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At least 1,513 records · Page 84

Tholins - Organic chemistry of interstellar grains and gas

The paper discusses tholins, defined as complex organic solids formed by the interaction of energy - for example, UV light or spark discharge - with various mixtures of cosmically abundant gases - CH4, C2H6, NH3, H2O, HCHO, and H2S. It is suggested that tholins occur in the interstellar medium and are responsible for some of the properties of the interstellar grains and gas. Additional occurrences of tholins are considered. Tholins have been produced experimentally; 50 or so pyrolytic fragments of the brown, sometimes sticky substances have been identified by gas chromatography-mass spectrometry, and the incidence of these fragments in tholins produced by different procedures is reported.

Sagan, C.↗

Consortium breccia 73255 - Genesis and history of two coarse-grained 'norite' clasts

A study of two clasts of coarse-grained anorthositic-noritic-troctolitic-suite norites from the fragment-laden melt rock 73255 is presented. Both clasts are igneous rocks crystallized from melts that were probably internally generated; clast 27,80 is a cumulate, and the parent magmas of both rocks probably crystallized below the lunar surface. Despite similar history, the parent rocks of the two clasts appear to be derived from distinct magma types: the 27,80 is characterized by plagioclase and orthopyroxene as the major constituents and by a high K, Nb, and Zr content, while the 27,45 type also contains augite and has a low content of K, Nb, and Zr.

James, O. B.↗

Iron and the formation of astrophysical dust grains

Condensation of metallic iron or the iron carbide cohenite Fe3C is proposed as the source of the approximately 1000 K dust condensate in nova shells, Wolf-Rayet stars, and other objects. Iron grains may serve as nucleation sites for carbon in carbon-star ejecta; however, nucleation of graphite at its equilibrium saturation temperature is almost certainly kinetically inhibited. A gas phase rich in CO, C2H2, and HCN is produced instead.

Lewis, J. S.↗

Impact of improved information on the structure of world grain trade

The benefits to be derived by the United States from improvements in global grain crop forecasting capability are discussed. The improvements in forecasting accuracy, which are a result of the use of satellite technology in conjunction with existing ground based estimating procedures are described. The degree of forecasting accuracy to be obtained from satellite technology is also examined. Specific emphasis is placed on wheat production in seven countries/regions: the United States; Canada; Argentina; Australia; Western Europe; the USSR; and all other countries in a group.

Source record↗

Crop identification studies using Landsat data Separation of barley from other spring small grains and corn and soybean decision logic

Two labeling procedures were developed which identify various agricultural crops through the use of Landsat data. One procedure separates barley from other spring small grains, and the other identifies corn and soybeans. For both procedures, a minimum data set (critical acquisition time) has been designated. Landsat data in both image format and various graphic displays were used along with ancillary data to obtain information which aided in labeling the spectral signatures. The corn and soybean procedure also employed a structured decision logic. Test results for the barley separation procedure emphasized the importance of obtaining a critical acquisition and showed some success especially in areas where spring crops followed the expected growth patterns. Two tests of the corn and soybean procedure produced good labeling accuracies. Problems with the procedure were easy to identify, and some solutions were implemented for the second test. Automation of various parts of the procedure and extension to other crops and regions were recommended.

Dailey, C. L.↗

Preliminary technical results review of FY81 experiments. Volume 1: Fiscal year 1981/82 spring small grains pilot experiment

Technical progress made in the foreign commodity production forecasting for the advancement of spring small grains (SSG) area estimation is reported with emphasis on results achieved since the last AgRISTARS level semiannual review. Major objectives and accomplishments are reviewed and the experiment is described. The technical approach data assessment, and data systems used are considered. Results of the group approach comparison study are presented along with preliminary aggregation results for SSG processing procedures. The outlook for the future is assessed.

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AgRISTARS: Supporting research. Spring small grains planting date distribution model

A model was developed using 996 planting dates at 51 LANDSAT segments for spring wheat and spring barley in Minnesota, Montana, North Dakota, and South Dakota in 1979. Daily maximum and minimum temperatures and precipitation were obtained from the cooperative weather stations nearest to each segment. The model uses a growing degree day summation modified for daily temperature range to estimate the beginning of planting and uses a soil surface wetness variable to estimate how a fixed number of planting days are distributed after planting begins. For 1979, the model predicts first, median, and last planting dates with root mean square errors of 7.91, 6.61, and 7.09 days, respectively. The model also provides three or four dates to represent periods of planting activity within the planting season. Although the full model was not tested on an independent data set, it may be suitable in areas other than the U.S. Great Plains where spring small grains are planted as soon as soil and air temperatures become warm enough in the spring for plant growth.

Hodges, T.↗

Origin of rapidly solidified metal-troilite grains in chondrites and iron meteorites

Quantitative evidence is adduced by cooling rate calculations for the impact melting, on the surface of a parent body, of troilite and metallic Fe, Ni inclusions found on 12 ordinary chondrites rather than their formation at depth from an internally derived melt. In the case of the Shaw and Rose City breccias of unmelted and melted material, their melted metal need not have cooled through 1000 C within a few meters of the surface. Shock-melted, fine-grained, irregular intergrowths of metal and troilite form in situ in many irons and some chondrites by rapid solidification at cooling rates greater than 100,000 C/sec, so that their kamacite and taenite compositions may result from annealing of metallic glass or very fine quench products at about 250 C.

Scott, E. R. D.↗

Making Pure Fine-Grained Inorganic Powder

Sustained arc plasma chemical reactor fabricates very-fine-grained inorganic solids having low thermal conductivity. Powder fabrication method, based on plasma tube technique produces pure solids without contamination commonly produced by grinding.

Wood, C.↗

Development, test and evaluation of a computerized procedure for using Landsat data to estimate spring small grains acreage

A number of methods which can provide information concerning crop acreages on the basis of a utilization of multispectral scanner (MSS) data require for their implementation a comparatively large amount of labor. The present investigation is concerned with a project designed to improve the efficiency of analysis through increased automation. The Caesar technique was developed to realize this objective. The processability rates of the Caesar procedure versus the historical state-of-the-art proportion estimation procedures were determined in an experiment. Attention is given to the study site, the aggregation technology, the results of the aggregation test, and questions of error characterization. It is found that the Caesar procedure, which has been developed for the spring small grains region of North America, is highly efficient and provides accurate results.

Mohler, R. R. J.↗

SSG-4 - An automated spring small grains proportion estimator

In connection with an implementation of the classification procedures employed in the Large Area Crop Inventory Experiment (LACIE), a human analyst had to provide labeled samples. The present investigation is concerned with an automated proportion estimation procedure which has been derived from the early field-labeling procedures used in LACIE. This procedure was developed for the U.S./Canada Spring Small Grains Pilot Experiment. It is demonstrated that the considered spatial/color-based proportion estimation procedure provides the agricultural remote-sensing community with the basic tools to develop unbiased and highly efficient procedures for obtaining crop area estimates at the end of the season.

Dennis, T. B.↗

Spectral properties of mixtures of montmorillonite and dark grains - Implications for remote sensing minerals containing chemically and physically adsorbed water

The spectral properties from 0.4 to 3 microns of montmorillonite plus dark carbon grains (called opaques) of various sizes are studied as a function of the weight fraction of opaques present. The reflectance level and band depths of the 1.4-, 1.9-, 2.2-, and 2.8-micron water and/or OH absorption features are analyzed using derived empirical relationships and scattering theory. It is found that the absorption band depths and reflectance level are a very nonlinear function of the weight fraction of opaques present but can be predicted in many cases by simple scattering theory. The 2.8-micron bound water fundamental band is the most difficult absorption feature to suppress. The overtone absorptions are suppressed a greater amount than the fundamental but are still apparent even when 10-20 wt pct opaques are present. The relationships observed and the simple scattering theory presented show that quantitative compositional remote sensing studies are feasible for surfaces containing complex mineral mixtures.

Clark, R. N.↗

Analysis of grain boundary phase devitrification of Y2O3- and Al2O3-doped Si3N4

The present study has the objective to show that a Fourier Transform IR (FTIR) spectrometer in a single-beam reflection mode can be used for direct comparison of fractured vs nonfractured Si3N4 surfaces. This can be done because the FTIR method permits a digital summation of nearly 1000 scans of the fracture surface. Commercial-grade Si3N4, Y2O3, and Al2O3 were used in the study. The samples were heat treated in a vacuum induction heating furnace at either 1000 C for 10 h or 1200 C for 10 h each. Use of Fourier transform IR reflection spectroscopic analysis and X-ray diffraction shows that 10 h at 1200 C is sufficient to devitrify the amorphous grain boundary phase of Si3N4 containing 15 percent Y2O3 + 2 percent Al2O3 densification aids.

Hench, L. L.↗

Lithification opf gas-rich chondrite regolith breccias by grain boundary and localized shock melting

The fine-grained matrices (less than 150 microns) of 14 gas-rich ordinary chondrile regolith breccias were studied in an attempt to decipher the nature of the lithification process that converted loose regolith material into consolidated breccias. It is found that there is a continuouos gradation in matrix textures from nearly completely clastic (class A) to highly cemented (class C) breccias in which the remining clasts are completely surrounded by interstitial, shock-melted material. It is concluded that this interstitial material is formed by shock melting in the porous regolith. In general, the abundances of solar-wind-implanted He-4 and Ne-20 are inversely correlated with the abundance of intenstitial, shock-melted, feldspathic material. Chondrites with the highest abundance of interstitial, melted material (class C) experienced the highest shock pressures and temperatures and suffered the most extensive degassing. It is this interstitial, feldspathic melt that lithifies and cements the breccias together; those breccias with very little interstitial melt (class A) are the most porous and least consolidated.

Bischoff, A.↗