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At least 1,495 records · Page 83
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Investigation of N 2 /O 2 plasma interaction with Pt-catalyst: effect of metastable adsorbates on product hysteresis

The coupling of catalysts and atmospheric-pressure plasma has the potential to improve the efficiency of certain catalytic reactions. Understanding the changes that the catalyst surface undergoes during exposure to plasma is key to improving plasma–catalytic performance. In this work, long term exposure of Pt–Al 2 O 3 powder catalyst to an Ar/N 2 /O 2 non-equilibrium atmospheric-pressure plasma-jet was investigated. Products produced by the interaction were analyzed downstream with Fourier-transform infrared spectroscopy while surface species were analyzed operandi with diffuse reflectance infrared Fourier transform spectroscopy. During exposure, the catalyst temperature was ramped cyclically between 100 °C and 350 °C to understand how substrate temperature affects the plasma–catalyst interaction. Long-lasting changes were revealed to take place on the catalyst surface during plasma exposure. At low temperatures, Pt–O and Pt–NO accumulate on the surface which react at elevated temperatures to form NO 2 . NO 2 initially appears to spill on to the Al 2 O 3 support as nitrites and nitrates instead of desorbing. Stable surface conditions are only achieved after prolonged plasma exposure, when nitrate sites on the Al 2 O 3 support are filled. By changing the catalyst temperature at various rates, the impact of total plasma species flux to the surface was analyzed. It was found that decreasing the heating rate increased the hysteresis in the pattern of NO 2 formation during thermal cycling. The variation with temperature demonstrates that plasma exposure results in a buildup of surface NO x and oxygen species which react or desorb at high temperatures. The observed changes are discussed from the generic viewpoint that a non-equilibrium plasma interacting with a catalyst at low temperature introduces metastable steady-state surface conditions. Upon heating above a threshold temperature, the introduced surface modifications can change either due to thermal effects, or, for a plasma environment, by additional interaction with the incident plasma species flux. The surface/material changes take place in a highly predictable fashion and after sufficient time above the threshold temperature reach a steady-state condition that is different from the transient behavior that is observed during initial heating. During cooling the plasma-surface interaction exhibits a different behavior than during heating, and this results in hysteresis of diverse observables. The metastability/hysteresis description appears quite generic and analogous to hysteresis behavior seen for different systems. Furthermore, it is expected to be useful for understanding the consequences of plasma–catalyst surface interactions for various systems.

36 MATERIALS SCIENCE↗
DOE OSTI2020

The Architecture of Metabolism Maximizes Biosynthetic Diversity in the Largest Class of Fungi

Abstract Ecological diversity in fungi is largely defined by metabolic traits, including the ability to produce secondary or “specialized” metabolites (SMs) that mediate interactions with other organisms. Fungal SM pathways are frequently encoded in biosynthetic gene clusters (BGCs), which facilitate the identification and characterization of metabolic pathways. Variation in BGC composition reflects the diversity of their SM products. Recent studies have documented surprising diversity of BGC repertoires among isolates of the same fungal species, yet little is known about how this population-level variation is inherited across macroevolutionary timescales. Here, we applied a novel linkage-based algorithm to reveal previously unexplored dimensions of diversity in BGC composition, distribution, and repertoire across 101 species of Dothideomycetes, which are considered the most phylogenetically diverse class of fungi and known to produce many SMs. We predicted both complementary and overlapping sets of clustered genes compared with existing methods and identified novel gene pairs that associate with known secondary metabolite genes. We found that variation among sets of BGCs in individual genomes is due to nonoverlapping BGC combinations and that several BGCs have biased ecological distributions, consistent with niche-specific selection. We observed that total BGC diversity scales linearly with increasing repertoire size, suggesting that secondary metabolites have little structural redundancy in individual fungi. We project that there is substantial unsampled BGC diversity across specific families of Dothideomycetes, which will provide a roadmap for future sampling efforts. Our approach and findings lend new insight into how BGC diversity is generated and maintained across an entire fungal taxonomic class.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Spatial distributions of X CO 2 seasonal cycle amplitude and phase over northern high-latitude regions

Satellite-based observations of atmospheric carbon dioxide (CO 2 ) provide measurements in remote regions, such as the biologically sensitive but undersampled northern high latitudes, and are progressing toward true global data coverage. Recent improvements in satellite retrievals of total column-averaged dry air mole fractions of CO 2 (X CO 2 ) from the NASA Orbiting Carbon Observatory 2 (OCO-2) have allowed for unprecedented data coverage of northern high-latitude regions, while maintaining acceptable accuracy and consistency relative to ground-based observations, and finally providing sufficient data in spring and autumn for analysis of satellite-observed X CO 2 seasonal cycles across a majority of terrestrial northern high-latitude regions. Here, we present an analysis of X CO 2 seasonal cycles calculated from OCO-2 data for temperate, boreal, and tundra regions, subdivided into 5° latitude by 20° longitude zones. We quantify the seasonal cycle amplitudes (SCAs) and the annual half drawdown day (HDD). OCO-2 SCAs are in good agreement with ground-based observations at five high-latitude sites, and OCO-2 SCAs show very close agreement with SCAs calculated for model estimates of X CO 2 from the Copernicus Atmosphere Monitoring Services (CAMS) global inversion-optimized greenhouse gas flux model v19r1 and the CarbonTracker2019 model (CT2019B). Model estimates of X CO 2 from the GEOS-Chem CO 2 simulation version 12.7.2 with underlying biospheric fluxes from CarbonTracker2019 (GC-CT2019) yield SCAs of larger magnitude and spread over a larger range than those from CAMS, CT2019B, or OCO-2; however, GC-CT2019 SCAs still exhibit a very similar spatial distribution across northern high-latitude regions to that from CAMS, CT2019B, and OCO-2. Zones in the Asian boreal forest were found to have exceptionally large SCA and early HDD, and both OCO-2 data and model estimates yield a distinct longitudinal gradient of increasing SCA from west to east across the Eurasian continent. In northern high-latitude regions, spanning latitudes from 47 to 72° N, longitudinal gradients in both SCA and HDD are at least as pronounced as latitudinal gradients, suggesting a role for global atmospheric transport patterns in defining spatial distributions of X CO2 seasonality across these regions. GEOS-Chem surface contact tracers show that the largest X CO 2 SCAs occur in areas with the greatest contact with land surfaces, integrated over 15–30d. The correlation of X CO 2 SCA with these land surface contact tracers is stronger than the correlation of X CO 2 SCA with the SCA of CO 2 fluxes or the total annual CO 2 flux within each 5° latitude by 20° longitude zone. This indicates that accumulation of terrestrial CO 2 flux during atmospheric transport is a major driver of regional variations in X CO 2 SCA.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Simulating measurable ecosystem carbon and nitrogen dynamics with the mechanistically defined MEMS 2.0 model

Abstract. For decades, predominant soil biogeochemical models have used conceptual soil organic matter (SOM) pools and only simulated them to a shallow depth in soil. Efforts to overcome these limitations have prompted the development of the new generation SOM models, including MEMS 1.0, which represents measurable biophysical SOM fractions, over the entire root zone, and embodies recent understanding of the processes that govern SOM dynamics. Here we present the result of continued development of the MEMS model, version 2.0. MEMS 2.0 is a full ecosystem model with modules simulating plant growth with above- and belowground inputs, soil water and temperature by layer, decomposition of plant inputs and SOM, and mineralization and immobilization of nitrogen (N). The model simulates two commonly measured SOM pools – particulate and mineral-associated organic matter (POM and MAOM, respectively). We present results of calibration and validation of the model with several grassland sites in the US. MEMS 2.0 generally captured the soil carbon (C) stocks (R2 of 0.89 and 0.6 for calibration and validation, respectively) and their distributions between POM and MAOM throughout the entire soil profile. The simulated soil N matches measurements but with lower accuracy (R2 of 0.73 and 0.31 for calibration and validation of total N in SOM, respectively) than for soil C. Simulated soil water and temperature were compared with measurements, and the accuracy is comparable to the other commonly used models. The seasonal variation in gross primary production (GPP; R2 = 0.83), ecosystem respiration (ER; R2 = 0.89), net ecosystem exchange (NEE; R2 = 0.67), and evapotranspiration (ET; R2 = 0.71) was well captured by the model. We will further develop the model to represent forest and agricultural systems and improve it to incorporate new understanding of SOM decomposition.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1969

Self-consistent many-electron theory of electron work functions and surface potential characteristics for selected metals

Electron work functions, surface potentials, and electron number density distributions and electric fields in the surface region of 26 metals were calculated from first principles within the free electron model. Calculation proceeded from an expression of the total energy as a functional of the electron number density, including exchange and correlation energies, as well as a first inhomogeneity term. The self-consistent solution was obtained via a variational procedure. Surface barriers were due principally to many-body effects; dipole barriers were small only for some alkali metals, becoming quite large for the transition metals. Surface energies were inadequately described by this model, which neglects atomistic effects. Reasonable results were obtained for electron work functions and surface potential characteristics, maximum electron densities varying by a factor of over 60.

Smith, J. R.↗
NASA NTRS1977

Propulsion cycle effects for a two-fan V/STOL aircraft

This paper discusses the results of an in-depth study investigating the impacts of variable pitch, geared turbofan cycle parameters on a two-fan, subsonic, V/STOL aircraft. Variations in fan pressure ratio, compressor pressure ratio and combustor exit temperature are presented as they affect critical mission legs, aircraft performance, engine thrust-to-weight ratio and as a total systems impact in terms of aircraft takeoff gross weight. Several parameters have counter acting components which, when combined, synergistically result in an optimum value for that parameter. Careful attention has been paid to the changes in aircraft installation penalties associated with each cycle parameter.

Feddersen, R. E.↗
NASA NTRS1978

Magnetic bearings for instruments in the space environment

A magnetic bearing development is documented, which has been successfully applied to support a 0.9 kg - 19 cm diameter rotor in 5 degrees of freedom, with fully controlled drive capability to plus or minus 200 rad/s in the other axis. The construction details are described and illustrated. Performance data on five design variations are presented which extend the load capacity to 8 kilograms at which point the bearing element on the rotor is less than one-half of 1 percent of the total load capacity.

Studer, P. A.↗
NASA NTRS1980

Future lunar gravity measurements

Future missions to the moon should include a detailed high-resolution global gravity survey from a low (15-30 km) polar orbiting spacecraft. The use of gravity gradiometer instruments on board the spacecraft will give higher-resolution data at lower total mission cost than the present Doppler tracking technique. Simulations show that although a three axis gradiometer system is preferred, and can even be used to estimate spacecraft attitude and altitude variation, a properly oriented single rotating gravity gradiometer can be used to resolve closely spaced mascons in both the along-track and cross-track directions.

Forward, R. L.↗
NASA NTRS1981

Ground-based photometry of comets in the spectral interval 3000 to 3500 angstrom

Abundances and production rates of CN, C3, and C2 for fifteen comets were determined and the variation of these parameters with helicentric distance for two comets were monitored. While these measurements provide much information about the similarities and differences among comets, only a small fraction of the total material in any of the comets observed was sampled.

Willis, R. L.↗
NASA NTRS1981

Electromagnetic deep-probing (100-1000 KMS) of the Earth's interior from artificial satellites: Constraints on the regional emplacement of crustal resources

An algorithm was developed to address the problem of electromagnetic coupling of ionospheric current systems to both a homogeneous Earth having finite conductivity, and to an Earth having gross lateral variations in its conductivity structure, e.g., the ocean-land interface. Typical results from the model simulation for ionospheric currents flowing parallel to a representative geologic discontinuity are shown. Although the total magnetic field component at the satellite altitude is an order of magnitude smaller than at the Earth's surface (because of cancellation effects from the source current), the anomalous behavior of the satellite observations as the vehicle passes over the geologic contact is relatively more important pronounced. The results discriminate among gross lithospheric structures because of difference in electrical conductivity.

Hermance, J. F.↗
NASA NTRS1986

Forecasts of time averages with a numerical weather prediction model

Forecasts of time averages of 1-10 days in duration by an operational numerical weather prediction model are documented for the global 500 mb height field in spectral space. Error growth in very idealized models is described in order to anticipate various features of these forecasts and in order to anticipate what the results might be if forecasts longer than 10 days were carried out by present day numerical weather prediction models. The data set for this study is described, and the equilibrium spectra and error spectra are documented; then, the total error is documented. It is shown how forecasts can immediately be improved by removing the systematic error, by using statistical filters, and by ignoring forecasts beyond about a week. Temporal variations in the error field are also documented.

Roads, J. O.↗
NASA NTRS1988

Acoustical scattering from finite compliant surfaces bounding a duct

Acoustic radiation effects of a finite compliant surface covering a transverse slot in a two-dimensional parallel walled rigid duct are investigated. Radiation from a harmonic source external to the duct is shown to impinge on the slot, reradiating to the half plane and propagating through the duct. Integral equation techniques are employed to study the cases of an open slot, a membrane cover, and a flexible plate cover. The total power radiated to the half plane external to the duct and to the region internal to the duct is determined, taking into account slot-width and fluid-loading variations and the effect of the surface on the power radiated.

Smith, M. E.↗
NASA NTRS1990

Modeling Solar Lyman Alpha Irradiance

Solar Lyman alpha irradiance is estimated from various solar indices using linear regression analyses. Models developed with multiple linear regression analysis, including daily values and 81-day running means of solar indices, predict reasonably well both the short- and long-term variations observed in Lyman alpha. It is shown that the full disk equivalent width of the He line at 1083 nm offers the best proxy for Lyman alpha, and that the total irradiance corrected for sunspot effect also has a high correlation with Lyman alpha.

Pap, J.↗
NASA NTRS1992

Superlattice barrier varactors

SBV (Single Barrier Varactor) diodes have been proposed as alternatives to Schottky barrier diodes for harmonic multiplier applications. However, these show a higher current than expected. The excess current is due to X valley transport in the barrier. We present experimental results showing that the use of a superlattice barrier and doping spikes in the GaAs depletion regions on either side of the barrier can reduce the excess current and improve the control of the capacitance vs. voltage characteristic. The experimental results consist of data taken from two types of device structures. The first test structure was used to study the performance of AlAs/GaAs superlattice barriers. The wafer was fabricated into 90 micron diameter mesa diodes and the resulting current vs. voltage characteristics were measured. A 10 period superlattice structure with a total thickness of approximately 400 A worked well as an electron barrier. The structure had a current density of about one A/sq cm at one volt at room temperature. The capacitance variation of these structures was small because of the design of the GaAs cladding layers. The second test structure was used to study cladding layer designs. These wafers were InGaAs and InAlAs layers lattice matched to an InP substrate. The layers have n(+) doping spikes near the barrier to increase the zero bias capacitance and control the shape of the capacitance vs. voltage characteristic. These structures have a capacitance ratio of 5:1 and an abrupt change from maximum to minimum capacitance. The measurements were made at 80 K. Based on the information obtained from these two structures, we have designed a structure that combines the low current density barrier with the improved cladding layers. The capacitance and current-voltage characteristics from this structure are presented.

Raman, C.↗
NASA NTRS1948

Effect of pressure ratio and inlet pressure on performance of experimental gas turbine at inlet temperature of 800 R

An experimental gas turbine was operated over a range of blade-jet speed ratios, total pressure ratios, and inlet total pressures at a constant inlet temperature of 800 R. Peak over-all efficiencies were obtained at blade-jet speed ratios from 0.525 to 0.575 for all runs. The variation in peak efficiency with inlet pressure and pressure ratio was of small magnitude for the conditions investigated.

TURBINES - AXIAL FLOW↗
NASA NTRS1993

Time-Accurate Unsteady Flow Simulations Supporting the SRM T+68-Second Pressure Spike Anomaly Investigation (STS-54B)

Time-accurate unsteady flow simulations are being performed supporting the SRM T+68sec pressure 'spike' anomaly investigation. The anomaly occurred in the RH SRM during the STS-54 flight (STS-54B) but not in the LH SRM (STS-54A) causing a momentary thrust mismatch approaching the allowable limit at that time into the flight. Full-motor internal flow simulations using the USA-2D axisymmetric code are in progress for the nominal propellant burn-back geometry and flow conditions at T+68-sec--Pc = 630 psi, gamma = 1.1381, T(sub c) = 6200 R, perfect gas without aluminum particulate. In a cooperative effort with other investigation team members, CFD-derived pressure loading on the NBR and castable inhibitors was used iteratively to obtain nominal deformed geometry of each inhibitor, and the deformed (bent back) inhibitor geometry was entered into this model. Deformed geometry was computed using structural finite-element models. A solution for the unsteady flow has been obtained for the nominal flow conditions (existing prior to the occurrence of the anomaly) showing sustained standing pressure oscillations at nominally 14.5 Hz in the motor IL acoustic mode that flight and static test data confirm to be normally present at this time. Average mass flow discharged from the nozzle was confirmed to be the nominal expected (9550 lbm/sec). The local inlet boundary condition is being perturbed at the location of the presumed reconstructed anomaly as identified by interior ballistics performance specialist team members. A time variation in local mass flow is used to simulate sudden increase in burning area due to localized propellant grain cracks. The solution will proceed to develop a pressure rise (proportional to total mass flow rate change squared). The volume-filling time constant (equivalent to 0.5 Hz) comes into play in shaping the rise rate of the developing pressure 'spike' as it propagates at the speed of sound in both directions to the motor head end and nozzle. The objectives of the present analysis are to: (1) capture the dynamic responses of the motor combustion gas flow to correlate with available low-frequency (less than 12.5 sample/sec) data and (2) observe the high-frequency (up to 50 Hz) characteristics of the response to determine any potentials for dynamic coupling.

Dougherty, N. S.↗
NASA NTRS1994

An X-ray study of five supernova remnants in the Carina spiral arm

The ROSAT Position Sensitive Proportional Counter (PSPC) is used to perform an exploratory study of four fields in the Carina spiral arm containing five radio supernova remnants, only one of which has previously been studied in X-rays. We present upper limits for the detection in X-rays of G298.5 - 0.3, G298.6 - 0.0, and G299.0+0.2, and report a 4 sigma detection of G296.8-0.3. In addition, we present detailed spatial and spectral analysis of the bright X-ray remnant G296.1-0.7, which has previously been studied by both the Einstein IPC and EXOSAT LE/CMA. We detect relatively slight, but statistically significant, variations in the spectrum across the remnant via spatially resolved spectral fits and a study of the spatial variation of hardness ratios. In general, the spectrum is characteristic of a thermal plasma with kT about 0.2 keV and N(sub H) about 1.5 x 10(exp 21/sq. cm). The total X-ray emitting mass is estimated to be about 250 solar mass for an optically estimated distance of 4 kpc to the remnant. At this distance, the linear dimensions of the remnant are roughly 35 - 50 pc, implying an age on the order of 20,000 yr. Assuming that X-ray and radio brightnesses are related by SIGMA(sub R) proportional to SIGMA(exp 0.69)(sub X) and that the four radio remnants have X-ray spectral characteristics similar to G296.1-0.7, we find that the column densities to these sources must be several times 10(exp 22)/sq cm in order to explain their low X-ray count rates. This column density is considerably in excess of the X-ray fitted column density to G296.1-0.7, but is comparable to the total column densities in H I measured via the 21 cm line in the directions to all five remnants. This implies that G296.1 - 0.7 is at a significantly smaller distance than the other remnants.

Hwang, Una↗
NASA NTRS1996

Total Solar Irradiance Variability: A Review

Observations of total solar irradiance from space within the last two decaades convinced the skeptics that total irradiance varies over a wide range of periodicities: from minutes to the 11-year solar activity cycle. Analyses based on these space-borne observations have demonstrated that the irradiance variations are directly related to changes at the photosphere and the solar interior.

solar irradiance solar luminosity irradiance model↗