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At least 1,513 records · Page 84

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NASA NTRS1999

The Impact of SN1987A with its Circumstellar Ring

Following is final report on the study "The Impact of SN1987A with its Circumstellar Ring", which is now complete. In 1994, it was predicted that the blast wave from SN1987A would strike the circumstellar ring in AD1999+/-3, and that the ring would brighten by several hundreds optically as the shock entered the ring. It was also predicted that the emission lines from the shocked ring would have linewidths of a few hundred km/s. Today, we see a "hot spot" on the ring that first appeared in Hubble Space Telescope (HST) images in 1995 and has doubled in brightness between August 1997 and February 1998. Moreover, spectra from STIS show that the emission lines from the hot spot have widths and blue shifts of order 200 km/s, just as we predicted in 1994. Our guess of 1999+/-3 for the impact time was lucky, because we assumed that the hot gas in the bubble between the supernova and the ring had a low density (approximately 10 cm(exp -3)). But it was pointed out that the ROSAT observations of soft X-rays from SN 1987A implied that the intervening gas had a higher density, (approximately 100 cm(exp -3)), which would delay the impact until ca. 2007. Others developed hydrodynamic models to fit the ROSAT X-ray emission spectrum and came to the same conclusion. But these models were oversimplified in that they assumed that the ring was perfectly round. Now we see clearly that the hot spot is a peninsula that protrudes inward from the ring -- the first spot on the ring to be struck by the blast wave. No doubt there are other protrusions on the ring, which we may expect to light up in the next few years until they finally merge to set the entire ring ablaze, probably within 5 - 10 years. It was also predicted that the X-ray emission must be accompanied by optical and ultraviolet emission from atoms in the supernova debris and in the circumstellar gas that cross the reverse shock and the blast wave, respectively, and that the Lyman-alpha and NV emission lines should be bright enough to see with the STIS.

McCray, Richard↗

NASA NTRS1971

Low-energy proton increases associated with interplanetary shock waves.

Impulsive increases in the low energy proton flux observed by the Explorer 34 satellite, in very close time association with geomagnetic storm sudden commencements are described. It is shown that these events are of short duration (20-30 min) and occur only during the decay phase of a solar cosmic-ray flare event. The differential energy spectrum and the angular distribution of the direction of arrival of the particles are discussed. Two similar increases observed far away from the earth by the Pioneer 7 and 8 deep-space probes are also presented. These impulsive increases are compared with Energetic Storm Particle events and their similarities and differences are discussed. A model is suggested to explain these increases, based on the sweeping and trapping of low energy cosmic rays of solar origin by the advancing shock front responsible for the sudden commencement detected on the earth.

Palmeira, R. A. R.↗

DOE OSTI2024

Multiconfigurational Electronic Structure of Nickel Cross-Coupling Catalysts Revealed by X-ray Absorption Spectroscopy

Ni II 2,2'-bipyridine complexes are commonly invoked intermediates in metallaphotoredox cross-coupling reactions. Despite their ubiquity, design principles targeting improved catalytic performance remain underdetermined. A series of Ni( R bpy)( R 'Ar)Cl (R = MeOOC, t-Bu, R' = CH 3 , CF 3 ) complexes were proposed to have multiconfigurational electronic structures on the basis of multiconfigurational/multireference calculations, with significant mixing of Ni → bpy metal-to-ligand charge transfer (MLCT) configurations into the ground-state wave function. Here, Ni K-edge and L 2,3 -edge X-ray absorption spectroscopies provide experimental support for the highly covalent and multiconfigurational electronic structures of these complexes. The pre-edge intensity in the K-edge spectrum reflects highly covalent Ni–aryl bonding. The L 3 -edge spectral shape is dependent on ligand functionalization, and a feature reflecting the MLCT character is assigned using prior ab initio and new semiempirical calculations. The results suggest the push/pull effects of the aryl/bpy ligands moderate the changes in electron density on Ni during the multiredox cross-coupling reaction cycle.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1975

A study of the use of vibration and stress wave sensing for the detection of bearing failure

Results from an experimental study of vibrations and stress waves emitted from ball bearings are presented. Fatique tests were run with both high quality bearings and man faulted bearings, all of one size. Tests were instrumented with different sensors to detect the noises from 10 Hz to 1 MHz. Frequency spectrum plots are presented. The modulation characteristics of the ultrasonic noises were analyzed, and acoustic emission type measurements were conducted. Results are presented which show that there are usable acoustic signal levels even beyond 500 KHz. These signal levels are modulated by a low frequency carrier which is a function of the stress loading and acoustic transmissibility. The results were correlated to fault size in the bearings. The correlation shows that the sensor used for signals from 100 KHz to 1 MHz gave the best sensitivity and detected the generation of very small spalls or pits.

Ensor, L. C.↗

NASA NTRS1978

Study of diatomic molecules. 2: Intensities

The theory of perturbations, giving the diatomic effective Hamiltonian, is used for calculating actual molecular wave functions and intensity factors involved in transitions between states arising from Hund's coupling cases a,b, intermediate a-b, and c tendency. The Herman and Wallis corrections are derived, without any knowledge of the analytical expressions of the wave functions, and generalized to transitions between electronic states with whatever symmetry and multiplicity. A general method for studying perturbed intensities is presented using primarily modern spectroscopic numerical approaches. The method is used in the study of the ScO optical emission spectrum.

Femenias, J. L.↗

NASA NTRS1983

Upper limits on the isotropic gravitational radiation background from pulsar timing analysis

A pulsar and the earth may be thought of as end masses of a free-mass gravitational wave antenna in which the relative motion of the masses is monitored by observing the Doppler shift of the pulse arrival times. Using timing residuals from PSR 1133 + 16, 1237 + 25, 1604-00, and 2045-16, an upper limit to the spectrum of the isotropic gravitational radiation background has been derived in the frequency band 4 x 10 to the -9th to 10 to the -7th Hz. This limit is found to be S(E) = 10 to the 21st f-cubed ergs/cu cm Hz, where S(E) is the energy density spectrum and f is the frequency in Hz. This would limit the energy density at frequencies below 10 to the -8th Hz to be 0.00014 times the critical density.

Hellings, R. W.↗

NASA NTRS1994

Application of the coded long-pulse technique to plasma line studies of the ionosphere

Recently, the coded long-pulse radar technique was tested at Arecibo Observatory, Puerto Rico using photoelectron-enhanced plasma lines in the daytime ionosphere. The technique immediately proved to be a powerful diagnostic tool for studying natural ionospheric phenomena. Our initial observations indicate that extremely accurate measurements of absolute electron density (0.01 to 0.03% error bars) can be achieved with an altitude resolution of 150 m and a temporal resolution of approx. 2 s. In addition, the technique provides information about electron density structure within a 150-m altitude cell and yields parameters from which the energy spectrum of suprathermal electrons (equal to or greater than 5 eV) can be deduced. Our earliest measurements are used to illustrate applications of the coded long-pulse technique to several aeronomic/ionsospheric areas of current interest. These include studies of neutral wave motions in the lower thermosphere, measurements of ion composition in the F(sub 1) region/upper ionosphere, and investigations of electron-gas thermal balance and photoelectron energy loss processes. The technique can be utilized to examine irregularity formation in the F region, probe electron acceleration processes in ionospheric modification experiments, verify the magnetic field dependence of Langmuir wave damping, and more generally test higher order corrections suggested for the Langmuir dispersion relation. It is anticipated that the latter tests will facilitate measurements of ionospheric currents.

Djuth, Frank T.↗

NASA NTRS1994

The Fraternal Twins of Quartet O4(+)

Eleven stationary geometries of quartet O4(+) have been studied by ab initio methods. The geometries were optimized at the Complete Active Space Self-Consistent Field (CASSCF) level of theory and the energies were calculated by the multiconfigurational second order pertubation method (CASPT2), using Double-Zeta Plus polarization (DZP), Triple-Zeta Plus Double Polarization (TZ2P), average Atomic Natural Orbital (ANO) (5s4p2d) and average ANO (6s5p3d2f) basis sets. The rectangular and trans-planar structures are found to be the most stable, with an energy barrier to conversion between the two at the threshold of dissociation. Both have a delocalized hole and are stable relative to separated 02 and 02(+)by 11.0 and 11.5 kcal/mol for the rectangular and the 2 trans-planar structure, respectively, compared with the experimentally deduced energy in the range of 9.2 to 10.8 kcal/mol. The adiabatic ionization potentials of 04 and 02 are computed to be 11.67 and 12.21 eV, while experimental values are 11.66 and 12.07 eV, respectively. The vibrational frequencies have been computed for all degrees of freedom at the CASSCF level of theory. Symmetry breaking is found to be a particular problem in the computation of the antisymmetric stretch frequency for the delocalized structures at the CASSCF level of theory. Attempts to rectify these problems using the restricted active space self-consistent field (RASSCF) method leads to additional difficulties, but further analysis yields insight into the symmetry breaking and problems with earlier calculations. Finally, a nonorthogonal configuration interaction (CI) calculation based on the interaction of localized CASSCF wave functions using the Complete Active Space State Interation (CASSI) method leads to a balanced treatment of the antisymmetric stretch which is free from symmetry breaking. The study explains the four most prominent absorption frequencies observed in the partially unassigned IR spectrum of O4(+) isolated in solid neon as the antisymmetric OO stretch, and the combination band of the symmetric and antisymmetric 00 stretch of both the rectangular and trans-planar structures.

Lindh, Roland↗

NASA NTRS1978

Bolt Stress Monitor

In photo, an engineer is using a new Ultrasonic Bolt Stress Monitor developed by NASA's Langley Research Center to determine whether a bolt is properly tightened. A highly accurate device, the monitor is an important tool in construction of such structures as pressure vessels, bridges and power plants, wherein precise measurement of the stress on a tightened bolt is critical. Overtightened or undertightened bolts can fail and cause serious industrial accidents or costly equipment break-downs. There are a number of methods for measuring bolt stress. Most widely used and least costly is the torque wrench, which is inherently inaccurate; it does not take into account the friction between nut and bolt, which has an influence on stress. At the other end of the spectrum, there are accurate stress-measuring systems, but they are expensive and not portable. The battery-powered Langley monitor fills a need; it is inexpensive, lightweight, portable and extremely accurate because it is not subject to friction error. Sound waves are transmitted to the bolt and a return signal is received. As the bolt is tightened, it undergoes changes in resonance due to stress, in the manner that a violin string changes tone when it is tightened. The monitor measures the changes in resonance and provides a reading of real stress on the bolt. The device, patented by NASA, has aroused wide interest and a number of firms have applied for licenses to produce it for the commercial market.

Source record↗

DOE OSTI2024

Nanoscale Imaging and Measurements of Grain Boundary Thermal Resistance in Ceramics with Scanning Thermal Wave Microscopy

Material thermal conductivity is a key factor in various applications, from thermal management to energy harvesting. With microstructure engineering being a widely used method for customizing material properties, including thermal properties, understanding and controlling the role of extended phonon-scattering defects, like grain boundaries, is crucial for efficient material design. However, systematic studies are still lacking primarily due to limited tools. In this study, we demonstrate an approach for measuring grain boundary thermal resistance by probing the propagation of thermal waves across grain boundaries with a temperature-sensitive scanning probe. The method, implemented with a spatial resolution of about 100 nm on finely grained Nb-substituted SrTiO 3 ceramics, achieves a detectability of about 2 × 10 –8 K m 2 W –1 , suitable for chalcogenide-based thermoelectrics. The measurements indicated that the thermal resistance of the majority of grain boundaries in the STiO 3 ceramics is below this value. While there are challenges in improving sensitivity, considering spatial resolution and the amount of material involved in the detection, the sensitivity of the scanning probe method is comparable to that of optical thermoreflectance techniques, and the method opens up an avenue to characterize thermal resistance at the level of single grain boundaries and domain walls in a spectrum of microstructured materials.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Two- and three-meson scattering amplitudes with physical quark masses from lattice QCD

We study systems of two and three mesons composed of pions and kaons at maximal isospin using four CLS ensembles with 𝑎 ≈ 0.063 fm, including one with approximately physical quark masses. Using the stochastic Laplacian-Heaviside method, we determine the energy spectrum of these systems including many levels in different momentum frames and irreducible representations. Using the relativistic two- and three-body finite-volume formalism, we constrain the two- and three-meson K matrices, including not only the leading 𝑠 wave, but also 𝑝 and 𝑑 waves. By solving the three-body integral equations, we determine, for the first time, the physical-point scattering amplitudes for 3⁢𝜋 + , 3⁢𝐾 + , 𝜋 + ⁢𝜋 + ⁢𝐾 + , and 𝐾 + ⁢𝐾 + ⁢𝜋 + systems. These are determined for total angular momentum 𝐽 𝑃 = 0 − , 1 + , and 2 − . We also obtain accurate results for 2⁢𝜋 + , 𝜋 + ⁢𝐾 + , and 2⁢𝐾 + phase shifts. We compare our results to chiral perturbation theory and to phenomenological fits.

FOS: Physical sciences↗

DOE OSTI2022

NMR evidence for a Peierls transition in the layered square-net compound LaAgSb 2

Here, we measured the central (1/2 ↔ –1/2) and first satellite (±3/2 ↔ ±1/2) lines of the 139 La NMR spectra as a function of temperature in LaAgSb 2 , in order to elucidate the origin and nature of the charge-density-wave (CDW) transitions at $T_{\text{CDW1}}$ = 207 K and $T_{\text{CDW2}}$ = 186 K. In the normal state, the Knight shift $\mathcal{K}$ reveals a fairly linear relationship with decreasing temperature, which is ascribed to a pseudogap in the spin excitation spectrum, pointing towards the material being an unconventional metal. Upon further cooling, $\mathcal{K}$ decreases more steeply below $T_{\text{CDW1}}$, indicative of the partial Fermi surface gap opening on top of the pseudogap. The most remarkable finding in our study is a clear splitting of the satellite lines at $T_{\text{CDW1}}$ observed for $H \parallel c$, whose temperature dependence behaves as the BCS order parameter in the weak-coupling limit, evidencing that the CDW transition induces the periodic lattice distortion. Our NMR findings therefore demonstrate that the CDW transition in LaAgSb 2 is of Peierls type, being driven by the electronic instability in the vicinity of the Fermi level.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2024

Universal orbital and magnetic structures in infinite-layer nickelates

We conducted a comparative study of the rare-earth infinite-layer nickelate films, RNiO 2 (R = La, Pr, and Nd), using resonant inelastic x-ray scattering (RIXS). We found that the gross features of the orbital configurations are essentially the same, with minor variations in the detailed hybridization. For low-energy excitations, we unambiguously confirm the presence of damped magnetic excitations in all three compounds. By fitting to a linear spin-wave theory, comparable spin exchange coupling strengths and damping coefficients are extracted, indicating a universal magnetic structure in the infinite-layer nickelates. Interestingly, while signatures of a charge order are observed in LaNiO 2 in the quasielastic region of the RIXS spectrum, it is absent in NdNiO 2 and PrNiO 2 . Furthermore, this prompts further investigation into the universality and the origins of charge order within the infinite-layer nickelates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS1982

Acoustic modal analysis of a full-scale annular combustor

An acoustic modal decomposition of the measured pressure field in a full scale annular combustor installed in a ducted test rig is described. The modal analysis, utilizing a least squares optimization routine, is facilitated by the assumption of randomly occurring pressure disturbances which generate equal amplitude clockwise and counter-clockwise pressure waves, and the assumption of statistical independence between modes. These assumptions are fully justified by the measured cross spectral phases between the various measurement points. The resultant modal decomposition indicates that higher order modes compose the dominant portion of the combustor pressure spectrum in the range of frequencies of interest in core noise studies. A second major finding is that, over the frequency range of interest, each individual mode which is present exists in virtual isolation over significant portions of the spectrum. Finally, a comparison between the present results and a limited amount of data obtained in an operating turbofan engine with the same combustor is made. The comparison is sufficiently favorable to warrant the conclusion that the structure of the combustor pressure field is preserved between the component facility and the engine.

Karchmer, A. M.↗

NASA NTRS1983

Acoustic modal analysis of a full-scale annular combustor

Karchmer, A. M.↗

NASA NTRS1989

Numerical modeling for primary atomization of liquid jets

In the proposed numerical model for primary atomization, surface-wave dispersion equations are solved in conjunction with the jet-embedding technique of solving mean flow equations of a liquid jet. Linear and approximate nonlinear models have been considered. In each case, the dispersion equation is solved over the whole wavelength spectrum to predict drop sizes, frequency, and liquid-mass breakup rates without using any empirical constants. The present model has been applied to several low-speed and high-speed jets. For the high-speed case (the LOX/H2 coaxial injector of the Space Shuttle Main Engine Preburner), predicted drop sizes and liquid breakup rates are in good agreement with the results of the CICM code, which have been calibrated against measured data.

Przekwas, A. J.↗

NASA NTRS1990

The propagation of RF wave in a tandem mirror plasma propulsion device

The propagation of RF waves launched in the end and the central cell of the tandem mirror propulsion device has been investigated both theoretically and experimentally. It was found that the amplitude of the wave excited in the plasma peaked while approaching the resonance, but then damped out, indicating strong absorption of the wave by the plasma. The absorption took place near the axis and the midplane of the device. The experimental results confirmed the theoretical prediction of the resonance effect. A very important discovery of this experiment was the broadening of the ICRF Fourier spectrum in the presence of the plasma.

Yang, T. F.↗

NASA NTRS2002

Lunar Radar Cross Section at Low Frequency

Recent bistatic measurements of the lunar radar cross-section have extended the spectrum to long radio wavelength. We have utilized the HF Active Auroral Research Program (HAARP) radar facility near Gakona, Alaska to transmit high power pulses at 8.075 MHz to the Moon; the echo pulses were received onboard the NASA/WIND spacecraft by the WAVES HF receiver. This lunar radar experiment follows our previous use of earth-based HF radar with satellites to conduct space experiments. The spacecraft was approaching the Moon for a scheduled orbit perturbation when our experiment of 13 September 2001 was conducted. During the two-hour experiment, the radial distance of the satellite from the Moon varied from 28 to 24 Rm, where Rm is in lunar radii.

Rodriguez, P.↗