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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,513 records · Page 84

Demographic data of Sedum lanceolatum from 2013 to 2014 under a climate manipulation experiment

Demographic data of Sedum lanceolatum under a climate manipulation experiment (heating and watering). Dataset includes one .csv with demographic data for 232 individuals monitored over 2013-2014 which was used, in part, to draw conclusions in "Elevation effects on vital rate sensitivities generate variation in neighbor effects on population growth rate in Sedum lanceolatum" by Herzog et al. (in review). All data was collected under a watering and warming experiment as part of the Alpine Treeline Warming Experiment at Niwot Ridge, Colorado, USA. There are two main data file formats in this archive: comma-separated values (.csv) which can be read using any simple text editor program, such as TextEdit (Mac) and Notepad (Windows). The .pdf data user’s guide can be read using Adobe Acrobat Reader, or any other compatible software.

54 ENVIRONMENTAL SCIENCES↗

Soil carbon, nitrogen, and ice content data (2014-2018) at Happy Valley and Sagwon Hills in Northern Alaska, United States

This dataset contains three data files from soil data collected by sampling soil cores and pits across a toposequence on two hillslopes in permafrost affected soils in Northern Alaska, USA. Soil cores and profiles were excavated to 3m or until auger refusal. Samples were collected by genetic soil horizons for laboratory analysis and organized into complete soil profiles ordered depth. Soil carbon, nitrogen, and ice stocks (stocks_by_core.csv) were calculated from the core dataset . Data for mean values by depth increments (20,50,100,150,200 cm) of total soc, total nitrogen, bulk density, and ice content were determined and made available in this dataset (soc-tn-bd-ice-slab_tables.csv). Stocks by site are included in a separate file (stocks_by_site.csv). Each of these three files also has an associated data dictionary file (stocks_by_core_dd.csv, soc-tn-bd-ice-slab_tables_dd.csv, stocks_by_site_dd.csv). Finally, an FLMD file is also included (FLMD_Happy_Valley_Sagwon.csv).

54 ENVIRONMENTAL SCIENCES↗

COMPASS-FME Terrestrial Ecosystem Manipulation to Probe the Effects of Storm Treatments (TEMPEST) Soil Greenhouse Gas Fluxes 04/2020-06/2024

Both raw and processed data measured using a LI-COR 7810 Greenhouse Gas Analyzer in the TEMPEST experiment, part of COMPASS-FME (https://compass.pnnl.gov/FME/COMPASSFME), at Smithsonian Environmental Research Center. This ecosystem-scale experiment probes the effects of saltwater versus freshwater flooding in a coastal deciduous forest.The data consist of both concentrations and fluxes of carbon dioxide and methane measured using static chambers on the soil surface, approximately every two weeks from early 2020 to mid 2024. Some of the measurement points are controls, and some subject to root-exclusion techniques; all measurements are embedded in the TEMPEST control, freshwater, and saltwater plots (see Hopple et al. 2023). These data were generated to understand changing soil greenhouse gas (CO2 and CH4) production and consumption. File types are comma-separated value (.csv) for data, and markdown (.md) for supplementary information.

54 ENVIRONMENTAL SCIENCES↗

Lignin-Derived Chemicals from Pulping Liquors: Cooperative Research and Development CRADA Number CRD-17-00714 (Final Report)

National Renewable Energy Laboratory (NREL) has developed a robust portfolio for lignin valorization using a “biological funneling” approach, which adopts a microbial process to convert the inherent heterogeneity of lignin-rich streams into single high-value products. In parallel, Sustainable Fiber Technologies (SFT) has developed a proprietary, high-pH process to convert non-woody biomass into valuable pulp for myriad biomaterial applications. Therefore, by combining the expertise of both SFT and NREL, this project aimed to valorize co-products from an industrial pulping process of non-woody feedstocks. A detailed analytical characterization of an SFT pulping stream was used to aid the development of a bench-scale separations strategy to isolate a mixture of low molecular weight compounds, and ultimately to aid in bioreactor cultivations used to produce polyhydroxyalkanoate (PHA) biopolymers at titers, rates, and yields necessary for moving towards commercialization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advancements in modeling fuel pulverization and cladding behavior during a LOCA

During a loss-of-coolant accident (LOCA), it is possible for nuclear fuel rods to undergo a three-step process known as fuel fragmentation, relocation, and dispersal (FFRD). The chance of FFRD occurring increases as the fuel burnup increases. To support the nuclear industry's desire to increase the discharge burnup of nuclear fuels in light-water reactors (LWRs), it is imperative to understand the mechanisms driving the evolution of FFRD. In this work, a multiscale modeling approach is used to garner insight into underlying mechanisms leading to the fine fragmentation (also known as pulverization) of nuclear fuel during a LOCA. This report includes a summary of the atomistic and phase-field studies to develop a new pulverization criterion for use in the engineering-scale Bison fuel performance code. Details are also provided on cladding model improvements related to hydrogen/hydride embrittlement and damage and anisotropic thermal creep. The new models are used on the existing integral and separate effects LOCA validation cases available in Bison.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

ROADRUNNER MiniFuel Experiment: Irradiation Target Design and Sample Characterization

High-density uranium nitride (UN) is a fuel candidate for several advanced nuclear reactor designs currently under development. Because there are limited UN performance data relative to fuel fabrication impurity and density variation, an irradiation campaign has been developed as part of a collaborative effort among the University of Texas at San Antonio (UTSA), Westinghouse Electric Company, Oak Ridge National Laboratory (ORNL), and Los Alamos National Laboratory (LANL) under the Nuclear Science User Facilities program. This project, entitled ROADRUNNER, or Research On ADvancing the peRformance of UraNium Nitrides in Extreme enviRonments, aimsto support UN fuel qualification for advanced reactors by investigating the impact of density and impurity variations on UN performance as a function of irradiation temperature and burnup. The MiniFuel experiment vehicle developed by ORNL, which leverages the High Flux Isotope Reactor, was selected to perform this accelerated separate-effects irradiation testing. The experiment test matrix consists of six MiniFuel targets containing miniature UN fuel disks, and targets three distinct burnup levels (37.5, 60, and 75 MWd/kg U) and three distinct temperatures (600, 900, and 1200°C). Neutronics and thermal analyses were performed to determine the experimental parameters needed to meet the desired irradiation conditions and to predict the experiment components temperatures. UN pellets were fabricated at LANL with tightly controlled parameters to produce specimens with three distinct densities and three levels of carbon content. The pellets were then thinned down by UTSA to the experiment-required thickness. The pre-characterization of the specimens includes density measurements, carbon and oxygen contents, microstructure analysis, and x-ray computed tomography. The selected specimens will be assembled into the MiniFuel experiment, and the first ROADRUNNER MiniFuel targets are intended for HFIR insertion during the Fall of 2024. After irradiation, the targets will be shipped to ORNL’s hot cell facility for disassembly. The post-irradiation examination on the fuel specimens includes fission gas release measurements, visual inspection, fuel swelling measurements, gamma spectroscopy, and microstructure analysis. The data collected post-irradiation will be used to develop fuel performance models.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Local Air Quality Impacts of a Peak-Shaving Diesel Generator Unit in Waynesville, North Carolina

The Waynesville Electric Department in Waynesville, North Carolina, operates a 2,000-kW diesel generator with a 4% capacity factor, emitting less than 1 ton annually of PM2.5, VOCs, carbon monoxide (CO), and sulfur dioxide (SO2), and approximately 1.8 tons of NO. The National Laboratory of the Rockies (NLR) conducted high-resolution, near-source air-quality modeling to evaluate the generator's impacts. Results indicate minimal effects on ambient pollutant concentrations: annual PM2.5 increases are below 0.0004 microgrm/m3 for local census tracts, while CO and SO2 levels increase by less than 0.00004 ppm and 0.0002 ppb, respectively. Estimated annual premature mortality attributable to PM2.5 exposure is less than 0.001 cases across Haywood County, with an associated economic impact of approximately $12,000. This report complements a separate technoeconomic analysis to inform Waynesville's investment strategies for demand reduction.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

NBS (National Bureau of Standards): Materials measurements

NBS work for NASA in support of NASA's Microgravity Science and Applications Program under NASA Government Order H-27954B (Properties of Electronic Materials) covering the period April 1, 1984 to March 31, 1985 is described. The work has been carried out in three independent tasks: Task 1--Surface Tensions and Their Variations with Temperature and Impurities; Task 2--Convention during Unidirectional Solidification; Task 3--Measurement of High Temperature Thermodynamic Properties. The results for each task are given separately in the body of the report.

Manning, J. R.↗

USML-1 Glovebox experiments

This report covers the development of and results from three experiments that were flown in the Materials Science Glovebox on USML-1: Marangoni convection in Closed Containers (MCCC), Double Float Zone (DFZ), and Fiber Pulling in Microgravity (FPM). The Glovebox provided a convenient, low cost method for doing simple 'try and see' experiments that could test new concepts or elucidate microgravity phenomena. Since the Glovebox provided essentially one (or possibly two levels of confinement, many of the stringent verification and test requirements on the experiment apparatus could be relaxed and a streamlined test and verification plan for flight qualification could be implemented. Furthermore, the experiments were contained in their own carrying cases whose external configurations could be identified early in the integration sequence for stowage considerations while delivery of the actual experiment apparatus could be postponed until only a few months before flight. This minimized the time fluids must be contained and reduced the possibility of corrosive reactions that could ruin the experiment. In many respects, this exercise was as much about developing a simpler, cheaper way of doing crew-assisted science as it was about the actual scientific accomplishments of the individual experiments. The Marangoni Convection in Closed Containers experiment was designed to study the effects of a void space in a simulated Bridgman crystal growth configuration and to determine if surface tension driven convective flows that may result from thermal gradients along any free surfaces could affect the solidification process. The Fiber Pulling in Microgravity experiment sought to separate the role of gravity drainage from capillarity effects in the break-up of slender cylindrical liquid columns. The Stability of a Double Float Zone experiment explored the feasibility of a quasi-containerless process in which a solidifying material is suspended by two liquid bridges of its own melt.

Naumann, Robert J.↗

A provisional regulatory gene network for specification of endomesoderm in the sea urchin embryo

We present the current form of a provisional DNA sequence-based regulatory gene network that explains in outline how endomesodermal specification in the sea urchin embryo is controlled. The model of the network is in a continuous process of revision and growth as new genes are added and new experimental results become available; see http://www.its.caltech.edu/~mirsky/endomeso.htm (End-mes Gene Network Update) for the latest version. The network contains over 40 genes at present, many newly uncovered in the course of this work, and most encoding DNA-binding transcriptional regulatory factors. The architecture of the network was approached initially by construction of a logic model that integrated the extensive experimental evidence now available on endomesoderm specification. The internal linkages between genes in the network have been determined functionally, by measurement of the effects of regulatory perturbations on the expression of all relevant genes in the network. Five kinds of perturbation have been applied: (1) use of morpholino antisense oligonucleotides targeted to many of the key regulatory genes in the network; (2) transformation of other regulatory factors into dominant repressors by construction of Engrailed repressor domain fusions; (3) ectopic expression of given regulatory factors, from genetic expression constructs and from injected mRNAs; (4) blockade of the beta-catenin/Tcf pathway by introduction of mRNA encoding the intracellular domain of cadherin; and (5) blockade of the Notch signaling pathway by introduction of mRNA encoding the extracellular domain of the Notch receptor. The network model predicts the cis-regulatory inputs that link each gene into the network. Therefore, its architecture is testable by cis-regulatory analysis. Strongylocentrotus purpuratus and Lytechinus variegatus genomic BAC recombinants that include a large number of the genes in the network have been sequenced and annotated. Tests of the cis-regulatory predictions of the model are greatly facilitated by interspecific computational sequence comparison, which affords a rapid identification of likely cis-regulatory elements in advance of experimental analysis. The network specifies genomically encoded regulatory processes between early cleavage and gastrula stages. These control the specification of the micromere lineage and of the initial veg(2) endomesodermal domain; the blastula-stage separation of the central veg(2) mesodermal domain (i.e., the secondary mesenchyme progenitor field) from the peripheral veg(2) endodermal domain; the stabilization of specification state within these domains; and activation of some downstream differentiation genes. Each of the temporal-spatial phases of specification is represented in a subelement of the network model, that treats regulatory events within the relevant embryonic nuclei at particular stages. (c) 2002 Elsevier Science (USA).

Non-NASA Center↗

An Update on the FIRE (Solar Probe) Mission

A joint U.S.-Russian mission to the sun named FIRE is currently being planned. The mission consists of two spacecraft, one U.S. built and the other Russian built. Both spacecraft will be launched from a single vehicle, separate after launch, travel to Jupiter for a gravity assist that will maneuver the spacecraft into highly elliptical polar orbits about the sun. The U.S. spacecraft will have a perihelion of 4 Rs and the Russian 10 Rs. A full complement of in situ fields and particles instruments are planned for both spacecraft to measure acceleration mechanisms and other characteristics of the solar wind. The strawman payloads and expected science return will be discussed.

FIRE Mission↗

Summary Report of Mission Acceleration Measurements for STS-89

Support of microgravity research on the 89th flight of the Space Transportation System (STS-89) and a continued effort to characterize the acceleration environment of the Space Shuttle Orbiter and the Mir Space Station form the basis for this report. For the STS-89 mission, the Space Shuttle Endeavour was equipped with a Space Acceleration Measurement System (SAMS) unit, which collected more than a week's worth of data. During docked operations with Mir, a second SAMS unit collected approximately a day's worth of data yielding the only set of acceleration measurements recorded simultaneously on the two spacecraft. Based on the data acquired by these SAMS units, this report serves to characterize a number of acceleration events and quantify their impact on the local nature of the accelerations experienced at the Mechanics of Granular Materials (MGM) experiment location. Crew activity was shown to nearly double the median root-mean-square (RMS) acceleration level calculated below 10 Hz, while the Enhanced Orbiter Refrigerator/Freezer operating at about 22 Hz was a strong acceleration source in the vicinity of the MGM location. The MGM science requirement that the acceleration not exceed plus or minus 1 mg was violated numerous times during their experiment runs; however, no correlation with sample instability has been found to this point. Synchronization between the SAMS data from Endeavour and from Mir was shown to be close much of the time, but caution with respect to exact timing should be exercised when comparing these data. When orbiting as a separate vehicle prior to docking, Endeavour had prominent structural modes above 3 Hz, while Mir exhibited a cluster of modes around 1 Hz. When mated, a transition to common modes was apparent in the two SAMS data sets. This report is not a comprehensive analysis of the acceleration data, so those interested in further details should contact the Principal Investigator Microgravity Services team at the National Aeronautics and Space Administration's John H. Glenn Research Center.

Hrovat, Kenneth↗

On-Orbit Radiometric Characterization of OLI (Landsat 8) for Applications in Aquatic Remote Sensing

Landsat-8 carries two separate sensors, namely the Operational Land Imager (OLI) and the Thermal Infrared Radiometer Suite (TIRS), that image the earth surface throughout the visible and thermal portions of the spectrum. Compared to Landsat heritage sensors, the OLI has enhanced features, which include its 12-bit radiometric resolution and the addition of a band centered at 443 nm. The dramatically improved data quality/quantity expands existing applications of Landsat imagery in aquatic sciences from the retrieval of bio-geochemical properties, such as near-surface concentrations of chlorophyll-a (CHL) and total suspended solids (TSS), to benthic mapping. This study offers analysis of OLI's absolute radiometric performance over bodies ofwater using benchmark observations, namely the top-of-atmosphere (TOA) ocean color observations and marine in situ radiometric measurements. Sensor-to-sensor comparisons are performed to derive gain factors (g1) from near-concurrent observations in TOA radiance and reflectance domains. The gains in the radiance domain were further validated/adjusted by determining a second set of gains (g2) via analysis of OLI-derived water-leaving radiance, i.e., L(sub w) (gamma), against in situ measurements made either at the Ocean Color AErosol RObotic NETwork (AERONETOC) sites or during field campaigns. The analyses yield the OLI calibration uncertainties that need to be accounted forwhen studying aquatic environments. Itwas found that, for the visible and near-infrared channels, the OLI radiometric responses, on average, are well in agreement (b 2 % discrepancies) with the TOA radiances estimated by ocean color satellites or those predicted by models based onmeasurements of aquatic and atmospheric properties. However, the TOA radiance at the new 443-nm band is found to be, on average, 3.4 % larger than the reference observations. The inter-sensor comparisons in the reflectance domain, however, indicated slightly different results with the OLI responses being low in the blue bands. To enhance the retrieval accuracy of aquatic-science products from OLI datasets, sets of temporally averaged gains (radiance and reflectance) are derived and recommended for use prior to the retrieval of in-water products.

Remote Sensing↗

Precision Pointing for the Wide-Field Infrared Survey Telescope (WFIRST)

The Wide-Field Infrared Survey Telescope (WFIRST) mission, scheduled for a mid-2020's launch, is currently in its definition phase. The mission is designed to investigate essential questions in the areas of dark energy, exoplanets, and infrared astrophysics. WFIRST will use a 2.4-meter primary telescope (same size as the Hubble Space Telescope's primary mirror) and two instruments: the Wide Field Instrument (WFI) and the Coronagraph Instrument (CGI). In order to ad-dress the critical science requirements, the WFIRST mission will conduct large-scale surveys of the infrared sky, requiring both agility and precision pointing (11.6 milli-arcsec stability, 14 milli-arcsec jitter). This paper describes some of the challenges this mission profile presents to the GNC subsystem, and some of the design elements chosen to accommodate those challenges. The high-galactic-latitude survey is characterized by 3-minute observations separated by slews ranging from 0.025 deg to 0.8 deg. The need for observation efficiency drives the slew and settle process to be as rapid as possible. A description of the shaped slew profile chosen to minimize excitation of structural oscillation, and the handoff from star tracker-gyro control to fine guidance sensor control is detailed. Also presented is the fine guidance sensor (FGS), which is integral with the primary instrument (WFI). The FGS is capable of tracking up to 18 guide stars, enabling robust FGS acquisition and precision pointing. To avoid excitation of observatory structural jitter, reaction wheel speeds are operationally maintained within set limits. In addition, the wheel balance law is designed to maintain 1-Hz separation between the wheel speeds to avoid reinforcing jitter excitation at any particular frequency. The wheel balance law and operational implications are described. Finally, the candidate GNC hardware suite needed to meet the requirements of the mission is presented.

Stoneking, Eric↗

Solid-state organic intermediate-band photovoltaic devices

In one aspect, solid-state organic intermediate-band photovoltaic devices are provided. A solid-state organic intermediate-band photovoltaic device, in some embodiments, comprises an organic electron donor and an organic electron acceptor, wherein the organic electron donor comprises a singlet energy level separated from a triplet energy level by an energy gap. The device also comprises a triplet sensitizer comprising singlet and triplet energy levels falling within the singlet-triplet energy gap of the electron donor.

14 SOLAR ENERGY↗

An Evaluation of Actinide Reactivity with CO 2 , O 2 , and O 2 /He Gases using Inductively Coupled Plasma Tandem Mass Spectrometry: Application to Simultaneous Measurement of 241 Am/ 241 Pu Ratios in Unseparated Complex Matrices

Accurate actinide measurements are critical within the field of nuclear science. Traditional methods for actinide quantification require time-consuming sample processing prior to analysis. There is a need for rapid analytical techniques that still maintain a high degree of accuracy. In this work, actinide reactivity was assessed for multiple oxygen-containing reaction gases using quadrupole inductively coupled plasma tandem mass spectrometry (Q-ICP-MS/MS) to evaluate actinide analysis in complex sample matrices without analyte-matrix separation. A novel method was developed to measure 241 Am/ 241 Pu in complex sample matrices using O 2 /He reaction gas with no matrix removal or analyte pre-concentration. This inline method reduces matrix-derived polyatomic interferences that complicate traditional ICP-MS analyses by mass-shifting to 241 Am 16 O + and 241 Pu 16 O 2 + , allowing Am and Pu to be mass separated for simultaneous analysis. While mass shifting is efficient, a small portion of Am + (<1.3%) and Pu + (<1.4%) react to from AmO 2 + and PuO + , respectively. Therefore, a mass balance approach was used, in combination with reactivity determined from 242 Pu and 243 Am standard solutions, to correct for residual 241 PuO + and 241 AmO 2 + . The method was validated by measuring 241 Am/ 241 Pu in Pu isotope standards CRM-136 and CRM-137 (separated in March/April 1970 and February 2022, respectively) in both neat solutions and complex matrices containing diluted soil (NIST SRM 2711a, >1000 µg·g -1 ). Method detection limits of 15.9 and 9.6 fg·g -1 were determined for 241 Am and 241 Pu, respectively, and 241 Am/ 241 Pu ratios were measured with accuracies within <3.5%. In conclusion, this work presents the first direct analysis of 241 Am/ 241 Pu in unseparated complex matrices, advancing capabilities for rapid actinide measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Leveraging graph clustering techniques for cyber‐physical system analysis to enhance disturbance characterisation

Abstract Cyber‐physical systems have behaviour that crosses domain boundaries during events such as planned operational changes and malicious disturbances. Traditionally, the cyber and physical systems are monitored separately and use very different toolsets and analysis paradigms. The security and privacy of these cyber‐physical systems requires improved understanding of the combined cyber‐physical system behaviour and methods for holistic analysis. Therefore, the authors propose leveraging clustering techniques on cyber‐physical data from smart grid systems to analyse differences and similarities in behaviour during cyber‐, physical‐, and cyber‐physical disturbances. Since clustering methods are commonly used in data science to examine statistical similarities in order to sort large datasets, these algorithms can assist in identifying useful relationships in cyber‐physical systems. Through this analysis, deeper insights can be shared with decision‐makers on what cyber and physical components are strongly or weakly linked, what cyber‐physical pathways are most traversed, and the criticality of certain cyber‐physical nodes or edges. This paper presents several types of clustering methods for cyber‐physical graphs of smart grid systems and their application in assessing different types of disturbances for informing cyber‐physical situational awareness. The collection of these clustering techniques provide a foundational basis for cyber‐physical graph interdependency analysis.

97 MATHEMATICS AND COMPUTING↗

PigmentHunter: A point-and-click application for automated chlorophyll-protein simulations

Chlorophyll proteins (CPs) are the workhorses of biological photosynthesis, working together to absorb solar energy, transfer it to chemically active reaction centers, and control the charge-separation process that drives its storage as chemical energy. Yet predicting CP optical and electronic properties remains a serious challenge, driven by the computational difficulty of treating large, electronically coupled molecular pigments embedded in a dynamically structured protein environment. To address this challenge, we introduce here an analysis tool called PigmentHunter, which automates the process of preparing CP structures for molecular dynamics (MD), running short MD simulations on the nanoHUB.org science gateway, and then using electrostatic and steric analysis routines to predict optical absorption, fluorescence, and circular dichroism spectra within a Frenkel exciton model. Inter-pigment couplings are evaluated using point-dipole or transition-charge coupling models, while site energies can be estimated using both electrostatic and ring-deformation approaches. The package is built in a Jupyter Notebook environment, with a point-and-click interface that can be used either to manually prepare individual structures or to batch-process many structures at once. Here, we illustrate PigmentHunter’s capabilities with example simulations on spectral line shapes in the light harvesting 2 complex, site energies in the Fenna–Matthews–Olson protein, and ring deformation in photosystems I and II.

14 SOLAR ENERGY↗