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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,531 records · Page 85
All sourcesNASA NTRSDOE OSTI
NASA NTRS1954

An Experimental Investigation of Reduction in Transonic Drag Rise at Zero Lift by the Addition of Volume to the Fuselage of a Wing-body-tail Configuration and a Comparison with Theory

An experimental investigation was made by the free-fall recoverable-model technique to assess at zero lift the possibilities of reducing the drag-rise coefficients of a wing-body-cruciform-tail combination by adding volume to the fuselage. The basic features of the test model were an unswept aspect-ratio-3.1 thin wing, a fineness-ratio-12.4 fuselage, and four 45 degrees sweptback tail surfaces. The tests covered a Mach number range of 0.84 to 1.15 with Reynolds numbers of 6.000.000 to 14,000,000, based on the wing mean aerodynamic chord. Considerable reduction in drag-rise coefficient was effected for several different modifications by the addition of properly distributed volume to the fuselage. In one instance, a reduction in drag coefficient was obtained by adding a volume which was almost four times the exposed wing volume. The computation method presented in NACA RM A53H17 generally predicted the supersonic drag-rise coefficients for each modification within 20 percent of the experimental values. As in the above-mentioned report, the predictions at a Mach number of one were not accurate. The changes in drag-rise coefficients resulting from the modifications were generally predicted with better accuracy than the values of drag-rise coefficients.

Holdaway, George H↗
NASA NTRS1993

Topographic Characterization

The National Aeronautics and Space Administration (NASA), other government agencies, and private industry have requirements to map and analyze 3-dimensional surfaces of varying regularity and material composition. This requires a high fidelity, 3-dimensional description of the work space. In cases where complete and current information about the space is not available, topographic characterization allows on-line initialization and/or modification of the work space database. The mapping environment is often challenging with regard to lighting, radiation, temperature, atmosphere, and causticity. This paper describes a system that provides topographic characterization based on fusing intensity and depth information, and describes the application of this technique for inspection of Shuttle thermal tiles.

Goode, Plesent W.↗
NASA NTRS2005

Simulation of the ATIC-2 Silicon Matrix for Protons and Helium GCR Primaries at 0.3, 10, and 25 TeV/Nucleon

The energy deposition distribution for protons and helium galactic cosmic ray primaries at 0.3, 10, and 25 TeV/nucleon in the ATIC-2 silicon matrix detector are simulated with GEANT4. The GEANT3 geometrical model of ATIC developed by the University of Maryland was combined with a GEANT4 application developed for the Deep Space Test Bed (DSTB) detector package. The new code included relatively minor modifications to completely describe the ATIC materials and a more detailed model of the Silicon Matrix detector. For this analysis all particles were started as a unidirectional beam at a single point near the center of the Silicon Matrix front surface. The point was selected such that each primary passed through at least two of the overlapping silicon pixels.

Watts, J.↗
NASA NTRS2003

Mars Reconnaissance Orbiter design approach for high-resolution surface imaging

One of the objectives of the MRO mission is to use the High-Resolution Imaging Science Experiment (HiRISE) to provide 50 cm/pixel images of future Mars landing sites. To achieve such detail, MRO must meet some very challenging target-relative pointing and pointing stability requirements. A combination of analysis, operational constraints, and spacecraft design modifications were utilized to ensure that the necessary pointing requirements will be met.

Mars↗
DOE OSTI2024

Modifying the Reactivity of Single Pd Sites in a Trimetallic Sn‐Pd‐Ag Surface Alloy: Tuning CO Binding Strength

Abstract Improving control over active‐site reactivity is a grand challenge in catalysis. Single‐atom alloys (SAAs) consisting of a reactive component doped as single atoms into a more inert host metal feature localized and well‐defined active sites, but fine tuning their properties is challenging. Here, a framework is developed for tuning single‐atom site reactivity by alloying in an additional inert metal, which this work terms an alloy‐host SAA. Specifically, this work creates about 5% Pd single‐atom sites in a Pd 33 Ag 67 (111) single crystal surface, and then identifies Sn based on computational screening as a suitable third metal to introduce. Subsequent experimental studies show that introducing Sn indeed modifies the electronic structure and chemical reactivity (measured by CO desorption energies) of the Pd sites. The modifications to both the electronic structure and the CO adsorption energies are in close agreement with the calculations. These results indicate that the use of an alloy host environment to modify the reactivity of single‐atom sites can allow fine‐tuning of catalytic performance and boost resistance against strong‐binding adsorbates such as CO.

Mohrhusen, Lars↗
DOE OSTI2020

Giant room temperature anomalous Hall effect and tunable topology in a ferromagnetic topological semimetal Co 2 MnAl

Weyl semimetals exhibit unusual surface states and anomalous transport phenomena. It is hard to manipulate the band structure topology of specific Weyl materials. Topological transport phenomena usually appear at very low temperatures, which sets challenges for applications. In this work, we demonstrate the band topology modification via a weak magnetic field in a ferromagnetic Weyl semimetal candidate, Co 2 MnAl, at room temperature. We observe a tunable, giant anomalous Hall effect (AHE) induced by the transition involving Weyl points and nodal rings. The AHE conductivity is as large as that of a 3D quantum AHE, with the Hall angle (Θ H ) reaching a record value (tan Θ H = 0.21) at the room temperature among magnetic conductors. Furthermore, we propose a material recipe to generate large AHE by gaping nodal rings without requiring Weyl points. Our work reveals an intrinsically magnetic platform to explore the interplay between magnetic dynamics and topological physics for developing spintronic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Inclusion of a cold hardening scheme to represent frost tolerance is essential to model realistic plant hydraulics in the Arctic–boreal zone in CLM5.0-FATES-Hydro

As temperatures decrease in autumn, vegetation of temperate and boreal ecosystems increases its tolerance to freezing. This process, known as hardening, results in a set of physiological changes at the molecular level that initiate modifications of cell membrane composition and the synthesis of anti-freeze proteins. Together with the freezing of extracellular water, anti-freeze proteins reduce plant water potentials and xylem conductivity. To represent the responses of vegetation to climate change, land surface schemes increasingly employ “hydrodynamic” models that represent the explicit fluxes of water from soil and through plants. The functioning of such schemes under frozen soil conditions, however, is poorly understood. Nonetheless, hydraulic processes are of major importance in the dynamics of these systems, which can suffer from, e.g., winter “frost drought” events. In this study, we implement a scheme that represents hardening into CLM5.0-FATES-Hydro. FATES-Hydro is a plant hydrodynamics module in FATES, a cohort model of vegetation physiology, growth, and dynamics hosted in CLM5.0. We find that, in frozen systems, it is necessary to introduce reductions in plant water loss associated with hardening to prevent winter desiccation. This work makes it possible to use CLM5.0-FATES-Hydro to model realistic impacts from frost droughts on vegetation growth and photosynthesis, leading to more reliable projections of how northern ecosystems respond to climate change.

58 GEOSCIENCES↗
NASA NTRS1986

Performance studies on the application of four-engine and two-engine USB propulsive lift to the E-2C aircraft

A study has been completed of the performance benefits to be derived from applying advanced upper-surface blowing (USB) propulsive-lift technology to the E-2C aircraft. The results of comparing four-engine with two-engine USB configurations are discussed, and engine sizing and aerodynamic/structural considerations pertaining to the E-2C/USB modification are examined. The effects of the modification on performance are described in detail with regard to takeoff distance and landing distance estimation in free-deck operations, operations using catapult and arresting gear, ceiling and radar surveillance missions, and range and endurance capability.

Riddle, D. W.↗
NASA NTRS1989

A concept for using the external tank from a National Space Transportation System (NSTS) for a lunar habitat

A concept for using the external tank from a National Space Transportation System for a lunar habitat is described. The tank is inserted in low earth orbit where it is outfitted as a 12-person lunar habitat. The tank modifications utilize existing structures and openings for man access without compromising the structural integrity of the tank. The modifications include installation of living quarters, instrumentation, and airlock; and thermal-control, environmental-control and life-support, and propulsion systems. The habitat is designed for unmanned transport to low lunar orbit and autonomously soft landed on the lunar surface. Supply to the habitat is provided by a space transfer vehicle and manned cargo lander. The lunar habitat concept is feasible by the year 2000 with the concurrent development of a space transfer vehicle and manned cargo lander for crew changeover and resupply.

King, C. B.↗
NASA NTRS1990

Using a microgravity environment to probe wave turbulence

The experimental key to observing stochasticity or turbulence in a distribution of interacting propagating waves is the achievement of high amplitude and the use of a medium with a large coefficient of nonlinearity. The research indicates that capillary waves are the best means of observing this phenomenon; however, gravitational modifications of the capillary wave dispersion law greatly reduce the large coefficient of nonlinearity. Thus, a search for wave turbulence in a large drop of fluid that is positioned in a microgravity experiment was conducted. Capillary waves that run around the surface of the drop are excited, and their power spectrum and higher order correlations are analyzed for wave turbulence. The theoretical calculations indicate that modulations of the power spectrum should propagate as second sound waves. These issues have consequences for signal processing and plasma confinement.

Putterman, S.↗
NASA NTRS1992

Genesis of mobile troughs in the upper westerlies

Stability calculations on basic-state velocity profiles representative of the preferred regions for the development of the upper-level disturbances active in Type B cyclogenesis show that conditions in these regions (weak low-level baroclinicity, large low-level static stability, and large surface roughness) are favorable for the growth of baroclinic waves with maximum amplitude near the tropopause. The structure of these waves compares favorably with observations of developing short-wavelength upper-level troughs in the atmosphere. Basic states characteristic of the storm track regions (strong low-level baroclinicity and small surface roughness) favor the development of baroclinic waves with maximum amplitude at the surface. The dynamics of both the surface-trapped and the upper-tropospheric waves can be interpreted concisely using concepts of potential vorticity. Based on these results, a possible mechanism for Type B cyclogenesis in the storm track regions is proposed that involves the propagation and structural modification of baroclinic wave packets in a zonally varying basic flow.

Whitaker, Jeffrey S.↗
NASA NTRSDate not supplied

Viability of Small Dimension Crew Quarters for Surface Habitation

During early planning for the Artemis program’s sustained phase of lunar activity, NASA planners have been held to work towards a NASA reference lunar lander concept. With this activity taking place prior to the awarding of a lander contract, NASA planners cannot assume which of several potential landers will be available. This has limited habitation team engineers to a 12-metric ton mass limit for the reference concept of the lunar Surface Habitat. Consequently, minimal approaches have been applied to many habitat systems and it is important to determine acceptable volume for crew quarters. A number of both NASA and non-NASA surface habitat concepts have proposed relatively small crew quarters due to this constraint. Consequently, there is a need to collect objective test data to confirm or refute the validity of small crew quarters. NASA-STD-3001 is looked to for guidance in its many standards but offers little to no help. While prior versions called for private habitation, the current version – Revision B – calls for “individual privacy” to “accommodate social retreat.” Proposed Revision C modifications change the language slightly to “accommodate sleep and social retreat.” This is not enough guidance to determine the size of a crew quarters or even its capabilities. Unfortunately, only a small number of US spacecraft have included crew quarters, primarily the International Space Station and the Skylab Space Station. The space shuttle orbiter sometimes flew a set of private bunks that some might consider a crew quarters. All of these are dramatically smaller than US standards for minimum jail cells. The first opportunity for NASA to test a small crew quarters in a surface habitat application has been created through the Exploration Atmospheres test series, which is evaluating human performance under reduced cabin pressures. The test is converting the 20-Foot Vacuum Chamber at Johnson Space Center into a habitat, with the lower level outfitted as an EVA test area and the upper two levels for human habitation. The test will place eight people (six test subjects and two technicians) inside the chamber for eleven days. All eight will sleep in private quarters during the test. Volume limitations in the chamber forced extremely small crew quarters, measuring approximately 2 meters in length, 0.85 meters in height, and 0.9 meters in width. The test cabin pressure of 8.2 psi and elevated oxygen also introduces significant material limitations, limiting outfitting options. Nonetheless, the crew quarters design requirements were to accommodate visual separation, auditory separation, olfactory separation, tactile separation, air flow control, lighting control, single person personal computing, physical work surface access, sleep accommodations, non-sleep rest/relaxation, meditation, stretching, two-person meetings, snacking, changing clothes, viewing appearance, video communication, and audio communication. This paper will detail the acceptability of the crew quarters as measured in the October 2021 Exploration Atmosphere test. Based on this data, the viability of the type of crew quarters used in the 20 Foot Chamber will be assessed. Design recommendations for a 30-60-day Surface Habitat crew quarters will be provided, along with recommendations for future testing.

Crew Quarters↗
DOE OSTI2023

Synthesis and Observation of Emergent Phenomena in Epitaxial Heusler Compound Heterostructures

The proposal was on the synthesis and observation of emergent phenomena in epitaxial Heusler compound heterostructures. The large range of properties and number of Heusler compounds opens up a wide number of potential compounds that will exhibit emergent phenomena. The similarity, large range of relatively inexpensive, large area, high crystal quality, III-V bulk substrates, lattice parameters and the ability to tune the lattice parameters through ternary or quaternary III-V compound semiconductor epitaxial growth, makes III-V semiconductors an ideal choice for substrates for epitaxial growth of Heusler compounds. A number of half Heusler compounds have been predicted to exhibit band inversion, making them topological and are therefore expected to exhibit spin-momentum locked topological surface states with linear dispersion. Others are predicted to be semimetals with Weyl points and others semiconducting and magnetic. During the course of this grant, emphasis has been on investigating Heusler compounds with emergent phenomena and demonstrating the ability to tune their properties through alloying and strain. We have grown toplogical semimetal (PtLuSb, PtMnBi), Weyl (Co 2 MnAl, Co 2 TiGe), half metal (PtMnSb, Co 2 MnSi, Co 2 MnAl x Si 1-x , Co2FeAl), and semiconducting (CoTiSb, NiTiSn) and tuned their properties through alloying and epitaxial strain. We also investigated the closely related materials of rare-earth monopnictide, some of which have also been predicted to be topological. During the attempts to grow the PtMnBi, it was discovered that Bi, another predicted topological material when ultrathin, could be grown epitaxially on InSb, results for which are also reported here. The main focus for this effort has been on using variable photon energy and spin-dependent angle resolved photoemission (ARPES) to determine bulk band structure and surface states of pristine epitaxial films grown on III-V semiconductor and MgO substrates and correlate results with theory and transport measurements. Theory has been critical to interpretation of experimental results and has been essential in guiding experiments. The research benefited from several strong collaborations between the PIs and the beamline scientists at the Advanced Light Source at Lawrence Berkeley Laboratory, the Stanford Linear Accelerator Center (SLAC) at Stanford and at the Max Lab at Lund University in Sweden. The strong experiment - theory collaboration between the PI’s groups, the Palmstrøm group at UCSB and the Janotti group at the University of Delaware, has been critical for interpreting the experimental ARPES and magnetotransport measurements results and making predictions to guide experiments. Weekly interactive Zoom meetings made this work well. A collaboration between the Palmstrøm group and Dr. Alexei Fedorov at the Advanced Light Source (ALS) resulted in significant modifications to his end chamber to accommodate the vacuum suitcase that was designed and constructed in the Palmstrøm group at UCSB. In collaboration with beamline scientists, Drs. Makoto Hashimoto and Donghui Lu at SLAC, Palmstrøm made modifications to the vacuum suitcase and developed special sample holders that allowed samples to be grown in the Palmstrøm MBE systems at UCSB and transported in the UHV vacuum suitcase to SLAC for ARPES measurements. The development of the vacuum suitcase was essential for this grant as it has allowed variable photon energies to be used to identify surface versus bulk states on samples that could not be capped and decapped using As- or Sb-capping layers.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Polymer Passivated All Inorganic Micro‐Structured CsPbI x Br y Perovskite Toward Highly Efficient Photodetectors

Abstract Solution‐processed inorganic perovskites cause chemical and structural defects unfavorable for photodetector application. Using a binary solvent, defects in CsPbI x Br y (CPIB) perovskite are passivated with poly 4‐vinylpyridine (PVP) and Poly methyl methacrylate (PMMA) polymers. X‐ray photoelectron spectroscopy and FTIR spectra reveal a Lewis base‐acid interaction between Pb 2+ and polymer, confirming the passivation of CPIB perovskite. Scanning electron microscopy analysis shows a dual‐surface morphology with microribbons and microcrystals in perovskites. After PMMA treatment, CPIB perovskite exhibits a blue shift in the bandgap (1.8 to 1.95 eV), while the PVP induced a redshift, reducing the bandgap to 1.7 eV. Blue shift in PL analysis indicates modification of grain boundaries. A higher lifetime obtained for CPIB/PVP confirms the restraint of non‐radiative recombinations. Photodetectors are fabricated with pristine CPIB, CPIB/PVP, and CPIB/PMMA perovskites. The passivated CPIB/PVP‐based photodetector exhibits a quick rise time of ≈23 ms and a decay time of ≈17 ms. It also demonstrates a remarkable photoresponsivity of 23 mA W −1 , an internal quantum efficiency of 4.9%, and a detectivity of 15.0 × 10 10 Jones at 10 mW cm −2 light intensity. This approach shows the potential for environmentally stable polymers to passivate inorganic perovskites for high photodetection performance.

Shah, Shruti↗
DOE OSTI2023

Interfacial Issues and Modification of Solid Electrolyte Interphase for Li Metal Anode in Liquid and Solid Electrolytes

Abstract The high energy density required for the next generation of lithium batteries will likely be enabled by a shift toward lithium metal anode from the conventional intercalation‐based anode such as graphite. However, several critical challenges for Li metal originate from its highly reactive nature and the hostless reaction of deposition and stripping impede the practical use of Li metal as an anode. The role of the solid electrolyte interphase (SEI) is very important for the Li metal anode where the SEI must protect the dynamically changing surface of the Li metal. Since the SEI‐generating reaction mechanisms for the two different electrolyte systems, liquid and solid, are considerably different, the SEI layers formed between the Li metal and the electrolytes in the two electrolyte systems have substantially different properties, causing different interfacial issues. Inhibition of the interfacial problems requires different strategies to reinforce the SEI layer for each of the electrolyte systems. However, the differences in the two electrolyte systems have not been clearly compared in the prior literature. In this report, the interfacial issues for the two different electrolyte systems are compared and different strategies for SEI modification are provided to overcome the issues.

25 ENERGY STORAGE↗
DOE OSTI2021

Binding mechanism and binding free energy of amino acids and citrate to hydroxyapatite surfaces as a function of crystallographic facet, pH, and electrolytes

Hydroxyapatite (HAP) is the major mineral phase in bone and teeth. The interaction of individual amino acids and citrate ions with different crystallographic HAP surfaces has remained uncertain for decades, creating a knowledge gap to rationally design interactions with peptides, proteins, and drugs. In this contribution, we quantify the binding mechanisms and binding free energies of the 20 end-capped natural amino acids and citrate ions on the basal (001) and prismatic (010)/(020) planes of hydroxyapatite at pH values of 7 and 5 for the first time at the molecular scale. We utilized over 1500 steered molecular dynamics simulations with highly accurate potentials that reproduce surface and hydration energies of (hkl) hydroxyapatite surfaces at different pH values. Charged residues demonstrate a much higher affinity to HAP than charge-neutral species due to the formation of superficial ion pairs and ease of penetration into layers of water molecules on the mineral surface. Binding free energies range from 0 to -60 kJ/mol and were determined with ~10% uncertainty. The highest affinity was found for citrate, followed by Asp(-) and Glu(-), and followed after a gap by Arg(+), Lys(+), as well as by His(+) at pH 5. The (hkl)-specific area density of calcium ions, the protonation state of phosphate ions, and subsurface directional order of the ions in HAP lead to surface-specific binding patterns. Amino acids without ionic side groups exhibit weak binding, between -3 and 0 kJ/mol, due to difficulties to penetrate the first layer of water molecules on the apatite surfaces. We explain recognition processes that remained elusive in experiments, in prior simulations, discuss agreement with available data, and reconcile conflicting interpretations. In conclusion, the findings can serve as useful input for the design of peptides, proteins, and drug molecules for the modification of bone and teeth-related materials, as well as control of apatite mineralization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Large-scale paleo water-table rise in a deep desert aquifer recorded by dissolved noble gases

Illuminating past hydrological and climatological conditions in arid regions may provide insights into future trends in groundwater availability. The main objective of this study is to explore paleorecharge processes in the deep regional Nubian Sandstone Aquifer (NSA), which stretches below the hyperarid deserts of the Sinai Peninsula (Egypt) and the Negev (Israel), using dissolved noble gas data. Extremely high amounts of dissolved excess air (Ne concentrations up to 4 × solubility equilibrium) were observed in the ancient ( 81 Kr-depleted) groundwater that was recharged during past pluvial epochs in the basin. Here, the observed unique excess air signal and the clear spatiotemporal structure of the noble gas compositions in the aquifer are hypothesized to reflect two major characteristics of the groundwater system: (a) large-scale, long-term rises in the water table that facilitate the entrapment and dissolution of air bubbles under increased hydrostatic pressure, and (b) the geological settings in the southern recharge area in Sinai, including an almost horizontal position of the layers and intercalation of low-permeability rock formations within the aquifer, which inefficiently reject air bubbles from groundwater, thereby allowing for substantial entrapment of bubbles that dissolve as the water table rises. Enhanced dissolution of entrapped air was also observed in other paleo-groundwater-containing regional sandstone aquifers across North Africa, which, together with the recent findings from the NSA, suggest that largescale water table fluctuations have likely extensively occurred during past pluvial periods over these (and possibly other) arid regions. A preliminary assessment of noble gas recharge temperatures (NGTs) indicates an apparent decoupling of surface and water table temperatures in the case of deep aquifers with a thick (hundreds of m) unsaturated zone. This observed decoupling calls for a re-evaluation of previously obtained NGT records and a need for future work to consider the modification of NGTs due to soil air fractionation and geothermal heating of the underlying deep unsaturated zones.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1981

Type 'A' V/STOL - One aircraft for all support missions

An investigation is conducted regarding the feasibility of developing a single support aircraft type for the Navy, taking into account the current naval inventory of utility aircraft types. Support mission characteristics are examined, giving attention to antisubmarine warfare, airborne early warning, marine assault, carrier on board delivery/vertical on board delivery, the aerial tanker mission, long-range rescue, surface attack, and aspects of combat, search, and rescue. With the aid of a sample design for a V/STOL aircraft with a medium disc loading lift system it is demonstrated that it is now possible to design an aircraft which, with minor modifications, can meet the wide variety of support missions.

Adelt, W. H.↗