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Biomass Resource Demand Characterization Study: Cooperative Research and Development Final Report, CRADA Number CRD-11-436

Competing demands for U.S. biomass resources and resulting impacts on regional feedstock availability could have a significant impact on the ability of the biofuels industry to transition to lower cost feedstocks, such as wood, agricultural residues, and energy crops, as well as on the ability of U.S. electric utilities and consumers to meet Renewable Portfolio Standards (RPS) and transition to lower carbon-footprint sources of electricity. Promulgation of regulations that place a cost on CO2 emissions from fossil fuels will also impact this situation as biomass to power applications become increasingly cost competitive. This increased competition for biomass feedstocks could create technical and economic risks for the Government, industry, and investors, and has the potential to impede commercialization of bio-energy in the U.S. at a meaningful scale.

09 BIOMASS FUELS↗

Drought-tolerant Biofuel Crops could be a Critical Hedge for Biorefineries

Numerous researchers and policymakers have raised concerns over the adverse effects that growing bioenergy crops on prime agricultural land has on food prices, carbon balances, water demand and environmental health. Biofuel policies such as the California Low Carbon Fuel Standard (LCFS) and the second US Renewable Fuel Standard (RFS2) already regulate biofuels for carbon emissions that occur due to indirect land use change. Biofuel producers can address these concerns and sidestep steep penalties for indirect land use change if they grow biofuel crops on land that has little or no economic value. The focus of most biofuel research over the last decade has been the development of biofuels from cellulosic feedstocks. It has been argued that deriving biofuels from non-food biomass, like switchgrass, and growing the crop on low value land would minimize competition with food production. Moreover, using non-irrigated rain-fed feedstocks can substantially reduce the lifecycle footprint of cellulosic biofuels. This has motivated scientists to study if biofuel crops can be genetically engineered to thrive on low-value, marginal lands. One example is the development of switchgrass genomics designed to enhance productivity. For a biofuel business, investing in the development of a product in expectation of a specific policy regime (i.e. the regulation of land use in fuel policy) is fraught with risk. While we believe that all fuel policies worldwide should reward biofuel crops grown on land that has little or no potential for growing food crops, there is good reason to believe that such globally coordinated policy on the subject of land use is unlikely. Hence, in this article, we assess the economic benefits of drought-tolerant switchgrass that may accrue to biofuel businesses independent of any incentives for the use of marginal land. The frequency of extreme weather and drought has increased in the U.S. over the last decade. While some researchers estimate that droughts are decreasing in severity and duration, most climate scientists report that advancing climate change is expected to worsen droughts throughout the U.S., especially in the Midwest, which is the nation’s largest producer of food crops. Scientists are increasingly convinced that climate change is leading to warmer extremes including severity of precipitation extremes. In the more likely scenario of worsening drought, we find that drought-tolerance of the cellulosic crop is critical for the biofuel industry to remain competitive, irrespective of whether the crop is grown on marginal or prime agricultural land. In other words, we find that over the lifetime of a typical biorefinery, there could be one or more years when a crop is likely to be severely diminished due to drought conditions, thereby driving cellulosic ethanol prices substantially higher than would otherwise be the case.

09 BIOMASS FUELS↗

Securing America’s Future. Realizing the Potential of the Department of Energy’s National Laboratories

The Department of Energy (DOE) laboratories are national assets that have contributed profoundly to the Nation’s security, scientific leadership, and economic competitiveness. In recognition of the continuing and evolving threats to our security and the dramatic increase in global economic and scientific competition, the laboratories are and will continue to be vitally important. Yet, the contributions of the National Laboratories are not inevitable, nor have they realized their full potential. This final report of the Commission to Review the Effectiveness of the National Energy Laboratories recommends ways the laboratories could overcome challenges to more efficiently and effectively accomplish the work for which they are uniquely suited.

99 GENERAL AND MISCELLANEOUS↗

Development and Implementation of Degree Programs in Electric Drive Vehicle Technology

The Electric-drive Vehicle Engineering (EVE) MS degree and graduate certificate programs have been continuing to make good progress, thanks to the funding and the guidance from DOE grant management group, the support from our University and College administrations, and to valuable inputs and feedback from our Industrial Advisory Board as well as our project partners Macomb Community College and NextEnergy. Table 1 below lists originally proposed Statement of Project Objectives (SOPO), which have all been completed successfully. Our program and course enrollments continue to be good and increasing, as shown in later sections. Our graduating students continue to get good job offers from local EV-related companies. Following the top recommendation from our Industrial Advisory Board, we were fortunate enough to be accepted into the prestigious EcoCAR2 (http://www.ecocar2.org/) North America university design competition, and have been having some modest success with the competition. But most importantly, EcoCAR2 offers the most holistic educational environment for integrating real-world engineering and design with our EVE graduate curriculum. Such integrations include true real-world hands-on course projects based on EcoCAR2 related tasks for the students, and faculty curricular and course improvements based on lessons and best practices learned from EcoCAR2. We are in the third and last year of EcoCAR2, and we have already formed a core group of students in pursuit of EcoCAR”3”, for which the proposal is due in early December.

33 ADVANCED PROPULSION SYSTEMS↗

A New Generation of Building Insulation by Foaming Polymer Blend Materials with CO 2

Advanced thermal insulation is among the most effective technologies in transforming our nation’s energy system and contributing to DOE’s stated goal of 50% less building energy consumption by 2030. The installation of an advanced thermal insulation would prevent energy waste without the need for any maintenance, and ISTN conservatively estimates that the commercialization of such a new technology would contribute to annual U.S. energy savings of 0.361 Quads and $8 billion in annual economic savings. The key challenge to improving building insulation is to maintain and surpass the industry standard of R-5 per inch insulation value in a cost-competitive manner. Improvements in R-value without cost-efficiency are not likely to impact the market given the cost-sensitive nature of the construction industry (insulation is already the lowest-cost component of the building envelope). However, significantly higher insulating value at competitive costs is extremely appealing to the market given the greater potential to save on energy consumption and costs over the long-term. Thus, our goal is to develop a super-thermal insulation with 50% greater insulation value (R-9 to R-10 per inch) and manufacturing costs that are equal on a per-R-value basis (< $0.70/ft 2 ).

36 MATERIALS SCIENCE↗

NSUF Irradiated Materials Library

The Nuclear Science User Facilities has been in the process of establishing an innovative Irradiated Materials Library concept for maximizing the value of previous and on-going materials and nuclear fuels irradiation test campaigns, including utilization of real-world components retrieved from current and decommissioned reactors. When the ATR national scientific user facility was established in 2007 one of the goals of the program was to establish a library of irradiated samples for users to access and conduct research through competitively reviewed proposal process. As part of the initial effort, staff at the user facility identified legacy materials from previous programs that are still being stored in laboratories and hot-cell facilities at the INL. In addition other materials of interest were identified that are being stored outside the INL that the current owners have volunteered to enter into the library. Finally, over the course of the last several years, the ATR NSUF has irradiated more than 3500 specimens as part of NSUF competitively awarded research projects. The Logistics of managing this large inventory of highly radioactive poses unique challenges. This document will describe materials in the library, outline the policy for accessing these materials and put forth a strategy for making new additions to the library as well as establishing guidelines for minimum pedigree needed to be included in the library to limit the amount of material stored indefinitely without identified value.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Subsurface Conditions Controlling Uranium Incorporation in Iron Oxides: A Redox Stable Sink

Toxic metals and radionuclides throughout the U.S. Department of Energy Complex pose a serious threat to ecosystems and to human health. Of particular concern is the redox-sensitive radionuclide uranium, which is classified as a priority pollutant in soils and groundwaters at most DOE sites owing to its large inventory, its health risks, and its mobility with respect to primary waste sources. The goal of this research was to contribute to the long-term mission of the Subsurface Biogeochemistry Program by determining reactions of uranium with iron (hydr)oxides that lead to long-term stabilization of this pervasive contaminant. The research objectives of this project were thus to (1) identify the (bio)geochemical conditions, including those of the solid-phase, promoting uranium incorporation in Fe (hydr)oxides, (2) determine the magnitude of uranium incorporation under a variety of relevant subsurface conditions in order to quantify the importance of this pathway when in competition with reduction or adsorption; (3) identify the mechanism(s) of U(VI/V) incorporation in Fe (hydr)oxides; and (4) determine the stability of these phases under different biogeochemical (inclusive of redox) conditions. Our research demonstrates that redox transformations are capable of achieving U incorporation into goethite at ambient temperatures, and that this transformation occurs within days at U and Fe(II) concentrations that are common in subsurface geochemical environments with natural ferrihydrites—inclusive of those with natural impurities. Increasing Fe(II) or U concentration, or initial pH, made U(VI) reduction to U(IV) a more competitive sequestration pathway in this system, presumably by increasing the relative rate of U reduction. Uranium concentrations commonly found in contaminated subsurface environments are often on the order of 1-10 μM, and groundwater Fe(II) concentrations can reach exceed 1 mM in reduced zones of the subsurface. The redox-driven U(V) incorporation mechanism may help to explain U retention in some geologic materials, improving our understanding of U-based geochronology and the redox status of ancient geochemical environments. Additionally, U(VI) may be incorporated within silicate minerals though encapsulation of U-bearing iron oxides, leading to a redox stable solid. Our research detailing previously unrecognized mechanism of U incorporation within sediment minerals may even lead to new approaches for in situ contamination remediation techniques, and will help refine models of U fate and transport in reduced subsurface zones.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the Path to SunShot. The Environmental and Public Health Benefits of Achieving High Solar Penetrations in the United States

Compared with fossil fuel generators, photovoltaics (PV) and concentrating solar power (CSP) produce far lower lifecycle levels of greenhouse gas (GHG) emissions and harmful pollutants including fine particular matter (PM2.5), sulfur dioxide (SO 2 ), and nitrogen oxides (NO x ). In this report, we monetize the emission reductions from achieving the U.S. Department of Energy's SunShot deployment goals: 14% of U.S. electricity demand met by solar in 2030 and 27% in 2050. We estimate that achieving these goals could reduce cumulative power-sector GHG emissions by 10% between 2015 and 2050, resulting in savings of $238-$252 billion. This is equivalent to 2.0-2.2 cents per kilowatt-hour of solar installed (cents/kWh-solar). Similarly, realizing these levels of solar deployment could reduce cumulative power-sector emissions of PM2.5 by 8%, SO 2 by 9%, and NOx by 11% between 2015 and 2050. This could produce $167 billion in savings from lower future health and environmental damages, or 1.4 cents/kWh-solar--while also preventing 25,000-59,000 premature deaths. To put this in perspective, this estimated combined benefit of 3.5 cents/kWh-solar due to SunShot-level solar deployment is approximately equal to the additional levelized cost of electricity reduction needed to make unsubsidized utility-scale solar competitive with conventional generators today. In addition, the analysis shows that achieving the SunShot goals could save 4% of total power-sector water withdrawals and 9% of total power-sector water consumption over the 2015-2050 period--a particularly important consideration for arid states where substantial solar will be deployed. These results have potential implications for policy innovation and the economic competitiveness of solar and other generation technologies.

14 SOLAR ENERGY↗

On the Path to SunShot. Emerging Issues and Challenges in Integrating High Levels of Solar into the Electrical Generation and Transmission System

This report examines how the bulk power system may need to evolve to accommodate the increased photovoltaic (PV) penetration resulting from achievement of the U.S. Department of Energy's SunShot cost targets. The variable and uncertain nature of PV-generated electricity presents grid-integration challenges. For example, the changing net load associated with high midday PV generation and low electricity demand can create 'overgeneration' that requires curtailment of PV output and reduces PV's value and cost-competitiveness. Accommodating the changes in net load resulting from increased variable generation requires enhancements to a power system's 'flexibility,' or ability to balance supply and demand over multiple time scales through options including changes in system operation, flexible generation, reserves from solar, demand response, energy storage, and enhanced transmission and regional coordination. For utility-scale PV with a baseline SunShot levelized cost of electricity (LCOE) of 6 cents/kWh, increasing the annual energy demand met by solar energy from 10% to 20% would increase the marginal LCOE of PV from 6 cents/kWh to almost 11 cents/kWh in a California grid system with limited flexibility. However, increasing system flexibility could minimize solar curtailment and keep PV cost-competitive at penetrations at least as high as 25%. In the longer term, energy storage technologies--such as concentrating solar power with thermal energy storage--could facilitate the cost-effective integration of even higher PV penetration. Efficient deployment of the grid-flexibility options needed to maintain solar's value will require various innovations, from the development of communication, control, and energy storage technologies to the implementation of new market rules and operating procedures.

14 SOLAR ENERGY↗

GRoW Buffalo Final Report

This document provides final reporting on the GRoW Home, University at Buffalo's entry to the 2015 Solar Decathlon competition in Irvine, CA. The report summarizes fundraising efforts, documents media outreach, lists online presence, analyzes the organizer's communication, describes post-competition life of the house and future employment plans for student team members. Last, it suggests improvements for future decathlons.

14 SOLAR ENERGY↗

On the Path to SunShot - Emerging Issues and Challenges in Integrating High Levels of Solar into the Electrical Generation and Transmission System

Increasing the use of grid-flexibility options (improved grid management, demand response, and energy storage) could enable 25% or higher penetration of PV at low costs (see Denholm et al. 2016). Considering the large-scale integration of solar into electric-power systems complicates the calculation of the value of solar. In fact a comprehensive examination reveals that the value of solar technologies—or any other power-system technology or operating strategy—can only be understood in the context of the generation system as a whole. This is well illustrated by analysis of curtailment at high PV penetrations within the bulk power and transmission systems. As the deployment of PV increases, it is possible that during some sunny midday periods due to limited flexibility of conventional generators, system operators would need to reduce (curtail) PV output in order to maintain the crucial balance between electric supply and demand. As a result, PV’s value and cost competitiveness would degrade. For example, for utility-scale PV with a baseline SunShot LCOE of 6¢/kWh, increasing the annual energy demand met by solar energy from 10% to 20% would increase the marginal LCOE of PV from 6¢/kWh to almost 11¢/kWh in a California grid system with limited flexibility. However, this loss of value could be stemmed by increasing system flexibility via enhanced control of variable-generation resources, added energy storage, and the ability to motivate more electricity consumers to shift consumption to lower-demand periods. The combination of these measures would minimize solar curtailment and keep PV cost-competitive at penetrations at least as high as 25%. Efficient deployment of the grid-flexibility options needed to maintain solar’s value will require various innovations, from the development of communication, control, and energy storage technologies to the implementation of new market rules and operating procedures.

14 SOLAR ENERGY↗

Manufacturing of Low Cost, Durable Membrane Electrode Assemblies Engineered for Rapid Conditioning

Over the past 20 years significant progress in membrane-electrode assembly (MEA) technology development for polymer electrolyte fuel cells (PEMFCs) has resulted in the PEMFC technology approaching a commercial reality for transportation applications. However, there remain two primary technical challenges to be addressed in the MEA. First and foremost is meeting the automotive cost targets: Producing a fuel cell stack cost competitive with today’s internal combustion engine. In addition to the material cost, MEA (and other components) and stack assembly production methods must be amenable for use in low cost, high speed, automotive assembly line. One impediment to this latter goal is that stack components must currently go through a long and tedious conditioning procedure before they produce optimal power. This so-called “break-in” can take many hours, and can involve quite complex voltage, temperature and/or pressure steps. These break-in procedures must be simplified and the time required reduced if fuel cells are to become a viable automotive engine. The second challenge is to achieve the durability targets in real-world automotive duty cycle operations. Significant improvements in cost, break-in time, and durability for the key component of fuel cell stacks, MEAs were achieved in this project. Advanced modeling was used to guide design of the new MEA to maximize performance and durability. A new, innovative process and manufacturing approach utilizing direct in-line coating using scalable, cost-competitive, continuous high volume 3-layer rolled-good manufacturing processes was developed and validated by single cell and short stack testing. In addition, the direct coating methods employed were shown to reduce the cost for sacrificial films. Furthermore, Gore has demonstrated a 10 µm reinforced membrane that is used in the new low-cost process and can meet automotive power density and durability targets. Across a wide range of operating conditions, the direct-coated MEA outperformed the commercial baseline MEA, and did so through a process that delivers MEAs at $92.35/m2 at a volume of 500,000 systems per year, according to Strategic Analysis (SA) estimates.

08 HYDROGEN↗

Low-Cost Bio-Based Carbon Fibers for High Temperature Processing

GrafTech International Holdings Inc. (GTI), under Award No. DE-EE0005779, worked with Oak Ridge National Laboratory (ORNL) under CRADA No. NFE-15-05807 to develop lignin-based carbon fiber (LBCF) technology and to demonstrate LBCF performance in high-temperature products and applications. This work was unique and different from other reported LBCF work in that this study was application-focused and scalability-focused. Accordingly, the executed work was based on meeting criteria based on technology development, cost, and application suitability. High-temperature carbon fiber based insulation is used in energy intensive industries, such as metal heat treating and ceramic and semiconductor material production. Insulation plays a critical role in achieving high thermal and process efficiency, which is directly related to energy usage, cost, and product competitiveness. Current high temperature insulation is made with petroleum based carbon fibers, and one goal of this protect was to develop and demonstrate an alternative lignin (biomass) based carbon fiber that would achieve lower cost, CO2 emissions, and energy consumption and result in insulation that met or exceeded the thermal efficiency of current commercial insulation. In addition, other products were targeted to be evaluated with LBCF. As the project was designed to proceed in stages, the initial focus of this work was to demonstrate lab-scale LBCF from at least 4 different lignin precursor feedstock sources that could meet the estimated production cost of $5.00/pound and have ash level of less than 500 ppm in the carbonized insulation-grade fiber. Accordingly, a preliminary cost model was developed based on publicly available information. The team demonstrated that 4 lignin samples met the cost criteria. In addition, the ash level for the 4 carbonized lignin samples was below 500 ppm. Processing as-received lignin to produce a high purity lignin fiber was a significant accomplishment in that most industrial lignin, prior to purification, had greater than 4X the ash level needed for this project, and prior to this work there was not a clear path of how to achieve the purity target. The lab scale development of LBCF was performed with a specific functional application in mind, specifically for high temperature rigid insulation. GTI is a consumer of foreign-sourced pitch and rayon based carbon fibers for use in its high temperature insulation products, and the motivation was that LBCF had potential to decrease costs and increase product competitiveness in the marketplace through lowered raw material costs, lowered energy costs, and decreased environmental footprint. At the end of this project, the Technology Readiness Level (TRL) remained at 5 for LBCF in high temperature insulation.

09 BIOMASS FUELS↗

User’s Guide for Biodegradation Reactions in TMVOCBio

TMVOCBio is an extended version of the TMVOC numerical reservoir simulator, with the capability of simulating multiple biodegradation reactions mediated by different microbial populations or based on different redox reactions, thus involving different electron acceptors. This modeling feature is implemented within the existing TMVOC module in iTOUGH2. TMVOCBio, originally developed by Battistelli (2003; 2004), uses a general modified form of the Monod kinetic rate equation to simulate biodegradation reactions, which effectively simulates the uptake of a substrate while accounting for various limiting factors (i.e., the limitation by substrate, electron acceptor, or nutrients). Two approaches are included: 1) a multiple Monod kinetic rate equation, which assumes all the limiting factors simultaneously affect the substrate uptake rate, and 2) a minimum Monod model, which assumes that the substrate uptake rate is controlled by the most limiting factor among those acting for the specific substrate. As the limiting factors, biomass growth inhibition, toxicity effects, as well as competitive and non-competitive inhibition effects are included. The temperature and moisture dependence of biodegradation reactions is also considered. This report provides mathematical formulations and assumptions used for modeling the biodegradation reactions, and describes additional modeling capabilities. Detailed description of input format for biodegradation reactions is presented along with sample problems.

59 BASIC BIOLOGICAL SCIENCES↗

HPC Innovation Center Feasibility Assessment Final Report CRADA No. TC02172.0

This was a collaborative effort between Lawrence Livermore National Security, LLC as manager and operator of Lawrence Livermore National Laboratory (LLNL) and IBM TJ Watson Research Center to research, assess feasibility and develop an implementation plan for a High Performance Computing Innovation Center (HPCIC) in the Livermore Valley Open Campus (LVOC). The ultimate goal of this work was to help advance the State of California and U.S. commercial competitiveness in the arena of High Performance Computing (HPC) by accelerating the adoption of computational science solutions, consistent with recent DOE strategy directives. The desired result of this CRADA was a well-researched, carefully analyzed market evaluation that would identify those firms in core sectors of the US economy seeking to adopt or expand their use of HPC to become more competitive globally, and to define how those firms could be helped by the HPCIC with IBM as an integral partner.

97 MATHEMATICS AND COMPUTING↗

A new class of tandems: Optically coupled III-V/silicon module with outdoor efficiency exceeding 30%

The aim of this project was to introduce a new class of technology—that of high-efficiency silicon-based tandem photovoltaic (PV) modules—that, with follow-on development, has a clear path to reduced levelized cost of electricity (LCOE) for utility-scale power generation. In particular, the objective of the project was to demonstrate the first 30%-efficient III-V/silicon module in outdoor conditions using a tandem geometry in which the sub-cells are detached physically but coupled optically. In present PV power plants installed in the US, the module makes up only approximately one-third of the cost; area-dependent balance-of-systems (BOS) costs such as installation materials, labor, land, and site prep made up an additional third, and area-independent BOS costs round out the final third. With this pricing structure, (annually averaged) module efficiency is a clear market driver: increase the annual energy output per module and the effective costs translated into $/W of both the module and the area-dependent BOS—two-thirds of the total cost—decrease proportionately. However, the dominant PV technology—flat-plate silicon modules—is reaching its theoretical efficiency limit, and thus a tandem technology in which silicon is coupled with a wider-bandgap cell is a promising route to remain responsive to market forces. As it is not trivial to couple silicon with other cells in conventional two-terminal geometries due to, e.g., lattice mismatch, this project introduced a new, four-terminal configuration using a “PVMirror.” A PVMirror utilizes PV cells as a three-in-one technology—they act as a concentrating mirror, spectrum splitter, and high-efficiency light-to-electricity converter. Light is incident upon a full-aperture dichroic mirror that reflects visible light and transmits infrared light. The transmitted light is absorbed in silicon PV cells that are placed behind the dichroic mirror and that convert IR photons to electricity with high efficiency. The dichroic mirror and silicon PV cells are affixed to a curved glass trough that tracks the sun about a single, North-South axis such that the reflected VIS light is concentrated at a common line focus, at which is placed a second, wider-bandgap GaAs PV cell having high efficiency at shorter wavelengths. The innovation of PVMirrors lies in their design, which maximizes annual energy output and minimizes the constraints placed on the sub-cells. In particular, the cells are free of lattice- and current-matching restrictions, neither cell requires a transparent rear electrode, and either sub-cell can be placed at the focus depending on their relative costs. Furthermore, the greatest benefit of PVMirrors is that they make use of a portion of the diffuse light whereas concentrator tandems cannot. This results in a benefit in energy yield and extends PVMirrors’ competitive range. Over the course of this one-year project, a silicon PVMirror and GaAs receiver were fabricated, characterized, and placed outdoors on a sun tracker, where the efficiency of the tandem “module” was measured for three days. Notable results include the first demonstration of this flexible tandem configuration, a maximum tandem efficiency of 29.6% (just shy of the 30% overall project goal), successful conversion of diffuse light into electricity, a thorough loss analysis indicating a path to over 31% efficiency, and a roadmap to cost-competitive PVMirror tandems using a wide-bandgap polycrystalline PVMirror and a silicon receiver. Development of a >18%-efficient wide-bandgap polycrystalline cell—the key enabler of this envisioned tandem—should be a future research focus. This project has laid the groundwork for a PV technology that, with continued development, has the potential to reach LCOEs as low as $0.03/kWh according to our calculations. Such a system would provide the public with inexpensive, clean solar power.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

2017 Alabama PV Soft Cost and Workforce Development

In 2016, the first comprehensive analysis of the solar market in Alabama was conducted. The market was found to be immature, but price competitive with other parts of the Southeast and the nation. A second survey was completed one year later in 2017 to help understand the changes in trends and changes in the solar market in AL over the calendar. AL is one of three states without comprehensive net metering legislation, yet remains cost competitive with other states around the US and the Southeast. Residential systems average 2.4/W DC, which is considerably lower than the nationwide median of 4/W. Commercial systems cost an average of 2.15/W-DC, which is also below the national median of 2.30/W for nonresidential systems over 500 kW.

14 SOLAR ENERGY↗

Lignite-plus-Biomass to Synthetic Jet Fuel with CO2 Capture and Storage: Design, Cost, and Greenhouse Gas Emissions Analysis for a Near-Term First-of-a-Kind Demonstration Project and Prospective Future Commercial Plants

We report on a 30-month design study for a first-of-a-kind (FOAK) demonstration plant that would be built at a site near Meridian, Mississippi, to coprocess lignite coal and woody biomass into jet fuel. The design uses an oxygen-blown TRIG™ gasifier developed by KBR and Southern Company. Fischer-Tropsch conversion of the syngas produces synthetic paraffinic kerosene (SPK) as the primary product, plus naphtha. Other co-products include electricity sold to the grid and CO 2 sold for use in enhanced oil recovery (EOR). Previous studies have identified coprocessing of various coals and biomass with CO 2 capture as promising options for cost-competitive production of low net lifecycle greenhouse gas (GHG) emissions synthetic fuels. The effort reported here goes beyond earlier studies in the level of detail in process design and cost estimation with the aim of improving the understanding of the economic prospects for lignite and woody biomass coprocessing systems. Key objectives in the design of the FOAK lignite/biomass-to-jet (LBJ) plant were to achieve net lifecycle GHG emissions for the SPK that are less than for conventional petroleum-derived jet fuel and to make process design and equipment selections such that the plant could be built and operated in the near term, e.g., before 2025. The process design was developed by researchers at Princeton University and the University of Queensland and validated by engineers at the WorleyParsons Group (WP). Commercial vendors provided design and cost estimates for several major plant components. Bare-erected capital costs and operating and maintenance costs were estimated by WP. The primary objective in building and operating the FOAK plant would be to demonstrate the technical viability of the LBJ concept as an essential first step toward launching commercial-scale plants in the longer term. With this in mind, the project team developed a set of principles to help guide the process design: the total plant cost should be less than 2 billion USD (to limit investment risk); the level of input biomass should be both proportionally significant to reflect biomass/lignite co-gasification and sufficient to achieve GHG emissions goals; process design decisions and vendor/equipment selections should prioritize the likelihood of technical success over minimizing the cost of jet fuel production. The resulting FOAK plant design capacity is 1,551 metric t/d (45.5% moisture) lignite and 556 t/d (43.3% moisture) biomass, for a total input of 295 MW HHV , of which 25% is biomass. The design output is 1,252 actual barrels per day of liquids, of which 80% is SPK (62.3 MW LHV ) and 20% is naphtha (13.9 MW LHV ). It exports 15 MW e of electricity after satisfying a 38 MW e onsite auxiliary load. Additional products are 1,326 t/d of pressurized pipeline-quality CO 2 and 49 t/day of sulfuric acid (93 wt% H 2 SO 4 ). With thinnings from sustainably-managed southern pine plantations as the biomass, and with captured CO 2 stored underground via EOR, the net lifecycle emissions for the SPK product are estimated to be about one-quarter of those for petroleum-derived jet fuel. The bare-erected cost (BEC) estimated by WP for this plant is 588 million USD (2015). The authors’ best estimate of total plant cost (TPC) is 1,230 million USD, arrived at by assuming engineering, procurement and construction management services (20% of BEC), process 5 contingencies (35% of BEC), and project contingencies (35% of the sum of all other costs, i.e., 35% of 1.55xBEC). Not surprisingly, an annual discounted cash flow (DCF) analysis determined that it would be impossible to generate a positive net present value (NPV) over a wide range in key input assumptions. An SPK production cost subsidy of nearly 400/bbl USD over a 20-year plant life would be required to achieve zero NPV under a baseline set of assumptions (including 3% real weighted average cost of capital and a levelized crude oil price of 80/bbl USD). Alternatively, a capital grant in excess of the TPC value would also achieve zero NPV. The poor financial results reflect the small scale of the plant, the design principle to prioritize technical success, the levels of contingencies appropriate for the relatively early stage of project development, and the first-of-a-kind nature of the plant. Technology innovations, learning via construction and operating experience, alternative plant configurations, and larger scale should improve economics of future plants. To help understand these prospects, a preliminary analysis of N th -of-a-kind (NOAK) plants was developed, but with the limitation that plants would use only equipment components that for the most part are already commercial today: consideration of advanced, not-yet-commercial technologies and of R&D-driven improvements in existing technologies were beyond the scope of this analysis. The analysis found that a variety of NOAK plant designs that coprocess lignite and woody biomass to make jet fuel are unlikely to be economically competitive without subsidy even in the presence of a high future carbon tax or equivalent greenhouse gas mitigation policy. This conclusion applies to process configurations and input biomass/lignite ratios that result in net GHG emissions as high as those for petroleum-derived jet fuel and as low as zero. In contrast, encouraging results were found for plants processing only biomass. The economics of these “BECCS” plants (biomass energy with CCS) improve dramatically with the strength of carbon mitigation policies because of their strongly negative net GHG emissions. These findings do not imply that coal/biomass coprocessing strategies for making synfuels with CCS are not economically promising – only that, in the case of lignite, much more than a 25% biomass coprocessing rate would be needed. However, our analysis shows that all such systems are unlikely to be economic in the absence of a strong carbon mitigation policy. Future R&D driven technological innovations could modify this conclusion. Among other R&D priorities, an emphasis on better understanding and reducing plant auxiliary loads is warranted.

09 BIOMASS FUELS↗