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At least 1,513 records · Page 84

Ionospheric projections of magnetospheric regions under low and high solar wind pressure conditions

The projection of magnetospheric regions into the dayside ionosphere as determined by particle precipitation characteristics was studied for dependence on solar wind parameters. It was found that the solar wind kinetic pressure p dramatically affected the map of magnetospheric projections. Under the constraint that p greater than or equal 4 nPa(yielding (p) = 5.9 nPa), the area of the cusp (magnetic latitude times magnetic local time extent) was 4.83 degree-hours; whereas under the constraint that p greater than or equal 2 nPa (yielding (p) = 1.5 nPa), the cusp area was only 1.01 degree-hours. The ionospheric footprint of the low-latitude boundary layer was similarly affected. Various possible correlations of p with other solar wind variables, including n, v, and absolute value of B(sub z), proved unable to account for the pressure effect. Because one criterion for identifying the cusp is high fluxes, the effect of nv was investigated with particular care, both in examples and statistically. Again, p itself had by far the most striking effect. Thus we concluded that some physical mechanism is needed to account for the pressure effect. One possibility is that increased direct solar wind plasma penetration of the magnetopause occurs under high-p conditions in the manner suggested by various proponents of impulsive penetration models. An alternative, which we find promising, is that, regardless of the original interplanetary magnetic field (IMF) strength, a high-p solar wind leads to a large compression factor for the magnetosheath field, which is the field actually in contact with the magnetosphere. From this latter viewpoint, the chief effect of high particle pressure is simply to enhance the effectiveness of the interaction of the IMF with the magnetosphere.

Newell, Patrick T.↗

Polymer-Oxygen Compatibility Testing: Effect of Oxygen Aging on Ignition and Combustion Properties

The oxygen compatibility of six polymers used in oxygen service was evaluated after exposure for 48 hours to oxygen pressures ranging from 350 to 6200 kPa (50 to 900 psia), and temperatures ranging from 50 to 250 C (122 to 302 F). Three elastomers were tested: CR rubber (C873-70), FKM fluorocarbon rubber (Viton A), and MPQ silicone rubber (MIL-ZZ-765, Class 2); and three thermoplastics were tested: polyhexamethylene adipamide (Zytel 42), polytetrafluoroethylene (Teflon TFE), and polychlorotrifluoroethylene (Neoflon CTFE M400H). Post-aging changes in mass, dimensions, tensile strength, elongation at break, and durometer hardness were determined. Also, the compression set was determined for the three elastomers. Results show that the properties under investigation were more sensitive to oxygen pressure at low to moderate temperatures, and more sensitive to temperature at low to moderate oxygen pressures. Inspection of the results also suggested that both chain scissioning and cross-linking processes were operative, consistent with heterogeneous oxidation. Attempts are underway to verify conclusively the occurrence of heterogeneous oxidation using a simple modulus profiling technique. Finally, the effect of aging at 620 kpa (90 psia) and 121 C (250 F) on ignition and combustion resistance was determined. As expected, aged polymers were less ignitable and combustible (had higher AlTs and lower heats of combustion). Special attention was given to Neoflon CTFE. More specifically, the effect of process history (compression versus extrusion molding) and percent crystallinity (quick- versus slow-quenched) on the AIT, heat of combustion, and impact sensitivity of Neoflon CTFE was investigated. Results show the AIT, heat of combustion, and impact sensitivity to be essentially independent of Neoflon CTFE process history and structure.

Waller, Jess M.↗

Autofrettage to Counteract Coefficient of Thermal Expansion Mismatch in Cryogenic Pressurized Pipes with Metallic Liners

Composite feedlines with metal liners have the potential to reduce weight/cost while providing the same level of permeation resistance and material compatibility of all-metal feedlines carrying cryogenic propellants in spacecraft. The major technical challenges are the large difference in Coefficient of Thermal Expansion between the liner and the composite, and the manufacturing method required to make a very thin liner with the required strength and dimensional tolerance. This study investigates the use of autofrettage (compressive preload) to counteract Coefficient of Thermal Expansion when pre-pressurization procedures cannot be used to solve this problem. Promising materials (aluminum 2219, Inconel 718, nickel, nickel alloy) and manufacturing techniques (chemical milling, electroplating) are evaluated to determine the best liner candidates. Robust, autofrettaged feedlines with a low Coefficient of Thermal Expansion liner (Inconel 718 or nickel alloy) are shown to successfully counteract mismatch at LOX temperature. A new concept, autofrettage by temperature, is introduced for high Coefficient of Thermal Expansion materials (aluminum and pure nickel) where pressure cannot be used to add compressive preload.

Wen, Ed↗

Hot Flow Anomalies at Venus

We present a multi-instrument study of a hot flow anomaly (HFA) observed by the Venus Express spacecraft in the Venusian foreshock, on 22 March 2008, incorporating both Venus Express Magnetometer and Analyzer of Space Plasmas and Energetic Atoms (ASPERA) plasma observations. Centered on an interplanetary magnetic field discontinuity with inward convective motional electric fields on both sides, with a decreased core field strength, ion observations consistent with a flow deflection, and bounded by compressive heated edges, the properties of this event are consistent with those of HFAs observed at other planets within the solar system.

Venusian↗

Producing Zirconium Diboride Components with Complex, Near-Net Shape Geometries by Aqueous Room-Temperature Injection Molding

Room-temperature injection molding is proposed as a novel, low-cost and more energy efficient manufacturing process capable of forming complex-shaped zirconium diboride (ZrB2) parts. This innovative processing method utilized aqueous suspensions with high powder loading and a minimal amount (5 vol.) of water-soluble polyvinylpyrrolidone (PVP), which was used as a viscosity modifier. Rheological characterization was performed to evaluate the room-temperature flow properties of ZrB2-PVP suspensions. ZrB2 specimens were fabricated with high green body strength and were machinable prior to binder removal despite their low polymer content. After binder burnout and pressureless sintering, the bulk density and microstructure of specimens were characterized using Archimedes technique and scanning electron microscopy. X-Ray Diffraction was used to determine the phase compositions present in sintered specimens. Ultimate strength of sintered specimens will be determined using ASTM C1323-10 compressive C-ring test.

Near-Net Shape Forming↗

I n s i t u observation of a phase transition in silicon carbide under shock compression using pulsed x-ray diffraction

The behavior of silicon carbide (SiC) under shock compression is of interest due to its applications as a high-strength ceramic and for general understanding of shock-induced polymorphism. Here we use the Matter in Extreme Conditions beamline of the Linac Coherent Light Source to carry out a series of time-resolved pump-probe x-ray diffraction measurements on SiC laser-shocked to as high as 206 GPa. Experiments on single crystals and polycrystals of different polytypes show a transformation from a low-pressure tetrahedral phase to the high-pressure rocksalt-type (B1) structure. We directly observe coexistence of the low- and high-pressure phases in a mixed-phase region and complete transformation to the B1 phase above 200 GPa. The densities measured by x-ray diffraction are in agreement with both continuum gas-gun studies and a theoretical B1 Hugoniot derived from static-compression data. Time-resolved measurements during shock loading and release reveal a large hysteresis upon unloading, with the B1 phase retained to as low as 5 GPa. The sample eventually reverts to a mixture of polytypes of the low-pressure phase at late times. Our study demonstrates that x-ray diffraction is an effective means to characterize the time-dependent structural response of materials undergoing shock-induced phase transformations at megabar pressures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Fiber/matrix debonding evaluation of SiCf/SiC composites using micropillar compression technique

Third-generation silicon carbide (SiC) composites reinforced by SiC fibers (Hi-Nicalon S [HNS] and Tyranno SA3 [SA3]) are attractive for use in next generation reactors owing to their high strength and chemical inertness at high temperatures, as well as enhanced radiation tolerance under neutron irradiation environments. To optimize composite performance, the interfacial mechanical properties of chemical vapor–infiltrated (CVI) SiC f /SiC composites are investigated in this effort by using a slant interface micropillar compression testing procedure. The micropillar test specimens, containing an inclined pyrolytic carbon (PyC) interphase, are prepared using a focused ion beam. The novel microcompression testing successfully quantifies the debond shear strength and internal friction coefficient of micropillar test samples by using the Mohr-Coulomb formulation. Furthermore, according to four types of SiCf/SiC composite microcompression test results, interfacial properties and debond mechanisms are significantly affected by the PyC layer thickness, the local bonding mechanism of the PyC interphase on the SiC fiber surface, and the surface roughness of fibers. Regardless of PyC thicknesses, SA3-reinforced CVI SiC f /SiC composites are found to have much higher debond shear strengths than HNS-reinforced SiC f /SiC CVI composites. By using this micropillar compression technique alongside analytical methods, we uncover new understandings of PyC interface properties. Additionally, the micropillar test results obtained are correlated with macroscopic mechanical properties of neutron-irradiated CVI SiCf/SiC composites.

42 ENGINEERING↗

Feeding properties and behavior of hammer- and knife-milled pine

This work reports the rheological characterization of hammer and knife-milled lodgepole pine materials as a function of grind size and moisture content. Characterizations included particle size and shape distributions, bulk density, compressibility at 10 kPa uniaxial pressure, elastic recovery from 10 kPa uniaxial pressure, shear strength, effective angle of internal friction, arching in a custom hopper, and feeding performance in volumetric and gravimetric auger feeders. Particle analysis indicates that the width and length distributions of the 3 mm hammer-milled and the 6 mm knife-milled materials are quite similar, and that all the materials have relatively short aspect ratios (< 4). Compressibility and elastic recovery both increased with increasing moisture content with both values increasing more than 10% and the effect being most severe for the 3 mm grind. Adding 3 kPa of pressure increased the critical arching width for all hopper arching tests, except for the 25 mm grind material with 20% MC, for which the critical arching width actually decreased with increased pressure. Interestingly, for materials with smaller particle sizes, the volumetric feed rate tends to decrease as moisture increases even though the density of the material increases with moisture content and the auger speeds are the same. Time variability of volumetric feed rate increased dramatically with increasing particle size but the impact of moisture content was not as clear. For nearly all tests, gravimetric auger feeding resulted in better feeding control and substantially decreased time variability in the material feed rate. These tests show that material feed rate and volumetric auger feed rate variability are dependent upon material shear strength, bulk density, and particle size. Shear tests indicate that material strength generally decreased with increasing particle size, although the impact of moisture was not entirely consistent.

09 BIOMASS FUELS↗

Mechanical properties of metal-ceramic nanolaminates: Effect of constraint and temperature

Al/SiC nanolaminates with equal nominal thicknesses of the Al and SiC layers (10, 25, 50 and 100 nm) were manufactured by magnetron sputtering. The mechanical properties were measured at 25 °C and 100 °C by means of nanoindentation and micropillar compression tests and the deformation mechanisms were analyzed by in situ micropillar compression tests in the transmission electron microscope. In addition, finite element simulations of both tests were carried out to ascertain the role played by the strength of the Al layers and by the elastic constraint of the ceramic layers on the plastic flow of Al in the mechanical response. It was found that the mechanical response was mainly controlled by the constraint during nanoindentation or micropillar compression tests of very thin layered (≈10 nm) laminates, while the influence of the strength of Al layers was not as critical. This behavior was reversed, however, for thick layered laminates (100 nm). Here, these mechanisms point to the different effects of layer thickness during nanoindentation and micropillar compression, at both temperatures, and showed the critical role played by constraint on the mechanical response of nanolaminates made of materials with a very large difference in the elasto-plastic properties.

36 MATERIALS SCIENCE↗

Solvent-Free Preparation of High Energy, Binder-Free Electrodes Enabled by Dry Compressible Holey Graphene

Graphene is an atomically thick sheet consisting of a graphitic carbon network with excellent mechanical strength, electrical and thermal conductivity, and chemical stability. Holey graphene, a structural derivative of graphene, has an array of through-the-thickness holes across the lateral surface of the nanosheet. The presence of these holes has minimal detrimental effect on the graphene properties and leads to enhanced performance in applications such as electronics, sensors, and energy storage. For example, these holes allow more facile cross-plane ion and gas transport than intact graphene, making holey graphene an ideal electrode material for electrochemical energy storage. This presentation will focus on the ability of holey graphene to be compression molded into robust articles or architectures under solvent-free conditions without the need for potentially parasitic binders. The unique dry compressibility of holey graphene has enabled facile fabrication of high mass loading electrodes with both high density and high porosity, which have found use in supercapacitors and various high-energy battery systems such as lithium-oxygen, lithium-sulfur, and lithium-selenium batteries.

Yi Lin↗

Collisionless isotropization of the solar-wind protons by compressive fluctuations and plasma instabilities

Compressive fluctuations are a minor yet significant component of astrophysical plasma turbulence. In the solar wind, long-wavelength compressive slow-mode fluctuations lead to changes in β{sub ∥p}≡8πn{sub p}k{sub B}T{sub ∥p}/B{sup 2} and in R{sub p}≡T{sub ⊥p}/T{sub ∥p}, where T{sub ⊥p} and T{sub ∥p} are the perpendicular and parallel temperatures of the protons, B is the magnetic field strength, and n{sub p} is the proton density. If the amplitude of the compressive fluctuations is large enough, R{sub p} crosses one or more instability thresholds for anisotropy-driven microinstabilities. The enhanced field fluctuations from these microinstabilities scatter the protons so as to reduce the anisotropy of the pressure tensor. We propose that this scattering drives the average value of R{sub p} away from the marginal stability boundary until the fluctuating value of R{sub p} stops crossing the boundary. We model this “fluctuating-anisotropy effect” using linear Vlasov–Maxwell theory to describe the large-scale compressive fluctuations. We argue that this effect can explain why, in the nearly collisionless solar wind, the average value of R{sub p} is close to unity.

79 ASTRONOMY AND ASTROPHYSICS↗

Using Post-tensioning in Large Scale Additive Parts for Load Bearing Structures

One of the perennial problems with additive manufacturing (AM) is the lack of inter-laminar bond strength between the layers, also known as z-strength. This can make the use of AM fabricated parts in load bearing applications problematic. This problem can be solved in some applications with post-tensioning. The use of post-tensioning in structures can be used to ensure that layer interfaces only see compressive stresses. This method is commonly used to strengthen concrete structures since concrete is weak in tension while strong in compression. This paper explores the successful application of post-tensioning to improve z-strength of large structures made with Big Area Additive Manufacturing (BAAM) where loads are significant. Theory and examples are presented herein.

Chesser, Phillip↗

Post-forming Room Temperature Brittle Fracture in a High-Strength Low-Alloy Steel Sheet After Various Forming Modes

The effects of various sheet forming modes on the post-forming room temperature fracture behavior of a 550-MPa yield strength high-strength low-alloy (HSLA) steel are investigated. In-plane biaxial stretching, plane strain (cold rolling), uniaxial tension, cylindrical cup drawing, and in-plane compression (IPC) are examined up to a von Mises effective prestrain ε{sub eff} = 0.7. Most of the results pertain to sub-size Charpy-type impact specimens prepared from the prestrained material. After sufficiently large prestrains, the fracture behavior is highly anisotropic. Low-energy fracture modes, namely cleavage and intergranular fracture, occur after all modes of prestraining along plane directions that are perpendicular to the principal compressive prestrain. These planes are parallel to the sheet surface after biaxial stretching and cold rolling and correspond to brittle splits extending into the primary, ductile fracture surface. After cup drawing, the brittle planes are oriented perpendicular to the circumferential compressive prestrain. This results in very low energy fractures propagating in the length direction of a fully drawn cup. After in-plane compression, brittle fracture occurs along planes that are perpendicular to the compression direction. The fracture toughness for a crack propagating along such a plane after IPC to ε{sub eff} = 0.38 was very low (12.7 MPa √m), much lower than in the undeformed condition (247 MPa√m). Changes in grain shape and in crystallographic texture caused by the various prestraining modes, as well as the microstructural damage at non-metallic inclusions and carbides, are examined to try to understand the fracture behavior.

36 MATERIALS SCIENCE↗

Ductile adhesive elastomers with force-triggered ultra-high adhesion strength

Elastomers play a vital role in many forthcoming advanced technologies in which their adhesive properties determine materials’ interface performance. Despite great success in improving the adhesive properties of elastomers, permanent adhesives tend to stick to the surfaces prematurely or result in poor contact depending on the installation method. Thus, elastomers with on-demand adhesion that is not limited to being triggered by UV light or heat, which may not be practical for scenarios that do not allow an additional external source, provide a solution to various challenges in conventional adhesive elastomers. Herein, we report a novel, ready-to-use, ultra high-strength, ductile adhesive elastomer with an on-demand adhesion feature that can be easily triggered by a compression force. The precursor is mainly composed of a capsule-separated, two-component curing system. After a force-trigger and curing process, the ductile adhesive elastomer exhibits a peel strength and a lap shear strength of 1.2 × 10 4 N m -1 and 7.8 × 10 3 kPa, respectively, which exceed the reported values for advanced ductile adhesive elastomers. The ultra-high adhesion force is attributed to the excellent surface contact of the liquid-like precursor and to the high elastic modulus of the cured elastomer that is reinforced by a two-phase design. In conclusion, incorporation of such on-demand adhesion into an elastomer enables a controlled delay between installation and curing so that these can take place under their individual ideal conditions, effectively reducing the energy cost, preventing failures, and improving installation processes.

36 MATERIALS SCIENCE↗

Feasibility study of applying an advanced composite structure technique to the fabrication of helicopter rotor blades

The fabrication of helicopter rotary wings from composite materials is discussed. Two composite spar specimens consisting of compressively prestressed stainless steel liner over-wrapped with pretensioned fiberglass were constructed. High liner strength and toughness together with the prescribed prestresses and final sizing of the part are achieved by means of cryogenic stretch forming of the fiber wrapped composite spar at minus 320 F, followed by release of the forming pressure and warm up to room temperature. The prestresses are chosen to provide residual compression in the metal liner under operating loads.

Gleich, D.↗

DESIGN OF STIFFENED CYLINDERS IN AXIAL COMPRESSION

The problem of optimum design of axially compressed cylinders stiffened by rings and stringers is discussed. Particular attention is devoted to configurations suitable for large launch vehicles. Consideration is given to the analytical techniques for determining strength as well as the procedure for optimization.

CYLINDER↗

Mechanics of vitrimer particle compression and fusion under heat press

The compression and fusion of vitrimer particles is a fundamental problem underlying the recycling of vitrimers. Incomplete particle compression can lead to voids in the fused vitrimer, thereby impacting its mechanical property. In this work, we present a two-dimensional finite element model to capture the interplay of multiple complex mechanisms including random particle packing, large deformation, inter-particle contact, thermally activated bulk stress relaxation, and interface healing. Specifically, we focus on understanding two key components of this problem: i) evolution of porosity during compression and fusion of randomly packed vitrimer particles, and ii) effective tensile modulus and strength of fused vitrimer. Using the finite element model, we first show that using smaller particles can reduce the porosity in the fused vitrimer, which only slightly increases the effective modulus, but the increase in tensile strength is more pronounced. In addition, under the same processing conditions, particles with mixed sizes can achieve better densification and higher tensile strength after fusion than uniformly sized particles with the same average radius. Regarding the effects of processing conditions, we discuss how the porosity and effective modulus of the fused vitrimer depend on the processing time, temperature and pressure, and find a general trend consistent with experimental observations, i.e. longer processing time, higher temperature or higher pressure can lead to lower porosity and higher modulus of the fused vitrimer. Finally, the theoretical insights towards the compression and fusion process as well as the simulation framework can be useful in optimizing the powder-based heat press process of vitrimer and its composites.

42 ENGINEERING↗

Anisotropic strength behavior of single-crystal TATB

High-rate strength behavior plays an important role in the shock initiation of high explosives, with plastic deformation serving to localize heat into hot spots and as a mechanochemical means to enhance reactivity. Recent simulations predict that detonation-like shocks produce highly reactive nanoscale shear bands in the layered crystalline explosive TATB (1,3,5-triamino-2,4,6-trinitrobenzene), but the thresholds leading to this response are poorly understood. We utilize molecular dynamics to simulate the high-rate compressive stress–strain response of TATB, with a focus on understanding flow behavior. Here, the dependence of strength on pressure and loading axis (crystal orientation) is explored. The deformation mechanisms fall broadly into two categories, with compression along crystal layers activating a buckling/twinning mode and compression normal to the layers producing nanoscale shear bands. Despite the complexity of the underlying mechanisms, the crystal exhibits relatively straightforward stress–strain curves. Most of the crystal orientations studied show rapid strain softening following the onset of yielding, which settles to a steady flow state. Trajectories are analyzed using five metrics for local states and structural order, but most of these metrics yield similar distributions for these deformation mechanisms. On the other hand, a recently proposed measure of intramolecular strain energy is found to most cleanly distinguish between these mechanisms, while also providing a plausible connection with mechanochemically accelerated decomposition kinetics. Localization of intramolecular strain energy is found to depend strongly on crystal orientation and pressure.

36 MATERIALS SCIENCE↗