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At least 1,513 records · Page 84

Nial-base composite containing high volume fraction of AlN for advanced engines

A particulate reinforced NiAl-AlN composite alloy has a NiAl matrix and greater than about 13 volume percent fine particles of AlN within the matrix. The particles preferably have a diameter from about 15 nanometers to about 50 nanometers. The particulate reinforced NiAl-AlN composite alloy may be prepared by cryomilling prealloyed NiAl in liquid nitrogen using grinding media having a diameter of from about 2 mm to about 6 mm at an impeller speed of from about 450 RPM to about 800 RPM. The cryomilling may be done for a duration of from about 4 hours to about 20 hours to obtain a cryomilled powder. The cryomilled powder may be consolidated to form the particulate reinforced NiAl-AlN composite alloy. The particulate reinforced alloy can further include a toughening alloy. The toughening alloy may include NiCrAlY, FeCrAY and FeAl.

Hebsur, Mohan G.↗

Rapid flow fractionation of particles combining liquid and particulate dielectrophoresis

Rapid, size-based, deposition of particles from liquid suspension is accomplished using a nonuniform electric field created by coplanar microelectrode strips patterned on an insulating substrate. The scheme uses the dielectrophoretic force both to distribute aqueous liquid containing particles and, simultaneously, to separate the particles. Size-based separation is found within nanoliter droplets formed along the structure after voltage removal. Bioparticles or macromolecules of similar size can also be separated based on subtle differences in dielectric property, by controlling the frequency of the AC current supplied to the electrodes.

King, Michael R.↗

SM-ND Age and REE Systematics of Larkman Nunatek 06319: Closed System Fractional Crystallization of a Shergottite Magma

Sm-Nd isotopic data were collected on mineral separates and bulk rock powders of LAR 06319, yielding an age of 180+/-13 Ma (2(sigma)). This age is concordant with the Lu-Hf age (197+/-29 Ma, [1]) determined in conjunction with these data and the Sm-Nd age (190+/-26 Ma) of Shih et al., 2009 [2]. The Sm-Nd data form at statistically significant isochron (Fig. 1) that is controlled largely by leachate-residue pairs (samples with the R suffix are residues after leaching in cold 2N HCl for 10 minutes).

Shafer, J. T.↗

The Smallest Lunar Grains: Analytical TEM Characterization of the Sub-micron Size Fraction of a Mare Soil

The chemical composition, mineralogical type, and morphology of lunar regolith grains changes considerably with decreasing size, and below the approx.25 m size range the correlation between these parameters and remotely-sensed lunar surface properties connected to space weathering increases significantly. Although trends for these parameters across grain size intervals greater than 20 m are now well established, the 0 to 20 m size interval remains relatively un-subdivided with respect to variations in grain modal composition, chemistry and microstructure. Of particular interest in this size range are grains in the approximate < 1 m diameter class, whose fundamental properties are now the focus of lunar research pertaining to electrostatic grain transport, dusty plasmas, and lunar dust effects on crew health and exploration systems. In this study we have used analytical transmission electron microscopy (TEM) to characterize the mineralogy, microstructure and major element composition of grains below the 1 m size threshold in lunar soil 10084.

Thompson, M.↗

SEE Tolerant Self-Calibrating Simple Fractional-N PLL

We show a reliable on-chip clock multiplier for SEE testing or RHBD applications. Fine control of clock frequency is provided without complex delta-sigma schemes. Conflicts that can occur with voted PLLs are discussed, and how to avoid them.

Shuler, Robert L.↗

The Volatile Fraction of Comets as Quantified at Infrared Wavelengths - An Emerging Taxonomy and Implications for Natal Heritage

It is relatively easy to identify the reservoir from which a given comet was ejected. But dynamical models demonstrate that the main cometary reservoirs (Kuiper Belt, Oort Cloud) each contain icy bodies that formed in a range of environments in the protoplanetary disk, and the Oort Cloud may even contain bodies that formed in disks of sibling stars in the Sun s birth cluster. The cometary nucleus contains clues to the formative region(s) of its individual components. The composition of ices and rocky grains reflect a range of processes experienced by material while on the journey from the natal interstellar cloud core to the cometary nucleus. For that reason, emphasis is placed on classifying comets according to their native ices and dust (rather than orbital dynamics). Mumma & Charnley [1] reviewed the current status of taxonomies for comets and relation to their natal heritage.

Mumma, M. J.↗

An Update on the Non-Mass-Dependent Isotope Fractionation under Thermal Gradient

Mass flow and compositional gradient (elemental and isotope separation) occurs when flu-id(s) or gas(es) in an enclosure is subjected to a thermal gradient, and the phenomenon is named thermal diffusion. Gas phase thermal diffusion has been theoretically and experimentally studied for more than a century, although there has not been a satisfactory theory to date. Nevertheless, for isotopic system, the Chapman-Enskog theory predicts that the mass difference is the only term in the thermal diffusion separation factors that differs one isotope pair to another,with the assumptions that the molecules are spherical and systematic (monoatomic-like structure) and the particle collision is elastic. Our previous report indicates factors may be playing a role because the Non-Mass Dependent (NMD) effect is found for both symmetric and asymmetric, linear and spherical polyatomic molecules over a wide range of temperature (-196C to +237C). The observed NMD phenomenon in the simple thermal-diffusion experiments demands quantitative validation and theoretical explanation. Besides the pressure and temperature dependency illustrated in our previous reports, efforts are made in this study to address issues such as the role of convection or molecular structure and whether it is a transient, non-equilibrium effect only.

Sun, Tao↗

Using Air Temperature to Quantitatively Predict the MODIS Fractional Snow Cover Retrieval Errors over the Continental US (CONUS)

In the middle to high latitude and alpine regions, the seasonal snow pack can dominate the surface energy and water budgets due to its high albedo, low thermal conductivity, high emissivity, considerable spatial and temporal variability, and ability to store and then later release a winters cumulative snowfall (Cohen, 1994; Hall, 1998). With this in mind, the snow drought across the U.S. has raised questions about impacts on water supply, ski resorts and agriculture. Knowledge of various snow pack properties is crucial for short-term weather forecasts, climate change prediction, and hydrologic forecasting for producing reliable daily to seasonal forecasts. One potential source of this information is the multi-institution North American Land Data Assimilation System (NLDAS) project (Mitchell et al., 2004). Real-time NLDAS products are used for drought monitoring to support the National Integrated Drought Information System (NIDIS) and as initial conditions for a future NCEP drought forecast system. Additionally, efforts are currently underway to assimilate remotely-sensed estimates of land-surface states such as snowpack information into NLDAS. It is believed that this assimilation will not only produce improved snowpack states that better represent snow evolving conditions, but will directly improve the monitoring of drought.

MODIS↗

Concentration Effects and Ion Properties Controlling the Fractionation of Halides during Aerosol Formation

During the aerosolization process at the sea surface, halides are incorporated into aerosol droplets, where they may play an important role in tropospheric ozone chemistry. Although this process may significantly contribute to the formation of reactive gas phase molecular halogens, little is known about the environmental factors that control how halides selectively accumulate at the air−water interface. In this study, the production of sea spray aerosol is simulated using electrospray ionization (ESI) of 100 nM equimolar solutions of NaCl, NaBr, NaI, NaNO2, NaNO3, NaClO4, and NaIO4. The microdroplets generated are analyzed by mass spectrometry to study the comparative enrichment of anions (f (Isub x-)) and their correlation with ion properties. Although no correlation exists between f (sub x-) and the limiting equivalent ionic conductivity, the correlation coefficient of the linear fit with the size of the anions R(sub x-), dehydration free-energy ΔGdehyd, and polarizability alpha, follows the order: (R(sub x-)(exp −2)) > (R(sub x-)(exp −1)) >(R(sub x-) > delta G(sub dehyd) > alpha. The same pure physical process is observed in H2O and D2O. The factor f (sub x-) does not change with pH (6.8−8.6), counterion (Li+, Na+, K+, and Cs+) substitution effects, or solvent polarity changes in methanol − and ethanol−water mixtures (0 <= xH2O <= 1). Sodium polysorbate 20 surfactant is used to modify the structure of the interface. Despite the observed enrichment of I− on the air−water interface of equimolar solutions, our results of seawater mimic samples agree with a model in which the interfacial composition is increasingly enriched in I− < Br− < Cl− over the oceanic boundary layer due to concentration effects in sea spray aerosol formation.

iodine↗