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CrRh2Ga crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two CrRh2Ga ribbons oriented in the (1, 0, 0) direction. Cr is bonded in a linear geometry to two equivalent Rh atoms. Both Cr–Rh bond lengths are 2.07 Å. Rh is bonded in a linear geometry to one Cr and one Ga atom. The Rh–Ga bond length is 2.53 Å. Ga is bonded in a linear geometry to two equivalent Rh atoms.
MnRh2Cu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two MnRh2Cu ribbons oriented in the (1, 0, 0) direction. Mn is bonded in a linear geometry to two equivalent Rh atoms. Both Mn–Rh bond lengths are 2.05 Å. Rh is bonded in a linear geometry to one Mn and one Cu atom. The Rh–Cu bond length is 2.47 Å. Cu is bonded in a linear geometry to two equivalent Rh atoms.
EuPmRh2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Eu is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Eu–Rh bond lengths are 3.04 Å. Pm is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Pm–Rh bond lengths are 3.04 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Eu and four equivalent Pm atoms.
YbRh2Bi is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Yb is bonded in a body-centered cubic geometry to eight equivalent Rh and six equivalent Bi atoms. All Yb–Rh bond lengths are 2.89 Å. All Yb–Bi bond lengths are 3.34 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Yb and four equivalent Bi atoms. All Rh–Bi bond lengths are 2.89 Å. Bi is bonded in a distorted body-centered cubic geometry to six equivalent Yb and eight equivalent Rh atoms.
YRh2Pb is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Y is bonded in a distorted body-centered cubic geometry to eight equivalent Rh and six equivalent Pb atoms. All Y–Rh bond lengths are 2.93 Å. All Y–Pb bond lengths are 3.38 Å. Rh is bonded in a distorted body-centered cubic geometry to four equivalent Y and four equivalent Pb atoms. All Rh–Pb bond lengths are 2.93 Å. Pb is bonded in a 8-coordinate geometry to six equivalent Y and eight equivalent Rh atoms.
Nd2RhSi3 crystallizes in the hexagonal P-62c space group. The structure is three-dimensional. there are two inequivalent Nd sites. In the first Nd site, Nd is bonded to twelve equivalent Si atoms to form NdSi12 cuboctahedra that share edges with twelve equivalent NdSi8Rh4 cuboctahedra and faces with eight NdSi12 cuboctahedra. There are six shorter (3.16 Å) and six longer (3.18 Å) Nd–Si bond lengths. In the second Nd site, Nd is bonded to four equivalent Rh and eight equivalent Si atoms to form a mixture of edge and face-sharing NdSi8Rh4 cuboctahedra. There are two shorter (3.17 Å) and two longer (3.19 Å) Nd–Rh bond lengths. There are four shorter (3.17 Å) and four longer (3.19 Å) Nd–Si bond lengths. Rh is bonded in a 3-coordinate geometry to six equivalent Nd and three equivalent Si atoms. All Rh–Si bond lengths are 2.40 Å. Si is bonded in a 1-coordinate geometry to six Nd, one Rh, and two equivalent Si atoms. Both Si–Si bond lengths are 2.39 Å.
TaRhSn is half-Heusler structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Ta is bonded to four equivalent Rh and six equivalent Sn atoms to form a mixture of distorted face and corner-sharing TaSn6Rh4 tetrahedra. All Ta–Rh bond lengths are 2.69 Å. All Ta–Sn bond lengths are 3.10 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Ta and four equivalent Sn atoms. All Rh–Sn bond lengths are 2.69 Å. Sn is bonded in a 4-coordinate geometry to six equivalent Ta and four equivalent Rh atoms.
Eu3Rh4Pb13 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Eu is bonded in a 12-coordinate geometry to four equivalent Rh and twelve equivalent Pb atoms. All Eu–Rh bond lengths are 3.62 Å. There are four shorter (3.57 Å) and eight longer (3.61 Å) Eu–Pb bond lengths. Rh is bonded in a 9-coordinate geometry to three equivalent Eu and six equivalent Pb atoms. All Rh–Pb bond lengths are 2.79 Å. There are two inequivalent Pb sites. In the first Pb site, Pb is bonded in a 9-coordinate geometry to three equivalent Eu, two equivalent Rh, and four Pb atoms. There are a spread of Pb–Pb bond distances ranging from 3.18–3.51 Å. In the second Pb site, Pb is bonded in a cuboctahedral geometry to twelve equivalent Pb atoms.
BeVRh2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two BeVRh2 ribbons oriented in the (1, 0, 0) direction. Be is bonded in a linear geometry to two equivalent Rh atoms. Both Be–Rh bond lengths are 2.29 Å. V is bonded in a linear geometry to two equivalent Rh atoms. Both V–Rh bond lengths are 2.05 Å. Rh is bonded in a linear geometry to one Be and one V atom.
CeRhIn2 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Ce is bonded in a 1-coordinate geometry to three equivalent Rh and ten equivalent In atoms. There are one shorter (2.81 Å) and two longer (3.13 Å) Ce–Rh bond lengths. There are a spread of Ce–In bond distances ranging from 3.35–3.47 Å. Rh is bonded in a 9-coordinate geometry to three equivalent Ce and six equivalent In atoms. There are four shorter (2.84 Å) and two longer (2.85 Å) Rh–In bond lengths. In is bonded in a 3-coordinate geometry to five equivalent Ce and three equivalent Rh atoms.
Tb3Rh is Cementite structured and crystallizes in the orthorhombic Pnma space group. The structure is two-dimensional and consists of two Tb3Rh sheets oriented in the (0, 0, 1) direction. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded in a 2-coordinate geometry to two equivalent Rh atoms. There are one shorter (2.85 Å) and one longer (2.86 Å) Tb–Rh bond lengths. In the second Tb site, Tb is bonded in a distorted bent 150 degrees geometry to two equivalent Rh atoms. There are one shorter (2.80 Å) and one longer (2.89 Å) Tb–Rh bond lengths. Rh is bonded in a 6-coordinate geometry to six Tb atoms.
HfZrRh2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two HfZrRh2 ribbons oriented in the (1, 0, 0) direction. Hf is bonded in a linear geometry to two equivalent Rh atoms. Both Hf–Rh bond lengths are 2.34 Å. Zr is bonded in a linear geometry to two equivalent Rh atoms. Both Zr–Rh bond lengths are 2.34 Å. Rh is bonded in a linear geometry to one Hf and one Zr atom.
TaRh2Ga crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TaRh2Ga ribbons oriented in the (1, 0, 0) direction. Ta is bonded in a linear geometry to two equivalent Rh atoms. Both Ta–Rh bond lengths are 2.18 Å. Rh is bonded in a linear geometry to one Ta and one Ga atom. The Rh–Ga bond length is 2.46 Å. Ga is bonded in a linear geometry to two equivalent Rh atoms.
MnRh2Tl is Heusler-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Mn is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Mn–Rh bond lengths are 2.67 Å. Rh is bonded in a distorted body-centered cubic geometry to four equivalent Mn and four equivalent Tl atoms. All Rh–Tl bond lengths are 2.85 Å. Tl is bonded in a body-centered cubic geometry to eight equivalent Rh atoms.
CeRhSi crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Ce is bonded in a 8-coordinate geometry to four equivalent Rh and four equivalent Si atoms. There are three shorter (3.07 Å) and one longer (3.25 Å) Ce–Rh bond lengths. There are three shorter (3.19 Å) and one longer (3.32 Å) Ce–Si bond lengths. Rh is bonded in a 3-coordinate geometry to four equivalent Ce and three equivalent Si atoms. All Rh–Si bond lengths are 2.32 Å. Si is bonded in a distorted trigonal planar geometry to four equivalent Ce and three equivalent Rh atoms.
TaRhP crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ta is bonded in a 11-coordinate geometry to six equivalent Rh and five equivalent P atoms. There are a spread of Ta–Rh bond distances ranging from 2.87–2.96 Å. There are a spread of Ta–P bond distances ranging from 2.57–2.74 Å. Rh is bonded in a 12-coordinate geometry to six equivalent Ta and four equivalent P atoms. There are a spread of Rh–P bond distances ranging from 2.35–2.48 Å. P is bonded in a 9-coordinate geometry to five equivalent Ta and four equivalent Rh atoms.
CeRhGa crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ce is bonded in a 2-coordinate geometry to four equivalent Rh and six equivalent Ga atoms. There are a spread of Ce–Rh bond distances ranging from 2.88–3.09 Å. There are a spread of Ce–Ga bond distances ranging from 3.14–3.23 Å. Rh is bonded in a 8-coordinate geometry to four equivalent Ce and four equivalent Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.55–2.62 Å. Ga is bonded in a 10-coordinate geometry to six equivalent Ce and four equivalent Rh atoms.
Rh2ZnIn is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rh is bonded in a body-centered cubic geometry to four equivalent Zn and four equivalent In atoms. All Rh–Zn bond lengths are 2.72 Å. All Rh–In bond lengths are 2.72 Å. Zn is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. In is bonded in a body-centered cubic geometry to eight equivalent Rh atoms.