrostatic interactions. Using multiple in situ surface sensitive experimental techniques, we show in this study that surface affinities of SCN – anions are so strong that they can adsorb at a negatively charged floating monolayer at the air–aqueous interface. This extreme example of ion-specific effects may be very important for understanding complex processes at aqueous interfaces, such as chemical separations of rare earth metals. Adsorbed SCN – ions at the floating monolayer increase the overall negative charge density, leading to enhanced trivalent rare earth adsorption. Surface sensitive X-ray fluorescence measurements show that the surface coverage of Lu 3+ ions can be triple the apparent surface charge of the floating monolayer in the presence of SCN – . Comparison to NO 3 – samples shows that the effects are strongly dependent on the character of the anion, providing further evidence of ion-specific effects dominating over electrostatics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the elastic properties of fiber composite laminates with statistically dispersed fiber and ply orientations.

Structural application of advanced composite filamentary materials requires lamination of the basic orthotropic plies into angle-ply laminates. This article reviews the effect on elastic properties of orientation dispersion. The conventional constitutive relations are recast in a homologous form to account for uniform orientation dispersion by addition of a single parameter. Graphical results are presented to show the behavior of the most important advanced composite materials. The results are directly useful for estimating effects of manufacturing inaccuracy and for design of partially oriented reinforced structures.

Robinson, E. Y.↗