Exo-electron emission during heterogeneous catalysis /the effect of external electric potentials/.
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Hoenig, S. A.↗
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Results for “Heterogeneity”
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Thermal conductivity of heterogeneous mixtures and lunar soils
The theoretical evaluation of the effective thermal conductivity of granular materials is discussed with emphasis upon the heat transport properties of lunar soil. The following types of models are compared: probabilistic, parallel isotherm, stochastic, lunar, and a model based on nonlinear heat flow system synthesis.
Vachon, R. I.↗
Heterogeneities in the solar nebula
Oxygen isotopic compositions of the high-temperatue phases in carbonaceous chondrites define a mixing line with an O-16 rich component and show little superimposed chemical isotope fractionation. Within a single inclusion in Allende, variations of delta O-18 and delta O-17 of 39% are found. The ordinary chondrites are slightly displaced from the terrestrial fractionation trend, implying that at least 0.2% of the oxygen in terrestrial rocks was derived from the O-16 rich component.
Clayton, R.↗
On the oscillation of the laterally heterogeneous earth, 1
The perturbative effects, as cause by lateral inhomogeneities in the earth structure and by Coriolis force, contaminate the originally toroidal and spheroidal earth's oscillations, making them of mixed type. For this reason, in order to make the computation of the perturbations more uniform and homogeneous, it was suggested that the earth's free oscillations be expanded into a series in terms of generalized harmonics familiar from the theory of angular momentum in quantum mechanics. Making use of Gibbsian symbolism and of some operators from the theory of angular momentum, explicit expressions were deduced for the perturbative terms in the differential equation of the earth's free oscillations. Decomposition of the strain tensor in terms of canonical vectors was also obtained.
Musen, P.↗
Amino terminal residue heterogeneity of bovine and ovine growth hormones as revealed by polyacrylamide gel electrophoresis
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Lorenson, M. G.↗
Heterogeneity in titaniferous lunar basalts
Small but real chemical differences exist between subsamples of fine-grained quench-textured titaniferous lunar basalts. The existence of different textural domains with different chemistries is thought to account for most of this variation. In addition to the textural domains, lunar sample 74275 has a population of olivine 'megacrysts' as well as dunite fragments. These materials are thought to be extraneous and to compromise the primary nature of 74275. Recognition of the small chemical variations present may aid in understanding some discrepancies in the experimental-petrology literature. However, these small variations have a distressing petrogenetic significance since they severely limit resolution in recognizing the number and depth of origin of primary magmas.
Walker, D.↗
Heterogeneous chemical reactions: Preparation of monodisperse latexes
It is demonstrated that a photoinitiated emulsion polymerization can be carried out to a significant conversion in a SPAR rocket prototype polymerization vessel within the six minutes allowed for the experiment. The percentage of conversion was determined by both dilatometry and gravimetric methods with good agreement. The experimental results lead to the following conclusions: (1) emulsion polymerizations can be carried out to conversions as high as 75%, using a stable micellized styrene-SLS system plus photoinitiator; (2) dilatometry can be used to accurately determine both the rate and conversion of polymerization; (3) thermal expansion due to the light source and heat of reaction is small and can be corrected for if necessary; (4) although seeded emulsion polymerizations are unfavorable in photoinitiation, as opposed to chemical initiation, polymerizations can be carried out to at least 15% conversion using 7940A seed particles, with 0.05% solids; and (5) photoinitiation should be used to initiate polymerization in the SPAR rocket experiments because of the mechanical simplicity of the experiment.
Vanderhoff, J. W.↗
Doubly-curved variable-thickness isoparametric heterogeneous finite element
This paper describes an element streamlined for the analysis of doubly-curved, variable-thickness structural components and illustrates its effective application to vibration and static problems. The element is isoparametric, doubly-curved, thin-shell and triangular with variable thickness and accounts for anisotropic, inhomogeneous elastic material behavior. The element has six nodes (three corner and three mid-side) with five degrees-of-freedom (DOF) per node - three translations and two rotations. Quadratic isoparametric interpolation polynomials are used to express the element geometry and displacement variables in terms of corresponding nodal variables.
Minich, M. D.↗
Observations of exoelectron emission associated with heterogeneous catalysis
It is suggested that the exoelectron emission from the catalyst may be used to monitor the rate of oxidation of CO and CH4 over palladium catalysts. Indirect heating of the catalyst and atmospheric pressure have no effect upon this monitoring system. Although the mechanism relating catalysis to exoelectron emission is not clear, it is considered possible that electron emission is triggered by the adsorption-desorption cycle.
Hoenig, S. A.↗
Heterogeneities in the solar nebula
Oxygen isotopic compositions of the high-temperature phases in carbonaceous chondrites define a mixing line with an 0-16-rich component and show little superimposed chemical isotope fractionation. Within a single inclusion in Allende, variations of delta 0-18 and delta 0-17 of 39 thousands are found. The ordinary chondrites are slightly displaced from the terrestrial fractionation trend, implying that at least 0.2 percent of the oxygen in terrestrial rocks was derived from the 0-16-rich component.
Clayton, R. N.↗
Instrumentation techniques for studying heterogeneous combustion
Velocity measurements in flames and the simultaneous measurement of droplet size and velocity with the aid of laser anemometry are considered along with methods of particle size measurement and techniques based on laser Raman spectroscopy. Attention is given to high-speed photography and holography, computer compensated thermocouples, and the determination of turbulence characteristics. The employment of suction probes is also discussed, taking into account sampling methods, the effects of temperature change in sampling probes on particle formation, and the chemical analysis of samples.
Chigier, N. A.↗
Seismic indication of broad-scale lateral heterogeneities in the lunar interior - A preliminary report
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Nakamura, Y.↗
Luna 24 - Lateral heterogeneity in the lunar crust
Results of petrological investigations of Luna 24 soil samples are compared with data from Apollo and other Luna missions in order to determine the large scale composition of the lunar surface and crust. Modal analysis of the 90 to 150 micron soil fraction and electron microprobe analysis of glass spheres and fragments of the Luna 24 core sample are presented. High and low MgO mare basalt compositional clusters are found, suggesting the derivation of southern Mare Crisium basalts from two magmas. A model of Luna 24 soils as being composed of a mixture of glass-poor mare material and glass-rich highland material is found to be consistent with glass and agglutinate modal abundances. Comparisons show that potassium, and by inference all lithophile trace elements, are depleted on the eastern limb of the moon relative to the central nearside. The observed depletion is interpreted to be characteristic of the underlying crust and mantle as well as the surface.
Warner, J. L.↗
Heterogeneous phase reactions of Martian volatiles with putative regolith minerals
The chemical reactivity of several minerals thought to be present in Martian fines is tested with respect to gases known in the Martian atmosphere. In these experiments, liquid water is excluded from the system, environmental temperatures are maintained below 0 C, and the solar illumination spectrum is stimulated in the visible and UV using a xenon arc lamp. Reactions are detected by mass spectrometric analysis of the gas phase over solid samples. No reactions were detected for Mars nominal gas over sulfates, nitrates, chloride, nontronite clay, or magnetite. Oxidation was not observed for basaltic glass, nontronite, and magnetite. However, experiments incorporating SO2 gas an expected product of volcanism and intrusive volatile release - gave positive results. Displacement of CO2 by SO2 occurred in all four carbonates tested. These reactions are catalyzed by irradiation with the solar simulator. A calcium nitrate hydrate released NO2 in the presence of SO2. These results have implications for the cycling of atmospheric CO2, H2O, and N2 through the regolith.
Clark, B. C.↗
Isotopic heterogeneities in the solar system - Special report
The paper discusses the nature of isotopic anomalies in solar system material with emphasis on correlated anomalies in refractory elements. Evidence for the existence of short-lived radioactive nuclides in the early solar system is used to estimate the time scale for the last injection of freshly synthesized nuclear material. It is shown that the early solar nebula was incompletely mixed and contained debris which was injected from a stellar source at most a few million years prior to the formation of the solar system. The average solar system material consists of ambient interstellar material deficient in certain nuclear species to which a small fraction of freshly synthesized material was added. The isotopic variations reflect slightly different proportions of nuclei from different stellar sources which were locally well mixed and homogenized prior to or during the formation of the early solar nebula condensates.
Wasserburg, G. J.↗
Radar measurement of heterogeneous small-scale surface texture on Mars Chryse
Radar measurements from Chryse Planitia in 1978 confirm earlier estimates of 4-5 deg rms slope (on meter scales) over 45-50 deg W longitude. The new measurements also confirm a skewing of the measured spectra. This has now been interpreted as a combined result of large-scale surface tilt and a side effect of the decrease in small-scale roughness as the subradar point moves from the basin floor toward the west.
Simpson, R. A.↗
Heating of the moon by heterogeneous accretion
Monte Carlo models of lunar accretion are developed by randomly sampling mass and velocity distributions of objects in the solar nebula in circumsolar and circumterrestrial orbits. The thermal effect of an impact is expressed as the volume of melt produced; the melt volumes produced by each Monte Carlo case are sorted into regions to produce percentage melt estimates as a function of radius. One-hundred cases are calculated to obtain a range of plausible thermal histories for lunar accretion. The average melt percentage estimates show substantial deep melting, but the spread of melt percentage values about the mean from the random sampling procedure is wide enough to include 0% melting for radii below 100 km and 100% melting for radii below 500 km.
Ransford, G. A.↗
Upper mantle heterogeneity: Comparisons of regions south of Australia with Philippine Basin
The nature of mass anomalies that occur beneath the regions of negative residual depth anomalies were identified. Residual geoid anomalies with negative residual depth anomalies are identified in the Philippine Basin (negative) and in the region south of Australia (positive and negative). In the latter region the geoid anomalies are eastward and the depth anomaly is northeast. It is suggested that the negative depth anomaly and the compensating mass excess in the uppermost mantle developed in the Eocene as the lithosphere of the west Philippine basin formed. Heating of the deeper upper mantle which causes slow surface wave velocities and negative gravity and geoid anomalies may be a younger phenomenon which is still in progress.
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