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At least 1,531 records · Page 85

Electron Energy-Loss Spectroscopy and Differential Phase Contrast Imaging with Active Decision in Multimodal Electron Microscopy: Isotopic detection at the atomic scale

Isotopic engineering provides a powerful route to control phonon behavior in crystalline solids, enabling fundamental studies of lattice dynamics and heat transport at the atomic scale. Here, we directly visualize isotope-dependent phonon propagation in epitaxial Cr 2 O 3 using aberration-corrected scanning transmission electron microscopy (STEM) combined with monochromated, high-energy-resolution electron energy-loss spectroscopy (EELS). Guided by ab initio phonon calculations, we demonstrate that optical phonon modes above 70 meV are predominantly oxygen-derived and exhibit measurable redshifts upon substitution of natural 16 O by enriched 18 O. Spatially resolved vibrational spectrum imaging reveals isotope-enriched tracer layers within Cr 2 O 3 thin films, correlating isotope concentration with phonon intensity variations and vibrational energy shifts. At the nanometer and atomic scales, vibrational EELS mapping uncovers coherent phonon propagation across isotopic interfaces, consistent with theoretical phonon density of states and dispersion relations. These results establish vibrational EELS as a quantitative probe for isotope-dependent phonon transport in materials, opening new possibilities for studying energy dissipation and lattice dynamics.

36 MATERIALS SCIENCE↗

Formation mechanisms of boron oxide films fabricated by large-area electron beam-induced deposition of trimethyl borate [Formation Mechanisms of Boron Oxide Fillms Fabricated by Large Area Electron Beam-Induced Deposition of Trimethyl Borate]

Boron-containing materials are increasingly drawing interest for the use in electronics, optics, laser targets, neutron absorbers, and high-temperature and chemically resistant ceramics. In this article, the first investigation into the deposition of boron-based material via electron beam-induced deposition (EBID) is reported. Thin films were deposited using a novel, large-area EBID system that is shown to deposit material at rates comparable to conventional techniques such as laser-induced chemical vapor deposition. The deposition rate and stoichiometry of boron oxide fabricated by EBID using trimethyl borate (TMB) as precursor is found to be critically dependent on the substrate temperature. By comparing the deposition mechanisms of TMB to the conventional, alkoxide-based precursor tetraethyl orthosilicate it is revealed that ligand chemistry does not precisely predict the pathways leading to deposition of material via EBID. Lastly, the results demonstrate the first boron-containing material deposited by the EBID process and the potential for EBID as a scalable fabrication technique that could have a transformative effect on the athermal deposition of materials.

36 MATERIALS SCIENCE↗

Numerical Simulation of Electron Magnetohydrodynamics with Landau-quantized Electrons in Magnetar Crusts

Abstract In magnetar crusts, magnetic fields are sufficiently strong to confine electrons into a small to moderate number of quantized Landau levels. This can have a dramatic effect on the crust's thermodynamic properties, generating field-dependent de Haas–van Alphen oscillations. We previously argued that the large-amplitude oscillations of the magnetic susceptibility could enhance the ohmic dissipation of the magnetic field by continuously generating small-scale, rapidly dissipating field features. This could be important to magnetar field evolution and contribute to their observed higher temperatures. To study this, we performed quasi-3D numerical simulations of electron MHD in a representative volume of neutron star crust matter, for the first time including the magnetization and magnetic susceptibility resulting from Landau quantization. We find that the potential enhancement in the ohmic dissipation rate due to this effect can be a factor ∼3 for temperatures of the order of 10 8 K, and ∼4.5 for temperatures of the order of 5 × 10 7 K, depending on the magnetic field configuration. The nonlinear Hall term is crucial to this amplification: without it, the magnetic field decay is only enhanced by a factor ≲2 even at 5 × 10 7 K. These effects generate a high wavenumber plateau in the magnetic energy spectrum associated with the small-scale de Haas–van Alphen oscillations. Our results suggest that this mechanism could help explain the magnetar heating problem, though due to the effect's temperature-dependence, full magneto-thermal evolution simulations in a realistic stellar model are needed to judge whether it is viable explanation.

Rau, Peter B. (ORCID:0000000152209277)↗