Influence of Zr substitution on the stabilization of ThMn{sub 12}-type (Nd{sub 1−α}Zr{sub α})(Fe{sub 0.75}Co{sub 0.25}){sub 11.25}Ti{sub 0.75}N{sub 1.2−1.4} (α = 0–0.3) compounds
The influence of Zr substitution in ThMn{sub 12} compounds was investigated using strip casting alloys. It was found that Zr substitution stabilized (Nd{sub 1−α}Zr{sub α})(Fe{sub 0.75}Co{sub 0.25}){sub 11.25}Ti{sub 0.75}N{sub 1.2−1.4} (α = 0–0.3) compounds. Specifically, a reduction in the lattice constant along the a-axis was observed. Energy-dispersive X-ray spectroscopy mapping combined with Cs-corrected scanning transmission electron microscopy indicated that Zr atoms preferentially occupied Nd 2a sites. Both the magnetic anisotropy field and saturation polarization were maximum at Zr substitution ratio α = 0.1. The (Nd{sub 1−α}Zr{sub α})(Fe{sub 0.75}Co{sub 0.25}){sub 11.25}Ti{sub 0.75}N{sub 1.2−1.4} (α = 0–0.3) compounds displayed higher saturation polarization than Nd{sub 2}Fe{sub 14}B at high temperatures.