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At least 1,513 records · Page 84

Laboratory Investigation of Direct Measurement of Ice Water Content, Ice Surface Area, and Effective Radius of Ice Crystals Using a Laser-Diffraction Instrument

The aircraft microphysics probe, PVM-100A, was tested in the Colorado State University dynamic cloud chamber to establish its ability to measure ice water content (IWC), PSA, and Re in ice clouds. Its response was compared to other means of measuring those ice-cloud parameters that included using FSSP-100 and 230-X 1-D optical probes for ice-crystal concentrations, a film-loop microscope for ice-crystal habits and dimensions, and an in-situ microscope for determining ice-crystal orientation. Intercomparisons were made in ice clouds containing ice crystals ranging in size from about 10 microns to 150 microns diameter, and ice crystals with plate, columnar, dendritic, and spherical shapes. It was not possible to determine conclusively that the PVM accurately measures IWC, PSA, and Re of ice crystals, because heat from the PVM evaporated in part the crystals in its vicinity in the chamber thus affecting its measurements. Similarities in the operating principle of the FSSP and PVM, and a comparison between Re measured by both instruments, suggest, however, that the PVM can make those measurements. The resolution limit of the PVM for IWC measurements was found to be on the order of 0.001 g/cubic m. Algorithms for correcting IWC measured by FSSP and PVM were developed.

Gerber, H.↗

Mars water vapor, near-surface

In a previous paper we concluded that the temperature sensors aboard the Viking landers (VL-1 and VL-2) were detecting the water vapor frost point. Analysis of one Mars year of data at both lander sites substantiates this conclusion. At VL-1 it is found that the water vapor mixing ratio is constant with height through the bulk of the atmosphere, most of the time. Exceptions are during the onset phases of the two major dust storms when temporary enhancement of near-surface vapor occurs (the same phenomenon is observed at VL-2), and some depletion of near-surface vapor during the decay phase of the first storm, possibly the second storm as well. The former suggests near-surface, northward transport of water vapor with the storms. The latter suggests adsorption of vapor on dust particles followed by surface deposition. At VL-2, severe near-surface depletion of water vapor occurs during northern autumn and winter. The residual vapor is in equilibrium with the surface condensate observed at the site during this period, indicating that the source region for the condensate must be aloft with downward transport by dust fall-out. Since the near-surface water vapor mixing ratio and concentration at VL-1 generally parallels the column abundance over VL-1 obtained by the orbiters, this suggests that VL-1 can be used to give a measure of column abundance for as long as the temperature sensors remain operational.

Ryan, J. A.↗

Dissolved Inorganic Carbon and Dissolved Organic Carbon Data for the East River Watershed, Colorado (2015-2025)

This data package contains mean values for dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) for water samples taken from the East River Watershed in Colorado. The East River is part of the Watershed Function Scientific Focus Area (WFSFA) located in the Upper Colorado River Basin, United States. DOC and DIC concentrations in water samples were determined using a TOC-VCPH analyzer (Shimadzu Corporation, Japan). DOC was analyzed as non-purgeable organic carbon (NPOC) by purging HCl-acidified samples with carbon-free air to remove DIC prior to measurement. After the acidified sample has been sparged, it is injected into a combustion tube filled with oxidation catalyst heated to 680 oC. The DOC in samples is combusted to CO2 and measured by a non-dispersive infrared (NDIR) detector. The peak area of the analog signal produced by the NDIR detector is proportional to the DOC concentration of the sample. DIC was determined by acidifying the samples with HCl first, and then purging with carbon-free air to release CO2 for analysis by NDIR detector. Total dissolved nitrogen (TDN) was analyzed using a Shimadzu Total Nitrogen Module (TNM-L) combined with the TOC-L analyzer (Shimadzu Corporation, Japan). TNM-L is a non-specific measurement of total nitrogen (TN). All nitrogen species in samples are combusted to nitrogen monoxide and nitrogen dioxide, then reacted with ozone to form an excited state of nitrogen dioxide. Upon returning to ground state, light energy is emitted. Then, TDN is measured using a chemiluminescence detector. All data reported are the mean values upon minimum of three replicate measurements, with a relative standard deviation < 3%. All samples were analyzed under a rigorous quality assurance and quality control (QA/QC) process. This data package contains (1) a zip file (dic_npoc_data_2014-2025.zip) containing a total of 337 files: 336 data files of DIC and NPOC data from across the Lawrence Berkeley National Laboratory (LBNL) Watershed Function Scientific Focus Area (SFA) which is reported in .csv files per location and a locations.csv (1 file) with latitude and longitude for each location; (2) a file-level metadata (v6_20250901_flmd.csv) file that lists each file contained in the dataset with associated metadata; (3) a data dictionary (v6_20250901_dd.csv) file that contains terms/column_headers used throughout the files along with a definition, units, and data type; and (4) PDF and docx files for the determiniation of Method Detection Limits (MDLs) for DIC and NPOC data, which has been updated in 2026-08. Missing values within the anion data files are noted as either "-9999" or "0.0" for not detectable (N.D.) data. There are a total of 113 locations containing DIC/NPOC data. Update on 2020-10-07: Updated the data files to remove times from the timestamps, so that only dates remain. The data values have not changed. Update on 2021-04-11: Added Determination of Method Detection Limits (MDLs) for DIC, NPOC and TDN Analyses document, which can be accessed as a PDF or with Microsoft Word.Update on 6/10/2022: versioned updates to this dataset was made along with these changes: (1) updated dissolved inorganic carbon and dissolved organic carbon data for all locations up to 2021-12-31, (2) removal of units from column headers in datafiles, (3) added row underneath headers to contain units of variables, (4) restructure of units to comply with CSV reporting format requirements, (5) added -9999 for empty numerical cells, and (6) the addition of the file-level metadata (flmd.csv) and data dictionary (dd.csv) were added to comply with the File-Level Metadata Reporting Format. Update on 2022-09-09: Updates were made to reporting format specific files (file-level metadata and data dictionary) to correct swapped file names, add additional details on metadata descriptions on both files, add a header_row column to enable parsing, and add version number and date to file names (v2_20220909_flmd.csv and v2_20220909_dd.csv). Update on 2023-08-08: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-01-05. The file level metadata and data dictionary files were updated to reflect the additional data added. Update on 2024-03-11: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-11-21. Further, revisions to the data files were made to remove incorrect data points (from 1970 and 2001). The reporting format specific files were updated to reflect the additional data added. Revised versions of the PDF and docx files for determination of MDLs for DIC and NPOC were added to replace previous versions. Update on 2025-05-15: Updates were made to both the data files and reporting format specific files. New available DIC and NPOC data was added, up until the end of WY2024 (September 30, 2024). International Generic Sample Numbers (IGSNs), when registered, were added to the data files. The reporting format specific files were updated to reflect the additional data added. Update on 2026-09-01: Updates were made to both the data files and reporting format specific files. New available DIC and NPOC data was added, up until the end of WY2025 (September 30, 2025). Updated versions, as of 2026-08-10, of the PDF and docx files for determination of MDLs for DIC and NPOC data were added to this dataset.

54 ENVIRONMENTAL SCIENCES↗

ISRU Technology Development for Extraction of Water from the Mars Surface

Goals: Develop technologies to extract water from planetary regolith considering production rate vs: energy/power consumption (efficiency, yield, heat recuperation options); Mass and sizing: modularity, batch sizes, soil feed options, etc.; Ruggedness in terms of soil, environmental, and operational parameters; seals and component wear, etc.; Removal of product and disposal of spent material. Summary: Technology development is underway for several ISRU water extraction hardware concepts for Mars application - Hydrated minerals (Auger dryer, Microwave, Open Air), Subsurface Ice (Rodwell); Models are developed with experimental and breadboard efforts for use in larger ISRU system models; Each effort consists of a 3 year development plan, with the goal of integrating into a larger subsystem test in 2020 - Concurrent technology advance allows for flexibility in system design; depending on architecture decisions and progress of associated subsystems.

In-Situ Resource Utilization↗

Understanding Changes in Water Availability in the Rio Grande/Rio Bravo del Norte Basin Under the Influence of Large-Scale Circulation Indices Using the Noah Land Surface Model

Water availability plays an important role in the socio-economic development of a region. It is however, subject to the influence of large-scale circulation indices, resulting in periodic excesses and deficits. An assessment of the degree of correlation between climate indices and water availability, and the quantification of changes with respect to major climate events is important for long-term water resources planning and management, especially in transboundary basins as it can help in conflict avoidance. In this study we first establish the correlation of the Pacific Decadal Oscillation (PDO) and El Nino-Southern Oscillation (ENSO) with gauged precipitation in the Rio Grande basin, and quantify the changes in water availability using runoff generated from the Noah land surface model. Both spatial and temporal variations are noted, with winter and spring being most influenced by conditions in the Pacific Ocean. Negative correlation is observed at the headwaters and positive correlation across the rest of the basin. The influence of individual ENSO events, classified using four different criteria, is also examined. El Ninos (La Ninas) generally cause an increase (decrease) in runoff, but the pattern is not consistent; percentage change in water availability varies across events. Further, positive PDO enhances the effect of El Nino and dampens that of La Nina, but during neutral/transitioning PDO, La Nina dominates meteorological conditions. Long El Ninos have more influence on water availability than short duration high intensity events. We also note that the percentage increase during El Ninos significantly offsets the drought-causing effect of La Ninas.

Khedun, C. Prakash↗

Groundwater and Terrestrial Water Storage

Groundwater is a vital resource and also a dynamic component of the water cycle. Unconfined aquifer storage is less responsive to short term weather conditions than the near surface terrestrial water storage (TWS) components (soil moisture, surface water, and snow). However, save for the permanently frozen regions, it typically exhibits a larger range of variability over multi-annual periods than the other components. Groundwater is poorly monitored at the global scale, but terrestrial water storage (TWS) change data from the Gravity Recovery and Climate Experiment (GRACE) satellite mission are a reasonable proxy for unconfined groundwater at climatic scales.

Rodell, Matthew↗

Boat-Dragged Riverbed and Mid-Column Water Quality along the Hanford Reach in the Columbia River Shorelines

This dataset contains water quality measurements used to identify sites of hydrologic exchange (i.e.hydrologic exchange flows; HEFs) in the Columbia River near Richland, WA by looking for anomalies in temperature and electrical conductivity (EC) along the bed of the river in February, June, July, August, and November 2017. These are ultimately the ‘ends’ of HEFs as they are locations of subsurface inflow to the river. This dataset contains dissolved oxygen (DO) measurements at 1-min intervals; temperature, EC, depth, and GPS coordinates at 1-second intervals; and N-NO3 at 2-min intervals along the river bed and mid-column water. DO measurements are included in this dataset for completeness but were not used in the analysis of HEFs due to the relatively long time interval of collection.

54 ENVIRONMENTAL SCIENCES↗

Seasonal-to-Interannual Variability in Antarctic Sea-Ice Dynamics, and Its Impact on Surface Fluxes and Water Mass Production

Strong seasonal and interannual signals in Antarctic bottom-water outflow remain unexplained yet are highly correlated with anomalies in net sea-ice growth in coastal polynyas. The mechanisms responsible for driving salination and replenishment and rejuvenation of the dense shelf "source" waters likely also generate pulses of bottom water outflow. The objective of this research is to investigate time-scales of variability in the dynamics of sea-ice in the Southern Ocean in order to determine the primary sites for production of dense shelf waters. We are using a merged satellite/buoy sea-ice motion data set for the period 1978-present day to compute the dynamics of opening and closing of coastal polynyas over the continental shelf. The Ocean Circulation and Climate Advanced Model (OCCAM) ocean general circulation model with coupled sea-ice dynamics is presently forced using National Center for Environmental Prediction (NCEP) data to simulate fluxes and the salination impact of the ocean shelf regions. This work is relevant in the context of measuring the influence of polar sea-ice dynamics upon polar ocean characteristics, and thereby upon global thermohaline ocean circulation. Interannual variability in simulated net freezing rate in the Southern Weddell Sea is shown for the period 1986-1993. There is a pronounced maximum of ice production in 1988 and minimum in 1991 in response to anomalies in equatorward meridional wind velocity. This follows a similar approximate 8-year interannual cycle in Sea Surface Temperature (SST) and satellite-derived ice-edge anomalies reported elsewhere as the "Antarctic Circumpolar Wave." The amplitude of interannual fluctuations in annual net ice production are about 40% of the mean value, implying significant interannual variance in brine rejection and upper ocean heat loss. Southward anomalies in wind stress induce negative anomalies in open water production, which are observed in passive microwave satellite images. Thus, cycles of enhanced poleward wind stress reduce ice growth by compacting the ice along the coastline and closing open water in leads and polynyas. Model simulations confirm that years of low ice production, such as 1991, coincide with years of lower than normal bottom water outflow. Future plans include the assimilation of satellite ice concentrations and ice drift dynamics to more accurately constrain boundary conditions in the model.

Drinkwater, Mark R.↗

Yakima River Basin Temporal Study: Sensor and Sample Data from Wenas Creek following the Evans Canyon Fire in Washington, USA

The Evans Canyon Fire occurred in Washington in August 2020 and burned 76,000 acres of the semi-arid shrub-steppe landscape at low to moderate severities. This fire burned across the Wenas Creek watershed, allowing for a sampling design that included a portion of the stream within the burned area and a reference site upstream of the burn. Monthly data was collected at an unburned (W10) and burned (W20) site from November 2020 to August 2022 for in situ hydrological and water chemistry sensor data, handheld sensor water chemistry data, general environmental context photos, and field metadata. This dataset is comprised of one folder with field photos and one main data folder containing (1) sensor and sample field protocols; (2) file-level metadata (flmd); (3) data dictionary (dd); (4) international geo-sample number (IGSN) mapping file; (5) field metadata; (6) readme; (7) methods codes; (8) dissolved organic carbon (DOC; measured as non-purgeable organic carbon; NPOC); (9) total nitrogen (TN); (10) total suspended solids (TSS); (11) sensor data (specific conductance, pH, total dissolved solids, temperature, pressure, dissolved oxygen, and turbidity) averages; and (12) sensor installation methods. All files are .csv, .jpg, .jpeg, or .pdf.

54 ENVIRONMENTAL SCIENCES↗

Anion Data for the East River Watershed, Colorado (2014-2025)

The anion data for the East River Watershed, Colorado, consist of fluoride, chloride, sulfate, nitrate, and phosphate concentrations collected at multiple, long-term monitoring sites that include stream, groundwater, and spring sampling locations. These locations represent important and/or unique end-member locations for which solute concentrations can be diagnostic of the connection between terrestrial and aquatic systems. Such locations include drainages underlined entirely or largely by shale bedrock, land covered dominated by conifers, aspens, or meadows, and drainages impacted by historic mining activity and the presence of naturally mineralized rock. Developing a long-term record of solute concentrations from a diversity of environments is a critical component of quantifying the impacts of both climate change and discrete climate perturbations, such as drought, forest mortality, and wildfire, on the riverine export of multiple anionic species. Such data may be combined with stream gauging stations co-located at each monitoring site to directly quantify the seasonal and annual mass flux of these anionic species out of the watershed. This data package contains (1) a zip file (anion_data_2014_2025.zip) containing a total of 386 files: 387 data files of anion data from across the Lawrence Berkeley National Laboratory (LBNL) Watershed Function Scientific Focus Area (SFA) which is reported in .csv files per location and a locations.csv (1 file) with latitude and longitude for each location; (2) a file-level metadata (v7_20260901_flmd.csv) file that lists each file contained in the dataset with associated metadata; (3) a data dictionary (v7_20260901_dd.csv) file that contains terms/column_headers used throughout the files along with a definition, units, and data type; and (4) a anion MDL fact sheet (anion_MDLs_202608 in PDF and docx formats). Missing values within the anion data files are noted as either "-9999" or "0.0" for not detectable (N.D.) data. There are a total of 47 locations containing anion data. Update on 2022-06-10: versioned updates to this dataset was made along with these changes: (1) updated anion data for all locations up to 2021-12-31, (2) removal of units from column headers in datafiles, (3) added row underneath headers to contain units of variables, (4) restructure of units to comply with CSV reporting format requirements, and (5) the addition of the file-level metadata (flmd.csv) and data dictionary (dd.csv) were added to comply with the File-Level Metadata Reporting Format. Update on 2022-09-09: Updates were made to reporting format specific files (file-level metadata and data dictionary) to correct swapped file names, add additional details on metadata descriptions on both files, add a header_row column to enable parsing, and add version number and date to file names (v2_20220909_flmd.csv and v2_20220909_dd.csv). Update on 2022-12-20: Updates were made to both the data files and reporting format specific files. Conversion issues affecting ER-PLM locations for anion data was resolved for the data files. Additionally, the flmd and dd files were updated to reflect the updated versions of these files. Available data was added up until 2022-03-14. Update on 2023-08-08: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-05-19. The file level metadata and data dictionary files were updated to reflect the additional data added. Update on 2024-03-11: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-09-11. Further, revisions to the data files were made to remove incorrect data points (from 1970 and 2001). The reporting format specific files were updated to reflect the additional data added. Update on 2025-05-15: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until the end of WY2024 (September 30, 2024). International Generic Sample Numbers (IGSNs), when registered, were added to the data files. The reporting format specific files were updated to reflect the additional data added. Update on 2026-09-01: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until the end of WY2025 (September 30, 2025). An anion MDL document was included in this update.

54 ENVIRONMENTAL SCIENCES↗

Development of an Operational Land Water Mask for MODIS Collection 6, and Influence on Downstream Data Products

Data from the Moderate Resolution Imaging Spectro-radiometer (MODIS)on-board the Earth Observing System Terra and Aqua satellites are processed using a land water mask to determine when an algorithm no longer needs to be run or when an algorithm needs to follow a different pathway. Entering the fourth reprocessing (Collection 6 (C6)) the MODIS team replaced the 1 km water mask with a 500 m water mask for improved representation of the continental surfaces. The new water mask represents more small water bodies for an overall increase in water surface from 1 to 2 of the continental surface. While this is still a small fraction of the overall global surface area the increase is more dramatic in certain areas such as the Arctic and Boreal regions where there are dramatic increases in water surface area in the new mask. MODIS products generated by the on-going C6 reprocessing using the new land water mask show significant impact in areas with high concentrations of change in the land water mask. Here differences between the Collection 5 (C5) and C6 water masks and the impact of these differences on the MOD04 aerosol product and the MOD11 land surface temperature product are shown.

Carroll, M. L.↗

Assessment of Oceanographic Conditions during the North Atlantic EXport Processes in the Ocean from RemoTe Sensing (EXPORTS) Field Campaign

This manuscript presents an overview of NASA’s EXport Processes in the Ocean from Remote Sensing 2021 Field Campaign in the North Atlantic (EXPORTS NA) and provides quantitative and dynamical descriptions of the physical processes modulating water transformations during the study. A major programmatic goal was to conduct the sampling in a Lagrangian mode so that ocean ecological and biogeochemical changes can be observed independent from physical advective processes. To accomplish this goal, EXPORTS NA conducted a multi-ship, multi-asset field sampling program within a retentive, anticyclonic mode water eddy. Beneath depths of ∼100 m, Lagrangian sampling assets remained within the eddy core waters (ECWs) throughout the experiment, demonstrating that the ECWs within the mode water eddy were retentive. However, strong westerly winds from four storm events deepened the mixed layer (ML) of the surface core waters (SCWs) above the eddy’s mode water core by 25-40 m and exchanged some of the SCWs with surface waters outside of the eddy via Ekman transport. Estimates of flushing times ranged from 5-8 days, with surface exchange fractions ranging from 20-75% and were consistent with particle tracking advected by combined geostrophic and Ekman velocities. The relative contributions of horizontal and vertical advection on changes in ECW tracers depended on the horizontal and vertical gradients of that tracer. For example, horizontal advection played a large role in ECW salinity fluxes, while vertical entrainment played a larger role in the fluxes of nutrients into SCW ML. Each storm injected nutrients and low oxygen waters into the ML, after which the surface ocean ecosystem responded by reducing nutrient concentrations and increasing %O2 saturation levels. Overall, ECW values of chlorophyll and POC were the largest at the onset of the field program and decreased throughout the campaign. The analysis presented provides a physical oceanographic context for the many measurements made during the EXPORTS NA field campaign while illustrating the many challenges of conducting a production-flux experiment, even in a Lagrangian frame, and the inherent uncertainties of interpreting biological carbon pump observations that were collected in a Eulerian frame of reference.

oceanography↗

Artificial linear brush abrasion of coatings for photovoltaic module first-surfaces

Natural soiling and the subsequent necessary cleaning of photovoltaic (PV) modules result in abrasion damage to the cover glass. The durability of the front glass has important economic consequences, including determining the use of anti-reflective and/or anti-soiling coatings as well as the method and frequency of operational maintenance (cleaning). Artificial linear brush abrasion using Nylon 6/12 bristles was therefore examined to explore the durability of representative PV first-surfaces, i.e., the surface of a module incident to direct solar radiation. Specimens examined include silane surface functionalized-, roughened (etched)-, porous silica-coated-, fluoropolymer-coated-, and ceramic (TiO 2 or ZrO 2 /SiO 2 /ZrO 2 /SiO 2 )-coated-glass, which are compared to monolithic-poly(methyl methacrylate) and -glass coupons. Characterization methods used in this study include: optical microscopy, ultraviolet–visible–near-infrared (UV-VIS-NIR) spectroscopy, sessile drop goniometry, white-light interferometry, atomic force microscopy (AFM), and depth-profiling X-ray photoelectron spectroscopy (XPS). The corresponding characteristics examined include: surface morphology, transmittance (i.e., optical performance), surface energy (water contact angle), surface roughness, scratch width and depth, and chemical composition, respectively. The study here was performed to determine coating failure modes; identify characterization methods that can detect nascent failures; compare the durability of popular contemporary coating materials; identify their corresponding damage characteristics; and compare slurry and dry-dust abrasion. This study will also aid in developing an abrasion standard for the PV industry.

14 SOLAR ENERGY↗

Active Phase on SrCo 1–x Fe x O -δ (0 ≤ x ≤ 0.5) Perovskite for Water Oxidation: Reconstructed Surface versus Remaining Bulk

Perovskite oxides based on earth-abundant transition metals have been extensively explored as promising oxygen evolution reaction (OER) catalysts in alkaline media. The (electro)chemically induced transformation of their initially crystalline surface into an amorphous state has been reported for a few highly active perovskite catalysts. However, little knowledge is available to distinguish the contribution of the amorphized surface from that of the remaining bulk toward the OER. In this work, we utilize the promoting effects of two types of Fe modification, i.e., bulk Fe dopant and Fe ions absorbed from the electrolyte, on the OER activity of SrCoO 3-δ model perovskite to identify the active phase. Transmission electron microscopy and X-ray photoelectron spectroscopy confirmed the surface amorphization of SrCoO 3-δ as well as SrCo 0.8 Fe 0.2 O 3-δ after potential cycling in Fe-free KOH solution. By further cycling in Fe-spiked electrolyte, Fe was incorporated into the amorphized surface of SrCoO 3-δ (SrCoO 3-δ + Fe 3+ ), yielding approximately sixfold increase in activity. Despite the difference in remaining perovskites, SrCoO 3-δ + Fe 3+ and SrCo 0.8 Fe 0.2 O 3-δ exhibited remarkably similar activity. These results reflect that the in situ developed surface species are directly responsible for the measured OER activity, whereas the remaining bulk phases have little impact.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗