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At least 1,549 records · Page 86

Pore-Scale Transport Effects in Electrochemical CO 2 Reduction on Gold via Coupled Microkinetic-Transport Modeling

A pore-resolved modeling framework is developed to quantify how pore-scale transport affects the intrinsic microkinetics of CO 2 -to-CO on Au. A DFT-informed microkinetic model is coupled self-consistently to a Generalized-Modified Poisson–Nernst–Planck (GMPNP) transport description in a single, electrolyte-filled cylindrical pore, allowing local concentrations and potential to feed back into site-specific reaction rates. FIB-SEM is used to determine pore sizes within realistic electrode materials. Across pore diameters, d p = 10–6000 nm, the surface-averaged CO 2 reduction rate is systematically reduced relative to the ideal microkinetic baseline where mass transport is not accounted for; the effectiveness factor 𝜂 𝑠,CO 2 , which quantifies this ratio, decreases rapidly at more negative potentials and is about 1% near −1.0 V vs SHE due to reactant depletion. Spatial maps reveal pore-bulk alkalization that emerges at higher cathodic bias, with a small, near-wall pH dip due to electrostatic repulsion of hydroxide at the cathode interface. For a fixed aspect ratio L p /d p , narrower pores exhibit larger 𝜂 𝑠,CO 2 by shortening diffusion paths, whereas variations in the aspect ratio L p /d p play a secondary role. A dimensionless analysis (surface/bulk Damköhler numbers) delineates operating regimes. In conclusion, this work offers a concept for incorporating microkinetic models into homogenized porous-electrode models through effectiveness factors and pore-size distribution.

Au-catalyst↗

Assessment of Vertical Mesh Refinement in Concurrently Nested Large-Eddy Simulations Using the Weather Research and Forecasting Model

To facilitate multiscale simulation using the Weather Research and Forecasting Model, vertical mesh refinement for one-way concurrent nested simulation was recently introduced. Grid refinement in the vertical dimension removes the requirement of different grid aspect ratios on the bounding versus the nested domain, such that results from refinement are in the horizontal directions only, and thereby can also reduce numerical errors on the bounding domain arising from large aspect ratios in the presence of complex terrain. Herein, the impacts of vertical grid refinement on the evolving downstream flow in nested large-eddy simulations are evaluated in relation to other model configuration choices, including turbulence subfilter-scale (SFS) stress models, mesh configuration, and alternative methods for calculating several near-surface flow parameters. Although vertical nesting requires coarsening of the vertical grid on the bounding domain, leading to a smaller range of resolved turbulence scales in the nest’s lateral boundary conditions, parameter values within the nested domains are generally only minimally impacted, relative to nesting using the same vertical grid on each domain. Two dynamic SFS models examined herein generally improved the simulated mean wind speed, turbulence kinetic energy, stresses and spectra, on both domains, and accelerated equilibration rates within nested domains, relative to two constant coefficient models. A new method of extrapolating horizontal velocity components to near-surface locations at nested domain lateral boundaries, and a correction to the calculation of deformation elements near the surface, are each shown to slightly alter the mean parameter values, yet only minimally impact equilibration rates within the nested domain.

14 SOLAR ENERGY↗

Advanced System Design Requirements for Large and Small Fixed-wing Aerial Application Systems for Agriculture

Several candidate aircraft configurations were defined over the range of 1000 to 10,000 pounds payload and evaluated over a broad spectrum of agricultural missions. From these studies, baseline design points were selected at 3200 pounds payload for the small aircraft and 7500 pounds for the large aircraft. The small baseline aircraft utilizes a single turboprop powerplant while the large aircraft utilizes two turboprop powerplants. These configurations were optimized for wing loading, aspect ratio, and power loading to provide the best mission economics in representative missions. Wing loading of 20 lb/sq ft was selected for the small aircraft and 25 lb/sq ft for the large aircraft. Aspect ratio of 8 was selected for both aircraft. It was found that a 10% reduction in engine power from the original configurations provided improved mission economics for both aircraft by reducing the cost of the turboprop. Refined configurations incorporate a 675 HP engine in the small aircraft and two 688 HP engines in the large aircraft.

Hinely, J. T., Jr.↗

Rough-wall turbulent boundary layers in the transition regime

An experimental investigation of turbulent boundary layers over two-dimensional spanwise groove and three-dimensional sandgrain roughnesses in the transition regime between hydraulically smooth and fully rough conditions is presented. It is found that a self-preserving state can be reached in boundary layers developing over both d-type groove and sandgrain roughnesses, and that the drag of a k-type rough wall can be reduced by lowering the spanwise aspect ratio of the roughness elements. The two roughness Reynolds numbers defining the boundaries of the transition regime of the k-type roughnesses are shown to decrease with increasing roughness-element spanwise aspect ratio, and the upper critical transition Reynolds number is shown to determine the roughness behavior in both the transition and fully rough regime.

Bandyopadhyay, Promode R.↗

Overview of the Integrated Adaptive Wing Technology Maturation Wind-Tunnel Test Objectives

The Integrated Adaptive Wing Technology Maturation wind-tunnel test is the culmination of a cooperative effort between NASA and Boeing to develop control techniques that can improve the performance and safety of higher aspect ratio flexible transport aircraft. The wind-tunnel test article, to be tested at the NASA Langley Research Center Transonic Dynamics Tunnel, is a semispan model of a modern transport configuration with an aspect ratio 13.5 wing based on the NASA Common Research Model. Multiobjective control laws have been developed targeting drag optimization, maneuver load alleviation, gust load alleviation, and modal suppression. In this paper, the integrated model design, active control system, and sensor suite will be presented, and pretest modeling and characterization activities will be described. A summary of the planned wind-tunnel test entries will provide an overview of the experimental approach and expected outcomes.

wind-tunnel↗

Thermoset composite having thermoplastic characteristics

A composite composition includes a thermoset resin and about 3 wt. % to about 35 wt. % of at least one material selected from the group consisting of cellulose nanofibrils (CNF), micro-sized cellulose fibers (MFC), and cellulose nanocrystals (CNC) dispersed therein as measured with respect to the overall weight of the composite composition. The cellulose nanofibrils and/or nanocrystals have an average diameter of about 5 nm to about 500 nm and an average aspect ratio in the range of about 5:1 to about 500:1. The cellulose micro-sized fibers have an average diameter of about 5 μm to about 100 μm and an average aspect ratio in the range of about 5:1 to about 250:1.

Ozcan, Soydan↗

Test of Point-Source Helicity Injection for Non-Solenoidal Startup in NSTX

This grant supported research activity focused on the development of Local Helicity Injection (LHI) as a technique for initiation and growth of spherical tokamak plasmas without the use of a traditional ohmic solenoid for magnetic induction. The LHI technique consists of injection of high-density current streams into a vacuum magnetic field consisting of toroidal and vertical fields. Under appropriate conditions, these streams become unstable and support magnetic reconnection to allow the system to reconfigure itself into a tokamak-like plasma magnetic configuration. This research program focused on three aspects of this plasma startup technique: 1) development and tests of appropriate electron current sources that provide sufficiently high injection currents into the near-plasma edge without strongly contaminating the resultant tokamak plasma with impurities; 2) development and validation of a 0-D power balance model to describe the evolution of the plasma current I p (t) during this startup process; and 3) initial estimates of I p levels achievable with this technique in NSTX-U scale plasmas. The 0-D model development included extremely low aspect ratio corrections to analytical formulae for the plasma inductances that produce voltages due to rapid changes in plasma size and location. Applications of this model to sample plasmas in the Pegasus ultra-low aspect ratio tokamak confirms the expectation that I p (t) is dominated by these induced voltages when injection occurs from the outer low-field side of the plasma. Conversly, I p (t) is dominated by an effective toroidal loop voltage arising from helicity conservation when injectors are placed in the inner high-field side divertor region. The activities pursued here, combined with more general research on LHI followed by the Pegasus experiment group, provide the tools needed for initial consideration of a MA-level plasma startup capability for the NSTX-U experiment. Simplified modeling for LHI on NSTX-U indicates that no showstoppers exist, and ~ 0.8MA appears accessible using a moderate current injection facility. However, many issues remain to be resolved to address extrapolating this technique to the larger sizes and magnetic field strengths of NSTX-U and larger fusion-grade tokamaks. These include, among others: I p scaling with helicity drive input; extending current injector technology; understanding electron confinement and the resulting helicity dissipation processes that determine the achievable I p ; the role of plasma stability in controlling the current evolution; and controlling plasma-material interactions and impurity content. These open issues will be further explored in a future experiment dedicated to integrated studies of non-solenoidal startup at higher magnetic fields and plasma currents.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Validation of the Poisson Stochastic Radiative Transfer Model

A new approach to validation of the Poisson stochastic radiative transfer method is proposed. In contrast to other validations of stochastic models, the main parameter of the Poisson model responsible for cloud geometrical structure - cloud aspect ratio - is determined entirely by matching measurements and calculations of the direct solar radiation. If the measurements of the direct solar radiation is unavailable, it was shown that there is a range of the aspect ratios that allows the stochastic model to accurately approximate the average measurements of surface downward and cloud top upward fluxes. Realizations of the fractionally integrated cascade model are taken as a prototype of real measurements.

Zhuravleva, Tatiana↗

Model Rotor Hover Performance at Low Reynolds Number

Hover performance data from four key experiments has been analyzed in detail to shed some light on model rotor hover performance at low Reynolds number. Each experiment used the simplest blade geometry. The blades were constant chord and untwisted. Three experiments used blades with the NACA 0012 airfoil from root to tip. The NACA 0015 was used in the earliest test. The four experiments provide data spanning a Reynolds number range of 136,500 to 548,700. The specific objective of this report is to ask and answer two questions: 1. Does blade aspect ratio influence hover performance or is rotor solidity the fundamental rotor geometry parameter for practical engineering purposes? ANSWER: Rotor solidity is the fundamental rotor geometry parameter for practical engineering purposes. Any effect of blade aspect ratio appears to be such a secondary variable that its effect lies within the range of experimental error. 2. Is Reynolds number a significant factor in scaling up hover performance to full-scale rotor performance? The answer is twofold. ANSWER: (a) Reynolds number effects on the increase of power with thrust do not appear to be a significant factor for practical engineering purposes, and (b) Reynolds number effects on minimum profile power at or very near zero rotor thrust could not be clearly established primarily because the low torque levels could not be accurately measured with the test equipment used. This has led to significant data scatter. A number of other observations can be made based on the analysis provided herein. For instance: 1. The test matrices used in the four key references contained far too few data points. A collective pitch variation of four or five data points is insufficient to establish experimental accuracy and data repeatability. 2. A common property of the power-versus-thrust (raised to the 3/2 exponent) graphs was that this curve was linear below the onset of blade stall. 3. The blade-to-blade interference at or near zero thrust may, in fact, be creating a turbulent flow field such that the effective Reynolds number at a blade element is considerably greater than what theories using two-dimensional (2D) airfoil properties at a blade element would calculate. 4. Definitive experiments answering the two key questions have yet to be made.

Model Rotor Hover Performance↗

Some effects of tip fins on wing flutter characteristics

A wind tunnel investigation has been conducted over the Mach number range from about 0.6 to 1.2 to determine the effects of large tip fins on the flutter characteristics of a swept wing. The basic wing configuration had an aspect ratio of 0.95, leading-edge sweep of 40 deg 0, and trailing-edge sweep of 21 deg. Two of these configurations were modified with tip fins of 60 deg dihedral and had effective aspect ratios of 1.5 and 2.2. In general, the results indicate that the addition of tip fins reduces the flutter speed, with the larger fin having the greater effect. Comparison of the experimental flutter speeds at Mach numbers between 0.60 and 0.90 with calculated values obtained by using doublet-lattice unsteady aerodynamic theory was good. Analytical results where structural and aerodynamic effects of the tip fins were isolated indicated that the reduction in flutter speed produced by the addition of the fins was caused by both effects, with the structural effect being the more pronounced.

Goetz, R. C.↗

Palladium-Percolated Networks Enabled by Low Loadings of Branched Nanorods for Enhanced H 2 Separations

Nanoparticles (NPs) at high loadings are often used in mixed matrix membranes (MMMs) to improve gas separation properties, but they can lead to defects and poor processability that impede membrane fabrication. Herein, it is demonstrated that branched nanorods (NRs) with controlled aspect ratios can significantly reduce the required loading to achieve superior gas separation properties while maintaining excellent processability, as demonstrated by the dispersion of palladium (Pd) NRs in polybenzimidazole for H 2 /CO 2 separation. Increasing the aspect ratio from 1 for NPs to 40 for NRs decreases the percolation threshold volume fraction by a factor of 30, from 0.35 to 0.011. An MMM with percolated networks formed by Pd NRs at a volume fraction of 0.039 exhibits H 2 permeability of 110 Barrer and H 2 /CO 2 selectivity of 31 when challenged with simulated syngas at 200 °C, surpassing Robeson's upper bound. In conclusion, this work highlights the advantage of NRs over NPs and nanowires and shows that right-sizing nanofillers in MMMs is critical to construct highly sieving pathways at minimal loadings. In conclusion, this work paves the way for this general feature to be applied across materials systems for a variety of chemical separations.

36 MATERIALS SCIENCE↗

Tailoring magnetization reversal of a single-domain bar nanomagnet via its end geometry

Nanoscale single-domain bar magnets are building blocks for a variety of fundamental and applied mesoscopic magnetic systems, such as artificial spin ices, magnetic shape-morphing microbots, and magnetic majority logic gates. The magnetization reversal switching field of the bar nanomagnets is a crucial parameter that determines the physical properties and functionalities of their constituted artificial systems. Previous methods on tuning the magnetization reversal switching field of a bar nanomagnet usually relied on modifying its aspect ratio, such as its length, width, and/or thickness. Here, we show that the switching field of a bar nanomagnet saturates when extending its length beyond a certain value, preventing further tailoring of the magnetization reversal via aspect ratios. We showcase a highly tunable switching field of a bar nanomagnet by tailoring its end geometry without altering its size. This provides an easy method to control the magnetization reversal of a single-domain bar nanomagnet. It would enable new research and/or applications, such as designing artificial spin ices with additional tuning parameters, engineering magnetic microbots with more flexibility, and developing magnetic quantum-dot cellular automata systems for low power computing.

36 MATERIALS SCIENCE↗

Stability and transport of gyrokinetic critical pedestals

Abstract A gyrokinetic threshold model for pedestal width–height scaling prediction is applied to multiple devices. A shaping and aspect ratio scan is performed on National Spherical Torus Experiment (NSTX) equilibria, finding Δ ped = 0.92 A 1.04 κ − 1.24 0.38 δ β θ , ped 1.05 for the wide-pedestal branch with pedestal width Δ ped , aspect ratio A , elongation κ , triangularity δ , and normalized pedestal height β θ , ped . The width–transport scaling is found to vary significantly if the pedestal height is varied either with a fixed density or fixed temperature, showing how fueling and heating sources affect the pedestal density and temperature profiles for the kinetic-ballooning-mode (KBM) limited profiles. For an NSTX equilibrium, at fixed density, the wide branch is Δ ped = 0.028 ( q e / Γ e − 1.7 ) 1.5 ∼ η e 1.5 and at fixed temperature Δ ped = 0.31 ( q e / Γ e − 4.7 ) 0.85 ∼ η e 0.85 , where q e and Γ e are turbulent electron heat and particle fluxes and η e = ∇ ln ⁡ T e / ∇ ln ⁡ n e for an electron temperature T e and density n e . Pedestals close to the KBM limit are shown to have modified turbulent transport coefficients compared to the strongly driven KBMs. The role of flow shear is studied as a width–height scaling constraint and pedestal saturation mechanism for a standard and lithiated wide pedestal discharge. Finally, the stability, transport, and flow shear constraints are combined and examined for an NSTX experiment.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

On the two-dimensional modelling of horizontal CVD reactors and its limitations

In order to clarify under what conditions two-dimensional theoretical models can realistically account for the actual growth rate distribution in horizontal CVD reactors, a systematic numerical study was performed, and the results were compared with published experimental data for the MOCVD of gallium arsenide. Three models of increasing complexity were studied. It is shown that two-dimensional models can produce realistic predictions only for reactors with large width-to-height (aspect) ratios, that are operated at subcritical Rayleigh number,i.e., under dominant forced flow conditions. But even then, depending on the carrier gas, thermal (Soret) diffusion must be included in the model. Furthermore, velocity corrections for finite aspect ratios must be made, and buoyancy effects can be significant in the entrance region. On the other hand, the results are relatively insensitive to axial diffusion, temperature dependence of transport properties (versus averaged properties), and an assumed Poiseuille velocity profile (versus a rigorous solution of the velocity field). Yet, boundary layer approximations are prone to give unrealistic results at the low Reynolds numbers typical for CVD operations.

Ouazzani, Jalil↗

Effect of Tube Geometry on Regenerative Cooling Performance

The flowfield characteristics in a rocket engine coolant channels are analyzed by use of a commercial CFD and multiphysics software developed by the CFD Research Corp. called CFD-ACE+. The channels are characterized by high Reynolds number flow, varying aspect ratio, varying curvature, asymmetric and symmetric heating. The supercritical hydrogen coolant introduces large property variations that have a strong influence on the developing flow and the resulting heat transfer. This paper only shows the effect of aspect ratio and curvature for constant properties.

Parris, Daniel K.↗

Carbon Nanofiber-Based, High-Frequency, High-Q, Miniaturized Mechanical Resonators

High Q resonators are a critical component of stable, low-noise communication systems, radar, and precise timing applications such as atomic clocks. In electronic resonators based on Si integrated circuits, resistive losses increase as a result of the continued reduction in device dimensions, which decreases their Q values. On the other hand, due to the mechanical construct of bulk acoustic wave (BAW) and surface acoustic wave (SAW) resonators, such loss mechanisms are absent, enabling higher Q-values for both BAW and SAW resonators compared to their electronic counterparts. The other advantages of mechanical resonators are their inherently higher radiation tolerance, a factor that makes them attractive for NASA s extreme environment planetary missions, for example to the Jovian environments where the radiation doses are at hostile levels. Despite these advantages, both BAW and SAW resonators suffer from low resonant frequencies and they are also physically large, which precludes their integration into miniaturized electronic systems. Because there is a need to move the resonant frequency of oscillators to the order of gigahertz, new technologies and materials are being investigated that will make performance at those frequencies attainable. By moving to nanoscale structures, in this case vertically oriented, cantilevered carbon nanotubes (CNTs), that have larger aspect ratios (length/thickness) and extremely high elastic moduli, it is possible to overcome the two disadvantages of both bulk acoustic wave (BAW) and surface acoustic wave (SAW) resonators. Nano-electro-mechanical systems (NEMS) that utilize high aspect ratio nanomaterials exhibiting high elastic moduli (e.g., carbon-based nanomaterials) benefit from high Qs, operate at high frequency, and have small force constants that translate to high responsivity that results in improved sensitivity, lower power consumption, and im - proved tunablity. NEMS resonators have recently been demonstrated using topdown, lithographically fabricated ap - proaches to form cantilever or bridgetype structures. Top-down approaches, however, rely on complicated and expensive e-beam lithography, and often require a release mechanism. Reso - nance effects in structures synthesized using bottom-up approaches have also recently been reported based on carbon nanotubes, but such approaches have relied on a planar two-dimensional (2D) geometry. In this innovation, vertically aligned tubes synthesized using a bottom- up approach have been considered, where the vertical orientation of the tubes has the potential to increase integration density even further. The simulation of a vertically oriented, cantilevered carbon nanotube was performed using COMSOL Multi - physics, a finite element simulation package. All simulations were performed in a 2D geometry that provided consistent results and minimized computational complexity. The simulations assumed a vertically oriented, cantilevered nanotube of uniform density (1.5 g/cu cm). An elastic modulus was assumed to be 600 GPa, relative permittivity of the nanotube was assumed to be 5.0, and Poisson s ratio was assumed to be 0.2. It should be noted that the relative permittivity and Poisson s ratio for the nanotubes of interest are not known accurately. However, as in previous simulations, the relative permittivity and Poisson s ratios were treated as weak variables in the simulation, and no significant changes were recognized when these variables were varied.

Kaul, Anupama B.↗

Near-axis expansion of stellarator equilibrium at arbitrary order in the distance to the axis

A direct construction of equilibrium magnetic fields with toroidal topology at arbitrary order in the distance from the magnetic axis is carried out, yielding an analytical framework able to explore the landscape of possible magnetic flux surfaces in the vicinity of the axis. This framework can provide meaningful analytical insight into the character of high-aspect-ratio stellarator shapes, such as the dependence of the rotational transform and the plasma beta limit on geometrical properties of the resulting flux surfaces. The approach developed here is based on an asymptotic expansion on the inverse aspect ratio of the ideal magnetohydrodynamics equation. The analysis is simplified by using an orthogonal coordinate system relative to the Frenet–Serret frame at the magnetic axis. The magnetic field vector, the toroidal magnetic flux, the current density, the field line label and the rotational transform are derived at arbitrary order in the expansion parameter. Moreover, a comparison with a near-axis expansion formalism employing an inverse coordinate method based on Boozer coordinates (the so-called Garren–Boozer construction) is made, where both methods are shown to agree at lowest order. Finally, as a practical example, a numerical solution using a W7-X equilibrium is presented, and a comparison between the lowest-order solution and the W7-X magnetic field is performed.

Physics↗

Hammerhead, an ultrahigh resolution ePix camera for wavelength-dispersive spectrometers

Wavelength-dispersive spectrometers (WDS) are often used in synchrotron and FEL applications where high energy resolution (in the order of eV) is important. Increasing WDS energy resolution requires increasing spatial resolution of the detectors in the dispersion direction. The common approaches are not ideal: using strip detectors loses the 2D position sensitivity (important for, e.g., background estimation) and the high counting rate; using pixel detectors with a small pitch results in complex charge sharing behaviour and typically have a small size. Developing pixel detectors with high aspect ratio and a small pitch in the wavelength dispersive direction would be ideal, however, it would require a substantial ASIC development. We present a new approach, with a novel sensor design using rectangular pixels with a high aspect ratio (between strips and pixels, further called “strixels”), and strixel redistribution to match the square pixel arrays of typical ASICs. This results in a sensor area of 17.4 mm × 77 mm, with a fine pitch of 25 µm in the horizontal direction resulting in 3072 columns and 176 rows. The sensors use ePix100 readout ASICs, leveraging their low noise (43 e - , or 180 eV rms). We present results obtained with a Hammerhead ePix100 camera, showing that the small pitch (25 µm) in the dispersion direction maximizes performance for both high and low photon occupancies, resulting in optimal WDS energy resolution. The low noise level at high photon occupancy allows precise photon counting, while at low occupancy, both the energy and the subpixel position can be reconstructed for every photon, allowing an ultrahigh resolution (in the order of 1 µm) in the dispersion direction and rejection of scattered beam and harmonics. Using strixel sensors with redistribution and flip-chip bonding to standard ePix readout ASICs results in ultrahigh position resolution (~1 µm) and low noise in WDS applications, leveraging the advantages of hybrid pixel detectors (high production yield, good availability, relatively inexpensive) while minimizing development complexity through sharing the ASIC, hardware, software and DAQ development with other versions of ePix cameras.

47 OTHER INSTRUMENTATION↗