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Tethered balloon-borne observations of thermal-infrared irradiance and cooling rate profiles in the Arctic atmospheric boundary layer

Clouds play an important role in controlling the radiative energy budget of the Arctic atmospheric boundary layer. To quantify the impact of clouds on the radiative heating or cooling of the lower atmosphere and of the surface, vertical profile observations of thermal-infrared irradiances were collected using a radiation measurement system carried by a tethered balloon. We present 70 profiles of thermal-infrared radiative quantities measured in summer 2020 during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition and in autumn 2021 and spring 2022 in Ny-Ålesund, Svalbard. Measurements are classified into four groups: cloudless, low-level liquid-bearing cloud, elevated liquid-bearing cloud, and elevated ice cloud. Cloudless cases display an average radiative cooling rate of about —2 K d—1 throughout the atmospheric boundary layer. Instead, low-level liquid-bearing clouds are characterized by a radiative cooling up to —80 K d—1 within a shallow layer at cloud top, while no temperature tendencies are identified underneath the cloud layer. Radiative transfer simulations are performed to quantify the sensitivity of radiative cooling rates to cloud microphysical properties. In particular, cloud top cooling is strongly driven by the liquid water path, especially in optically thin clouds, while for optically thick clouds the cloud droplet number concentration has an increased influence. Additional radiative transfer simulations are used to demonstrate the enhanced radiative importance of the liquid relative to ice clouds. To analyze the temporal evolution of thermal-infrared radiation profiles during the transitions from a cloudy to a cloudless atmosphere, a respective case study is investigated.

54 ENVIRONMENTAL SCIENCES↗

Monitoring of Liquid Metal Reactor Heater Zones with Recurrent Neural Network Learning of Temperature Time Series

Advanced high-temperature fluid reactors (ARs), such as sodium fast reactors (SFRs) and molten salt cooled reactors (MSCRs) utilize high-temperature fluids at ambient pressure. To melt the fluid during reactor startup and prevent fluid freezing during cooldown, the thermal–hydraulic systems of such ARs include heater zones consisting of specific heaters with controllers, temperature sensors, and thermal insulation. The failure of heater zones due to insulation material degradation or improper installation, resulting in parasitic heat losses, can lead to fluid freezing. The detection of faults using a heat-transfer model is difficult because of a lack of knowledge of the experimental details. Data-driven machine learning of heater zone temperature time series offers a viable alternative. In this study, we benchmarked the performance of recurrent neural networks (RNNs) in an analysis of heat-up transient temperature time series of heater zones installed on a liquid sodium vessel. The RNN models include long short-term memory (LSTM) and gated recurrent unit (GRU) networks, as well as their bi-directional variants, BiLSTM and BiGRU. Anomalous temperature points were designated using a percentile-based threshold applied to residual fluctuations in the detrended temperature time series. Additionally, the impact of the exponentially weighted moving average (EWMA) method on detection accuracy was examined. The RNN models’ performance was assessed using precision, recall, and F 1 score metrics. Results demonstrated that RNN models effectively detect anomalies in temperature time series with the best models for each heater zone achieving F 1 scores of over 93%. To explain the variations in RNN model performance across different heater zones, we used Kullback–Leibler (KL) divergence to quantify the relative entropy between training and testing data, and the Detrended Fluctuation Analysis (DFA) to assess long-range temporal correlations. For datasets with strong long-range correlations and minimal relative entropy between training and testing data, GRU is the best-performing model. When the data exhibits weaker long-term correlations and a significant relative entropy between training and testing distributions, BiGRU shows the best performance. For the data sets with intermediate values of both KL divergence and DFA, the best performance is obtained with LSTM and BiLSTM, respectively.

gated recurrent unit↗

Early season prediction of within-field crop yield variability by assimilating CubeSat data into a crop model

Accurate early season predictions of crop yield at the within-field scale can be used to address a range of crop production, management, and precision agricultural challenges. While the remote sensing of within-field insights has been a research goal for many years, it is only recently that observations with the required spatio-temporal resolutions, together with efficient assimilation methods to integrate these into modeling frameworks, have become available to advance yield prediction efforts. Here we explore a yield prediction approach that combines daily high-resolution CubeSat imagery with the APSIM crop model. The approach employs APSIM to train a linear regression that relates simulated yield to simulated leaf area index (LAI). That relationship is then used to identify the optimal regression date at which the LAI provides the best prediction of yield: in this case, approximately 14 weeks prior to harvest. Instead of applying the regression on satellite imagery that is coincident, or closest to, the regression date, our method implements a particle filter that integrates CubeSat-based LAI into APSIM to provide end-of-season high-resolution (3 m) yield maps weeks before the optimal regression date. The approach is demonstrated on a rainfed maize field located in Nebraska, USA, where suitable collections of both imagery and in-situ data were available for assessment. The procedure does not require in-field data to calibrate the regression model, with results showing that even with a single assimilation step, it is possible to provide yield estimates with good accuracy up to 21 days before the optimal regression date. Yield spatial variability was reproduced reasonably well, with a strong correlation to independently collected measurements (R 2 = 0.73 and rRMSE = 12%). When the field averaged yield was compared, our approach reduced yield prediction error from 1 Mg/ha (control case based on a calibrated APSIM model), to 0.5 Mg/ha (using satellite imagery alone), and then to 0.2 Mg/ha (results with assimilation up to three weeks prior to the optimal regression date). Such a capacity to provide spatially explicit yield predictions early in the season has considerable potential to enhance digital agricultural goals and improve end-of-season yield predictions.

54 ENVIRONMENTAL SCIENCES↗

Rapid AI-based Dissection of Ashes using Raman and XRF Spectroscopy (RADAR-X)

Waste-to-energy (WTE) facilities incinerate ~35 million tons of municipal solid waste annually in the United States. The incineration process reduces the mass and the volume of the waste fraction by over 75 and 95%, respectively. The fraction left after incineration remains as ash residues and is referred to as WTE ash, compromising of bottom and fly ash. In the United States, ~10 million tons of WTE ashes are generated annually and predominantly landfilled because of the lack of secondary end-use pathways. This incurs a significant financial burden (landfilling costs) on U.S. WTE facilities and also results in the loss of materials to the landfill. The primary objective of this research is to understand better the elemental and mineralogical composition of WTE ashes from diverse origins and find composition dependent upcycling pathways for diverting these ashes from landfills. This primary objective was addressed through three research tasks –(Task I) An AI-led Multi-Modal Approach for Compositional Analysis, (Task II) Developing a Dissolution-Based Test for Real Time Analysis, and (Task III) Establishing composition-dependent end uses. The chemical composition of WTE ash is dependent on two factors, i.e., the input waste composition and the operational parameters of a WTE facility (combustion conditions). Amongst these two factors, the input waste composition will likely show spatial and temporal variation. As a result, the chemical composition of WTE ash will also fluctuate. To understand the spatial and temporal variation in WTE ash composition, in Task I, we collected 128 ash samples (62 bottom ash and 66 fly ash samples) from 11 WTE facilities located in 11 U.S. states and characterized them via X-ray Fluorescence, powder X-ray Diffraction, and Raman Spectroscopy. The findings from this extensive characterization work indicated that the key elements in WTE fly ashes are Ca, Cl (greater than 10 wt. %), Si, S, K, Zn ( between 1 and 10 wt. %), Mg, Al, P, Ti, Fe, Cu, Br, and Pb (between 0.1 and 1 wt. %). Similarly, the key elements in WTE bottom ash fraction finer than 45μm are Ca (greater than 10 wt. %), Mg, Al, Si, S, Cl, K, Ti, Fe, Zn (between 1 and 10 wt. %), P, V, Cr, Mn, Cu, Br, and Pb (between 0.1 and 1 wt. %). Here, we note that the dominant fraction of WTE bottom ash is the coarse fraction. The coarse WTE bottom ash fraction (rich in silicon) was not characterized in this study because of excessive grinding requirements and their unsuitability as a supplementary cementitious material due to their coarse nature. The elements in WTE bottom ashes are present as calcite, anhydrite, vaterite, hydroxyapatite, quartz, bassanite, gehlenite, akermanite, hydrocalumite, and portlandite. Similarly, the mineralogical species present in WTE fly ashes are calcium chloride hydroxide, halite, calcite, anhydrite, sylvite, hydrocalumite, vaterite, hannebachite, quartz, and bassanite. Temporal variation in ash composition may also result in significant fluctuations in chemical compositions. Therefore, a WTE facility may need to monitor the ash composition (elemental and mineralogical composition) in real time. In Task I, we evaluated the possibility of using a portable X-ray fluorescence (XRF) spectrometer to monitor the elemental composition in real-time. Specifically, we collected XRF data on identical specimens via a portable XRF spectrometer (low-end) and a lab-based benchtop XRF spectrometer (high-end). The collected data was used to train an A.I. algorithm (portable XRF data as an input and benchtop XRF data as an output) to predict accurate elemental composition using portable XRF data. Finally, we developed a 2-minute photobleaching protocol to monitor the mineralogical characteristics of WTE ashes via Raman spectroscopy. Overall, the activities in Task I improved our understanding of ash composition and developed techniques to monitor elemental and mineralogical composition in near real-time. Based on the findings of Task I, we find that WTE ashes exhibit wide variability in mineralogy. For ICP-based elemental analysis, all the mineralogical species in WTE ashes must be brought into solution. This is traditionally accomplished with acid digestion using a combination of multiple acids. However, acid digestion with multiple acids is time-consuming and often fails to ensure complete digestion of the ash matrix. To address this limitation, in Task II, we developed an alkali-fusion-based digestion protocol using a combination of lithium tetraborate, lithium metaborate, and their combinations as possible alkali fluxes for digesting WTE ashes entirely and rapidly. The validity of the developed method was evaluated on two standard ash specimens, i.e., SRM 1633c coal fly ash and BCR-176R incineration fly ash specimen. The findings suggest that the developed protocol can ensure complete digestion of elements such as Al, Ba, Ca, Cr, Cu, Mg, Mn, P, Sr, V, Zn, Be, K, and rare earth elements. The recent changes in the energy market towards renewables and increased metal recycling have resulted in reduced supplies of supplementary cementitious materials (coal fly ash and slag). Therefore, in Task III, we evaluated the possibility of employing WTE ashes as SCMs. As the chemical composition of WTE ashes varies temporally (on an hourly basis), there was also a need to develop tests that can evaluate the suitability of material to act as supplementary cementitious material rapidly, i.e., in a few minutes. Therefore, in Task II, we also developed a rapid test to assess the suitability of a material to act as an SCM in 5 minutes. This represents a significant advance over the state-of-the-art R 3 test, which takes ~144 hours. This test was initially validated on amorphous aluminosilicates, such as calcined clays, and could be extended to evaluate other industrial by-products, such as WTE ashes. In Task III, we evaluated the possibility of employing WTE ashes for two applications, i.e., as an SCM and a lime substitute for clay stabilization. The findings from Task I indicated that WTE ashes are enriched in chlorine and, therefore, cannot be used directly as an SCM due to corrosion-related risks and altered hydration kinetics. Accordingly, we developed an ash treatment protocol to reduce the solubility of chlorine-containing species in WTE ashes. The developed treatment protocol also immobilized lead in certain mineral forms. As a result of the treatment, WTE ashes can be used as SCMs without any corrosion or heavy metal leaching concerns. The second application examined in this study was clay stabilization. WTE ashes are calcium-rich and can be an adequate lime replacement for clay stabilization. Our findings reveal that the sum of the concentrations of Ca(OH) 2 and CaClOH controls the clay stabilization capability of WTE ashes. In summary, in this work, we evaluated the elemental and mineralogical characteristics of U.S. WTE ashes from diverse origins and developed tests to evaluate the chemical characteristics of these ashes in real time through a portable XRF and a benchtop Raman spectrometer. Based on the chemical characteristics of these ashes, we developed an ash treatment process to enable the use of WTE ashes as an SCM and also evaluated the possibility of employing these ashes for clay stabilization. Overall, the findings from this work enables the diversion of WTE ashes from landfills for multiple end-uses, i.e., as an SCM or a lime substitute for clay stabilization.

36 MATERIALS SCIENCE↗

Study on Application of Distributed Network of Sensors with List Mode for NMAC Literature Review

Nuclear material accounting and control (NMAC) for nuclear security detects, deters, and resolves questions related to unauthorized removal (i.e. theft) or misuse of nuclear material. NMAC also serves as a key insider threat mitigation measure and aids in recovery of nuclear material that is missing. Effective nuclear security depends on NMAC for timely and accurate information about nuclear material types, quantities, and locations. Bulk nuclear material processing facilities, however, present unique challenges for effective NMAC due to the presence of large quantities of material in-process and the accumulation of residual material holdup within process equipment. These holdup accumulations can obscure accurate physical inventory taking and complicate efforts to resolve NMAC irregularities at the facility level. Bulk material monitoring systems often rely on material balance calculations and indirect measurement techniques, which may mask protracted theft of smaller amounts of nuclear material. These monitoring limitations have generated increased interest in continuous monitoring technologies, including distributed non-destructive assay (NDA) sensor networks capable of providing real-time or near-real-time measurement of material movement and accumulation within bulk processing environments. Recent advancements in distributed networks of NDA radiation detectors and sensing technologies provide an opportunity to address these limitations. Although such distributed sensor networks have been implemented in select facilities for IAEA Safeguards applications, their potential for supporting NMAC functions specifically tailored to nuclear security objectives remains largely unexplored. Furthermore, emerging list-mode data acquisition technologies have reached high technology readiness levels, enabling time-correlated detection of nuclear events across multiple temporal scales. These capabilities provide enhanced opportunities for accurate holdup measurement, continuous process monitoring, and improved detection of material theft or misuse over time. The increasing global expansion of civil nuclear power and development of related bulk material processing facilities, including those supporting high-assay low-enriched uranium (HALEU) and other advanced reactor fuel fabrication, further increases the need for advanced measurement and monitoring strategies for NMAC.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Dust pollution in China affected by different spatial and temporal types of El Niño

Dust is an important aerosol affecting air quality in China in the winter and spring seasons. Dust in China is potentially influenced by the interannual climate variability associated with El Niño. Here, the impacts of El Niño with different temporal and spatial types on dust pollution in boreal winter and spring in China and the potential mechanisms are investigated using a state-of-the-art Earth system model (E3SMv1). We find that the eastern Pacific (EP) and central Pacific (CP) El Niño both increase wintertime dust concentrations by 5–50 µg m –3 over central-eastern China. Due to a stronger wind and lower relative humidity, which favor dust emissions near sources, and a strengthened northwesterly and reduced precipitation, which are conducive to dust transport, dust concentrations during the CP El Niño are 5–20 µg m –3 higher in northern China than during the EP El Niño, although the changes are mostly insignificant. El Niño with a short duration (SD) increases boreal winter dust concentrations by 20–100 µg m –3 over northern China relative to the climatological mean, while there is a decrease of 5–50 µg m –3 during the long-duration (LD) El Niño, which is also related to the El Niño-induced changes in atmospheric circulation, precipitation, and relative humidity. In the following spring season, all types of El Niño events enhance dust over northern China, but only the increase during the LD El Niño is statistically significant, suggesting that the weaker intensity but longer duration of the LD El Niño events can significantly affect spring dust in China. Our results contribute to the current knowledge of the influence of El Niño on dust pollution, which has profound implications for air pollution control and dust storm prediction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Role of Lightning in Controlling Interannual Variability of Tropical Tropospheric Ozone and OH and its Implications for Climate

Nitrogen oxides (NO(x) = NO + NO2) produced by lightning make a major contribution to the production of the dominant tropospheric oxidants (OH and ozone). These oxidants control the lifetime of many trace gases including long-lived greenhouse gases, and control the source-receptor relationship of inter-hemispheric pollutant transport. Lightning is affected by meteorological variability, and therefore represents a potentially important tropospheric chemistry-climate feedback. Understanding how interannual variability (IAV) in lightning affects IAV in ozone and OH in the recent past is important if we are to predict how oxidant levels may change in a future warmer climate. However, lightning parameterizations for chemical transport models (CTMs) show low skill in reproducing even climatological distributions of flash rates from the Lightning Imaging Sensor (LIS) and the Optical Transient Detector (OTD) satellite instruments. We present an optimized regional scaling algorithm for CTMs that enables sufficient sampling of spatiotemporally sparse satellite lightning data from LIS to constrain the spatial, seasonal, and interannual variability of tropical lightning. We construct a monthly time series of lightning flash rates for 1998-2010 and 35degS-35degN, and find a correlation of IAV in total tropical lightning with El Nino. We use the IAV-constraint to drive a 9-year hindcast (1998-2006) of the GEOS-Chem 3D chemical transport model, and find the increased IAV in LNO(x) drives increased IAV in ozone and OH, improving the model fs ability to simulate both. Although lightning contributes more than any other emission source to IAV in ozone, we find ozone more sensitive to meteorology, particularly convective transport. However, we find IAV in OH to be highly sensitive to lightning NO(x), and the constraint improves the ability of the model to capture the temporal behavior of OH anomalies inferred from observations of methyl chloroform and other gases. The sensitivity of OH is explained using photochemical reaction rates which show a "magnification" effect of the initial lightning NO perturbation on OH primary production, HO(x) recycling, and OH loss frequencies. This influence on OH may represent a negative feedback, if lightning increases in a warming world..

Murray, Lee T.↗

A Small Spacecraft Swarm Deployment and Stationkeeping Strategy for Sun-Earth L1 Halo Orbits

Spacecraft orbits about the Sun-Earth librarian point L1 have been of interest since the 1950s. An L1 halo orbit was first achieved with the International Sun-Earth Explorer-3 (ISEE-3) mission, and similar orbits around Sun-Earth L1 were achieved in the Solar and Heliospheric Observatory (SOHO), Advanced Composition Explorer (ACE), Genesis, and Deep Space Climate Observatory (DSCOVR) missions. With recent advancements in CubeSat technology, we envision that it will soon be feasible to deploy CubeSats at L1. As opposed to these prior missions where one large satellite orbited alone, a swarm of CubeSats at L1 would enable novel science data return, providing a topology for intersatellite measurements of heliophysics phenomena both spatially and temporally, at varying spatial scales.The purpose of this iPoster is to present a flight dynamics strategy for a swarm of numerous CubeSats orbiting Sun-Earth L1. The presented method is a coupled, two-part solution. First, we present a deployment strategy for theCubeSats that is optimized to produce prescribed, time-varying intersatellite baselines for the purposes of collectingmagnetometer data as well as radiometric measurements from cross-links. Second, we employ a loose controlstrategy that was successfully applied to SOHO and ACE for minimized stationkeeping propellant expenditure. Weemphasize that the presented solution is practical within the current state-of-the-art and heritage CubeSat technology,citing capabilities of CubeSat designs that will launch on the upcoming Exploration Mission 1 (EM-1) to lunar orbitsand beyond. Within this iPoster, we present animations of the simulated deployment strategy and resulting spacecrafttrajectories. Mission design parameters such as total v required for long-term station keeping andminimum/maximum/mean spacecraft separation distances are also presented.

Optimal control↗

Separating Spatial and Temporal Variations of the Aurora Using Two Nearly Colocated Satellites

This final report describes the efforts accomplished during the grant's period of performance, covering the period of 1 May 1997 to 30 April 2001, of a NASA Supporting Research and Technology Program grant under the Ionospheric, Thermospheric, and Mesospheric Physics component of the Sun-Earth Connections program. We have met and exceeded the goals set forth in the proposed research objectives. Referred publications have appeared in the scientific literature and several others are in the review process. In addition, numerous invited and contributed presentations of these studies were presented at national and international meetings during the performance period. One graduate student completed his PhD and won two AGU Best Student Paper awards based on research funded by this grant. These studies are summarized below. The science goal delineated in the initial proposal was "to systematically explore the temporal and spatial characteristics of the aurora in a way heretofore impossible, using data from two coplanar DMSP spacecraft." We accomplished this goal through a series of related studies. One study used these unique data to establish the role of Ps6 waves in coupling between the magnetosphere and the auroral ionosphere (omega bands) during the recovery phase of a magnetic storm; the published paper demonstrated the causal relationships between geospace processes occurring in different regions and established a simple conceptual model based on the fortuitous constellation of observations. In the second string of papers, we used these data to explore velocity-dispersed ions (VDIS) in and near the cusp, to test region identification models, and to look at space/time structure of auroral precipitation. On the first topic, the unique DMSP data revealed a remarkable double VDIS with a latitudinal overlap. This could only be explained in terms of a unified reconnection geometry that builds on several earlier unrelated models. The paper outlining this discovery has drawn considerable attention from the community and is currently in press - it adds significantly to the debate over whether reconnection is study state versus bursty and patchy versus global. The second paper develops the model further by incorporating the electron signature - these ionospheric particle precipitation signatures reveal the presence of magnetospheric "fossilized" FTEs, demonstrating the power of ionospheric measurements as a remote diagnostic of magnetospheric processes. Finally, the general nature of aurora] stability and coherence and region identification by particle characteristics were fully explored in a final paper. We identify candidate mechanisms controlling coherence time scales and length scales and refine boundary region identification criteria. We also use the dual-DMSP observations to identify the open and closed LLBL region and related its significance to the generalized bursty, multiple x-line model developed in the first paper. All of these topics are chapters of Dr. Boudouridis' recently completed PhD thesis.

Spence, Harlan E.↗

Sea Surface Salinity Distribution in the Southern Ocean as Observed from Space

Large-scale spatial and temporal variabilities of sea surface salinity (SSS) in the Southern Ocean from 2011 to 2017 were studied using products derived from microwave sensors on board Aquarius, Soil Moisture and Ocean Salinity (SMOS), and Soil Moisture Active and Passive (SMAP) satellites. Four products, three from Aquarius and one from SMOS, were evaluated and shown to be generally consistent within 0.3 to 0.6 psu and agree favorably with in situ measurements. However, although the Aquarius products show consistent seasonality of SSS with high values of 34.45 psu in October and low values of 33.40 psu in May, theSMOS and SMAP products lack such seasonal variations. This may be caused by larger uncertainties in the SMOS and SMAP data due in part to the lack of concurrent scatterometer measurements that is used to correct for roughness effects. The four products provide similar spatial distributions of SSS with root mean square difference from 0.25 to 0.58 psu. Differences among Aquarius products are mainly due to varying salinity retrieval algorithms, smoothing, and masking of sea ice, while the SMOS product showed the highest SSS deviation that is likely due to the bias adjustment done on the data set. Our analyses show that SSS in the Southern Ocean region has significant meridional variations with the lowest SSS near the ice edge and highest at lower latitudes. The SSS is also lowest in summer indicating the predominant influence of sea ice and glacial melt, but it stays low near ice edges even during the growth season. Salinity together with temperature is the key parameters that control the state and circulation of the World's oceans. The large‐scale distribution of the sea surface salinity of the Southern Ocean is quantified for the first time using Aquarius, Soil Moisture and Ocean Salinity, and Soil Moisture Active and Passive satellite microwave data. Seasonal and interannual changes in the distribution as affected by the sea ice cover, surface temperature, and precipitation are evaluated. Comparative studies were done, using four different products that are publicly available, in conjunction with in situ observations to gain insights into the true nature of the distribution and how consistently the sea surface salinity is depicted by the different products. There are general consistencies in the products, and discrepancies are attributed to different algorithms, smoothing techniques, and sea ice masking. Aquarius data are shown to have higher accuracy than Soil Moisture and Ocean Salinity and Soil Moisture Active and Passive products in part because of having concurrent scatterometer that provides accurate correction to roughness effects.

Garcia-Eidell, Cynthia↗

An Exploration of Discontinuous Time Synchronous Averaging for Helicopter HUMS Using Cruise and Terminal Area Vibration Data

Recent research using NASA Ames AH-1 and OH-58C helicopters, and NASA Glenn test rigs, has shown that in-flight vibration data are typically non-stationary [l-4]. The nature and extent of this non-stationarity is most likely produced by several factors operating simultaneously. The aerodynamic flight environment and pilot commands provide continuously changing inputs, with a complex dynamic response that includes automatic feedback control from the engine regulator. It would appear that the combined effects operate primarily through an induced torque profile, which causes concomitant stress modulation at the individual internal gear meshes in the transmission. This notion is supported by several analyses, which show that upwards of 93% of the vibration signal s variance can be explained by knowledge of torque alone. That this relationship is stronger in an AH-1 than an OH-58, where measured non-stationarity is greater, suggests that the overall mass of the vehicle is an important consideration. In the lighter aircraft, the unsteady aerodynamic influences transmit relatively greater unsteady dynamic forces on the mechanical components, quite possibly contributing to its greater non-stationarity . In a recent paper using OH-58C pinion data [5], the authors have shown that in computing a time synchronous average (TSA) for various single-value metric computations, an effective trade-off can be obtained between sample size and measured stationarity by using data from only a single mesh cycle. A mesh cycle, which is defined as the number of rotations required for the gear teeth to return to their original mating position, has the property of representing all of the discrete phase angles of the opposing gears exactly once in the average. Measured stationarity is probably maximized because a single mesh cycle of the pinion gear occurs over a very short span of time, during which time-dependent non-stationary effects are kept to a minimum. Clearly, the advantage of local stationarity diminishes as the temporal duration of the cycle increases. This is most evident for a planetary mesh cycle, which can take several minutes to complete.

Huff, Edward M.↗

Degradability of Biodegradable Soil Moisture Sensor Components and Their Effect on Maize (Zea mays L.) Growth

Inexpensive and no-maintenance biodegradable soil moisture sensors could improve existing knowledge on spatial and temporal variability of available soil water at field-scale. Such sensors can unlock the full potential of variable-rate irrigation (VRI) systems to optimize water applications in irrigated cropping systems. The objectives of this study were to assess (i) the degradation of soil moisture sensor component materials and (ii) the effects of material degradation on maize (Zea Mays L.) growth and development. This study was conducted in a greenhouse at Colorado State University, Colorado, USA, by planting maize seeds in pots filled with three growing media (field soil, silica sand, and Promix commercial potting media). The degradation rate of five candidate sensor materials (three blends of beeswax and soy wax, balsa wood, and PHBV (poly(3-hydroxybutyrate-co-3-hydroxyvalerate))) was assessed by harvesting sensor materials at four maize growth stages (30, 60, 90, and 120 days after transplanting). All materials under consideration showed stability in terms of mass and dimension except PHBV. PHBV was degraded entirely within 30 days in soil and Promix, and within 60 days in sand. Balsa wood did now show any significant reduction in mass and dimensions in all growth media. Similarly, there was no significant mass loss across wax blends (p = 0.05) at any growth stage, with a few exceptions. Among the wax blends, 3:1 (beeswax:soy wax) was the most stable blend in terms of mass and dimension with no surface cracks, making it a suitable encapsulant for soil sensor. All materials under consideration did not have any significant effect on maize growth (dry biomass, green biomass, and height) as compared to control plants. These results indicated that 3:1 beeswax:soy wax blend, PHBV, and balsa wood could be suitable candidates for various components of biodegradable soil moisture sensors.

Dahal, Subash (ORCID:0000000205489103)↗

Structure and Dynamics of Domains in Ferroelectric Nanostructures – Phase-Field Modeling (Final Technical Report)

Domain pattern formation is one of the most common phenomena in nature and is a topic of immense interest in many fields ranging from materials science and physics to chemistry and biology. This DOE sponsored research project explored the basic science concerning the thermodynamic stability of mesoscale polarization domain patterns and their temporal evolution mechanisms during formation and subsequent switching in ferroelectric nanostructures and heterostructures. The project employed the computational phase-field method in combination of microelasticity and electrostatic theories. The research was carried out in close collaboration with a number of experimental groups who used High Resolution Transmission Electron Microscopy (HRTEM), in situ TEM with Scanning Probe Microscopy (SPM), or Piezoresponse Force Microscopy (PFM) to characterize the domain structures and dynamics of ferroelectric thin films and heterostructures and who grow high-quality ferroelectric and multiferroic thin films using advanced growth techniques such as Molecular Beam Epitaxy (MBE), Pulsed Laser Deposition (PLLD), and sputtering. The research efforts of the project help establish the phase-field method as the most powerful method for understanding and predicting domain structures in ferroelectric thin films and nanostructures. The findings of the project led to the basic understanding of stability and switching mechanisms of ferroelectric domains under different mechanical boundary conditions and under either homogeneous capacitor configurations or local fields using metallic probes as electrodes and the emergence of charged domain walls during domain switching. The project predicted the spatial length scales, temperature ranges, and electromechanical conditions for different polar states in heterostructures and guided the discovery of both transient and stable novel polarization states containing vortex lattices in oxide superlattices. The project resulted in 134 journal publications and 6 PhD theses with all the PhD graduates currently working in either academia or industry within the United States. The basic understanding on the stability of mesoscale polar states and pattern evolution achieved by the project improved our ability to control and engineer properties of ferroelectric thin films and heterostructures for potential applications in nanoscale electronic devices.

36 MATERIALS SCIENCE↗

Atmosphere-Biosphere Interaction Study (Field Campaign Report)

The objective of this campaign was to collect hyperspectral reflectance measurements and complementary optical and infrared data of land surface (i.e., vegetation and soil) throughout the growing season (i.e., from March to September) at high temporal frequency (e.g., < 30 minutes). To collect the measurements, the EcoSpec system, a tower-based sensor system housing seven optical and infrared sensors that was developed at Argonne National Laboratory, was deployed to the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility Southern Great Plains (SGP) atmospheric observatory (within the crop, south of the eddy correlation flux measurement system [ECOR] tower). The EcoSpec system consists of a spectroradiometer having 2,151 channels (350–2,500 nm), red-greenblue (RGB) camera, diffuse radiometer, thermal infrared (TIR) sensors, albedometers, Photochemical Reflectance Index (PRI) sensors, Normalized Difference Vegetation Index (NDVI) sensors, and wetness sensor. The system is designed to collect an array of land surface measurements, including hyperspectral reflectance of plants and soils, RGB photos capturing contextual information of land surface, radiant temperature of sky and land surface, incoming and reflected shortwave radiation, and incoming radiation components (direct and diffuse) as frequent as every minute from up to 12 discrete positions around the tower. This would allow us to capture inherent heterogeneity of the terrestrial ecosystem and to obtain representative spectral signatures of the plant and soil surfaces via averaging those measurements. The SGP site provides advanced atmospheric and other physical measurements that are essential for our investigation of ecosystem functions using hyperspectral reflectance measurements of land surfaces. Located in the mid-latitudes, the SGP site exhibits dynamic seasonality and a wide range of meteorological variability and flux properties that make it ideal for studying interactions between near-surface atmosphere and biosphere across a range of environmental conditions. The atmosphere, plants, and soil control terrestrial carbon and water cycles. To make more accurate climate forecasts, researchers need to understand ecosystem dynamics at the biosphere–atmosphere interface. Even though our ability to forecast ecosystem dynamics and climate at both the regional and global scales has advanced significantly, we still do not know how local phenomena affecting water and carbon fluxes—such as diurnal variations—interrelate with large-scale atmospheric/climate phenomena, and vice versa. The lack of a more thorough understanding of ecosystem dynamics and climate interactions is a key knowledge gap for the improvement of earth system models (ESMs).

54 ENVIRONMENTAL SCIENCES↗

Automated Tracking of Shallow Maritime Clouds on Geostationary Imagery to Extract Lifecycle Characteristics

Shallow moist convection is ubiquitous throughout the tropics and represents a key player in boundary layer processes. Satellites have provided many statistics on shallow clouds, such as size, structure, and geographical coverage, from static views of recurring cloud fields. But determining why certain cloud features appear and persist for different periods requires a time-evolving view of their behaviors. Geostationary satellites provide a unique opportunity to follow the time evolution of individual convective features, given their enhanced spatial and temporal sampling. A cloud-tracking tool was developed to identify properties of cloud lifecycle from the NASA Cloud, Aerosol, and Monsoon Processes Philippines Experiment (CAMP2EX) field campaign of 2019. The mission conducted intensive sampling of shallow cumulus in the West Pacific Ocean, in tandem with Rapid Scan imagery from the Advanced Himawari Imager (AHI) on the Japan Meteorological Agency’s (JMA) Himawari-8 satellite. Shallow cumulus was segmented according to thresholds in 0.5-km visible reflectance and with blurring techniques. Despite being limited to daytime hours, the segmentations yielded the best resolution possible for capturing cloud initiation and decay. The tracking procedure is based on a computer vision package that includes Kalman filters for motion prediction, object overlap search, and the Hungarian (or Kuhn-Munkres) matching algorithm for track designation. AHI radiances available within the tracked cloud boundaries are assembled to form individual spectral histories. The resulting catalog provides thousands of cloud histories for domains measuring only a few degrees in latitude and longitude. We present an overview of the cloud-tracking tool, strategies to identify development stages from cloud tracks, and preliminary results that document cumulus lifecycle properties from satellite. The application of AHI 0.5-km reflectance has both strengths and limitations when attempting to track lifecycles of the smallest resolvable clouds. We show that by aggregating cloud tracks from a few case studies of CAMP2EX, we can discern differences in cloud lifetime and development according to ensembles selected from areas of interest. The results demonstrate an ability to quantify lifetimes and assess rates of change in cloud characteristics that are likely controlled by the surrounding environment and meteorology.

Cloud Tracking↗

Comparison of Seasonal Terrestrial Water Storage Variations from GRACE with Groundwater-level Measurements from the High Plains Aquifer (USA)

This study presents the first direct comparison of variations in seasonal GWS derived from GRACE TWS and simulated SM with GW-level measurements in a semiarid region. Results showed that variations in GWS and SM are the main sources controlling TWS changes over the High Plains, with negligible storage changes from surface water, snow, and biomass. Seasonal variations in GRACE TWS compare favorably with combined GWS from GW-level measurements (total 2,700 wells, average 1,050 GW-level measurements per season) and simulated SM from the Noah land surface model (R = 0.82, RMSD = 33 mm). Estimated uncertainty in seasonal GRACE-derived TWS is 8 mm, and estimated uncertainty in TWS changes is 11 mm. Estimated uncertainty in SM changes is 11 mm and combined uncertainty for TWS-SM changes is 15 mm. Seasonal TWS changes are detectable in 7 out of 9 monitored periods and maximum changes within a year (e.g. between winter and summer) are detectable in all 5 monitored periods. Grace-derived GWS calculated from TWS-SM generally agrees with estimates based on GW-level measurements (R = 0.58, RMSD = 33 mm). Seasonal TWS-SM changes are detectable in 5 out of the 9 monitored periods and maximum changes are detectable in all 5 monitored periods. Good correspondence between GRACE data and GW-level measurements from the intensively monitored High Plains aquifer validates the potential for using GRACE TWS and simulated SM to monitor GWS changes and aquifer depletion in semiarid regions subjected to intensive irrigation pumpage. This method can be used to monitor regions where large-scale aquifer depletion is ongoing, and in situ measurements are limited, such as the North China Plain or western India. This potential should be enhanced by future advances in GRACE processing, which will improve the spatial and temporal resolution of TWS changes, and will further increase applicability of GRACE data for monitoring GWS.

Strassberg, Gil↗

Range Imaging without Moving Parts

Range-imaging instruments of a type now under development are intended to generate the equivalent of three-dimensional images from measurements of the round-trip times of flight of laser pulses along known directions. These instruments could also provide information on characteristics of targets, including roughnesses and reflectivities of surfaces and optical densities of such semi-solid objects as trees and clouds. Unlike in prior range-imaging instruments based on times of flight along known directions, there would be no moving parts; aiming of the laser beams along the known directions would not be accomplished by mechanical scanning of mirrors, prisms, or other optical components. Instead, aiming would be accomplished by using solid-state devices to switch input and output beams along different fiber-optic paths. Because of the lack of moving parts, these instruments could be extraordinarily reliable, rugged, and long-lasting. An instrument of this type would include an optical transmitter that would send out a laser pulse along a chosen direction to a target. An optical receiver coaligned with the transmitter would measure the temporally varying intensity of laser light reflected from the target to determine the distance and surface characteristics of the target. The transmitter would be a combination of devices for generating precise directional laser illumination. It would include a pulsed laser, the output of which would be coupled into a fiber-optic cable with a fan-out and solid-state optical switches that would enable switching of the laser beam onto one or more optical fibers terminated at known locations in an array on a face at the focal plane of a telescope. The array would be imaged by the telescope onto the target space. The receiver optical system could share the aforementioned telescope with the transmitter or could include a separate telescope aimed in the same direction as that of the transmitting telescope. In either case, light reflected from the target would be focused by the receiver optical system onto an array of optical fibers matching the array in the transmitter. These optical fibers would couple the received light to one or more photodetector( s). Optionally, the receiver could include solid-state optical switches for choosing which optical fiber(s) would couple light to the photodetector(s). This instrument architecture is flexible and can be optimized for a wide variety of applications and levels of performance. For example, it is scalable to any number of pixels and pixel resolutions and is compatible with a variety of ranging and photodetection methodologies, including, for example, ranging by use of modulated (including pulsed and encoded) light signals. The use of fixed arrays of optical fibers to generate controlled illumination patterns would eliminate the mechanical complexity and much of the bulk of optomechanical scanning assemblies. Furthermore, digital control of the selection of the fiber-optic pathways for the transmitted beams could afford capabilities not seen in previous three-dimensional range-imaging systems. Instruments of this type could be specialized for use as, for example, proximity detectors, three-dimensional robotic vision systems, airborne terrain-mapping systems, and inspection systems.

Blair, J. Bryan↗

COMPASS-FME Terrestrial Ecosystem Manipulation to Probe the Effects of Storm Treatments (TEMPEST) Experiment Level 2 Sensor Data v2-1

This is the version v2-1 Level 2 (L2) data release for COMPASS-FME environmental sensors located at our Terrestrial Ecosystem Manipulation to Probe the Effects of Storm Treatments (TEMPEST) experimental site. This manipulative, ecosystem-scale TEMPEST experiment addresses the potential for freshwater and estuarine-water disturbance events to alter tree function, species composition, and ecosystem processes in a deciduous coastal forest in MD, USA. The experiment uses a large-unit (2000 m2), un-replicated experimental design, with three 50 m × 40 m plots serving as control, freshwater, and estuarine-water treatments. Level 2 (L2) data consist of sensor observations from the COMPASS-FME synoptic sites, TEMPEST, and DELUGE. Compared to the L1 data, these are more consistent (always 15-minute timestamps for the entire year); better QA/QC’d (out of bounds, out of service, and extreme outlier values are removed); and more complete, with a gap-filled time series available alongside the main observations, and additional derived (calculated) variables. L2 data are intended to be rapidly and easily usable in analyses and simulations. However, algorithmic outlier identification always carries the risk of removing valid data, and Level 1 data may be more suitable for analyses that focus on variability or extreme events. This dataset includes: - An overall dataset README file that describes the current version, gives citation and contact information, etc. - Site- and year-specific folders, each holding variable-specific Parquet (a high performance, space efficient format; see https://parquet.apache.org) data files for each site and plot in that year. - Metadata files within each site-year folder provide full information on data units, expected ranges, contact information, detailed flood times, as well as a general description of the site. - Environmental sensor types that appear in the data files include weather (ClimaVUE50, CS, RM Young, and LI instruments in the graphs below); soil conditions (TEROS12); soil redox state (Redox); groundwater variables (AquaTROLL200 and AquaTROLL600); open water sondes (Exo); tree sap velocity (Sapflow); and system voltage and state (Datalogger). Data are reported every 15 minutes. Please see v2-1 TEMPEST L2 Sensor Package Quick Start.pdf for detailed information on data package structure, temporal coverage, and versioning. Data files are in Apache Parquet, a high performance, space efficient format for tabular data. These files can be read using R's `arrow` package (https://arrow.apache.org/docs/r/), with similar tools available in other languages. The TEMPEST flood events occurred on the following dates. They lasted for ~10 hours each day and delivered ~80,000 gallons to each plot; many data streams are available at 1 or 5 minute frequency during these periods. * Tests: Aug 25 (fresh plot) and Sep 9 (salt plot), 2021 * TEMPEST 1: June 22, 2022 * TEMPEST 2: June 6-7, 2023 * TEMPEST 3: June 11-13, 2024

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC TEMPERATU↗