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At least 1,513 records · Page 84

Assessment of critical flaw sizes and crack driving forces during additive manufacturing of metallic materials

Additive manufacturing (AM) of complex engineering components is often plagued by a high susceptibility to cracking, particularly in high-strength metallic materials. While alloy design efforts have made progress in mitigating solidification defects, there remains a need for mechanistic guidelines to predict susceptibility to solid-state cracking. To address this gap, driving forces for the growth of melt pool cracks are calculated across a wide range of alloys using an efficient computational framework. Calculations are coupled with rapid single track laser experiments to elucidate trends in cracking from laser melting. The analyses conducted here highlight the important role of material properties in susceptibility to cracking, notably fracture toughness and elastic modulus. An important finding is that residual stresses that are limited in magnitude to the yield stress of the material are likely insufficient to drive cracking during cooling. Furthermore, the implications of these results are discussed in the context of alloy design for AM and residual stress accumulation during AM.

36 MATERIALS SCIENCE↗

Which way does the dendrite grow? Competition among epitaxy, preferred growth direction, and thermal gradients in powder bed fusion additive manufacturing

The as-processed microstructure of metal alloy parts manufactured through laser powder bed fusion (LPBF) is heavily derived from the cellular dendritic solidification. The growth direction of dendrites within the melt pool is determined through competition among epitaxial growth, preferred growth directions, and maximum thermal gradients. However, the dominant factor and the specific role of each in developing melt pool microstructures remain unknown. Here, in this study, we performed single laser track scans on an SS316L single crystal substrate and combined experimental characterization of microstructure and crystal orientations with Computational Fluid Dynamics simulations of thermal gradients to evaluate the role of each factor in determining dendritic growth direction and evolution. Our results reveal that epitaxial growth dominates microstructure development by preferentially growing along a single 〈100〉 variant of the single crystal substrate adjacent to the melt pool boundary. Under LPBF’s highly curved and rapidly evolving thermal field, this preferential dendrite variant selection and its continued growth from the melt pool boundary to the centerline are governed by the local temperature gradient magnitude at the solid-liquid interface, rather than by the instantaneous maximum temperature gradient direction alone. Using these findings, we successfully predict changes in the dendrite growth direction with changing laser scan direction on a single crystal substrate, and show that the geometric melt pool centerline can deviate from the microstructural centerline because asymmetric local temperature gradient magnitudes transiently limit growth, resulting in different dendrite travel distances on each side of the melt pool.

36 MATERIALS SCIENCE↗

Reduction of water content in calcium aluminate cement with/out phosphate modification for alternative cementation technique

Cementation of the secondary aqueous wastes from TEPCO Fukushima Daiichi Nuclear Power Plant is challenging due to the significant strontium content and radioactivity, leading to a potential risk of hydrogen gas generation via radiolysis of water content. The present study investigates the reduction of water content in calcium aluminate cement (CAC) with/out phosphate modification by a heat-treatment during the solidification. The reduction of water in the CAC was found restricted by the rapid formation of crystalline hydration phases, whereas the phosphate-modified system allowed the gradual reduction of water, achieving the reduction of 60% water content at 95 °C. Curing at 60–95 °C also eliminated the significant cracks found at 35 °C in the phosphate system. The possible difference in the amorphous products, NaCaPO{sub 4}·nH{sub 2}O type at 35°C and Ca(HPO{sub 4})·xH{sub 2}O type at 60–95 °C, may have contributed to the improvement in the microstructure together with the change in the pore size distribution.

36 MATERIALS SCIENCE↗

Ordering in liquid and its heredity impact on phase transformation of Mg-Al-Ca alloys

It is a long-sought goal to achieve desired mechanical properties through tailoring phase formation in alloys, especially for complicated multi-phase alloys. In fact, unveiling nucleation of competitive crystalline phases during solidification hinges on the nature of liquid. Here we employ ab initio molecular dynamics simulations (AIMD) to reveal liquid configuration of the Mg-Al-Ca alloys and explore its effect on the transformation of Ca-containing Laves phase from Al 2 Ca to Mg 2 Ca with increasing Ca/Al ratio (r Ca/Al ). There is structural similarity between liquid and crystalline phase in terms of the local arrangement environment, and the connection schemes of polyhedras. The forming signature of Mg 2 Ca, as hinted by the topological and chemical short-range order originating from liquid, ascends monotonically with increasing r Ca/Al . However, Al 2 Ca crystal-like order increase at first and then decrease at the crossover of r Ca/Al = 0.74, corresponding to experimental composition of phase transition from Al 2 Ca to Mg 2 Ca. The origin of phase transformation across different compositions lies in the dense packing of atomic configurations and preferential bonding of chemical species in both liquid and solid. The present finding provides a feasible scenario for manipulating phase formation to achieve high performance alloys by tailoring the crystal-like order in liquid.

36 MATERIALS SCIENCE↗

Microstructural banding of directed energy deposition-additively manufactured 316L stainless steel

The microstructures of 316 L stainless steel created by rapid solidification are investigated here by comparing the similar microstructures of individual hatches of directed energy deposition additive manufacturing (DED-AM) and those of single, laser surface-melted tracks formed on a solid plate. High recoil pressure, which is exponentially dependent on the laser beam power density, induces convection of the melt pool, which causes formation of microstructural bands in the as-solidified microstructure. The microstructural bands are associated with changes in the chromium concentration and are a significant component of the inhomogeneous microstructure of DED-AM.

36 MATERIALS SCIENCE↗

Heavy ion irradiation response of an additively manufactured 316LN stainless steel

Additive manufacturing has become an appealing technique to fabricate three-dimensional metallic materials and components for nuclear reactors. However, response of additively manufactured alloys to high-dose heavy ion irradiations at elevated temperatures is still not well understood. Here, an additively manufactured 316LN austenitic stainless steel with high-density solidification cells was irradiated using 3.5 MeV Fe ion to a peak dose of 220 dpa at 450 °C. Microscopy studies show a lower Frank loop density and smaller size in the additively manufactured sample compared with its cold worked counterpart, and the cellular structures may largely suppress the formation of perfect loops and dislocation networks and reduce the magnitude of solute segregations comparing with high angle grain boundaries. In conclusion, the present work advances the understanding on the high-temperature irradiation response of additively manufactured steels for nuclear reactor applications.

36 MATERIALS SCIENCE↗

Application of X-ray computed tomography for the characterization of graphite morphology in compact-graphite iron

Highlights: • X-ray Tomography is a powerful technique for graphite morphology characterization. • 3D characterization reveals true nodularity and spatial connectivity of graphite. • Tri-modal distribution of SG suggests a multi-stage graphite nucleation process. - Abstract: In the present study, high-energy X-ray tomography technique was used to characterize the graphite morphology of compact graphite iron. The size, shape, spatial connectivity and structure of different graphite morphologies were examined in 3D using computer-aided image analysis. In addition, nodularity analysis was performed in 3D and the results are compared to the traditional 2D technique. It is found that the variation of nodularity within 2 × 2 × 1.2 mm{sup 3} of the sample can be as high as 20 (%) from 2D analysis and the averaged nodularity (2D) is higher than that from 3D analysis. The size distribution of spheroidal graphite shows a tri-modal distribution, which suggests a multi-step nucleation process during solidification.

36 MATERIALS SCIENCE↗

Microstructural evolution and growth behavior of intermetallic compounds at the liquid Al/solid Fe interface by synchrotron X-ray radiography

Highlights: • A layered and tongue-like η phase was in-situ observed by synchrotron radiation X-ray radiography. • The coalescence of η phase bottom resulted in dissolution, further increasing the growth rate. • The θ phase growth behavior with different morphologies during cooling was analyzed. - Abstract: The growth of Inter-Metallic Compounds (IMCs) with dissolution was investigated on the liquid Al/solid Fe interconnection by using synchrotron radiation real-time imaging technology. At the initial stage of holding at 850 °C, a layer of the η-Fe{sub 2}Al{sub 5} phase formed at the interface, and tongue-like η grew into α-Fe. The tongue-like η phase had a stronger (001) texture than the layered phase. The coalescence of tongue-like η started at the bottom, followed by the dissolution of IMCs, which leads to a further increase in its growth rate. During solidification stage, the dotted, needle-like and flake θ-FeAl{sub 3} phases were sequentially formed.

36 MATERIALS SCIENCE↗

Microstructure and mechanical behavior of hot-work tool steels processed by Selective Laser Melting

Highlights: • H11 and a modified H11 hot work tool steels have been produced by SLM. • As-built alloys are characterized by α-Fe cells surrounded by C-rich γ-Fe regions. • Rapidly solidified structures revealed able to respond to precipitation hardening. • Mechanical behavior of AM H11 is similar to that obtained by conventional processes. - Abstract: The present study is aimed at identifying and testing high-strength alloys for tooling applications featuring suitable processability for laser-based additive manufacturing technologies. The microstructure and mechanical properties of the H11 hot-work tool steel and a leaner version of the same alloy (L-H11) processed by Selective Laser Melting were assessed as a function of specific microstructural conditions obtained by performing different heat treatments. Tempering was performed on quenched alloys or simply from as built material. The rapidly solidified microstructures revealed able to respond directly to precipitation hardening treatment without performing any prior solution annealing. The microstructure of the as-built alloys revealed characterized by α-Fe dendritic cells decorated at boundaries by C-rich γ-Fe regions. Air quenching was responsible for the transformation of the solidification cells into lath martensitic structures and for the formation of the M{sub 3}C phase, which transformed into more complex carbide species on tempering. The hardness of quenched and tempered H11 steel is similar to that obtained by processing the alloy with conventional routes, and the final hardness gap between the two SLM processed H11 and L-H11 alloys treated according to optimal tempered condition was limited to 62 HV.

36 MATERIALS SCIENCE↗

Effect of Bi on the microstructure and mechanical properties of Sn-Zn alloys processed by rolling

Highlights: • Sn-Zn-Bi is proposed for the first time as the cladding in linear explosive device. • Bi can significantly refine the microstructure of Sn-Zn. • Bi can enhance both strength and ductility of Sn-Zn processed by rolling. • The 5 wt% Bi in Sn-3Zn leads to finest and most homogenous grains after rolling. - Abstract: Sn-Zn based alloys including Sn-3Zn, Sn-3Zn-1Bi, and Sn-3Zn-5Bi were prepared by casting and rolling, in efforts to assess their feasibility for the application as cladding materials in detonating and explosive cords. It was found that Bi significantly refined the solidification microstructure, changing the configuration of Sn-Zn eutectic from well-aligned Zn-rich precipitates/needles to misaligned Zn-rich flakes. During deformation, second phases like Zn-rich precipitates and Bi particles, and Bi solutes were effective in grain refinement since second phase particles provided more sites for nucleation and more obstacles to growth of new recrystallized grains. Tensile results revealed that Bi addition enhanced both strength and ductility of the rolled Sn-Zn-Bi alloys. The Sn-3Zn-5Bi alloy possessed superior strength and ductility (UTS: 84.4 MPa; Yield strength: 68.3 MPa; Elongation: 75.2%) due to its finest and most homogeneous equiaxed grains. Based on decent mechanical properties, the Sn-Zn-Bi alloys could be well qualified for the application as cladding materials.

36 MATERIALS SCIENCE↗

Influence of Mn addition on the microstructure and mechanical properties of a directionally solidified γ-TiAl alloy

Highlights: • Mn addition can significantly improve the yield strength of TiAl alloy. • Introduction of Mn facilitates the operation of twinning-controlled deformation. • Twin-dislocation interactions cause a continuous increase in work hardening rate. - Abstract: TiAl alloys with nominal compositions of Ti-47Al-2Nb-2Cr-(0, 1, 3, 5)Mn were prepared via electromagnetic cold crucible directional solidification (ECCDS), and the influence of Mn addition on the microstructure and mechanical properties of the alloys was investigated. The experimental results showed that the Mn atoms were dissolved within the TiAl alloy, and no Mn compounds were formed. Based on the X-ray diffraction (XRD) analysis results, the peak angle of the Mn-containing sample shifted to a higher value, indicating lattice shrinkage. The Mn addition also increased the volume fraction of the B2 phase. The yield strength of the TiAl alloy monotonically increased as the content of the substitutional-solute Mn atoms increased. The ultimate strengths of the TiAl alloys containing 1 at.%, 3 at.%, and 5 at.% Mn consequently decreased because micro-cracks were preferentially formed in the B2 phase during room-temperature deformation. The introduction of substitutional-solute Mn atoms could result in a reduction of the stacking-fault energy of the γ phase, and facilitate the operation of twinning-controlled plastic-deformation during the intermediate stage of the plastic deformation process. The interaction between the deformation twins and movable dislocations led to a continuous increase in the work-hardening rate.

36 MATERIALS SCIENCE↗

Pulsed laser powder bed fusion additive manufacturing of A356

Highlights: • Dense A356 specimens (98 ± 0.4%) were fabricated using a customized P-LPBF system. • Microstructure and grain morphology were examined using LOM, SEM, and EBSD. • Solidification front velocities (R) were evaluated through the KGT model. • A columnar grain structure was observed and predicted by the Hunt's criterion. - Abstract: A356 (Al7SiMg) specimens were fabricated through pulsed laser powder bed fusion (P-LPBF) additive manufacturing. Microstructural examinations and analyses were carried out through the usage of light optical microscopy (LOM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The results revealed a fine cellular microstructure with the intercellular network consisting of Al cells and defined by a network of Si arms. The Al cells at the center of the melt pools and within the melt pool boundary bands were measured to be 423 ± 49 nm and 664 ± 76 nm, respectively. The presence of a fine columnar grain structure and epitaxial growth on partially melted grains was observed and explained by the KGT model and Hunt's criterion.

36 MATERIALS SCIENCE↗

Characterization of texture and grain boundary character distributions of selective laser melted Inconel 625 alloy

Highlights: • <110> texture along layer build direction was generated in as-SLMed Inconel 625. • The stress relief process dominates texture and GBCD evolution. • SLMed IN 625 alloy can be GBEed via suitable post annealing. - Abstract: Select laser melting (SLM) is one of the practical metal additive manufacturing processes to fabricate complex structures. The inhomogeneous microstructure and high residual stress are typically resulted from a non-uniform melting and rapid solidification during a SLM process, which has the significant impact on part dimensional instability, corrosion resistance, and mechanical properties. The bulk of current research is limited to the general characterization of grain size, texture, and mechanical properties. However, grain boundary character distribution (GBCD) and its relationship with texture are yet to be understood. This study has shown that the preferred <110> along building direction and <100> along laser scanning direction were produced. The high density of low angle grain boundary (LAGB) can be an indicator of residual stress levels in the as-SLMed samples. The newly-developed ∑3, ∑9 and ∑27 grain boundaries were heavily populated, and the cluster of grains interfaced by ∑3{sup n} (n = 0, 1, 2…) was introduced at the expense of LAGB only at high recrystallization annealing (1150°C or over). The research results suggest that GBCD optimization be possible in the SLMed Inconel 625 alloy via suitable post annealing, which allows improving intergranular corrosion resistance and enhancing mechanical properties.

36 MATERIALS SCIENCE↗

Defects and 3D structural inhomogeneity in electron beam additively manufactured Inconel 718

Highlights: • A protocol for 3D characterization of structure and defects in additively manufactured EBM 718 is presented. • Lack of fusion defects disrupt local microstructure, creating isolated regions of equiaxed grains. • Clustering of micron-scale nitrides is attributed to a particle rafting process. • Normalized size-number density relationship of carbides matches that of industrial ingots. • Removal of porosity via post-processing will not correct microstructural inhomogeneities created by lack of fusion defects. - Abstract: Material structure and defects created during additive manufacturing contribute to the variability in mechanical properties of these parts, limiting their use for critical applications. Three-dimensional crystallographic, structural, and chemical information in electron beam melted Inconel 718 was collected from the sub-micron to the millimeter scale using the TriBeam tomography system. The relationship of defects to the surrounding microstructure has been studied in detail. Lack of fusion defects created sharp discontinuities in the grain morphology that extended several build layers beyond the layer where the defect originated. Nitrides and carbides in the size range of 1.25 μm to 10 μm were observed throughout the volume, with pronounced nitride clustering. The similarities between solidification in additive manufacturing and traditional manufacturing processes are demonstrated by the comparable size and distribution of carbides measured for industrial-scale samples of 718. Defects created during additive manufacturing cannot be easily remedied via standard post-processing techniques, and will likely diminish the mechanical performance of additively manufactured parts.

36 MATERIALS SCIENCE↗

Effects of Sr, Ce and P on the microstructure and mechanical properties of rapidly solidified Al7Si alloys

Highlights: • Rapid solidification caused formation of nanoscaled Si particle chains. • Sr or Ce induced the columnar transition zone only at extremely high cooling rate. • Enhancement of hardness is attributed to fine dispersion of eutectic Si, grain refinement and the supersaturation of Si. • Sr or Ce caused further enhancement of hardness, attributing to Si modification. - Abstract: A series of Al7Si based alloys with trace addition of Sr, Ce or P were prepared using melt-spinning at two different high cooling rates, and the microstructure as well as the hardness of the ribbons was comprehensively studied. The results show that Sr or Ce induces the formation of columnar transition zone and modifies the morphology of eutectic Si phase from dispersed particle chains to fine fibers only at extremely high cooling rate. However, P has little effect on the microstructure of either α-Al or eutectic Si. Compared with conventional casting, the Al7Si ribbons exhibit extremely high hardness due to the fine dispersion of eutectic Si, the grain refinement and the supersaturation of Si. The hardness is further enhanced by Sr or Ce addition at extremely high cooling rate, especially for columnar and equiaxed zones, attributing to the modification effect on Si phase.

36 MATERIALS SCIENCE↗

Effects of boron addition on the morphology of silicon phases in Al-Si casting alloys

Highlights: • The influence of boron on Si phase was studied. • Boron addition reduces the length of eutectic Si plates in Al-11Si alloys. • Boron addition promotes the nucleation temperature of primary Si phases in Al-14Si alloys. • Boron addition increases the twin density in the <112>{sub Si} growth direction of eutectic Si in Al-11Si and Al-14Si alloys. - Abstract: The influence of B elements on the morphology of Si phases in Al-11Si and Al-14Si alloys has been investigated employing Optical Microscope, Scanning Electron Microscopy, Transmission Electron Microscopy and Differential Scanning Calorimetry. In Al-11Si alloy, the addition of B element not only refines the primary Al dendrites, but also reduces the length of eutectic Si plates. In Al-14Si alloys, the addition of B element promotes the nucleation temperature of primary Si phases, but shows weak influence on the nucleation temperature of eutectics. The effects of B element on the morphologies of both primary Si particle and eutectics can be attributed to the interaction between B and Si elements during the solidification process.

36 MATERIALS SCIENCE↗

Effects of Nb and Ta additions on the strength and coarsening resistance of precipitation-strengthened Al-Zr-Sc-Er-Si alloys

Highlights: • Nb and Ta micro-additions are made to a dilute Al-Er-Sc-Zr-Si alloys. • Zr-enriched primary L1{sub 2} precipitates form on solidification. • Secondary L1{sub 2} precipitates form on aging, and show improved coarsening resistance. • Nb and Ta are enriched at the secondary nanoprecipitate/matrix interface. • Micro-additions of Nb and Ta have similar effects as V, previously studied. - Abstract: A dilute Al-0.07Zr-0.02Sc-0.005Er-0.06Si (at.%) alloy was microalloyed with 0.08 at.% Nb or Ta. Atom-probe tomography reveals that, upon aging, Nb and Ta partition to the coherent L1{sub 2}-Al{sub 3}(Zr,Sc,Er) nanoprecipitates (with average concentrations of 0.2 and 0.08 at.%, respectively), with both segregating at the matrix/nanoprecipitate heterophase interface. This is consistent with the Nb- and Ta-modified alloys exhibiting, as compared to the unmodified alloy: (i) higher peak microhardness, from a higher nanoprecipitate volume fraction and/or lattice parameter mismatch; and (ii) improved aging resistance, from slower nanoprecipitate coarsening due to the small diffusivities of niobium and tantalum in aluminum. Analogous results were previously reported for a V-modified alloy.

36 MATERIALS SCIENCE↗

A comparison of Ti-6Al-4V in-situ alloying in Selective Laser Melting using simply-mixed and satellited powder blend feedstocks

Highlights: • Satelliting mixing is proposed for preparing powder feedstocks for AM. • Satelliting allows the creation of blended feedstocks of improved homogeneity. • Sample homogeneity is affected by particle size distribution and powder mixing technique. - Abstract: In-situ alloying within laser powder-bed fusion, specifically Selective Laser Melting (SLM), has been investigated for the formulation of novel alloys from elemental powders to extend the benefits offered by these technologies. Inadequate preparation of the powder feedstock prior to in-situ alloying can yield inhomogeneous microstructures, often deteriorating the mechanical performance of the deposited parts. The present work was designed to assess the use of the ‘satelliting’ method to create powder feedstocks for in-situ laser powder-bed fusion. The research was carried out on Ti-6Al-4V. Ti-6Al-4V feedstocks obtained by mixing or satelliting elemental powders were investigated and compared to a reference pre-alloyed material. The processability of the different feedstocks was assessed by comparing the microstructure of the deposits originating from the different powder blends. Results show that the powder percolation and particle size distribution of the feedstocks translate in deposited microstructures exhibiting different porosity, elemental segregation, and average grain size, revealing the impact of the powder blend characteristics on the laser energy absorbance and solidification of the alloy. This study provides fundamental insights of how to formulate powder feedstock and aims to support future research activities on the design and development of new alloys for use in powder-based additive manufacturing.

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