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At least 1,531 records · Page 85
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Boundary Layer Controls on the Shallow-to-Deep Cumulus Transition (Final Technical Report)

This project advanced our understanding of the processes governing cumulus cloud formation and provides an improved observational basis for validating earth system models. To be specific, the project used laser- and radar-remote sensors to examine the physical properties of updrafts that rise from earth’s surface and initiate clouds deeper in the atmosphere. These updrafts comprise “thermals” and “plumes” and occur at small spatial and temporal scales (e.g., 10s of minutes, 100s of meters). These small scales preclude explicit representation in most earth system and climate models, and thus necessitate “sub-grid-scale” parameterization of updraft processes. The innovation of this project was to directly measure the size, shape, strength and water vapor content of these updrafts with Doppler and Raman lidars, respectively, and to link these updraft properties to cloud processes using vertically pointed weather radars. The resulting data sets comprise 100s of thousands of updrafts and thousands of clouds, which far exceeds previous efforts, and thereby provides a robust statistical and physical representation of these processes. From these large datasets the project produced a sequence of scientific analyses that: (1) Elucidate how variations in the turbulent structure of the convective boundary layer control shallow cumulus convection, (2) Quantify the upward transport of water vapor to cloud base via thermals and plumes, (3) Validate large-eddy simulations of updrafts and shallow convective clouds, (4) Demonstrate a size-to-strength relationship between updraft width and updraft speed, and (5) Demonstrate how updrafts interact with the stability at the top of the convective boundary layer to modulate the depth and vigor of convective clouds. These results have been disseminated via several published journal articles, academic theses, and conference presentations. Collectively these results contribute to the Atmospheric System Research (ASR) program’s goal to “improve understanding of the key cloud, aerosol, precipitation, and radiation processes that affect the Earth’s radiative balance and hydrological cycle, particularly processes that limit the predictive ability of regional and global earth system models”.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1998

Martian Polar Region Impact Craters: Geometric Properties From Mars Orbiter Laser Altimeter (MOLA) Observations

The Mars Orbiter Laser Altimeter (MOLA) instrument onboard the Mars Global Surveyor (MGS) spacecraft has so far observed approximately 100 impact landforms in the north polar latitudes (>60 degrees N) of Mars. Correlation of the topography with Viking Orbiter images indicate that many of these are near-center profiles, and for some of the most northern craters, multiple data passes have been acquired. The northern high latitudes of Mars may contain substantial ground ice and be topped with seasonal frost (largely CO2 with some water), forming each winter. We have analyzed various diagnostic crater topologic parameters for this high-latitude crater population with the objective of characterizing impact features in north polar terrains, and we explore whether there is evidence of interaction with ground ice, frost, dune movement, or other polar processes. We find that there are substantial topographic variations from the characteristics of midlatitude craters in the polar craters that are not readily apparent from prior images. The transition from small simple craters to large complex craters is not well defined, as was observed in the midlatitude MOLA data (transition at 7-8 km). Additionally, there appear to be additional topographic complexities such as anomalously large central structures in many polar latitude impact features. It is not yet clear if these are due to target-induced differences in the formation of the crater or post-formation modifications from polar processes.

Garvin, J. B.↗
DOE OSTI2024

Deciphering between enhanced light emission and absorption in multi-mode porphyrin cavity polariton samples

Abstract It remains unclear how the collective strong coupling of cavity-confined photons to the electronic transitions of molecular chromophore leverages the distinct properties of the polaritonic constituents for future technologies. In this study, we design, fabricate, and characterize multiple types of Fabry-Pérot (FP) mirco-resonators containing copper(II) tetraphenyl porphyrin (CuTPP) to show how cavity polariton formation affects radiative relaxation processes in the presence of substantial non-Condon vibronic coupling between two of this molecule’s excited electronic states. Unlike the prototypical enhancement of Q state radiative relaxation of CuTPP in a FP resonator incapable of forming polaritons, we find the light emission processes in multimode cavity polariton samples become enhanced for cavity-exciton energy differences near those of vibrations known to mediate non-Condon vibronic coupling. We propose the value of this detuning is consistent with radiative relaxation of Herzberg-Teller polaritons into collective molecular states coupled to the cavity photon coherently. We contrast the feature stemming from light emission from the HT polariton state with those that occur due to polariton-enhanced light absorption. Our results demonstrate the landscape of molecular and photonic interactions enabled by cavity polariton formation using complex chromophores and how researchers can design resonators to leverage these interactions to characterize and control polaritonic properties.

Odewale, Elizabeth O.↗
NASA NTRS2004

Combining Hard with Soft Materials in Nanoscale Under High-Pressure High-Temperature Conditions

Nano-composites with a primary nanocrystalline ceramic matrix and a secondary nanocrystalline material (metal or semiconductor) were synthesized by infiltration of an appropriate liquid into ceramic compacts under pressures of up to 8 GPa and temperatures of up to 2000 K. The purpose of our work is to obtain nanocomposites which constitute homoger?ous mixtures of two phases, both forming nano- grains of about 10 nm in size. The high pressure is used to bring the porosity of the compacted powders down to the nano-scale and force a given liquid into the nano-sized pores. The advantage of the infiltration technique is that, in a single, continuous process, we start with a nanocrystalline powder, compress it to form the matrix of the composite, and crystallize and/or synthesize a second nanomaterial in the matrix pores. The key limitation of this technology is, that the pores in the matrix need to stay open during the entire process of infiltration. Thus the initial powder should form a rigid skeleton, otherwise the so-called self-stop process can limit cr block a further flow of the liquid phase and hinder the process of the composite formation. Therefore powders of only very hard ceramic materials like diamond, Sic, or Alz03, which can withstand a substantial external load without undesired deformation, can be used as the primary phase. With this technique, using diamond and S i c ceramic powders infiltrated by liquid metals (AI, Zn, Sn, Ag, Au) and semiconductors (Si, Ge, GaAs, CdTe), we obtained nano-composites with the grain size in the range of 10 - 30 nm. Our work addresses the key problem in manufacturing bulk nanocrystalline materials, i.e. preservation of nano-scale during the fabrication process. In this paper we discuss basic technical and methodological problems associated with nano-infiltration based on the results obtained for Zn-Sic composites.

Palosz, B.↗
NASA NTRS2021

High-resolution Laboratory Measurements of K-shell X-ray Line Polarization and Excitation Cross Sections in Helium-like S XV Ions

We report measurements of electron-impact excitation cross sections for the strong K-shell n = 2 -> 1 transitions in S XV, using the LLNL EBIT-I electron beam ion trap, two crystal spectrometers, and the EBIT Calorimeter Spectrometer. The cross sections are determined by direct normalization to the well-known cross sections of radiative electron capture, measured simultaneously. Using contemporaneous polarization measurements with the two crystal spectrometers, whose dispersion planes are oriented parallel and perpendicular to the electron beam direction, the polarization of the direct excitation line emission is determined, and in turn the isotropic total cross sections are extracted. We further experimentally investigate various line-formation mechanisms, finding that radiative cascades and collisional inner-shell ionization dominate the degree of linear polarization and total line emission cross sections of the forbidden line, z.

atomic data↗
NASA NTRS1997

Physical Processing of Cometary Nuclei

Cometary nuclei preserve a cosmo-chemical record of conditions and processes in the primordial solar nebula, and possibly even the interstellar medium. However, that record is not perfectly preserved over the age of the solar system due to a variety of physical processes which act to modify cometary surfaces and interiors. Possible structural and/or internal processes include: collisional accretion, disruption, and reassembly during formation; internal heating by long and short-lived radionuclides; amorphous to crystalline phase transitions, and thermal stresses. Identified surface modification processes include: irradiation by galactic cosmic rays, solar protons, UV photons, and the Sun's T Tauri stage mass outflow; heating by passing stars and nearby supernovae; gardening by debris impacts; the accretion of interstellar dust and gas and accompanying erosion by hypervelocity dust impacts and sputtering; and solar heating with accompanying crust formation. These modification processes must be taken into account in both the planning and the interpretation of the results of a Comet Nucleus Sample Return Mission. Sampling of nuclei should be done at as great a depth below the surface crust as technically feasible, and at vents or fissures leading to exposed volatiles at depth. Samples of the expected cometary crust and near-surface layers also need to be returned for analysis to achieve a better understanding of the effects of these physical processes. We stress that comets are still likely less modified dm any other solar system bodies, but the degree of modification can vary greatly from one comet to the next.

Weissman, Paul R.↗
NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 12

Topics discussed include: The Ancient Lakes in Hellas Basin Region as Seen Through the First Year of Mars Express HRSC-Camera; DISR Observations of Craters at Titan at the Huygens Landing Site: Insights Anticipated; The Sun s Dust Disk - Discovery Potential of the New Horizons Mission During Interplanetary Cruise; Evidence for Aqueously Precipitated Sulfates in Northeast Meridiani Using THEMIS and TES Data; Integrated Spectroscopic Studies of Anhydrous Sulfate Minerals; Venusian Channel Formation as a Subsurface Process; Reexamination of Quartz Grains from the Permian-Triassic Boundary Section at Graphite Peak, Antarctica; Observations of Calcium Sulfate Deposits at High Latitudes by OMEGA/Mex at Km/Pixel Resolutions; Observations of the North Permanent Cap of Mars in Mid-Summer by OMEGA/MEX at km per Pixel Resolutions; Classification and Distribution of Patterned Ground in the Southern Hemisphere of Mars Genesis: Removing Contamination from Sample Collectors; Thermal Characterization of Fe3O4 Nanoparticles Formed from Poorly Crystalline Siderite; Hydrogen Abundances in Metal Grains from the Hammadah Al Hamra (HaH) 237 Metal-rich Chondrite: A Test of the Nebular-Formation Theory; REE and Some Other Trace Elements Distributions of Mineral Separates in Atlanta (EL6); The Composition and Origin of the Dewar Geochemical Anomaly; Asteroid Modal Mineralogy Using Hapke Mixing Models: Testing the Utility of Spectral Lookup Tables; and The Huygens Mission at Titan: Results Highlights. (sup 182)Hf-(sup 182)W Chronometry and an Early Differentiation in the Parent Body of Ureilites Ground Penetrating Radar in Sedimentary Rocks Mars, Always Cold, Sometimes Wet: New Constraints on Mars Denudation Rates and Climate Evolution from Analog Studies at Haughton Crater, Devon Island, High Arctic Europa s Porous Ice Rheology and Implications for Ice-penetrating Radar Scattering Loss Surface Generated Cracks on Europa

Source record↗
NASA NTRS1987

Is there a weak mixed polarity background field? Theoretical arguments

A number of processes associated with the formation of active regions produce 'U-loops': fluxtubes having two ends at the photosphere but otherwise still embedded in the convection zone. The mass trapped on the field lines of such loops makes them behave in a qualitatively different way from the 'omega-loops' that form active regions. It is shown that U-loops will disperse though the convection zone and form a weak (down to a few gauss) field that covers a significant fraction of the solar surface. This field is tentatively identified with the inner-network fields observed at Kitt Peak and Big Bear. The process by which these fields escape through the surface is described; a remarkable property is that it can make active region fields apparently disappear in situ. The mixed polarity moving magnetic features near sunspots are interpreted as a locally intense form of this disappearance by escape of U-loops.

Spruit, H. C.↗
DOE OSTI2023

Tuning Bulk Redox and Altering Interfacial Reactivity in Highly Fluorinated Cation-Disordered Rocksalt Cathodes

Lithium-excess, cation-disordered rocksalt (DRX) materials have been subject to intense scrutiny and development in recent years as potential cathode materials for Li-ion batteries. Despite their compositional flexibility and high initial capacity, they suffer from poorly understood parasitic degradation reactions at the cathode-electrolyte interface. These interfacial degradation reactions deteriorate both the DRX material and electrolyte, ultimately leading to capacity fade and voltage hysteresis during cycling. In this work, differential electrochemical mass spectrometry (DEMS) and titration mass spectrometry are combined to quantify the extent of bulk redox and surface degradation reactions for a set of Mn 2+/4+ -based DRX oxyfluorides during initial cycling with a high-voltage charging cutoff (4.8 V vs Li/Li + ). Increasing the fluorine content from 7.5 to 33.75% is shown to diminish oxygen redox and suppresses high-voltage O 2 evolution from the DRX surface. Additionally, electrolyte degradation processes resulting in the formation of both gaseous species and electrolyte-soluble protic species are observed. Subsequently, DEMS is paired with a fluoride-scavenging additive to demonstrate that increasing fluorine content leads to increased dissolution of fluorine from the DRX material into the electrolyte. Finally, a suite of ex situ spectroscopy techniques (X-ray photoelectron spectroscopy, inductively coupled plasma optical emission spectroscopy, and solid-state nuclear magnetic resonance spectroscopy) are employed to study the change in DRX composition during charging, revealing the dissolution of manganese and fluorine from the DRX material at high voltages. Here this work provides insight into the degradation processes occurring at the DRX-electrolyte interface and points toward potential routes of interfacial stabilization.

25 ENERGY STORAGE↗
NASA NTRS2005

A Preliminary Investigation of the E-Beam Induced Polymerization of Maleimide and Norbornene End-capped Polyimides

A research area of high activity in connection with aerospace engineering has been the development of polymer thermosetting resins that can resist temperature as high as 300 C while maintaining adequate toughness, and providing ease of processing to enable low temperature and low cost composite fabrication methods. In order to meet such requirements, sequential interpenetrating polymer networks (IPNs) based on bismaleimide (BMI) and cyanate ester (CE) monomers were investigated. In these systems, a polycyanurate network is first formed in the presence of BMI and appropriate reactive diluent monomers and in a second step, a network based on the BMI is created in the presence of a fully formed polycyanurate network. The materials developed can be processed at relatively low temperature (less than 150 C) and with the aid of electron beam (EB) curing. Of major importance to the success of this work was the identification of a reactive diluent that improves ease of processing and has tailored reactivity to allow for the controlled synthesis of CE-BMI sequential IPNs. Based on solubility and reactivity of a number of reactive diluents, N-acryloylmorpholine (AMP) was selected as a comonomer for BMI copolymerization. A donor-acceptoreaction mechanism was suggested to explain the relative reactivity of a variety of reactive diluents towards maleimide functionality. The optimum processing parameters for the formation of the first network were determined through the study of metal catalyzed cure and hydrolysis of cyanate esters, whereas the reaction behavior for second network formation in terms of the influence of EB dose rate and temperature was elucidated through an in-situ kinetics study of maleimide and AMP copolymerization. Structure-property relationships were developed which allowed for the design of improved resin systems. In particular, appropriate network coupler possessing cyanate ester and maleimide functionality was synthesized to link the polycyanurate first network to the BMI/AMP second network and thus form linked sequential IPNs (LIPNs). Consequently, Tg as high as 370 C was achieved and a fracture toughness of 120 Joules per square meters was obtained for resin systems that possess adequately low viscosity for processing using liquid molding techniques at low temperature.

Palmese, Giuseppe R.↗
NASA NTRS1985

Paleohydrologic Implications of Valley Networks of Mars

Valley networks in the heavily cratered terrains of Mars represent an ancient epoch of hydrologic conditions greatly different from those of today. Available crater counts on the valley networks indicate formation during the high flux of impacting bodies charaterizing the early heavy bombardment phase of Martian history. Two populations of valleys are recognized in the equatorial regions of Mars: pristine and degraded. The latter probably formed at the very end of the heavy bombardment phase, extending into the post-heavy bombardment by formation in the intercrater plains. Pristine valleys generally form segments of larger networks with degraded components. This suggests that valley formation was a prolonged process coeval with the heavy bombardment period and extending just beyond that period in martian history. The pristine networks and pristine portions of compound networks on Mars show morphological attributes consistent with an origin by headward growth through spring sapping. On Earth spring sapping occurs where groundwater out-streamflow can be generated by insolation changes associated with orbital parameters or with geothermal effects, such as might be associated with impact or with the volcanic emplacement of the intercrater plains. Thus, it is appropriate to specify the most conservation deviation from modern hydrologic conditions on Mars that could account for the ancient epoch of valley formation.

Baker, V. R.↗
DOE OSTI2022

Direct observation of Mn distribution/speciation within and surrounding a basidiomycete fungus in the production of Mn-oxides important in toxic element containment

Biogenic manganese (Mn) oxides occur ubiquitously in the environment including the uranium (U) mill tailings at the Ningyo-toge U mine in Okayama, Japan, being important in the sequestration of radioactive radium (Ra). To understand the nanoscale processes in Mn oxides formation at the U mill tailings site, Mn 2+ absorption by a basidiomycete fungus, Coprinopsis urticicola, isolated from Ningyo-toge mine water samples, was investigated in the laboratory under controlled conditions utilizing electron microscopy, synchrotron-based X-ray analysis, and fluorescence microscopy with molecular pH probe. The fungus’ growth was first investigated in an agar-solidified medium supplemented with 1.0 mmol/L of Mn 2+ , ± Cu 2+ (50 – 200 µM), ± Zn 2+ (50 – 200 µM), or ± diphenyleneiodonium chloride (DPI) (50 – 100 µM) at 25 °C. The results revealed that Zn 2+ has no significant effects on the Mn oxides formation, whereas Cu 2+ and DPI significantly inhibit both fungal growth and Mn oxidation, indicating superoxide-mediated Mn oxidation. During the interaction of Mn 2+ with the fungi in solution medium at the initial pH of 5.67, a small fraction of Mn 2+ infiltrated into the fungal hyphae within 8 h, forming a few tens nm-sized concentrates of soluble Mn2+ in the intracellular pH of ~6.5, which can be released back to solution within a day as shown in a subsequent releasing experiment. After 1 day of incubation, Mn oxides began to precipitate on the hyphae, which were characterized to be fibrous nanocrystals with a hexagonal birnessite-structure, these forming spherical aggregates with a diameter of ~1.5 µm. When the fungi were reacted using the Ningyo-toge mine water, the Mn concentration decreased at a rate of 1.0 mmol·day-1 per unit dry weight. The nanoscale processes associated with the fungi derived from the Ningyo-toge mine area provides additional insights into the existing mechanisms of Mn oxidation by filamentous fungi at other U mill tailings sites under circumneutral pH conditions. Such processes add to the class of reactions important to the sequestration of toxic elements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1994

Origins of interstellar and solar system: Carbonaceous materials

Carbon is a crucial atom in cosmochemistry. It is well-established that carbon is synthesized in stellar interiors after the main sequence, is ejected by red giants as small carbonaceous grains during their 'carbon star' phase, resides in the interstellar medium, and was later incorporated into the solar system. The mechanisms of carbon grain formation and later chemical processing are complex because, with only small thermodynamic differences, carbon can take on a bewildering variety of forms: diamond; oxides; carbides; graphite; aliphatic hydrocarbons; polycyclic aromatic hydrocarbons (PAH's); fullerenes; amorphous carbon; and other compounds. These are evidence for many of the forms of carbon found in astronomical observations. We seek to understand the possible astrophysical sites and conditions of the origins of different forms of carbon by combining state-of-the-art capabilities of carbon chemistry with astrophysical modeling. The work is a collaboration between Prof. Frenklach, a leading carbon materials scientist with both laboratory and computer modeling expertise and Prof. Feigelson, an astrophysicist with interests in star formation. The largest effort under this grant was devoted to developing this concept into a comprehensive quantitative model. In addition to explaining the astronomical properties of red giants producing carbonaceous grains, our model also can incorporate recent meteoritic findings. Finally, our induced nucleation grain formation model provides a natural explanation for the widespread presence of PAH emission bands in the Galactic interstellar medium. A brief synopsis of other activities sponsored under this grant and a list of publications from this grant is included.

Feigelson, Eric D.↗
NASA NTRS2014

Global and Regional Impacts of HONO on the Chemical Composition of Clouds and Aerosols

Recently, realistic simulation of nitrous acid (HONO) based on the HONO/NO(sub x) ratio of 0.02 was found to have a significant impact on the global budgets of HO(sub x) (OH + HO2) and gas phase oxidation products in polluted regions, especially in winter when other photolytic sources are of minor importance. It has been reported that chemistry-transport models underestimate sulphate concentrations, mostly during winter. Here we show that simulating realistic HONO levels can significantly enhance aerosol sulphate (S(VI)) due to the increased formation of H2SO4. Even though in-cloud aqueous phase oxidation of dissolved SO2 (S(IV)) is the main source of S(VI), it appears that HONO related enhancement of H2O2 does not significantly affect sulphate because of the predominantly S(IV) limited conditions, except over eastern Asia. Nitrate is also increased via enhanced gaseous HNO3 formation and N2O5 hydrolysis on aerosol particles. Ammonium nitrate is enhanced in ammonia-rich regions but not under ammonia-limited conditions. Furthermore, particle number concentrations are also higher, accompanied by the transfer from hydrophobic to hydrophilic aerosol modes. This implies a significant impact on the particle lifetime and cloud nucleating properties. The HONO induced enhancements of all species studied are relatively strong in winter though negligible in summer. Simulating realistic HONO levels is found to improve the model measurement agreement of sulphate aerosols, most apparent over the US. Our results underscore the importance of HONO for the atmospheric oxidizing capacity and corroborate the central role of cloud chemical processing in S(IV) formation.

HONO↗
NASA NTRS2014

Global and Regional Impacts of HONO on the Chemical Composition of Clouds and Aerosols

Recently, realistic simulation of nitrous acid (HONO) based on the HONO / NOx ratio of 0.02 was found to have a significant impact on the global budgets of HOx (OH + HO2) and gas phase oxidation products in polluted regions, especially in winter when other photolytic sources are of minor importance. It has been reported that chemistry-transport models underestimate sulphate concentrations, mostly during winter. Here we show that simulating realistic HONO levels can significantly enhance aerosol sulphate (S(VI)) due to the increased formation of H2SO4. Even though in-cloud aqueous phase oxidation of dissolved SO2 (S(IV)) is the main source of S(VI), it appears that HONO related enhancement of H2O2 does not significantly affect sulphate because of the predominantly S(IV) limited conditions, except over eastern Asia. Nitrate is also increased via enhanced gaseous HNO3 formation and N2O5 hydrolysis on aerosol particles. Ammonium nitrate is enhanced in ammonia-rich regions but not under ammonia-limited conditions. Furthermore, particle number concentrations are also higher, accompanied by the transfer from hydrophobic to hydrophilic aerosol modes. This implies a significant impact on the particle lifetime and cloud nucleating properties. The HONO induced enhancements of all species studied are relatively strong in winter though negligible in summer. Simulating realistic HONO levels is found to improve the model measurement agreement of sulphate aerosols, most apparent over the US. Our results underscore the importance of HONO for the atmospheric oxidizing capacity and corroborate the central role of cloud chemical processing in S(IV) formation

Global and regional impacts↗
DOE OSTI2023

Adsorbate-Induced Adatom Formation on Lithium, Iron, Cobalt, Ruthenium, and Rhenium Surfaces

Recent experimental and theoretical studies have demonstrated the reaction-driven metal–metal bond breaking in metal catalytic surfaces even under relatively mild conditions. Here, we construct a density functional theory (DFT) database for the adsorbate-induced adatom formation energy on the close-packed facets of three hexagonal close-packed metals (Co, Ru, and Re) and two body-centered cubic metals (Li and Fe), where the source of the ejected metal atom is either a step edge or a close-packed surface. For Co and Ru, we also considered their metastable face-centered cubic structures. We studied 18 different adsorbates relevant to catalytic processes and predicted noticeably easier adatom formation on Li and Fe compared to the other three metals. The NH 3 - and CO-induced adatom formation on Fe(110) is possible at room temperature, a result relevant to NH 3 synthesis and Fischer-Tropsch synthesis, respectively. There also exist other systems with favorable adsorbate effects for adatom formation relevant to catalytic processes at elevated temperatures (500–700 K). Our results offer insight into the reaction-driven formation of metal clusters, which could play the role of active sites in reactions catalyzed by Li, Fe, Co, Ru, and Re catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Effect of Thermal Oxidation on the Structure, Surface Texturing, and Microstructure Evolution in Nanocrystalline Ga-O-N Films

An extensive examination of the nanoscale, crystallographic growth dynamics of the system, which is impacted by the thermal energy given to the GaN, is carried out to derive a deeper understanding of the growth kinetics, morphology and microstructure evolution, chemical bonding, and optical properties of Ga-O-N films. Thermal annealing of GaN films is performed in the temperature range of 900–1200 °C. Crystal structure, phase formation, chemical composition, surface morphology, and microstructure evolution of Ga-O-N films are investigated as a function of temperature. Increasing temperature induces surface oxidation, which results in the formation of stable β-Ga2O3 phase in the GaN matrix, where the overall film composition evolves from nitride (GaN) to oxynitride (Ga-O-N). While GaN surfaces are smooth, planar, and featureless, oxidation induced granular-to-rod shaped morphology evolution is seen with increasing temperature to 1200 °C. The considerable texturing and stability of the nanocrystalline Ga-O-N on Si substrates can be attributed to the surface and interface driven modification because of thermal treatment. Corroborating with structure and chemical changes, Raman spectroscopic analyses also indicate that the chemical bonding evolution progresses from fully Ga-N bonds to Ga-O-N. While the GaN oxidation process starts with the formation of β-Ga 2 O 3 at an annealing temperature of 1000 °C, higher annealing temperatures induce structural distortion with the potential formation of Ga-O-N bonds. The structure-phase-chemical composition correlation, which will be useful for nanocrystalline materials for selective optoelectronic applications, is established in Ga-O-N films made by thermal treatment of GaN.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Black hole–neutron star mergers: The first mass gap and kilonovae

Observations of X-ray binaries indicate a dearth of compact objects in the mass range from ~2 –5 M ⊙ . The existence of this (first mass) gap has been used to discriminate between proposed engines behind core-collapse supernovae. From LIGO/Virgo observations of binary compact remnant masses, several candidate first mass gap objects, either neutron stars (NSs) or black holes (BHs), were identified during the O3 science run. Motivated by these new observations, we study the formation of BH-NS mergers in the framework of isolated classical binary evolution, using population synthesis methods to evolve large populations of binary stars (Population I and II) across cosmic time. We present results on the NS to BH mass ratios (q = M NS /M BH ) in merging systems, showing that although systems with a mass ratio as low as q = 0.02 can exist, typically BH-NS systems form with moderate mass ratios q = 0.1 –0.2. If we adopt a delayed supernova engine, we conclude that ~30% of BH-NS mergers may host at least one compact object in the first mass gap (FMG). Even allowing for uncertainties in the processes behind compact object formation, we expect the fraction of BH-NS systems ejecting mass during the merger to be small (from ~0.6 –9%). In our reference model, we assume: (i) the formation of compact objects within the FMG, (ii) natal NS/BH kicks decreased by fallback, (iii) low BH spins due to Tayler-Spruit angular momentum transport in massive stars. We find that ≲1% of BH-NS mergers will have any mass ejection and about the same percentage will produce kilonova bright enough to have a chance of being detected with a large (Subaru-class) 8 m telescope. Interestingly, all these mergers will have both a BH and an NS in the FMG.

79 ASTRONOMY AND ASTROPHYSICS↗