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At least 1,531 records · Page 85

Identification and characterization of structural nonlinearities in the Space Shuttle Main Engine

Structural nonlinearities should be considered in the analysis and modeling of mechanical systems for accuracy in predicting dynamic behavior. Moreover, checks for nonlinearity should address the type and class of nonlinearity in the structure and identify the probable cause. A series of experimental modal survey tests were carried out to determine and characterize the structural nonlinearities of the Space Shuttle Main Engine main injector. Different excitation regimes at various amplitudes were utilized to induce vibration and strain, and acceleration measurements were taken at judiciously selected locations. The test results indicated that both stiffness and damping nonlinearities were present.

Panossian, H. V.↗

Fatigue failure at low temperatures

The fatigue failure of steel 20 at low temperatures is considered. Strain hardening of the surface layers is found to occur in adiabatic conditions at low temperatures. That increases the fatigue strength. Fatigue cracks form and grow along the grain boundaries. The influence of impurities on the fatigue failure of low-carbon steel is studied.

42 ENGINEERING↗

Controlling structural phases of Sn through lattice engineering

Topology and superconductivity, two distinct phenomena, offer unique insight into quantum properties and their applications in quantum technologies, spintronics, and sustainable energy technologies. Tin (Sn) plays a pivotal role here as an element because of its two structural phases, α-Sn exhibiting topological characteristics and β-Sn showing superconductivity. Here, we demonstrate precise control of these phases in Sn thin films using molecular beam epitaxy with systematically varied lattice parameters of the buffer layer. The Sn films exhibit either β-Sn or α-Sn phases as the buffer layer's lattice constant varies from 6.10 Å to 6.48 Å, spanning the range from GaSb (like InAs) to InSb. Further, the crystal structures of α- and β-Sn films are characterized by x-ray diffraction and confirmed by Raman spectroscopy and scanning transmission electron microscopy. Atomic force microscopy validates the smooth, continuous surface morphology. Electrical transport measurements further verify the phases: resistance drop near 3.7 K for β-Sn superconductivity and Shubnikov-de Haas oscillations for α-Sn topological characteristics. Density functional theory shows that α-Sn is stable under tensile strain and β-Sn under compressive strain, aligning well with experimental findings. Hence, this study introduces a platform controlling Sn phases through lattice engineering, enabling innovative applications in quantum technologies and beyond.

36 MATERIALS SCIENCE↗

Growth window and effect of substrate symmetry in hybrid molecular beam epitaxy of a Mott insulating rare earth titanate

The conditions for the growth of stoichiometric GdTiO{sub 3} thin films by molecular beam epitaxy (MBE) are investigated. It is shown that relatively high growth temperatures (>750 Degree-Sign C) are required to obtain an MBE growth window in which only the stoichiometric film grows for a range of cation flux ratios. This growth window narrows with increasing film thickness. It is also shown that single-domain films are obtained by the growth on a symmetry-matched substrate. The influence of lattice mismatch strain on the electrical and magnetic characteristics of the GdTiO{sub 3} thin film is investigated.

36 MATERIALS SCIENCE↗

An Integrated Numerical Method to Predict the Strain Sensing Behavior of Flexible Conductive Fibers under Electric–Thermal Conditions

Flexible conductive textiles have attracted an increasing amount of attention due to being flexible and stretchable with multi-functions, in addition to the strain sensing function. In this paper, an integrated numerical method is established to predict the strain sensing behavior of PPy-coated flexible conductive fibers. Based on our previous investigation on the strain sensing behavior of the PPy-coated elastic conductive fibers, it has been known that the main strain sensing mechanisms of the conductive fibers are micro-cracks opening under stretching and closing under unloading. Therefore, in the numerical approach, extended finite element method is used to simulate the multi-crack initiation and propagation. Then, by establishing a representative element model including a single crack, the resistance variation with the increase in crack width/depth can be obtained using the electric–thermal package in ABAQUS software. Combining the relationship between crack width and strain, the relationship between fractional increment in resistance (ΔR/R{sub 0}) and the strain can be obtained. The prediction of the fractional increment in resistance (ΔR/R{sub 0}) versus strain is consistent with the experimental results of PPy-coated Lycra fibers. The new integrated method is further verified by experimental results of PPy-coated XLA fibers, showing that the integrated numerical approach can capture the complicated strain sensing mechanisms of PPy-coated elastic fibers and predict the strain sensing behavior of flexible conductive fibers. This approach will make it possible to shorten the period, and reduce the cost in R&D of the PPy-coated electrically conductive fibers, comparing with the corresponding experimental work.

36 MATERIALS SCIENCE↗

Characterization of the strain-rate–dependent mechanical response of single cell–cell junctions

Cell–cell junctions are essential components in multicellular structures and often experience strains of different magnitudes and rates. However, their mechanical behavior is currently underexplored due to the lack of techniques to quantitatively characterize junctional stress–strain relationships. Here we developed a polymeric microstructure to strain the mutual junction of a single cell pair while simultaneously recording the junction stress and observed previously unseen strain-rate–dependent junction responses. We showed that cytoskeleton growth could relax the stress buildup and prevent junction failure at low strain rates, while high strain rates led to synchronized junction failures at remarkably large strains (over 200%). We expect this platform and our biophysical understanding to form the foundation for the rate-dependent mechanics of cell–cell junctions.

36 MATERIALS SCIENCE↗

High performance Nb/TiNi nanocomposites produced by packaged accumulative roll bonding

Taking full advantage of intrinsic high strength of nano-reinforcements has been proven difficult in a composite until the concept of strain matching was experimental verified in a nanowire Nb/TiNi in-situ composite, which was obtained via solidifying eutectic Nb/TiNi and subsequent severe wire drawing. However, the volume fraction of the nano-reinforcement was dictated by eutectic reaction, which severely limited the development of high-performance composites. Here, the martensitic transformation nanocomposites were successfully acquired with increased volume fraction and changeable morphology of the nano-reinforcement through hot packaged ARB (PARB) and subsequent wire drawing. The nano-reinforcement with lamellar configuration in the composite could exhibit a large lattice strain of similar to 3.8%, which demonstrated the applicability and effectiveness of the strain matching principle in nano-lamellar composite. The obtained composites show a yield strength over 2.0 GPa and a quasi-linear elastic strain as larger as similar to 6.5% with adjustable apparent elastic modulus from 30 to 50 GPa.

42 ENGINEERING↗

Strain-Driven Mn-Reorganization in Overlithiated Li x Mn 2 O 4 Epitaxial Thin-Film Electrodes

Here, lithium manganate Li x Mn 2 O 4 (LMO) is a lithium ion cathode that suffers from the widely observed but poorly understood phenomenon of capacity loss due to Mn dissolution during electrochemical cycling. Here, operando X-ray reflectivity (low- and high-angle) is used to study the structure and morphology of epitaxial LMO (111) thin film cathodes undergoing lithium insertion and extraction to understand the inter-relationships between biaxial strain and Mn-dissolution. The initially strain-relieved LiMn 2 O 4 films generate in-plane tensile and compressive strains for delithiated (x < 1) and overlithiated (x > 1) charge states, respectively. The results reveal reversible Li insertion into LMO with no measurable Mn-loss for 0 < x < 1, as expected. In contrast, deeper discharge (x > 1) reveals Mn loss from LMO along with dramatic changes in the intensity of the (111) Bragg peak that cannot be explained by Li stoichiometry. These results reveal a partially reversible site reorganization of Mn ions ithin the LMO film that is not seen in bulk reactions and indicates a transition in Mn-layer toichiometry from 3:1 to 2:2 in alternating cation planes. Density functional theory calculations confirm that compressive strains (at x = 2) stabilize LMO structures with 2:2 Mn site distributions, therefore providing new insights into the role of lattice strain in the stability of LMO.

25 ENERGY STORAGE↗

Determination of residual stress in a microtextured α titanium component using high-energy synchrotron X-rays

A shrink-fit sample is manufactured with a Ti-8Al-1Mo-1V alloy to introduce a multiaxial residual stress field in the disk of the sample. A set of strain and orientation pole figures are measured at various locations across the disk using synchrotron high-energy X-ray diffraction. Two approaches—the traditional sin 2 Ψ method and the bi-scale optimization method—are taken to determine the stresses in the disk based on the measured strain and orientation pole figures, to explore the range of solutions that are possible for the stress field within the disk. While the stress components computed using the sin 2 Ψ method and the bi-scale optimization method have similar trends, their magnitudes are significantly different. Lastly, it is suspected that the local texture variation in the material is the cause of this discrepancy.

42 ENGINEERING↗

Monodomain Liquid‐Crystal Elastomer Lattices for Broad Strain‐Rate Mechanical Damping

Designing structures that effectively dissipate energy across a broad range of mechanical loading rates, including those from compression, shock, and vibration, poses a significant engineering challenge. In this study, liquid‐crystal elastomers (LCEs), which possess anisotropic properties due to the alignment of their polymer backbone, are explored. As a result, LCEs exhibit a soft elastic response under mechanical loading, making them ideal for energy dissipation. Advances in additive manufacturing (AM) enable simple fabrication of foamlike dissipative structures with complex lattice geometries. Herein, direct ink write 3D printing, an extrusion AM method, is used to fabricate aligned, monodomain LCE lattice structures for broad strain‐rate mechanical damping. In this work, it is shown that these structures can dissipate strain energy in quasi‐static environments, comparable to traditional elastomeric lattices, and provide improved damping under high strain‐rate drop testing due to LCE soft elasticity. Additionally, under dynamic mechanical vibration, monodomain LCE lattices enhance damping at structural natural frequencies and provide high‐frequency attenuation. Finally, in these findings, a promising method is presented for fabricating mechanical damping devices that effectively dissipate energy across a broad range of loading rates.

3D printings↗

A human factors approach towards the design of a new glovebox glove for Los Alamos National Laboratory

Present day glovebox gloves at Los Alamos National Laboratory (LANL) are underdeveloped and ergonomically inaccurate. This problem results in numerous sprain and strain injuries every year for employees who perform glovebox work. In addition to injuries, using the current glovebox glove design also contributes to breaches and contamination. The current glove used today at LANL has several problems: (1) The length of the fingers is incorrect, (2) the web spacing between the fingers is nonexistent, (3) the angles between each digit on the finger are incorrect, (4) the thumb is placed inaccurately, and (5) the length of the hand is incorrect.

42 ENGINEERING↗

Performance Evaluation and Modeling of Erosion Resistant Turbine Engine Thermal Barrier Coatings

The erosion resistant turbine thermal barrier coating system is critical to the rotorcraft engine performance and durability. The objective of this work was to determine erosion resistance of advanced thermal barrier coating systems under simulated engine erosion and thermal gradient environments, thus validating a new thermal barrier coating turbine blade technology for future rotorcraft applications. A high velocity burner rig based erosion test approach was established and a new series of rare earth oxide- and TiO2/Ta2O5- alloyed, ZrO2-based low conductivity thermal barrier coatings were designed and processed. The low conductivity thermal barrier coating systems demonstrated significant improvements in the erosion resistance. A comprehensive model based on accumulated strain damage low cycle fatigue is formulated for blade erosion life prediction. The work is currently aiming at the simulated engine erosion testing of advanced thermal barrier coated turbine blades to establish and validate the coating life prediction models.

Miller, Robert A.↗

Burner liner thermal/structural load modelling

The objective of this program is to develop a thermal data transfer computer program module for the burner liner thermal structural load modeling program. This will be accomplished by (1) reviewing existing methodologies for thermal data transfer and selecting three heat transfer codes for application in this program; (2) evaluating the selected codes to establish criteria for developing a computer program module to transfer thermal data from the heat transfer codes to selected stress analysis codes; (3) developing the automated thermal load transfer module; and (4) verifying and documenting the module. In aircraft turbine engine hot section components, cyclic thermal stresses are the most important damage mechanism. Consequently, accurate and reliable prediction of thermal loads is essential to improving durability. To achieve this goal, a considerable effort over the past 20 years has been devoted to the acquisition of engine temperature test data, as well as the development of accurate, reliable, and efficient computer codes for the prediction of steady state and transient temperatures and for the calculation of elastic and inelastic cyclic stresses and strains in hot section components. There is a need for continued development of these codes, because the availability of more accurate analysis techniques for complex configurations has enabled engine designers to use more sophisticated designs to achieve higher cycle efficiency and reduce weight.

Maffeo, R. J.↗

CRISPR EnAbled trackable genome engineering for isopropanol production in Escherichia coli

Isopropanol is an important target molecule for sustainable production of fuels and chemicals. Increases in DNA synthesis and synthetic biology capabilities have resulted in the development of a range of new strategies for the more rapid design, construction, and testing of production strains. Here, we report on the use of such capabilities to construct and test 903 different variants of the isopropanol production pathway in Escherichia coli . We first constructed variants to explore the effect of codon optimization, copy number, and translation initiation rates on isopropanol production. The best strain (PA06) produced isopropanol at titers of 17.5 g/L, with a yield of 0.62 (mol/mol), and maximum productivity of 0.40 g/L/h. We next integrated the isopropanol synthetic pathway into the genome and then used the CRISPR EnAbled Trackable genome Engineering (CREATE) strategy to generate an additional 640 individual RBS library variants for further evaluation. After testing each of these variants, we constructed a combinatorial library containing 256 total variants from four different RBS levels for each gene. The best producing variant, PA14, produced isopropanol at titers of 7.1 g/L at 24 h, with a yield of 0.75 (mol/mol), and maximum productivity of 0.62 g/L/h (which was 0.22 g/L/h above the parent strain PA07). As a result, we demonstrate the ability to rapidly construct and test close to ~1000 designer strains and identify superior performers.

09 BIOMASS FUELS↗

Through-thickness microstructural evolution during grain boundary engineering type thermomechanical processing and its implication on sensitization behavior in austenitic stainless steel

Highlights: • GBE-treated 304L steel exhibits thickness-dependent microstructural evolution. • Degree of sensitization increases from surface to interior in GBE specimen. • Low fractal dimension and large TRD size lead to lesser sensitization at surface. • As-received specimen shows high albeit thickness-independent sensitization behavior. • Higher residual strain leads to higher sensitization at surface of deformed sample. - Abstract: Through-thickness microstructural variations and their synergistic influence on degree of sensitization in grain boundary engineering (GBE) treated 304L stainless steel was compared with solution-annealed and marginally cold-worked (~ 3% thickness reduction) specimens. The solution-annealed specimen has shown higher degree of sensitization due to the presence of lower fraction of Σ3 (as well as other low Σ CSL) boundaries and dominant random high-angle boundaries (RHAGBs) connectivity. However, it has shown thickness-independent sensitization behavior as grain boundary character distribution, residual strain and grain boundary network topology towards thickness direction are similar. Owing to higher residual strain, as revealed by local misorientation analysis, the cold-worked specimen showed maximum degree of sensitization (higher than solution-annealed condition) at surface. The GBE specimen has shown much lower degree of sensitization at surface due to higher-fraction of Σ3 boundaries and discontinuous RHAGBs connectivity. However, increasing fraction of RHAGBs and their connectivity, as confirmed by twinning-related domain and fractal analysis, cause more sensitization at interior of this specimen. In spite of this, the degree of sensitization at the interior of GBE specimen is lower than the solution-annealed or cold-worked specimen. Even though the residual strain in GBE specimen is higher than the solution-annealed condition, the lower degree of sensitization indicates that the grain boundary character distribution and grain boundary network topology have higher implication than residual strain in controlling sensitization.

36 MATERIALS SCIENCE↗