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At least 1,531 records · Page 85

Stratospheric HNO3 quantification from line-by-line nonlinear least-squares analysis of high-resolution balloon-borne solar absorption spectra in the 870/cm region

Line parameters for the nu(5) and 2nu(9) bands and associated hot bands of HNO3 have been calculated and compared with laboratory spectra, and the results are presented. Spectral intervals near 870/cm for which best agreement was obtained are used to quantitatively analyze HNO3 absorption features in 0.02/cm resolution stratospheric solar absorption spectra.

Goldman, A.↗

Optical interstellar absorption lines toward 29 stars

Observations of optical interstellar absorption lines of Ti II, Ca II, and/or Na I acquired at an instrumental resolution typically of 5.6 km/s are reported for 29 stars. The data were recorded primarily with a Digicon detector and achieve 2 sigma detection limits generally near an equivalent width of 1 mA. The primary purpose of the observations is, in combination with previously published data, to provide a comprehensive, high-sensitivity survey of Ti II, Ca II, and Na I absorption at all velocities, toward 41 stars for which a correspondingly complete survey of certain ultraviolet interstellar lines also is available. New high-velocity optical interstellar lines at /v(LSR)/ greater than about 25 km/s are found toward four of the 29 stars.

Hobbs, L. M.↗

Measurement of individual hydrometeor absorption cross sections utilizing microwave cavity perturbation techniques

A technique for measurement of individual hydrometeor absorption cross sections is presented. Cross sections are inferred by inserting the hydrometeor into a high Q resonant cavity and measuring the Q perturbation. Tests were conducted in a 10.64 GHz, TM(010) cavity. Absorption cross sections were measured at room temperature for 0.5 to 2.0 mm water drops, and were found to agree with the Rayleigh theory. Cross sections were also measured as a function of temperature, and from these the dielectric loss term lm(-K) was inferred for supercooled water down to -17 C.

Hansman, R. J., Jr.↗

The relative importance of aerosol scattering and absorption in remote sensing

The relative importance of aerosol optical thickness and absorption is illustrated through computing radiances for radiative transfer models. The radiance of sunlight reflected from models of the earth-atmosphere system is computed as a function of the aerosol optical thickness and its albedo of single scattering; it is noted that the albedo varies from 0.6 in urban environment to nearly 1 in areas with low graphitic carbon content. The calculations are applied to the example of satellite measurements of biomass. It is found that when surface classifications are made by means of clustering techniques the presence of gradients in the aerosol optical properties results in the dispersion of points in the plot correlating radiances viewed in two different directions. Finally, though such a remote sensing parameter as contrast is weakly affected by aerosol absorption, it is highly dependent on its optical thickness.

Fraser, R. S.↗

Relative spectral absorption of solar radiation by water vapor and cloud droplets

A moderate (20/cm) spectral resolution model which accounts for both the highly variable spectral transmission of solar radiation through water vapor within and above cloud, as well as the more slowly varying features of absorption and anisotropic multiple scattering by the cloud droplets, is presented. Results from this model as applied to the case of a typical 1 km thick stratus cloud in a standard atmosphere, with cloud top altitude of 2 km and overhead sun, are discussed, showing the relative importance of water vapor above the cloud, water vapor within the cloud, and cloud droplets on the spectral absorption of solar radiation.

Davies, R.↗

Enhancement of intensity-dependent absorption in InP and GaAs at 1.9 microns by doping

It is pointed out that the study of intensity-dependent absorption (IDA) in general, and two-photon absorption (TPA), in particular, has suffered from experimental difficulties and inadequate theoretical models. Bass et al. (1979) could improve the experimental situation by making use of laser calorimetry to obtain directly the TPA coefficient of a medium with a high degree of sensitivity. In the present investigation, the employed technique has been used to study the effect of deep level dopants on IDA in InP and GaAs. It is found that the coefficient for IDA is strongly dependent on the presence of Fe in InP and Cr in GaAs. The conducted investigation had the objective to examine the effect of deep level impurities on IDA processes in InP and GaAs. Fe-doped InP and Cr-doped GaAs were compared with undoped crystals.

Li, N.-L.↗

Identification of atmospheric C2H2 lines in the 3230-3340/cm region of high resolution solar absorption spectra recorded at the National Solar Observatory

A search has been conducted for the presence of absorption lines of atmospheric acetylene (C2H2), taking into account the 3230-3340/cm interval of 0.01/cm resolution solar absorption spectra recorded with the interferometer of the Solar Observatory on Kitt Peak. A total of 12 lines belonging to the strong nu-3 and nu-2 + nu-4 + nu-5 bands has been identified in this interval. This letter provides a report regarding the identification analysis of selected atmospheric C2H2 lines in a representative set of Kitt Peak solar spectra.

Rinsland, C. P.↗

Ultraviolet absorption by highly ionized halo gas near the Galactic center

Initial results are presented for a program to survey highly ionized gas in the Milky Way disk and halo. High-resolution IUE (International Ultraviolet Explorer) far-UV spectra were obtained for 12 stars at galactocentric distances less than 6 kpc. The stars are 0.7-2.2 kpc away from the plane. Most of the spectra contain exceedingly strong and broad interstellar absorption lines of weakly and highly ionized atoms. In addition to the normally strong lines of Si IV and C IV, strong interstellar NV lines have been detected in the spectra of eight stars. The detection of NV absorption (amounting to more than 10 times the predicted NV) provides an important new constraint on models for the origin of Galactic halo gas. A Galactic fountain operating in the presence of known UV and EUV radiation might explain the observations.

Savage, B. D.↗

Brewster-plate spoiler - A novel method for reducing the amplitude of interference fringes that limit tunable-laser absorption sensitivities

A simple method is described for substantially reducing the amplitude of interference fringes that limit the sensitivities of tunable-laser high-resolution absorption spectrometers. A lead-salt diode laser operating in the 7-micron region is used with a single Brewster-plate spoiler to reduce the fringe amplitude by a factor of 30 and also to allow the detection of absorptances 0.001 percent in a single laser scan without subtraction techniques, without complex frequency modulation, and without distortion of the molecular line-shape signals. Application to multipass-cell spectrometers is described.

Webster, C. R.↗

Ultraviolet interstellar absorption toward stars in the Small Magellanic Cloud. III - The structure and kinematics of the Small Magellanic Cloud

The structural and kinematic properties of the Small Magellanic Cloud (SMC) were studied by combining IUE satellite observations of individual bright stars (Sk 159 and HD 5980) with existing optical and radio data. It is shown that the SMC has a complex structure due to gravitational interaction with the Milky Way and the Large Magellanic Cloud (LMC). Stars observed in the southwest regions of the SMC were associated with the 134 km/s H I complex. H II regions in the SMC were distributed according to a rotational velocity of 167 km/s. All IUE high-dispersion targets exhibit ultraviolet absorption near 100 km/s and 200 km/s. It is shown that the absorption arises in the widespread H I complexes at velocities similar to the H II regions. Some possible explanations for the origin of H II and H I regions in the SMC are discussed. The locations of the nine high-dispersion IUE targets in the SMC are given.

Fitzpatrick, E. L.↗

Hydride absorption refrigerator system for ten Kelvin and below

A very long-life, lightweight and efficient hydride absorption refrigerator system was built to operate at ten Kelvin and below. The system consists of four basic stages of refrigeration. The first stage is accomplished by an active refrigeration system. The second stage is operated by a hydride absorption system, wherein a heated hydride powder drives off high pressure hydrogen through a Joule-Thomson/heat exchanger expansion loop such that the hydrogen is partially liquefied. In the third stage, the vapor pressure over the collected liquid hydrogen is lowered by absorbing the hydrogen vapor onto a different low pressure, worn hydride. With a 1.7 torr partial pressure of hydrogen gas in the hydride, liquid hydrogen is solidified and sublimes at 10 K. Long-life adiabatic demagnetization refrigerators, helium desorption, or helium diaphragm compressors are used to cool to 4 K or below. It is shown that the hydride concepts provide an extremely efficient means of refrigeration to 10 K, and that an entire sorption refrigeration process can be accomplished solely by using low grade heat energy at about 150 C.

Jones, J. A.↗

Semidiurnal temperature oscillation and E-region absorption over Haringhata

An attempt has been made to explain the observed asymmetry in the diurnal curves on absorption for the E region at 2.2 MHz for the field station at Haringhata (22 deg 56'N, 88 deg 36'E). A comparison between the computed and observed diurnal curves on absorption revealed that a part of the asymmetry was a manifestation of the effect of semidiurnal temperature oscillation present in the E layer. It was further noted that the degree of the asymmetry of the observed diurnal curves depends profoundly on the rate of downwards phase progression of the temperature oscillation.

Purkait, N. N.↗

Emission, absorption and group delay of microwaves in the atmosphere in relation to water vapour content over the Indian subcontinent

The advent of satellite communication for global coverage has apparently indicated a renewed interest in the studies of radio wave propagation through the atmosphere, in the VHF, UHF and microwave bands. The extensive measurements of atmosphere constituents, dynamics and radio meterological parameters during the Middle Atmosphere Program (MAP) have opened up further the possibilities of studying tropospheric radio wave propagation parameters, relevant to Earth/space link design. The three basic parameters of significance to radio propagation are thermal emission, absorption and group delay of the atmosphere, all of which are controlled largely by the water vapor content in the atmosphere, particular at microwave bands. As good emitters are also good absorbers, the atmospheric emission as well as the absorption attains a maximum at the frequency of 22.235 GHz, which is the peak of the water vapor line. The group delay is practically independent of frequency in the VHF, UHF and microwave bands. However, all three parameters exhibit a similar seasonal dependence originating presumably from the seasonal dependence of the water vapor content. Some of the interesting results obtained from analyses of radiosonde data over the Indian subcontinent collected by the India Meteorological Department is presented.

Sen, A. K.↗

A Study of the Ultraviolet Absorptions in the Spectra of DA White Dwarfs

Systematic investigations of the ultraviolet spectra of the hydrogen-rich white dwarfs were conducted with the International Ultraviolet Explorer satellite (IUE). This is to follow up on the work reported in Nelan and Wegner (1985) that the strong absorptions found earlier near lambda lambda 1600 and 1400 (cf. Greenstein 1980; Wegner 1982 and 1984, b) in the spectra of the cooler DA are absorptions produced by the H2 and H2(+) quasi-molecules. Observations of new DA white dwarfs obtained with the IUE are summarized.

Wegner, G. A.↗

Laboratory evaluation and application of microwave absorption properties under simulated conditions for planetary atmospheres

After long arduous work with the simulator, measurements of the refractivity and absorptivity of nitrogen under conditions similar to those for Titan were completed. The most significant measurements, however, were those of the microwave absorption from gaseous ammonia under simulated conditions for the Jovian atmospheres over wavelengths from 1.3 to 22 cm. The results of these measurements are critical in that they confirm the theoretical calculation of the ammonia opacity using the Ben-Reuven lineshape. The application of both these results, and results obtained previously, to planetary observations at microwave frequencies were especially rewarding. Applications of the results for ammonia to radio astronomical observations of Jupiter in the 1.3 to 20 cm wavelength range and the application of results for gaseous H2SO4 under simulated Venus conditions are discussed.

Steffes, P. G.↗

Accurate quantum yields by laser gain vs absorption spectroscopy - Investigation of Br/Br(asterisk) channels in photofragmentation of Br2 and IBr

Various techniques have been used to study photodissociation dynamics of the halogens and interhalogens. The quantum yields obtained by these techniques differ widely. The present investigation is concerned with a qualitatively new approach for obtaining highly accurate quantum yields for electronically excited states. This approach makes it possible to obtain an accuracy of 1 percent to 3 percent. It is shown that measurement of the initial transient gain/absorption vs the final absorption in a single time-resolved signal is a very accurate technique in the study of absolute branching fractions in photodissociation. The new technique is found to be insensitive to pulse and probe laser characteristics, molecular absorption cross sections, and absolute precursor density.

Haugen, H. K.↗

Upper limits for stratospheric H2O2 and HOCl from high resolution balloon-borne infrared solar absorption spectra

Solar absorption spectra from two stratospheric balloon flights have been analyzed for the presence of H2O2 and HOCl absorption in the 1230.0 to 1255.0 per cm region. The data were recorded at 0.02 per cm resolution during sunset with the University of Denver interferometer system on October 27, 1978 and March 23, 1981. Selected spectral regions were analyzed with the technique of nonlinear least squares spectral curve fitting. Upper limits of 0.33 ppbv for H2O2 and 0.36 ppbv for HOCl near 28 km are derived from the 1978 flight data while upper limits of 0.44 ppbv for H2O2 and 0.43 ppbv for HOCl at 29.5 km are obtained from the 1981 flight data.

Larsen, J. C.↗

On interstellar Fe X forbidden line absorption. III - The lambda 6367 feature

Echelle spectra of Zeta Oph and HD 190603 are reported which show a weak interstellar absorption feature near 6367 A. The feature had been previously detected only toward two members of the Cepheus OB2 association in an extensive search for interstellar Fe X forbidden line absorption (lambda 6375). On the basis of the resulting radial velocities, the two new detections exclude the preliminary identification of the lambda 6367 feature with high-velocity Fe X ions in the hot, X-ray-emitting gas and demonstrate that the feature arises instead in the ordinary diffuse clouds. This unidentified feature may be either a molecular transition or a very weak diffuse interstellar band.

Hobbs, L. M.↗