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At least 1,513 records · Page 84

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NASA NTRS2005

How to Extend the Capabilities of Space Systems for Long Duration Space Exploration Systems

For sustainable Exploration Missions the need exists to assemble systems-of-systems in space, on the Moon or on other planetary surfaces. To fulfill this need new and innovative system architecture is needed that can be satisfied with the present lift capability of existing rocket technology without the added cost of developing a new heavy lift vehicle. To enable ultra-long life missions with minimum redundancy and lighter mass the need exists to develop system soft,i,are and hardware reconfigurability, which enables increasing functionality and multiple use of launched assets while at the same time overcoming any components failures. Also the need exists to develop the ability to dynamically demate and reassemble individual system elements during a mission in order to work around failed hardware or changed mission requirements. Therefore to meet the goals of Space Exploration Missions in hiteroperability and Reconfigurability, many challenges must be addressed to transform the traditional static avionics architecture into architecture with dynamic capabilities. The objective of this paper is to introduce concepts associated with reconfigurable computer systems; review the various needs and challenges associated with reconfigurable avionics space systems; provide an operational example that illustrates the needs applicable to either the Crew Exploration Vehicle or a collection of "Habot like" mobile surface elements; summarize the approaches that address key challenges to acceptance of a Flexible, Intelligent, Modular and Affordable reconfigurable avionics space system.

Marzwell, Neville I.↗

NASA NTRS2018

Decadal Changes in Summertime Reactive Oxidized Nitrogen and Surface Ozone over the Southeast United States

Widespread efforts to abate ozone (O3) smog have significantly reduced emissions of nitrogen oxides (NOx) over the past 2 decades in the Southeast US, a place heavily influenced by both anthropogenic and biogenic emissions. How reactive nitrogen speciation responds to the reduction in NOx emissions in this region remains to be elucidated. Here we exploit aircraft measurements from ICARTT (International Consortium for Atmospheric Research on Transport and Transformation - July-August 2004), SENEX (Southeast Nexus - June-July 2013), and SEAC4RS (Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys - August-September 2013) and long-term ground measurement networks alongside a global chemistry-climate model to examine decadal changes in summertime reactive oxidized nitrogen (RON) and ozone over the Southeast US. We show that our model can reproduce the mean vertical profiles of major RON species and the total (NO (sub y)) in both 2004 and 2013. Among the major RON species, nitric acid (HNO3) is dominant (approximately 42-45 percent), followed by NOx (31 percent), total peroxy nitrates (Sigma PNs; 14 percent), and total alkyl nitrates (Sigma ANs; 9-12 percent) on a regional scale. We find that most RON species, including NOx, Sigma PNs, and HNO3, decline proportionally with decreasing NOx emissions in this region, leading to a similar decline in NO (sub y). This linear response might be in part due to the nearly constant summertime supply of biogenic VOC (Volatile Organic Compounds) emissions in this region. Our model captures the observed relative change in RON and surface ozone from 2004 to 2013. Model sensitivity tests indicate that further reductions of NOx emissions will lead to a continued decline in surface ozone and less frequent high-ozone events.

Li, Jingyi↗

NASA NTRS2011

Reactive Oxygen Species on the Early Earth and Survival of Bacteria

An oxygen-rich atmosphere appears to have been a prerequisite for complex, multicellular life to evolve on Earth and possibly elsewhere in the Universe. However it remains unclear how free oxygen first became available on the early Earth. A potentially important, and as yet poorly constrained pathway, is the production of oxygen through the weathering of rocks and release into the near-surface environment. Reactive Oxygen Species (ROS), as precursors to molecular oxygen, are a key step in this process, and may have had a decisive impact on the evolution of life, present and past. ROS are generated from minerals in igneous rocks during hydrolysis of peroxy defects, which consist of pairs of oxygen anions oxidized to the valence state -1 and during (bio) transformations of iron sulphide minerals. ROS are produced and consumed by intracellular and extracellular reactions of Fe, Mn, C, N, and S species. We propose that, despite an overall reducing or neutral oxidation state of the macroenvironment and the absence of free O2 in the atmosphere, organisms on the early Earth had to cope with ROS in their microenvironments. They were thus under evolutionary pressure to develop enzymatic and other defences against the potentially dangerous, even lethal effects of oxygen and its derived ROS. Conversely it appears that microorganisms learned to take advantage of the enormous reactive potential and energy gain provided by nascent oxygen. We investigate how oxygen might be released through weathering. We test microorganisms in contact with rock surfaces and iron sulphides. We model bacteria such as Deionococcus radiodurans and Desulfotomaculum, Moorella and Bacillus species for their ability to grow or survive in the presence of ROS. We examine how early Life might have adapted to oxygen.

Balk, Melikea↗

DOE OSTI2020

Formation of phenanthrenyl radicals via the reaction of acenaphthyl with acetylene

Ab initio G3(MP2,CC)/B3LYP/6–31G** calculations of the potential energy surface for the reaction of 3-acenaphthyl radical with acetylene were combined with Rice-Ramsperger-Kassel-Marcus Master Equation calculations of the temperature- and pressure-dependent reaction rate constants and product branching ratios with the goal to examine the transformation of an edge five-membered ring into a six-membered one. The reaction mechanism has been shown to contain two stages: (1) the formation of 3-ethynylacenaphthylene + H in the 3-acenaphthyl + C 2 H 2 reaction via acetylene addition to the radical site and an H loss, (2) the formation of the 1-phenanthrenyl radical in the 3-ethynylacenaphthylene + H reaction via H addition to the five-membered ring followed by the ring flip. The results of kinetic modeling show this pathway being faster than the pathway proposed earlier featuring the CCH chemisorption on the six-membered ring without involvement of the five-membered ring. A kinetic test demonstrated the dominance of the former pathway for the formation of pyrene from naphthalene. Here, it is expected that the new mechanism plays a major role in the transformation of five-membered rings on edges of PAH structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Restructuring of the Lewis Acid Sites in Y-Modified Dealuminated Beta-Zeolite by Hydrothermal Treatment

Yttrium-modified dealuminated Betazeolite (Y-BEA) represents a type of Lewis acid zeolite that has gained attention for its potential to efficiently catalyze the conversion of biomass-derived oxygenates. The structure of the Y active sites and their dynamics during biomass conversion reactions, which normally involve substantial amounts of water, necessitate thorough investigation for the rational design of more active and stable catalysts. Here, we conducted a study where a series of Y-BEA catalysts with different yttrium loadings (1–7 wt.%) were subjected to hydrothermal treatment (450 °C, 20% water) and investigated for their structural and catalytic activity changes through a combination of multiple characterizations and kinetic measurements. The number of acid sites of Y-BEA decreased without a change in acid strength following the hydrothermal treatment, which was confirmed by the results of acid site titration, infrared spectroscopy of probe molecules, and kinetic measurements for probe reactions (acetone aldol condensation). Structural analysis using X-ray diffraction (XRD), specific surface area measurement, X-ray absorption spectroscopy (XAS), and X-ray photoelectron spectroscopy (XPS) demonstrated that both the zeolite structure and the isolation status of the Y site remain intact after hydrothermal treatment. Further, the Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) spectra, thermogravimetric analysis (TGA), and operando 1 H and 29 Si magic-angle spinning (MAS) nuclear magnetic resonance (NMR) revealed the dehydroxylation of Y-BEA induced by hydration-rearrangement-condensation restructuring during the high-temperature steam treatment. Dehydroxylation affects the structure of Y sites by reducing their vicinal silanol sites. In conclusion, this conversion of Lewis acidic Y sites into nonacidic sites is the primary factor behind the change in acid site quantity and catalytic activity on Y-BEA.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Mechanochemistry-driven phase transformation of crystalline covalent triazine frameworks assisted by alkaline molten salts

We report covalent triazine frameworks (CTFs) have shown wide applications in the fields of separation, catalysis, energy storage, and beyond. However, it is a long-term challenging subject to fabricate high-quality CTF materials via facile procedures. Herein, a mechanochemistry-driven procedure was developed to achieve phase transformation of crystalline CTFs assisted by alkaline molten salts. The transformation of CTF-1 from staggered AB to eclipsed AA stacking mode was achieved by short time (30 min) mechanochemical treatment in the presence of molten salts composed of LiOH/KOH, generating high-quality CTF-1 material with high crystallinity, high surface area (625 m 2 g -1 ), and permanent/ordered porosity without carbonization under ambient conditions. This facile procedure could be extended to provide nanoporous three-dimensional CTF materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2026

Stimulated geologic hydrogen: from mechanistic control to engineered rock transformation

Geologic hydrogen (GeoH 2 ) generated from subsurface iron-rich rock–water reaction (i.e., serpentinization) is emerging as a promising candidate for the next primary energy source. Yet, accelerating GeoH 2 production from geological to human timescales via enhanced serpentinization remains a formidable scientific and technical challenge. Here, in this Review, we decipher the mechanistic control and explore strategies for accelerating in situ, engineered iron-rich rock transformation into carbon-free GeoH 2 by orders of magnitude. Serpentinization rate is hindered by low porosity and permeability of source rocks, suboptimal temperatures, unfavorable water chemistry, inefficient Fe 2+ -to-Fe 3+ conversion, thermodynamic constraints, and low reactive surface area. While closed-system experiments provide valuable mechanistic insights, open-system conditions with fluid circulation are more crucial for economically viable GeoH 2 production. We assess stimulation techniques from enhanced hydrocarbon and geothermal recovery as tools to be adopted or adapted for increasing reactive surface areas for stimulated GeoH2 production. We estimate that 7.40 × 10 5 to 1.73 × 10 6 million metric tons (Mt) of hydrogen could be engineered over 20 to 50 years from about 10% iron-rich rocks within 10 km depth of continental crust. Enabling GeoH 2 as a viable energy source requires not only advancing scientific frontiers but also forming a global GeoH 2 research network and innovation ecosystem to address the critical scientific, technical, societal, economic, and policy challenges.

08 HYDROGEN↗

DOE OSTI2026

Unsupervised atomic data mining via multi-kernel graph autoencoders for machine learning force fields

Constructing a chemically diverse dataset while avoiding sampling bias is critical to training efficient and generalizable force fields. However, in computational chemistry and materials science, many common dataset generation techniques are prone to oversampling regions of the potential energy surface. Furthermore, these regions can be difficult to identify and isolate from each other or may not align well with human intuition, making it challenging to systematically remove bias in the dataset. While traditional clustering and pruning (down-sampling) approaches can be useful for this, they can often lead to information loss or a failure to properly identify distinct regions of the potential energy surface due to difficulties associated with the high dimensionality of atomic descriptors. In this work, we introduce the Multi-kernel Edge Attention-based Graph Autoencoder (MEAGraph) model, an unsupervised approach for analyzing atomic datasets. MEAGraph combines multiple linear kernel transformations with attention-based message passing to capture geometric sensitivity and enable effective dataset pruning without relying on labels or extensive training. Demonstrated applications on niobium, tantalum, and iron datasets show that MEAGraph efficiently groups similar atomic environments, allowing for the use of basic pruning techniques for removing sampling bias. This approach provides an effective method for representation learning and clustering that can be used for data analysis, outlier detection, and dataset optimization.

Materials science↗

DOE OSTI2023

Making and breaking terahertz waves with fluid plasmas

Vigorous research efforts during the past several decades have successfully closed the “terahertz gap” between microwaves and infrared light, offering new and increasingly efficient ways to produce, detect, and manipulate radiation fields in the terahertz (THz) frequency range. In our laboratory, THz time-domain spectroscopy (THz-TDS) and optical-pump THz-probe (OPTP) experiments have been routinely utilized as ultrafast spectroscopy tools to investigate a variety of emerging quantum materials and metamaterials. The ultrafast THz pulses are produced by femtosecond laser excitation of photoconductive antennas, semiconductor surfaces (InAs), and nonlinear crystals (ZnTe, GaSe, and LiNbO 3 ). Photoconductive antennas and nonlinear crystals also allow for the coherent detection of these pulses in the time domain, with amplitude and phase spectra obtained in the frequency domain via fast Fourier transform. Although such solid-state schemes are highly desirable in many aspects and thus also commonly utilized in many research laboratories and industrial applications, they typically suffer from limited bandwidths due to the absorption and frequency dispersion induced primarily by phonon resonances, limiting THz applications such as spectroscopy of emerging materials, imaging and detection, and biomedical characterization.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

NASA NTRS1981

Fourier spectroscopy on planetary missions including Voyager

In the last dozen years spaceborne Fourier transform spectrometers have obtained infrared emission spectra of Earth, Mars, Jupiter, Saturn and Titan as well as of the Galilean and other Saturnian satellites and Saturn's rings. Intercomparisons of the properties of planetary atmospheres and of the characteristics of solid surfaces are now feasible. The principles of remotely sensing the environment on a planetary body are dicussed. Special consideration is given to the most recent results obtained by the Voyager infrared investigation on the Saturn system.

Hanel, R. A.↗

NASA NTRS1982

A study of persistent elevated pollution episodes in the northeastern United States

To examine chemical transformation within stagnant air masses and the atmospheric processes acting upon such air masses, the United States EPA sponsored a study in the summer of 1980 in the northeastern region of the country. Ten research aircraft and several mobile and stationary surface monitoring platforms participated in an intensive measurement program between 16 July and 15 August 1980. Pollutants of interest included SO2, NO, NO(x), HC, O3, sulfate, nitrate, and aerosols in general. This paper summarizes the activities of these research aircraft. Three aircraft and one helicopter logged a total of 353 flight hours during 100 missions in the program. The flight patterns and data collected for each mission are documented. This summary will allow scientists who are interested in this data base to identify subsets of the data for model development.

Vaughan, W. M.↗

NASA NTRS1982

Investigation of Antarctic crust and upper mantle using MAGSAT and other geophysical data

Antarctica is the perfect proving ground for testing data reduction procedures which are alternatives to the standard procedure employing polynomial fitting. Unreduced data (observed values minus corefield model theo each pass) were averaged in 3 degree bins. The resulting map was then high pass filtered using a finite Fourier transform filter so that spectral peaks between 4200 km and 5280 km were diminished by 1/3, peaks corresponding to wavelengths greater than or equal to 5280 km were diminished by 1/2, and the d.c. component was set equal to zero. The surface subtracted in this way differs from the polynomials used in the standard method in that it is static over the 5 north data window. The map produced is presented and the effects of the static model are compared to those of the dynamic mode.

Bentley, C. R.↗

NASA NTRS1985

Investigation of Low-temperature Solders for Cryogenic Wind Tunnel Models

The advent of high Reynolds number cryogenic wind tunnels has forced alteration of manufacturing and assembly techniques and eliminated usage of many materials associated with conventional wind tunnel models. One of the techniques affected is soldering. Solder alloys commonly used for wind tunnel models are susceptible to low-temperature embrittlement and phase transformation. The low-temperature performance of several solder alloys is being examined during research and development activities being conducted in support of design and fabrication of cryogenic wind tunnel models. Among the properties examined during these tests are shear strength, surface quality, joint stability, and durability when subjected to dynamic loading. Results of these tests and experiences with recent models are summarized.

Firth, G. C.↗

NASA NTRS1987

Prediction of vortex shedding from circular and noncircular bodies in subsonic flow

An engineering prediction method and associated computer code VTXCLD are presented which predict nose vortex shedding from circular and noncircular bodies in subsonic flow at angles of attack and roll. The axisymmetric body is represented by point sources and doublets, and noncircular cross sections are transformed to a circle by either analytical or numerical conformal transformations. The leeward vortices are modeled by discrete vortices in crossflow planes along the body; thus, the three-dimensional steady flow problem is reduced to a two-dimensional, unsteady, separated flow problem for solution. Comparison of measured and predicted surface pressure distributions, flowfield surveys, and aerodynamic characteristics are presented for bodies with circular and noncircular cross sectional shapes.

Mendenhall, Michael R.↗

NASA NTRS1990

PAN AIR: A computer program for predicting subsonic or supersonic linear potential flows about arbitrary configurations using a higher order panel method. Volume 1: Theory document (version 3.0)

An outline of the derivation of the differential equation governing linear subsonic and supersonic potential flow is given. The use of Green's Theorem to obtain an integral equation over the boundary surface is discussed. The engineering techniques incorporated in the Panel Aerodynamics (PAN AIR) program (a discretization method which solves the integral equation for arbitrary first order boundary conditions) are then discussed in detail. Items discussed include the construction of the compressibility transformation, splining techniques, imposition of the boundary conditions, influence coefficient computation (including the concept of the finite part of an integral), computation of pressure coefficients, and computation of forces and moments. Principal revisions to version 3.0 are the following: (1) appendices H and K more fully describe the Aerodynamic Influence Coefficient (AIC) construction; (2) appendix L now provides a complete description of the AIC solution process; (3) appendix P is new and discusses the theory for the new FDP module (which calculates streamlines and offbody points); and (4) numerous small corrections and revisions reflecting the MAG module rewrite.

Epton, Michael A.↗

NASA NTRS1991

Radiometric rectification - Toward a common radiometric response among multidate, multisensor images

A method is developed for relating scene digital counts among several images of the same scene by identifying radiometric control sets with mean reflectances that are basically constant. The average digital-count values of the control sets are utilized to compute linear transforms that relate digital count values between images. Two Landsat TM images are studied by means of the technique using simulations of a wide range of atmospheric conditions. In the visible and near-IR bands the algorithm effectively adjusts the surface reflectance for the effects of relative atmospheric differences to within 1 percent. The proposed method is found to be an effective relative correction procedure that can be used when atmospheric optical-depth data and calibration coefficients are not available.

Hall, F. G.↗

NASA NTRS2003

Advantages of Brahms for Specifying and Implementing a Multiagent Human-Robotic Exploration System

We have developed a model-based, distributed architecture that integrates diverse components in a system designed for lunar and planetary surface operations: an astronaut's space suit, cameras, all-terrain vehicles, robotic assistant, crew in a local habitat, and mission support team. Software processes ('agents') implemented in the Brahms language, run on multiple, mobile platforms. These mobile agents interpret and transform available data to help people and robotic systems coordinate their actions to make operations more safe and efficient. The Brahms-based mobile agent architecture (MAA) uses a novel combination of agent types so the software agents may understand and facilitate communications between people and between system components. A state-of-the-art spoken dialogue interface is integrated with Brahms models, supporting a speech-driven field observation record and rover command system. An important aspect of the methodology involves first simulating the entire system in Brahms, then configuring the agents into a runtime system Thus, Brahms provides a language, engine, and system builder's toolkit for specifying and implementing multiagent systems.

Clancey, William J.↗

NASA NTRS1981

PAN AIR: A Computer Program for Predicting Subsonic or Supersonic Linear Potential Flows About Arbitrary Configurations Using a Higher Order Panel Method: Theory Document (Version 1.1) - Volume 1

Magnus, Alfred E.↗