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At least 1,513 records · Page 84

Radiation response of FeCrAl-coated Zircaloy-4

Coating the surface of Zircaloy-4 light water reactor fuel cladding tube is of considerable interest for enhancing its accident tolerance. In this study, thermal annealing of FeCrAl-coated Zircaloy-4 at 725 °C for 500 h, was used to induce interfacial reactions between Zircaloy-4 and FeCrAl. The interface zones were then irradiated by 3.5 MeV Zr ions at 400 °C, up to 50, 100, 150 peak dpa values. Transmission electron microscopy (TEM) and scanning TEM were used to characterize microstructural and composition changes before and after ion irradiation. Three interfacial phases were identified: FeZr 3 , (Fe,Cr) 2 Zr, and ZrC. The widest intermetallic layer, FeZr3, had large grains. The narrower phases, (Fe,Cr)2Zr and ZrC, contained small grains and were often mixed. The unexpected observation of the ZrC phase was attributed to the presence of very small impurity level concentrations of carbon in the powder material. No void swelling was observed in any of the phases, including the FeCrAl coating and Zircaloy-4 substrate. (Fe,Cr) 2 Zr, however, fully amorphized after irradiation, even at the lowest dpa.

36 MATERIALS SCIENCE↗

Field studies in support of Nimbus-E surface composition mapping radiometer

If the outputs of the two channels are spacially registered and combined to generate a third variable which reflects the differences between the two outputs, then this variable can then be redisplayed in image form and its magnitude should be relatable to the silica content of the rocks imaged. Two methods were proposed for generating this third variable, the first is to take the difference in apparent temperature between the two channels and the second is to ratio the voltage outputs of the two channels. The responses of the two channel high resolution surface composition mapping radiometer and the thermal channels of the MSDS scanner were calculated from data recorded with the NASA IR pallet and simulate the output of these systems had they been flying over the same targets as the IR pallet.

Lyon, R. J. P.↗

Fractures on Europa - Possible response of an ice crust to tidal deformation

The surface of Europa contains a planetwide system of low albedo lineaments which have been interpreted as fractures in an icy crust. The pattern of fractures on the surface consists of radial and concentric fractures having the general appearance of tension cracks within a region near the antipode of the sub-Jupiter point. Outside this region, linear fractures intersect at angles near 60 deg, suggesting that they are conjugate shear fractures. The orientation of this pattern on the surface suggests that a principal axis of the deformation that produced the fractures was approximately radial to Jupiter. Fracturing may thus be consistent with an origin due to cyclical tidal deformation resulting from orbital eccentricity. Orbital eccentricity related to a relatively recent establishment of orbital resonance among the Galilean satellites may explain the presence of fractures in a relatively young, lightly cratered planetary surface.

Helfenstein, P.↗

Methodology for Time-Domain Estimation of Storm Time Geoelectric Fields Using the 3-D Magnetotelluric Response Tensors

Geoelectric fields at the Earth's surface caused by magnetic storms constitute a hazard to the operation of electric power grids and related infrastructure. The ability to estimate these geoelectric fields in close to real time and provide local predictions would better equip the industry to mitigate negative impacts on their operations. Here we report progress toward this goal: development of robust algorithms that convolve a magnetic storm time series with a frequency domain impedance for a realistic three-dimensional (3-D) Earth, to estimate the local, storm time geoelectric field. Both frequency domain and time domain approaches are presented and validated against storm time geoelectric field data measured in Japan. The methods are then compared in the context of a real-time application.

Kelbert, Anna↗

Sub-Picometer Dynamic Measurements of a Diffuse Surface

Future space observatory missions are forecasting the need for sensing and controlling wave front error and system alignment stability to picometer scale. Picometer stability performance demands precision knowledge of the mirror and metering structure materials to the same degree. A high-speed electronic speckle pattern interferometer was designed and built to demonstrate measurements of both static and dynamic responses of picometer amplitudes in materials of diffuse surface subjected to very low energy disturbances. This paper describes the details of a test to impart a dynamic disturbance of picometer scale and measure the response of a composite material.The results of the test are also reported and show conclusively that sub-picometer scale effects can be accurately measured in an open test environment outside a vacuum chamber.

Saif, Babak↗

Low Latency DESDynI Data Products for Disaster Response, Resource Management and Other Applications

We are developing onboard processor technology targeted at the L-band SAR instrument onboard the planned DESDynI mission to enable formation of SAR images onboard opening possibilities for near-real-time data products to augment full data streams. Several image processing and/or interpretation techniques are being explored as possible direct-broadcast products for use by agencies in need of low-latency data, responsible for disaster mitigation and assessment, resource management, agricultural development, shipping, etc. Data collected through UAVSAR (L-band) serves as surrogate to the future DESDynI instrument. We have explored surface water extent as a tool for flooding response, and disturbance images on polarimetric backscatter of repeat pass imagery potentially useful for structural collapse (earthquake), mud/land/debris-slides etc. We have also explored building vegetation and snow/ice classifiers, via support vector machines utilizing quad-pol backscatter, cross-pol phase, and a number of derivatives (radar vegetation index, dielectric estimates, etc.). We share our qualitative and quantitative results thus far.

applications↗

Evaluation of liquid cloud albedo susceptibility in E3SM using coupled eastern North Atlantic surface and satellite retrievals

The impact of aerosol number concentration on cloud albedo is a persistent source of spread in global climate predictions due to multi-scale, interactive atmospheric processes that remain difficult to quantify. We use 5 years of geostationary satellite and surface retrievals at the US Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) eastern North Atlantic (ENA) site in the Azores to evaluate the representation of liquid cloud albedo susceptibility for overcast cloud scenes in the DOE Energy Exascale Earth System Model version 1 (E3SMv1) and provide possible reasons for model–observation discrepancies. The overall distribution of surface 0.2 % CCN concentration values is reasonably simulated, but simulated liquid water path (LWP) is lower than observed and layer mean droplet concentration (N d ) comparisons are highly variable depending on the N d retrieval technique. E3SMv1's cloud albedo is greater than observed for given LWP and N d values due to a lower cloud effective radius than observed. However, the simulated albedo response to N d is suppressed due to a correlation between the solar zenith angle (SZA) and N d created by the seasonal cycle that is not observed. Controlling for this effect by examining the cloud optical depth (COD) shows that E3SMv1's COD response to CCN concentration is greater than observed. For surface-based retrievals, this is only true after controlling for cloud adiabaticity because E3SMv1's adiabaticities are much lower than observed. Assuming a constant adiabaticity in surface retrievals as done in top-of-atmosphere (TOA) retrievals narrows the retrieved ln N d distribution, which increases the cloud albedo sensitivity to ln N d to match the TOA sensitivity. The greater sensitivity of COD to CCN is caused by a greater Twomey effect in which the sensitivity of N d to CCN is greater than observed for TOA-retrieved N d , and once model–observation cloud adiabaticity differences are removed, this is also true for surface-retrieved N d . The LWP response to N d in E3SMv1 is overall negative as observed. Despite reproducing the observed LWP–N d relationship, observed clouds become much more adiabatic as N d increases, while E3SMv1 clouds do not, associated with more heavily precipitating clouds that are partially but not completely caused by deeper clouds and weaker inversions in E3SMv1. These cloud property differences indicate that the negative LWP–N d relationship is likely not caused by the same mechanisms in E3SMv1 and observations. The negative simulated LWP response also fails to mute the excessively strong Twomey effect, highlighting potentially important confounding factor effects that likely render the LWP–N d relationship non-causal. N d retrieval scales and assumptions, particularly related to cloud adiabaticity, contribute to substantial spreads in the model–observation comparisons, though enough consistency exists to suggest that aerosol activation, drizzle, and entrainment processes are critical areas to focus E3SMv1 development for improving the fidelity of aerosol–cloud interactions in E3SM.

54 ENVIRONMENTAL SCIENCES↗

A Modular Approach to Model Oscillating Control Surfaces Using Navier Stokes Equations

The use of active controls for rotorcraft is becoming more important for modern aerospace configurations. Efforts to reduce the vibrations of helicopter blades with use of active-controls are in progress. Modeling oscillating control surfaces using the linear aerodynamics theory is well established. However, higher-fidelity methods are needed to account for nonlinear effects, such as those that occur in transonic flow. The aeroelastic responses of a wing with an oscillating control surface, computed using the transonic small perturbation (TSP) theory, have been shown to cause important transonic flow effects such as a reversal of control surface effectiveness that occurs as the shock wave crosses the hinge line. In order to account for flow complexities such as blade-vortex interactions of rotor blades higher-fidelity methods based on the Navier-Stokes equations are used. Reference 6 presents a procedure that uses the Navier-Stokes equations with moving-sheared grids and demonstrates up to 8 degrees of control-surface amplitude, using a single grid. Later, this procedure was extended to accommodate larger amplitudes, based on sliding grid zones. The sheared grid method implemented in EulerlNavier-Stokes-based aeroelastic code ENS AERO was successfully applied to active control design by industry. Recently there are several papers that present results for oscillating control surface using Reynolds Averaged Navier-Stokes (RANS) equations. References 9 and 10 report 2-D cases by filling gaps with overset grids. Reference 9 compares integrated forces with the experiment at low oscillating frequencies whereas Ref. 10 reports parametric studies but with no validation. Reference II reports results for a 3D case by modeling the gap region with a deformed grid and compares force results with the experiment only at the mid-span of flap. In Ref. II grid is deformed to match the control surface deflections at the section where the measurements are made. However, there is no indication in Ref. II that the gaps are explicitly modeled as in Ref. 6. Computations using overset grids are reported in Ref. 12 for a case by adding moving control surface to an existing blade but with no validation either with an experiment or another computation.

Navier↗

Lidar Observations Revealing Transport of O3 in the Presence of a Nocturnal Low-Level Jet: Regional Implications for "Next-Day" Pollution

Remotely sensed profiles of ozone (O3) and wind are presented continuously for the first time during anocturnal low-level jet (NLLJ) event occurring after a severe O3 episode in the Baltimore-Washington D.C.(BW) urban corridor throughout 11-12 June 2015. High-resolution O3 lidar observations indicate a well mixedand polluted daytime O3 reservoir, which decayed into a contaminated nocturnal residual layer(RL) with concentrations between 70 and 100 ppbv near 1 km above the surface. Observations indicatethe onset of the NLLJ was responsible for transporting polluted O3 away from the region, while simultaneouslyaffecting the height and location of the nocturnal residual layer. High-resolution modelinganalyses and next-day (12 June) lidar, surface, and balloon-borne observations indicate the trajectory ofthe NLLJ and polluted residual layer corresponds with ''next-day'' high O3 at sites throughout thesouthern New England region (New York, Connecticut, Massachusetts). The novel O3 lidar observationsare evidence of both nocturnal advection (via high NLLJ wind fields) and entrainment of the pollutedresidual layer in the presence of the ''next-day'' convectively growing boundary layer. In the greatercontext, the novel observational suite described in this work has shown that the chemical budget in areasdownwind of major urban centers can be altered significantly overnight during transport events such asthe NLLJ.

ozone↗

Multivariate environmental and trait-based controls of transpiration in the Central Amazon Rainforest

Tropical forest tree mortality is increasing due to more severe droughts, yet our understanding of how tree traits and life strategies are linked to drought stress has been limited by measurement scarcity. The BIONTE (BIOmass and NuTrient Experiment) near Manaus, Brazil hosts one of the world’s largest sap flow installations, with sensors in 90 canopy trees across a wood density gradient monitored since June 2022. The 2023 El Niño drought provided a unique opportunity to evaluate how water availability impacts tree transpiration. An interpretable machine learning framework was used to study the complex interactions between transpiration and multiple environmental variables such as soil water availability and vapor pressure deficit (VPD), and how these interactions vary with wood density and individual trees. We found varying responses of transpiration from different trees during the El Niño drought. Transpiration generally increased with temperature, with stronger effects in wetter areas and in trees with low to medium wood density. However, this response was modulated by stomatal sensitivity to VPD, which constrained transpiration under high atmospheric demand, particularly in intermediate-moisture area. The inflection in transpiration rate at high temperatures (>32°C) underscores the role of stomatal and hydraulic regulation in limiting water loss and protecting trees from excessive evaporative demand. Analysis of soil water contribution to transpiration revealed unimodal patterns in wetter area, with peak contributions near 0.45 cm 3 cm -3 of surface soil water and declining or flat responses beyond that threshold, suggesting a shift from water- to energy-limited transpiration. In contrast, drier areas exhibited limited transpiration sensitivity to soil water conditions and minimal trait-based variation in VPD responses, indicating supply-limited conditions. Despite higher wood density trees being generally more resilient, this study shows diverse tree drought resilience, prompting further investigation into the specific traits and dynamics between environmental variables in regulating transpiration and other physiological processes in trees.

Drought↗

Peroxide-modified titanium dioxide: a chemical analog of putative Martian soil oxidants

Hydrogen peroxide chemisorbed on titanium dioxide (peroxide-modified titanium dioxide) is investigated as a chemical analog to the putative soil oxidants responsible for the chemical reactivity seen in the Viking biology experiments. When peroxide-modified titanium dioxide (anatase) was exposed to a solution similar to the Viking labeled release (LR) experiment organic medium, CO2 gas was released into the sample cell headspace. Storage of these samples at 10 degrees C for 48 hr prior to exposure to organics resulted in a positive response while storage for 7 days did not. In the Viking LR experiment, storage of the Martian surface samples for 2 sols (approximately 49 hr) resulted in a positive response while storage for 141 sols essentially eliminated the initial rapid release of CO2. Heating the peroxide-modified titanium dioxide to 50 degrees C prior to exposure to organics resulted in a negative response. This is similar to, but not identical to, the Viking samples where heating to approximately 46 degrees C diminished the response by 54-80% and heating to 51.5 apparently eliminated the response. When exposed to water vapor, the peroxide-modified titanium dioxide samples release O2 in a manner similar to the release seen in the Viking gas exchange experiment (GEx). Reactivity is retained upon heating at 50 degrees C for three hours, distinguishing this active agent from the one responsible for the release of CO2 from aqueous organics. The release of CO2 by the peroxide-modified titanium dioxide is attributed to the decomposition of organics by outer-sphere peroxide complexes associated with surface hydroxyl groups, while the release of O2 upon humidification is attributed to more stable inner-sphere peroxide complexes associated with Ti4+ cations. Heating the peroxide-modified titanium dioxide to 145 degrees C inhibited the release of O2, while in the Viking experiments heating to this temperature diminished but did not eliminated the response. Although the thermal stability of the titanium-peroxide complexes in this work is lower than the stability seen in the Viking experiments, it is expected that similar types of complexes will form in titanium containing minerals other than anatase and the stability of these complexes will vary with surface hydroxylation and mineralogy.

Review↗

Process drivers, inter-model spread, and a path forward: What do we know about Arctic Amplification?

Over the recent decades, rapid changes have been observed in the Arctic resulting from enhanced surface warming in the Arctic relative to the rest of the globe, a phenomenon called Arctic Amplification. While surface-based amplification of Arctic warming in response to increased CO2 has been established. The driving mechanisms, relevant processes, and the relative roles of local and remote mechanisms to Arctic Amplification remain unclear. Research over the last decade has made it clear that coupling between the atmosphere, sea ice, and ocean play a key role in Arctic Amplification. This presentation summarizes recent research on the fundamental role that atmosphere-sea ice-ocean interactions and energy exchanges play in driving Arctic Amplification, how these interactions manifest as radiative climate feedbacks, and how these processes influence the differences in the projected Arctic climate change across CMIP5 and 6. We hypothesize that models that simulate larger warming do so by generating a larger local atmospheric circulation response that more effectively redistributes energy drawn from the ocean in sea ice retreat regions Arctic-wide and contributing to a larger increase in downwelling long wave radiation. This process is also fundamentally tied to the Arctic lapse rate feedback.

Arctic amplification↗

Probing Heterogeneous Charge Distributions at the α-Al 2 O 3 (0001)/H 2 O Interface

Unlike metal or semiconductor electrodes, the surface charge resulting from the protonation or deprotonation of insulating mineral oxides is highly localized and heterogeneous in nature. In this work the Stark active C≡N stretch of potassium thiocyanate is used as a molecular probe of the heterogeneity of the interfacial electrostatic potential at the α-Al 2 O 3 (0001)/H 2 O interface. Vibrational sum frequency generation (vSFG) measurements performed in the OH stretching region suggest that thiocyanate species organize interfacial water similarly to halide ions. Changes in the electrostatic potential are then tracked via Stark shifts of the vibrational frequency of the thiocyanate stretch. Our vSFG measurements show that we can simultaneously measure the vSFG response of SCN – ions experiencing charged and neutral surface sites. We assign local potentials of +308 and -154 mV to positively and negatively charged aluminol groups that are present at pH = 4 and pH = 10, respectively. Thiocyanate anions at positively charged surface sites and negatively charged surface sites and those participating in contact ion pairing adopt similar orientations and are oppositely oriented relative to thiocyanate ions near neutral surface sites. All four species followed Langmuir adsorption isotherms. Density functional theory–molecular dynamics (DFT-MD) simulations of SCN – near the neutral α-Al 2 O 3 (0001)/H 2 O interface show that the vSFG response in the C≡N stretch region originates from a SCN–H–O–Al complex, suggesting the surface site specificity of these experiments. To our knowledge this is the first spectroscopic measurement of local potentials associated with a heterogeneously charged surface. The ability to probe the evolution of local charges in situ could provide vital insight into many industrial, electrochemical, and geochemically relevant interfaces.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Feasibility study of a synthesis procedure for array feeds to improve radiation performance of large distorted reflector antennas

Surface errors on parabolic reflector antennas degrade the overall performance of the antenna. The errors are in the form of roughness on the surface, distortions in the shape, or structural design details. They cause amplitude and phase errors in the aperture field which lower the gain, raise the sidelobes, and fill in the nulls. These are major problems in large space reflector antennas. Planned mobile satellite communications systems having limited signal margin need high gain from the space reflectors. Future multiple beam antenna systems requiring spatial isolation to allow frequency reuse could be rendered useless if high sidelobes are present. High sidelobes are also responsible for noise. Ways of compensating for surface errors by pattern synthesis using an array of feed antennas are examined. Pattern corrections are directed specifically toward portions of the pattern requiring improvements. The pattern synthesis does not require knowledge of the surface errors. Both the amplitude and phase of the high side lobes caused by the distortion are required.

Stutzman, W. L.↗

Shock Response of Polymethyl Methacrylate (PMMA) Under Explosive Loading

Abstract The dynamic response of polymethyl methacrylate (PMMA) is well understood for one-dimensional planar impact shocks, but limited research has been performed on the response of PMMA under spherical shock loading. In this work, the shock decay of an explosively-driven shock wave into PMMA was experimentally measured. PMMA cubes of various geometries were explosively loaded with an RP-80 detonator to produce the explosive shock wave. High-speed schlieren imaging was implemented to measure the explosively-driven shock wave velocity throughout the PMMA cubes. Photon Doppler velocimetry (PDV) was used to measure the particle velocity imparted by the shock wave at the surface of the cubes. The material shock response was studied at distances from 21.91 to 133.3 mm from the explosive source. The particle velocity history measured by PDV was compared to the wave profile visualized in the high-speed images. The shock wave pulse amplitude decreased with increased distance from the source. The conducted experiments extend the PMMA shock Hugoniot relating to the lower shock and particle velocity regime.

Torres, S. M. (ORCID:0009000287177206)↗

The atmospheric load response of the ocean determined using Geosat altimeter data

Sea-surface heights derived from the Geosat altimeter data for the November 1986 - November 1987 period are compared with the Fleet Numerical Oceanographic Center and the NMC sea-level atmospheric pressure fields, to verify the open ocean inverted barometer (IB) response. It is shown that fits along the satellite track consistently yield results that are only 60-70 percent of the IB results. Fits at fixed geographic locations show a clear dependence of the absolute value of the regression coefficient with latitude: a steady decrease from 70 deg to about 20 deg, and then a sudden increase again nearer to the equator, with similar results obtained for the Northern and the Southern Hemispheres. The sign of the departure from IB is found to be consistent with the expected effects of errors in the pressure fields and with wind-induced changes in sea level that are correlated with pressure fluctuations.

Vandam, Tonie M.↗

A modular methodology for time-domain stochastic seismic wave propagation

Presented here is a modular methodology for time-domain stochastic seismic wave propagation analysis. Presented methodology is designed to analyse uncertain seismic motions as an input, propagating through uncertain material. Traditional approach for uncertain wave propagation relies on models that include deep bedrock, local soil site, and their random process and random field information. Such models can become quite large and computationally intractable. The modular approach proposed herein features two step approach that allows separate consideration of the deep bedrock and local site along with corresponding random field information. In this work, the first step considers an auxiliary stochastic motions problem in the bedrock. Stochastic local site response can then be simulated in a reduced domain within certain depth from the surface. Application of uncertain seismic motions at depth, for local uncertain site response is done using stochastic effective forces developed through the Domain Reduction Method. By using Hermite polynomial chaos expansion to represent the non-Gaussian random field of material parameters and non-stationary random process of seismic motion, the proposed modular methodology is formulated using intrusive stochastic Galerkin approach, as seen in the Stochastic Elastic–Plastic Finite Element Method (SEPFEM). Developed modular methodology is illustrated using a 1-D stochastic seismic wave propagation analysis with three cases, and simulation results are also verified with results from conventional approach.

58 GEOSCIENCES↗

Impulse response measurements of fast scintillator-based current mode detectors

In this study, experimental measurements were performed to characterize the impulse response of seven different gamma ray detector prototypes being considered to be fielded as a current mode diagnostic for neutron-diagnosed subcritical experiments at the Nevada National Security Site (NNSS). For such experiments, the impulse response of the fielded detector is required to have a full-width half-maximum (FWHM) of approximately 5 ns or less and a low amplitude tail. Each of the detector prototypes evaluated in this work were selected based on the potential to meet this performance requirement. An impulse of bremsstrahlung x-rays created from 2 MeV electrons from the NNSS’s Transformational Diagnostics and Imaging, Los Alamos, linear accelerator was measured with each detector. The measured impulse response was evaluated for each detector configuration. A comparison of these impulse responses revealed a relationship between fast timing performance and scintillator material, geometry, surface reflectivity conditions, and photomultiplier tube (PMT) selection. The detector configuration yielding an impulse response with the shortest FWHM of 3.82 ± 0.11 ns and possessing a low amplitude tail was a 5-inch (12.7-cm) diameter, 5-inch (12.7-cm) height cylindrical EJ-399-17-VI liquid scintillator in a black-painted housing coupled to an Adit D798B 5-inch (12.7-cm) PMT by means of a 0.079-inch (0.2-cm) EJ-560 optical coupling pad.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗