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At least 1,531 records · Page 85

Sub-millisecond keyhole pore detection in laser powder bed fusion using sound and light sensors and machine learning

Laser powder bed fusion is a mainstream additive manufacturing technology widely used to manufacture complex parts in prominent sectors, including aerospace, biomedical, and automotive industries. However, during the printing process, the presence of an unstable vapor depression can lead to a type of defect called keyhole porosity, which is detrimental to the part quality. In this study, we developed an effective approach to locally detect the generation of keyhole pores during the printing process by leveraging machine learning and a suite of optical and acoustic sensors. Simultaneous synchrotron x-ray imaging allows the direct visualization of pore generation events inside the sample, offering high-fidelity ground truth. A neural network model adopting SqueezeNet architecture using single-sensor data was developed to evaluate the fidelity of each sensor for capturing keyhole pore generation events. Our comparative study shows that the near infrared images gave the highest prediction accuracy, followed by 100 kHz and 20 kHz microphones, and the photodiode sensitive to processing laser wavelength had the lowest accuracy. Using a single sensor, over 90% prediction accuracy can be achieved with a temporal resolution as short as 0.1 ms. A data fusion scheme was also developed with features extracted using SqueezeNet neural network architecture and classification using different machine learning algorithms. Our work demonstrates the correlation between the characteristic optical and acoustic emissions and the keyhole oscillation behavior, and thereby provides strong physics support for the machine learning approach.

36 MATERIALS SCIENCE↗

An Assessment of the Safeguards Implications of Particle and Alloy Formation in MSRs

Molten salt reactors (MSRs) present unique challenges for applying safeguards measures and differ significantly from traditional nuclear reactors. Although the special fissionable materials within MSRs principally exist as dissolved species within the fuel salt, key actinides of interest may also be converted to solid phases including alloys and precipitated oxides via chemical and electrochemical reactions. These solid-phase components will complicate the nuclear material accounting and control (NMAC) approaches that have, so far, primarily targeted measurements of the liquid salt itself. For example, most of the proposed monitoring and characterization methods for MSRs are reliant on homogeneity of the salt and the ability to maintain accountable materials in solution. Solid deposits and particulates could invalidate the assumption of homogeneity and necessitate the use of new models and measurement tools to permit a full accounting of all nuclear material in an MSR. To address this, the likelihood of solids formation in MSRs, estimated the rate at which these solids could form, and assessed the monitoring tools that are available to account for the presence of these materials were examined. Specifically, three solid forming mechanisms were investigated, including (1) the accumulation of actinides within the MSR’s structural materials due to alloying, (2) the accumulation of actinides within noble metal fission product particulates, and (3) the generation of actinide oxides from interactions with salt impurities. These modeling-informed studies were completed with considerations to both fluoride- and chloride-containing salts. It was determined that, although measurable amounts of special fissionable material were expected to alloy with the structural elements and fission products, the predicted amounts were below levels considered as significant quantities (SQ) by the International Atomic Energy Agency (IAEA). However, it was determined that sufficiently large oxygen concentrations could potentially lead to significant quantities of special fissionable material being converted to solid oxide phases. As such, a comparative study of technologies that are commercially available to assist in monitoring and accountancy of this material was presented. Policy implications, design recommendations, and suggestions for follow-on experimental work were also presented to further assist reactor vendors in designing and controlling the fuel salt chemistry to address potential safeguards considerations.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Improved Nested Sampling and Surrogate-Enabled Comparison With Other Marginal Likelihood Estimators

Estimating marginal likelihood is of central importance to Bayesian model selection and/or model averaging. The nested sampling method has been recently used together with the Metropolis-Hasting (M-H) sampling algorithm for estimating marginal likelihood. This study develops a new implementation of nested sampling by using the DiffeRential Evolution Adaptive Metropolis (DREAMzs) sampling algorithm. The two implementations of nested sampling are evaluated for four models of a synthetic groundwater flow modeling. The DREAMzs-based nested sampling outperforms the M-H-based nested sampling in terms of their accuracy, convergence, efficiency, and stability, which is attributed to the fact that DREAMzs is more robust than M-H for parameter sampling. The nested sampling method is also compared with four other methods (arithmetic mean, harmonic mean, stabilized harmonic mean, and thermodynamic integration) commonly used for estimating marginal likelihood and posterior probability of the four groundwater models. The comparative study requires hundreds of millions of model executions, which would not be possible without using surrogate models to replace the original models. Using the arithmetic mean estimator as the reference, the comparison reveals that thermodynamic integration outperforms nested sampling in terms of accuracy and stability, whereas nested sampling is more computationally efficient to reach to convergence. Here, the harmonic mean and stabilized harmonic mean methods give the worst marginal likelihood estimation. Accurate marginal likelihood estimation is important for accurate estimation of posterior model probability and better predictive performance of Bayesian model averaging.

54 ENVIRONMENTAL SCIENCES↗

Fractionation of sulfur isotopes by Desulfovibrio vulgaris mutants lacking hydrogenases or type I tetraheme cytochrome c3

The sulfur isotope effect produced by sulfate reducing microbes is commonly used to trace biogeochemical cycles of sulfur and carbon in aquatic and sedimentary environments. To test the contribution of intracellular coupling between carbon and sulfur metabolisms to the overall magnitude of the sulfur isotope effect, this study compared sulfur isotope fractionations by mutants of Desulfovibrio vulgaris Hildenborough. We tested mutant strains lacking one or two periplasmic (Hyd, Hyn-1, Hyn-2, and Hys) or cytoplasmic hydrogenases (Ech and CooL), and a mutant lacking type I tetraheme cytochrome (TpI-c3). In batch culture, wild-type D. vulgaris and its hydrogenase mutants had comparable growth kinetics and produced the same sulfur isotope effects. This is consistent with the reported redundancy of hydrogenases in D. vulgaris. However, the TpI-c3 mutant (cycA) exhibited slower growth and sulfate reduction rates in batch culture, and produced more H2 and an approximately 50% larger sulfur isotope effect, compared to the wild type. The magnitude of sulfur isotope fractionation in the CycA deletion strain, thus, increased due to the disrupted coupling of the carbon oxidation and sulfate reduction pathways. In continuous culture, wild-type D. vulgaris and the CycA mutant produced similar sulfur isotope effects, underscoring the influence of environmental conditions on the relative contribution of hydrogen cycling to the electron transport. The large sulfur isotope effects associated with the non-ideal stoichiometry of sulfate reduction in this study imply that simultaneous fermentation and sulfate reduction may be responsible for some of the large naturally-occurring sulfur isotope effects. Overall, mutant strains provide a powerful tool to test the effect of specific redox proteins and pathways on sulfur isotope fractionation.

59 BASIC BIOLOGICAL SCIENCES↗

Fiber-Detector Subsystem Loss Comparison for A Ground-Based Photon-Counting Optical Receiver

In this paper we present a comparative study of the losses associated with fiber-coupled single-photon detectors in two different configurations, each with the goal of receiving a pulsed-position modulated signal with a maximum data rate of 267 Mbps. First, we consider a 7x1 few-mode-fiber (FMF) photonic lantern coupled to seven individual superconducting nanowire single photon detectors (SNSPDs). In the second configuration we assess a single FMF coupled to a 16-channel monolithic SNSPD array. In each case we measure and compare combined fiber coupling, SNSPD blocking, and system efficiency losses under emulated atmospheric turbulence conditions. We address subsystem impact on link performance and analyze feasibility for future NASA lunar and deep-space optical communications missions.

Fiber optics↗

Fiber-Detector Subsystem Loss Comparison for A Ground-Based Photon-Counting Optical Receiver

A comparative study of the losses associated with fiber-coupled single-photon detectors in two different configurations, each with the goal of receiving a pulsed-position modulated signal with a maximum data rate of 267 Mbps. First, we consider a 7x1 few-mode-fiber (FMF) photonic lantern coupled to seven individual superconducting nanowire single photon detectors (SNSPDs). In the second configuration we assess a single FMF coupled to a 16-channel monolithic SNSPD array. In each case we measure and compare combined fiber coupling, SNSPD blocking, and system efficiency losses under emulated atmospheric turbulence conditions. We address subsystem impact on link performance and analyze feasibility for future NASA lunar and deep-space optical communications missions.

Fiber optics↗

Performance Analysis of Transposition Models Simulating Solar Radiation on Inclined Surfaces

Transposition models have been widely used in the solar energy industry to simulate solar radiation on inclined photovoltaic panels. Following numerous studies comparing the performance of transposition models, this work aims to understand the quantitative uncertainty in state-of-the-art transposition models and the sources leading to the uncertainty. Our results show significant differences between two highly used isotropic transposition models, with one substantially underestimating the diffuse plane-of-array irradiances when diffuse radiation is perfectly isotropic. In the empirical transposition models, the selection of the empirical coefficients and land surface albedo can both result in uncertainty in the output. This study can be used as a guide for the future development of physics-based transposition models and evaluations of system performance.

14 SOLAR ENERGY↗

TEST REPORT #21: Compressor Calorimeter Test of R-404A Alternatives ARM-31a, D2Y-65, L-40, and R32/ R-134a (50/50)

As a contribution to the AHRI Low-GWP Alternative Refrigerants Evaluation Program (AREP), this study compares the performance of four lower-GWP alternative refrigerants, ARM-31a, D2Y-65, L-40, and R-32 + R-134a mixture, to that of refrigerant R-404A (baseline) in a scroll compressor designed for medium temperature refrigeration applications. These comparisons were carried out via compressor calorimeter tests performed on a compressor designed for refrigerant R-404A and having a nominal rated capacity of 23,500 Btu/hr. Tests were conducted over a suction dew point temperature range of -10°F to 35°F in 5°F increments and a discharge dew point temperature range of 70°F to 140°F in 10°F increments. All the tests were performed with 20°F superheat, 40°F superheat, and 65°F suction temperature. A liquid subcooling level of 10°F to 15°F was maintained for all the test conditions. However, the cooling capacities reported in this study are normalized for 0°F subcooling. The tests showed that the compressor energy efficiency ratio (EER) and cooling capacity with all four alternative refrigerants tested are higher at higher saturation suction and saturation discharge temperature and lower at lower saturation suction and saturation discharge temperature, compared to that of R-404A. Discharge temperatures of all the alternative refrigerants were higher than that of R-404A at all test conditions.

Alternative Refrigerants↗

Novel Aldo-Keto Reductases for the Biocatalytic Conversion of 3-Hydroxybutanal to 1,3-Butanediol: Structural and Biochemical Studies

The nonnatural alcohol 1,3-butanediol (1,3-BDO) is a valuable building block for the synthesis of various polymers. One of the potential pathways for the biosynthesis of 1,3-BDO includes the biotransformation of acetaldehyde to 1,3-BDO via 3-hydroxybutanal (3-HB) using aldolases and aldo-keto reductases (AKRs). This pathway requires an AKR selective for 3-HB, but inactive toward acetaldehyde, so it can be used for one-pot synthesis. In this work, we screened more than 20 purified uncharacterized AKRs for 3-HB reduction and identified 10 enzymes with significant activity and nine proteins with detectable activity. PA1127 from Pseudomonas aeruginosa showed the highest activity and was selected for comparative studies with STM2406 from Salmonella enterica serovar Typhimurium, for which we have determined the crystal structure. Both AKRs used NADPH as a cofactor, reduced a broad range of aldehydes, and showed low activities toward acetaldehyde. The crystal structures of STM2406 in complex with cacodylate or NADPH revealed the active site with bound molecules of a substrate mimic or cofactor. Site-directed mutagenesis of STM2406 and PA1127 identified the key residues important for the activity against 3-HB and aromatic aldehydes, which include the residues of the substrate-binding pocket and C-terminal loop. Our results revealed that the replacement of the STM2406 Asn65 by Met enhanced the activity and the affinity of this protein toward 3-HB, resulting in a 7-fold increase in k cat / K m . Our work provides further insights into the molecular mechanisms of the substrate selectivity of AKRs and for the rational design of these enzymes toward new substrates. IMPORTANCE In this study, we identified several aldo-keto reductases with significant activity in reducing 3-hydroxybutanal to 1,3-butanediol (1,3-BDO), an important commodity chemical. Biochemical and structural studies of these enzymes revealed the key catalytic and substrate-binding residues, including the two structural determinants necessary for high activity in the biosynthesis of 1,3-BDO. This work expands our understanding of the molecular mechanisms of the substrate selectivity of aldo-keto reductases and demonstrates the potential for protein engineering of these enzymes for applications in the biocatalytic production of 1,3-BDO and other valuable chemicals.

59 BASIC BIOLOGICAL SCIENCES↗

The fabrication of polyfluorene and polycarbazole-based photovoltaic devices using an air-stable process route

We report a comparative study based on the fabrication of polymer:fullerene photovoltaic (PV) devices incorporating carbazole, fluorene, and a PTB based co-polymer. We have explored the efficiency and performance of such devices when the active polymer:fullerene layer is deposited by spin-casting either under nitrogen or ambient conditions. We show that PV devices based on carbazole and fluorene based materials have very similar power conversion efficiencies when processed under both air and nitrogen, with other photobleaching measurements suggesting that such materials have comparatively enhanced photostability. Devices based on the PTB co-polymer, however, have reduced efficiency when processed in air.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A comparison of mechanical properties of some foams and honeycombs

A comparative study is conducted of the mechanical properties of foam-core and honeycomb-core sandwich panels, using a normalizing procedure based on common properties of cellular solids and related properties of dense solids. Seven different honeycombs and closed-foam cells are discussed; of these, three are commercial Al alloy honeycombs, one is an Al-alloy foam, and two are polymeric foams. It is concluded that ideal, closed-cell foams may furnish compressive strengths which while isotropic can be fully comparable to the compressive strengths of honeycombs in the thickness direction. The shear strength of ideal closed-cell foams may be superior to the shear strength of honeycombs.

Bhat, Balakrishna T.↗

Atomic-Scale Characterization and Electronic Properties of Gold-Capped Niobium Films for Superconducting Qubits

Niobium thin films are central to superconducting qubits, but their complex native oxides contribute significantly to microwave losses. A promising mitigation strategy is to suppress oxide formation using engineered thin-film encapsulation layers. Recent experiments have shown that ∼10 nm metallic overlayers on Nb capacitor films can improve the energy relaxation time T1 of transmon qubits. Here, we present a comparative study of Au-capped Nb films fabricated in situ by molecular beam epitaxy and ex situ by sequential deposition benchmarked against bare Nb films. Using complementary structural, chemical, and spectroscopic techniques, we correlate the interface quality with superconducting electronic properties of the Au surface. Low-temperature scanning tunneling spectroscopy (STS) provides spatially resolved quasiparticle density-of-states maps. While both Au-capped Nb samples exhibit large areas with uniform, fully gapped density of states, clear differences emerge between the two interfaces. Compared to in situ Nb-Au, ex situ Nb-Au exhibits a reduced induced superconducting gap, broadened coherence peak, and localized in-gap states, consistent with a residual NbxOy layer at the interface. Supported by complementary structural and chemical analyses, these findings demonstrate that STS directly links nanoscale superconducting properties to interface preparation, highlighting the importance of controlled in situ encapsulation for minimizing dissipation and improving quantum coherence.

Makita, Junki [MIT; Temple U.] (ORCID:000000026889↗

Growth and magnetoelectric properties of (00l)-oriented La{sub 0.67}Sr{sub 0.33}MnO{sub 3}/PbZr{sub 0.52}Ti{sub 0.48}O{sub 3} heterostructure films

C-axis oriented La{sub 0.67}Sr{sub 0.33}MnO{sub 3}(LSMO)/PbZr{sub 0.52}Ti{sub 0.48}O{sub 3}(PZT) films are fabricated successfully by sol-gel method on LaAlO{sub 3} (00l) substrates. The structure, composition and morphology of the films are investigated by X-ray diffractometer (XRD, θ-2θ scan, ω-scan and ϕ-scan), X-ray photoelectron spectroscope (XPS), field emission scanning electron microscope (FESEM) and high resolution transmission electron microscope (HRTEM). The electric and magnetic properties of randomly and c-axis oriented LSMO/PZT films are studied comparably using ferroelectric testing apparatus and physical property measurement system (PPMS). It is found that the epitaxial LSMO/PZT composite films show well controlled growth along c-axis, and much better magnetoelectric properties than the randomly oriented ones. The ME voltage coefficient increases from 23 mV cm{sup −1} Oe{sup −1} for the randomly oriented LSMO/PZT composite films to 52 mV cm{sup −1} Oe{sup −1} for c-axis oriented ones prepared using the low cost sol-gel method presented in this study, which shows high potential in promising applications. - Highlights: •Epitaxial LSMO/PZT films were fabricated successfully by sol-gel method on LAO (00l) substrate. •The prepared films exhibit well-defined multiferroic properties for the epitaxial LSMO/PZT films. •Epitaxial LSMO/PZT films show superior magnetoelectric properties to the randomly oriented ones.

36 MATERIALS SCIENCE↗

Crystallographically uniform arrays of ordered (In)GaN nanocolumns

In this work, through a comparative study of self-assembled (SA) and selective area grown (SAG) (In)GaN nanocolumn (NC) ensembles, we first give a detailed insight into improved crystallographic uniformity (homogeneity of crystallographic tilts and twists) of the latter ones. The study, performed making use of: reflective high energy electron diffraction, X-ray diffraction and scanning electron microscopy, reveals that unlike their SA counterparts, the ensembles of SAG NCs show single epitaxial relationship to both sapphire(0001) and Si(111) underlying substrates. In the second part of the article, making use of X-ray diffraction, we directly show that the selective area growth leads to improved compositional uniformity of InGaN NC ensembles. This further leads to improved spectral purity of their luminescence, as confirmed by comparative macro-photoluminescence measurements performed on SA and SAG InGaN NC ensembles. An improved crystallographic uniformity of NC ensembles facilitates their integration into optoelectronic devices, whereas their improved compositional uniformity allows for their employment in single-color optoelectronic applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Power of Exclusion using Automated Osteometric Sorting: Pair‐Matching,

Abstract This study compares the original pair‐matching osteometric sorting model ( J Forensic Sci 2003 ;48:717) against two new models providing validation and performance testing across three samples. The samples include the Forensic Data Bank, USS Oklahoma , and the osteometric sorting reference used within the Defense POW / MIA Accounting Agency. A computer science solution to generating dynamic statistical models across a commingled assemblage is presented. The issue of normality is investigated showing the relative robustness against non‐normality and a data transformation to control for normality. A case study is provided showing the relative exclusion power of all three models from an active commingled case within the Defense POW / MIA Accounting Agency. In total, 14,357,220 osteometric t ‐tests were conducted. The results indicate that osteometric sorting performs as expected despite reference samples deviating from normality. The two new models outperform the original, and one of those is recommended to supersede the original for future osteometric sorting work.

Lynch, Jeffrey James↗

Feed the fish: A review of aquaculture feeders and their strategic implementation

Automatic feeders are revolutionizing aquaculture by enabling precise and controlled feeding regimens that optimize growth, reduce feed waste, and enhance the overall efficiency of farming operations. Demand feeders provide some similar benefits but with feeding tailored to fish appetites and, in some cases, feed dispersal without electricity. This review explores the evolution, technological advancements, and applications of these feeders with a survey of recent research. It looks at common feeder designs and compares the pros and cons of five automatic feeder configurations in commercial use today. The article contrasts feeders and feed sizes for farmed species in different life stages and facilities, from hatcheries to ponds and offshore cages. It discusses the importance of species-tailored feeding strategies as well as impacts on fish behavior and health, nutrient delivery, and environmental sustainability. Incorporating sensors and on-site computing enables optimization in feeding algorithms that feeders then implement precisely and reliably. The review compiles results from multiple studies comparing growth rate, weight, and feed conversion ratio (FCR) outcomes from automatic feeders and demand feeders versus traditional hand-feeding regimens. The integration of feeders with real-time monitoring and data analytics is also discussed, highlighting future directions for research and adoption across the industry.

42 ENGINEERING↗

Interrelationship of Thermal Effects on Calcium Sulfate Dihydrate Casts Containing Borax and Kaolin: Differential Thermal Analysis (DTA), Thermogravimetric Analysis (TGA), and Contact Dilatometry

The core composition of gypsum wallboard is calcium sulfate dihydrate (CaSO 4 ·2H 2 O) with varying impurities, additives, or both. This study compares here two commercially calcined sources of hemihydrate (CaSO 4 ·½H 2 O) from a natural source and a synthetic by-product of flue gas desulfurization and neutralization to reagent grade hemihydrate. Two common ingredients, borax and kaolin, are mixed into a slurry with distilled water. The analysis supports the hypothesis that minor components in the cast have an effect on the high temperature performance of gypsum casts. The analysis is enhanced when the differential thermal analysis, thermogravimetric analysis, and dilatometry data are combined to study the changes in density versus heat flow. Specifically, the thermal performance is affected by (1) the impurities found in hemihydrate sources; (2) during the fluidization phase, the reaction of borax with free Ca ++ ions to form new borate salts that melt at lower temperatures; and (3) the intercalation of these and other ions with kaolin, providing thermal stability by reducing the formation of thermally active salts.

36 MATERIALS SCIENCE↗

Intelligent Control of Thermal Energy Storage in the Manufacturing Sector for Plant-Level Grid Response

Industrial facilities are seeking new strategies that help in providing savings mechanisms for demand charges. Demand charges are the charges incurred by industrial facilities as a result of power usage. Thermal energy storage has advanced significantly with lots of new applications, garnering the interest of many industrial facilities. These applications could be used to shave the industrial facilities’ peak electric demand and reduce their demand charges. This paper aims to demonstrate the efficacy of thermal energy storage in reducing demand charges and highlight new developments in the integration of smart control systems with thermal energy storage. The study compares energy consumption and peak demand for a facility equipped with and without thermal energy storage tanks using a fixed schedule for charging and discharging. Additionally, the paper examines the impact of incorporating a smart controller to determine when to charge and discharge the tank based on the facility’s real-time power usage and a given setpoint. The results indicate cost savings from the use of thermal energy storage tanks under two proposed scenarios, reflected in the reduced cost of power consumption for the studied facility. The incorporation of a smart controller with the thermal energy storage tank in the facility studied could provide estimated savings of 3.3% per year of power consumption charges, without considering the contribution of any incentives. The estimated savings provided by the fixed schedule scenario are 2.7% per year.

25 ENERGY STORAGE↗