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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,495 records · Page 83
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DOE OSTI2014

Joint XMM-Newton and Chandra observations of the NGC 1407/1400 complex: A tail of an early-type galaxy and a tale of a nearby merging group

The nearby group centered on its bright central galaxy NGC 1407 has been suggested by previous kinematic studies to be an unusually dark system. It is also known for hosting a bright galaxy, NGC 1400, with a large radial velocity (1200 km s{sup –1}) with respect to the group center. Previous ROSAT X-ray observations revealed an extended region of enhanced surface brightness just eastward of NGC 1400. We investigate the NGC 1407/1400 complex with XMM-Newton and Chandra observations. We find that the temperature and metallicity of the enhanced region are different (cooler and more metal rich) than those of the surrounding group gas but are consistent with those of the interstellar medium (ISM) in NGC 1400. The relative velocity of NGC 1400 is large enough that much of its ISM could have been ram pressure stripped while plunging through the group atmosphere. We conclude that the enhanced region is likely to be hot gas stripped from the ISM of NGC 1400. We constrain the motion of NGC 1400 using the pressure jump at its associated stagnation front and the total mass profile of the NGC 1407 group. We conclude that NGC 1400 is moving within ∼30° of the line of sight with Mach number M≲3. We do not detect any obvious shock features in this complex, perhaps because of the high line-of-sight motion of NGC 1400. With an XMM-Newton pointing on the relatively relaxed eastern side of NGC 1407, we derive a hydrostatic mass for this group of ∼1 × 10{sup 13} M {sub ☉} within 100 kpc. The total mass extrapolated to the virial radius (681 kpc) is 3.8 × 10{sup 13} M {sub ☉}, which puts an upper limit of ∼300 M{sub ⊙}/L{sub B{sub ⊙}} on the mass-to-light ratio of this group. This suggests that the NGC 1407 group is not an unusually dark group.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Model of the expansion of H II region RCW 82

This paper aims to resolve the problem of formation of young objects observed in the RCW 82 H II region. In the framework of a classical trigger model the estimated time of fragmentation is larger than the estimated age of the H II region. Thus the young objects could not have formed during the dynamical evolution of the H II region. We propose a new model that helps resolve this problem. This model suggests that the H II region RCW 82 is embedded in a cloud of limited size that is denser than the surrounding interstellar medium. According to this model, when the ionization-shock front leaves the cloud it causes the formation of an accelerating dense gas shell. In the accelerated shell, the effects of the Rayleigh-Taylor (R-T) instability dominate and the characteristic time of the growth of perturbations with the observed magnitude of about 3 pc is 0.14 Myr, which is less than the estimated age of the H II region. The total time t {sub ∑}, which is the sum of the expansion time of the H II region to the edge of the cloud, the time of the R-T instability growth, and the free fall time, is estimated as 0.44 < t {sub ∑} < 0.78 Myr. We conclude that the young objects in the H II region RCW 82 could be formed as a result of the R-T instability with subsequent fragmentation into large-scale condensations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

A test of star formation laws in disk galaxies. II. Dependence on dynamical properties

We use the observed radial profiles of the mass surface densities of total, Σ {sub g}, and molecular, Σ{sub H2}, gas, rotation velocity, and star formation rate (SFR) surface density, Σ{sub sfr}, of the molecular-rich (Σ{sub H2} ≥ Σ{sub HI}/2) regions of 16 nearby disk galaxies to test several star formation (SF) laws: a 'Kennicutt-Schmidt (K-S)' law, Σ{sub sfr}=A{sub g}Σ{sub g,2}{sup 1.5}; a 'Constant Molecular' law, Σ{sub sfr} = A {sub H2}Σ{sub H2,2}; the turbulence-regulated laws of Krumholz and McKee (KM05) and Krumholz, McKee, and Tumlinson (KMT09); a 'Gas-Ω' law, Σ{sub sfr}=B{sub Ω}Σ{sub g}Ω; and a shear-driven 'giant molecular cloud (GMC) Collision' law, Σ{sub sfr} = B {sub CC}Σ {sub g}Ω(1-0.7β), where β ≡ d ln v {sub circ}/d ln r. If allowed one free normalization parameter for each galaxy, these laws predict the SFR with rms errors of factors of 1.4-1.8. If a single normalization parameter is used by each law for the entire galaxy sample, then rms errors range from factors of 1.5-2.1. Although the Constant Molecular law gives the smallest rms errors, the improvement over the KMT, K-S, and GMC Collision laws is not especially significant, particularly given the different observational inputs that the laws utilize and the scope of included physics, which ranges from empirical relations to detailed treatment of interstellar medium processes. We next search for systematic variation of SF law parameters with local and global galactic dynamical properties of disk shear rate (related to β), rotation speed, and presence of a bar. We demonstrate with high significance that higher shear rates enhance SF efficiency per local orbital time. Such a trend is expected if GMC collisions play an important role in SF, while an opposite trend would be expected if the development of disk gravitational instabilities is the controlling physics.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Spatial confinement of the IBEX Ribbon: A dominant turbulence mechanism

The narrow ribbon of enhanced energetic neutral atom flux observed by the Interstellar Boundary Explorer spacecraft has prompted numerous ideas to explain its structure and properties. One of these ideas is the 'neutral solar wind' scenario, which identifies the source particles as pickup protons in the local interstellar medium originating in solar wind charge-exchange interactions. This scenario has been thought to require unrealistically weak pitch-angle scattering of the pickup protons to explain the narrow structure. Recently, Schwadron and McComas suggested that this structure could result from a spatial retention of the pickup protons, rather than from a restricted pitch-angle distribution. Here, we present a physically motivated, quantitative mechanism to produce such a spatial configuration. This mechanism is based on the 'dominant turbulence' assumption, which can be applied where the production of new pickup protons is slow, and has been used to successfully explain the level of turbulent heating observed in the outer solar wind. This formalism predicts a pickup isotropization process which adds or subtracts energy from the ambient turbulent fluctuations, depending on the initial pitch angle of the pickup protons. We show that a simple model of this process can yield a ribbon structure in qualitative agreement with the observations. The results of this simple model are not yet quantitatively satisfactory, but we suggest several improvements which may reduce the quantitative discrepancy.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Active galactic nucleus feedback in the hot halo of NGC 4649

Using the deepest available Chandra observations of NGC 4649, we find strong evidences of cavities, ripples, and ring-like structures in the hot interstellar medium that appear to be morphologically related with the central radio emission. These structures show no significant temperature variations in correspondence with higher pressure regions (0.5 kpc < r < 3 kpc). On the same spatial scale, a discrepancy between the mass profiles obtained from stellar dynamic and Chandra data represents the telltale evidence of a significant nonthermal pressure component in this hot gas, which is related to the radio jet and lobes. On a larger scale we find agreement between the mass profile obtained from Chandra data and planetary nebulae and globular cluster dynamics. The nucleus of NGC 4649 appears to be extremely radiatively inefficient, with highly sub-Bondi accretion flow. Consistent with this finding, the jet power evaluated from the observed X-ray cavities implies that a small fraction of the accretion power calculated for the Bondi mass accretion rate emerges as kinetic energy. Comparing the jet power to radio and nuclear X-ray luminosity, the observed cavities show behavior similar to those of other giant elliptical galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Laboratory infrared spectroscopy of gaseous negatively charged polyaromatic hydrocarbons

Based largely on infrared spectroscopic evidence, polycyclic aromatic hydrocarbon (PAH) molecules are now widely accepted to occur abundantly in the interstellar medium. Laboratory infrared spectra have been obtained for a large variety of neutral and cationic PAHs, but data for anionic PAHs are scarce. Nonetheless, in regions with relatively high electron densities and low UV photon fluxes, PAHs have been suggested to occur predominantly as negatively charged ions (anions), having substantial influence on cloud chemistry. While some matrix spectra have been reported for radical anion PAHs, no data is available for even-electron anions, which are more stable against electron detachment. Here we present the first laboratory infrared spectra of deprotonated PAHs ([PAH-H]{sup –}) in the wavelength ranges between 6 and 16 μm and around 3 μm. Wavelength-dependent infrared multiple-photon electron detachment is employed to obtain spectra for deprotonated naphthalene, anthracene, and pyrene in the gas phase. Spectra are compared with theoretical spectra computed at the density functional theory level. We show that the relative band intensities in different ranges of the IR spectrum deviate significantly from those of neutral and positively charged PAHs, and moreover from those of radical anion PAHs. These relative band intensities are, however, well reproduced by theory. An analysis of the frontier molecular orbitals of the even- and odd-electron anions reveals a high degree of charge localization in the deprotonated systems, qualitatively explaining the observed differences and suggesting unusually high electric dipole moments for this class of PAH molecules.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2014

Characterizing the structure of diffuse emission in Hi-GAL maps

We present a study of the structure of the Galactic interstellar medium (ISM) through the Δ-variance technique, related to the power spectrum and the fractal properties of infrared/submillimeter maps. Through this method, it is possible to provide quantitative parameters, which are useful for characterizing different morphological and physical conditions, and better constraining the theoretical models. In this respect, the Herschel Infrared Galactic Plane Survey, carried out at five photometric bands from 70 to 500 μm, constitutes a unique database for applying statistical tools to a variety of regions across the Milky Way. In this paper, we derive a robust estimate of the power-law portion of the power spectrum of four contiguous 2° × 2° Hi-GAL tiles located in the third Galactic quadrant (217° ≲ ℓ ≲ 225°, –2° ≲ b ≲ 0°). The low level of confusion along the line of sight, testified by CO observations, makes this region an ideal case. We find very different values for the power spectrum slope from tile to tile but also from wavelength to wavelength (2 ≲ β ≲ 3), with similarities between fields attributable to components located at the same distance. Thanks to comparisons with models of turbulence, an explanation of the determined slopes in terms of the fractal geometry is also provided, and possible relations with the underlying physics are investigated. In particular, an anti-correlation between ISM fractal dimension and star formation efficiency is found for the two main distance components observed in these fields. A possible link between the fractal properties of the diffuse emission and the resulting clump mass function is discussed.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Experiments of water formation on warm silicates

When dust grains have a higher temperature than they would have in dense clouds, and when H, H{sub 2}, and O{sub 2} have a negligible residence time on grains, the formation of water should still be possible via the hydrogenation of OH and Eley-Rideal-type reactions. We determined that the OH desorption energy from an amorphous silicate surface is at least 143 meV (1656 K). This is 400 K higher than the value previously used in chemical models of the interstellar medium and is possibly as high as 410 meV (4760 K). This extends the temperature range for the efficient formation of water on grains from about 30 K to at least 50 K, and possibly over 100 K. We do not find evidence that water molecules leave the surface upon formation. Instead, through a thermal programmed desorption experiment, we find that water formed on the surface of an amorphous silicate desorbs at around 160 K. We also measured the cross-sections for the reaction of H and D with an O{sub 3} layer on an amorphous silicate surface at 50 K. The values of the cross-sections, σ{sub H} = 1.6 ± 0.27 Å{sup 2} and σ{sub D} = 0.94 ± 0.09 Å{sup 2}, respectively, are smaller than the size of an O{sub 3} molecule, suggesting the reaction mechanism is more likely Eley-Rideal than hot-atom. Information obtained through these experiments should help theorists evaluate the relative contribution of water formation on warm grains versus in the gas phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

An expanded HST/WFC3 survey of M83: Project overview and targeted supernova remnant search

We present an optical/NIR imaging survey of the face-on spiral galaxy M83, using data from the Hubble Space Telescope Wide Field Camera 3 (WFC3). Seven fields are used to cover a large fraction of the inner disk, with observations in nine broadband and narrowband filters. In conjunction with a deep Chandra survey and other new radio and optical ground-based work, these data enable a broad range of science projects to be pursued. We provide an overview of the WFC3 data and processing and then delve into one topic, the population of young supernova remnants (SNRs). We used a search method targeted toward soft X-ray sources to identify 26 new SNRs. Many compact emission nebulae detected in [Fe II] 1.644 μm align with known remnants and this diagnostic has also been used to identify many new remnants, some of which are hard to find with optical images. We include 37 previously identified SNRs that the data reveal to be <0.''5 in angular size and thus are difficult to characterize from ground-based data. The emission line ratios seen in most of these objects are consistent with shocks in dense interstellar material rather than showing evidence of ejecta. We suggest that the overall high elemental abundances in combination with high interstellar medium pressures in M83 are responsible for this result. Future papers will expand on different aspects of the these data including a more comprehensive analysis of the overall SNR population.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

A parametric modeling approach to measuring the gas masses of circumstellar disks

The disks that surround young stars are mostly composed of molecular gas, which is harder to detect and interpret than the accompanying dust. Disk mass measurements have therefore relied on large and uncertain extrapolations from the dust to the gas. We have developed a grid of models to study the dependencies of isotopologue CO line strengths on disk structure and temperature parameters and find that a combination of {sup 13}CO and C{sup 18}O observations provides a robust measure of the gas mass. We apply this technique to Submillimeter Array observations of nine circumstellar disks and published measurements of six well studied disks. We find evidence for selective photodissociation of C{sup 18}O and determine masses to within a factor of about three. The inferred masses for the nine disks in our survey range from 0.7 to 6 M {sub Jup}, and all are well below the extrapolation from the interstellar medium gas-to-dust ratio of 100. This is consistent with the low masses of planets found around such stars, and may be due to accretion or photoevaporation of a dust-poor upper atmosphere. However, the masses may be underestimated if there are more efficient CO depletion pathways than those known in molecular clouds and cold cores.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Active galactic nuclei emission line diagnostics and the mass-metallicity relation up to redshift z ∼ 2: The impact of selection effects and evolution

Emission line diagnostic diagrams probing the ionization sources in galaxies, such as the Baldwin-Phillips-Terlevich (BPT) diagram, have been used extensively to distinguish active galactic nuclei (AGN) from purely star-forming galaxies. However, they remain poorly understood at higher redshifts. We shed light on this issue with an empirical approach based on a z ∼ 0 reference sample built from ∼300,000 Sloan Digital Sky Survey galaxies, from which we mimic selection effects due to typical emission line detection limits at higher redshift. We combine this low-redshift reference sample with a simple prescription for luminosity evolution of the global galaxy population to predict the loci of high-redshift galaxies on the BPT and Mass-Excitation (MEx) diagnostic diagrams. The predicted bivariate distributions agree remarkably well with direct observations of galaxies out to z ∼ 1.5, including the observed stellar mass-metallicity (MZ) relation evolution. As a result, we infer that high-redshift star-forming galaxies are consistent with having normal interstellar medium (ISM) properties out to z ∼ 1.5, after accounting for selection effects and line luminosity evolution. Namely, their optical line ratios and gas-phase metallicities are comparable to that of low-redshift galaxies with equivalent emission-line luminosities. In contrast, AGN narrow-line regions may show a shift toward lower metallicities at higher redshift. While a physical evolution of the ISM conditions is not ruled out for purely star-forming galaxies and may be more important starting at z ≳ 2, we find that reliably quantifying this evolution is hindered by selections effects. The recipes provided here may serve as a basis for future studies toward this goal. Code to predict the loci of galaxies on the BPT and MEx diagnostic diagrams and the MZ relation as a function of emission line luminosity limits is made publicly available.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Magnetohydrodynamic simulations of a jet drilling an H I cloud: Shock induced formation of molecular clouds and jet breakup

The formation mechanism of the jet-aligned CO clouds found by NANTEN CO observations is studied by magnetohydrodynamical (MHD) simulations taking into account the cooling of the interstellar medium. Motivated by the association of the CO clouds with the enhancement of H I gas density, we carried out MHD simulations of the propagation of a supersonic jet injected into the dense H I gas. We found that the H I gas compressed by the bow shock ahead of the jet is cooled down by growth of the cooling instability triggered by the density enhancement. As a result, a cold dense sheath is formed around the interface between the jet and the H I gas. The radial speed of the cold, dense gas in the sheath is a few km s{sup –1} almost independent of the jet speed. Molecular clouds can be formed in this region. Since the dense sheath wrapping the jet reflects waves generated in the cocoon, the jet is strongly perturbed by the vortices of the warm gas in the cocoon, which breaks up the jet and forms a secondary shock in the H I-cavity drilled by the jet. The particle acceleration at the shock can be the origin of radio and X-ray filaments observed near the eastern edge of the W50 nebula surrounding the galactic jet source SS433.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Fermi bubbles inflated by winds launched from the hot accretion flow in Sgr A*

A pair of giant gamma-ray Bubbles has been revealed by Fermi-LAT. In this paper we investigate their formation mechanism. Observations have indicated that the activity of the supermassive black hole located at the Galactic center, Sgr A*, was much stronger than at the present time. Specifically, one possibility is that while Sgr A* was also in the hot accretion regime, the accretion rate should be 10{sup 3}-10{sup 4} times higher during the past ∼10{sup 7} yr. On the other hand, recent magnetohydrodynamic numerical simulations of hot accretion flows have unambiguously shown the existence and obtained the properties of strong winds. Based on this knowledge, by performing three-dimensional hydrodynamical simulations, we show in this paper that the Fermi Bubbles could be inflated by winds launched from the 'past' hot accretion flow in Sgr A*. In our model, the active phase of Sgr A* is required to last for about 10 million years and it was quenched no more than 0.2 million years ago. The central molecular zone (CMZ) is included and it collimates the wind orientation toward the Galactic poles. Viscosity suppresses the Rayleigh-Taylor and Kelvin-Helmholtz instabilities and results in the smoothness of the Bubbles edge. The main observational features of the Bubbles can be well explained. Specifically, the ROSAT X-ray features are interpreted by the shocked interstellar medium and the interaction region between the wind and CMZ gas. The thermal pressure and temperature obtained in our model are consistent with recent Suzaku observations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Statistical techniques for detecting the intergalactic magnetic field from large samples of extragalactic Faraday rotation data

Rotation measure (RM) grids of extragalactic radio sources have been widely used for studying cosmic magnetism. However, their potential for exploring the intergalactic magnetic field (IGMF) in filaments of galaxies is unclear, since other Faraday-rotation media such as the radio source itself, intervening galaxies, and the interstellar medium of our Galaxy are all significant contributors. We study statistical techniques for discriminating the Faraday rotation of filaments from other sources of Faraday rotation in future large-scale surveys of radio polarization. We consider a 30° × 30° field of view toward the south Galactic pole, while varying the number of sources detected in both present and future observations. We select sources located at high redshifts and toward which depolarization and optical absorption systems are not observed so as to reduce the RM contributions from the sources and intervening galaxies. It is found that a high-pass filter can satisfactorily reduce the RM contribution from the Galaxy since the angular scale of this component toward high Galactic latitudes would be much larger than that expected for the IGMF. Present observations do not yet provide a sufficient source density to be able to estimate the RM of filaments. However, from the proposed approach with forthcoming surveys, we predict significant residuals of RM that should be ascribable to filaments. The predicted structure of the IGMF down to scales of 0.°1 should be observable with data from the Square Kilometre Array, if we achieve selections of sources toward which sightlines do not contain intervening galaxies and RM errors are less than a few rad m{sup –2}.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Magnetic field amplification in the thin X-ray rims of SN 1006

Several young supernova remnants, including SN 1006, emit synchrotron X-rays in narrow filaments, hereafter thin rims, along their periphery. The widths of these rims imply 50-100 μG fields in the region immediately behind the shock, far larger than expected for the interstellar medium compressed by unmodified shocks, assuming electron radiative losses limit rim widths. However, magnetic field damping could also produce thin rims. Here we review the literature on rim width calculations, summarizing the case for magnetic field amplification. We extend these calculations to include an arbitrary power-law dependence of the diffusion coefficient on energy, D∝E {sup μ}. Loss-limited rim widths should shrink with increasing photon energy, while magnetic-damping models predict widths almost independent of photon energy. We use these results to analyze Chandra observations of SN 1006, in particular the southwest limb. We parameterize the FWHM in terms of energy as FWHM ∝E{sub γ}{sup m{sub E}}. Filament widths in SN 1006 decrease with energy; m{sub E} ∼ –0.3 to –0.8, implying magnetic field amplification by factors of 10-50, above the factor of four expected in strong unmodified shocks. For SN 1006, the rapid shrinkage rules out magnetic damping models. It also favors short mean free paths (small diffusion coefficients) and strong dependence of D on energy (μ ≥ 1).

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

The cosmic-ray population of the galactic central molecular zone

The conditions in the Galactic Center are often compared with those in starburst systems, which contain higher supernova rates, stronger magnetic fields, more intense radiation fields, and larger amounts of dense molecular gas than in our own Galactic disk. Interactions between such an augmented interstellar medium and cosmic rays result in brighter radio and γ-ray emission. Here, we test how well the comparisons between the Galactic Center and starburst galaxies hold by applying a model for cosmic-ray interactions to the Galactic Center to predict the resulting γ-ray emission. The model only partially explains the observed γ-ray and radio emission. The model for the γ-ray spectrum agrees with the data at TeV energies but not at GeV energies. Additionally, as the fits of the model to the radio and γ-ray spectra require significant differences in the optimal wind speed and magnetic field strength, we find that the single-zone model alone cannot account for the observed emission from the Galactic Center. Our model is improved by including a soft, additional cosmic-ray population. We assess such a cosmic-ray population and its potential sources and find that a cosmic-ray electron spectrum is energetically favored over a cosmic-ray proton spectrum.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

The HETDEX pilot survey. V. The physical origin of Lyα emitters probed by near-infrared spectroscopy

We present the results from a Very Large Telescope/SINFONI and Keck/NIRSPEC near-infrared spectroscopic survey of 16 Lyα emitters (LAEs) at z = 2.1-2.5 in the COSMOS and GOODS-N fields discovered from the Hobby Eberly Telescope Dark Energy Experiment Pilot Survey. We detect rest-frame optical nebular lines (Hα and/or [O III] λ5007) for 10 of the LAEs and measure physical properties, including the star formation rate (SFR), gas-phase metallicity, gas mass fraction, and Lyα velocity offset. We find that LAEs may lie below the mass-metallicity relation for continuum-selected star-forming galaxies at the same redshift. The LAEs all show velocity shifts of Lyα relative to the systemic redshift ranging between +85 and +296 km s{sup –1} with a mean of +180 km s{sup –1}. This value is smaller than measured for continuum-selected star-forming galaxies at similar redshifts. The Lyα velocity offsets show a moderate correlation with the measured SFR (2.5σ), but no significant correlations are seen with the SFR surface density, specific SFR, stellar mass, or dynamical mass (≲1.5σ). Exploring the role of dust, kinematics of the interstellar medium (ISM), and geometry on the escape of Lyα photons, we find no signature of selective quenching of resonantly scattered Lyα photons. However, we also find no evidence that a clumpy ISM is enhancing the Lyα equivalent width. Our results suggest that the low metallicity in LAEs may be responsible for yielding an environment with a low neutral hydrogen column density and less dust, easing the escape of Lyα photons over that in continuum-selected star-forming galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Millimeter observations of CS, HCO{sup +}, and CO toward five planetary nebulae: following molecular abundances with nebular age

Millimeter and sub-millimeter observations of CO, CS, and HCO{sup +} have been conducted toward five planetary nebulae (PNe: K4-47, NGC 6537 (Red Spider), M2-48, NGC 6720 (Ring), and NGC 6853 (Dumbbell)), spanning an age range of 900-10,000 yr, using the Sub-Millimeter Telescope and the 12 m antenna of the Arizona Radio Observatory. The J = 5 → 4, J = 3 → 2, and J = 2 → 1 transitions of CS at 245, 147, and 98 GHz, as well as the J = 3 → 2 and J = 1 → 0 lines of HCO{sup +} at 268 and 89 GHz, were detected toward each source. At least three rotational transitions of CO have also been observed, including the J = 6 → 5 and J = 4 → 3 lines at 691 and 461 GHz. CS had not been definitively identified previously in PNe, and new detections of HCO{sup +} were made in four of the five nebulae. From a radiative transfer analysis of the CO and CS data, kinetic temperatures of T {sub K} ∼ 10-80 K and gas densities of n(H{sub 2}) ∼ 0.1-1 × 10{sup 6} cm{sup –3} were determined for the molecular material in these sources. Column densities for CO, CS, and HCO{sup +} were N {sub tot} ∼ 0.2-5 × 10{sup 16} cm{sup –2}, N {sub tot} ∼ 0.4-9 × 10{sup 12} cm{sup –2}, and N {sub tot} ∼ 0.3-5 × 10{sup 12} cm{sup –2}, respectively, with fractional abundances, relative to H{sub 2}, of f ∼ 0.4-2 × 10{sup –4}, f ∼ 1-4 × 10{sup –8}, and f ∼ 1 × 10{sup –8}, with the exception of M2-48, which had f(HCO{sup +}) ∼ 10{sup –7}. Overall, the molecular abundances do not significantly vary over a duration of 10,000 yr, in contrast to predictions of chemical models. The abundances reflect the remnant asymptotic giant branch shell material, coupled with photochemistry in the early PN phase. These observations also suggest that PNe eject substantial amounts of molecular material into the diffuse interstellar medium.

79 ASTRONOMY AND ASTROPHYSICS↗