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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,495 records · Page 83
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

No effect of diffraction on Pluto-Charon mutual events

Mulholland and Gustafson (1987) made the interesting suggestion that observations of Pluto-Charon mutual events might show significant dependence on both wavelength and telescope aperture because of diffraction effects. In this letter, observations are presented that show the predicted effects to be absent and demonstrate that the parameters of the system are such that the events can be accurately analyzed with geometrical optics.

Tholen, D. J.↗
NASA NTRS1991

Point-Diffraction Interferometer For Flow Experiments

Improved point-diffraction interferometer used in both real-time visualization and recording of supersonic and transonic flow fields about airfoils and other test bodies in wind tunnels. System relatively insensitive to vibrations, but very sensitive to optical quality of wind-tunnel windows. Designed to handle higher laser powers and to use available light efficiently.

Bachalo, William D.↗
NASA NTRS1999

Teflon FEP Analyzed After Retrieval From the Hubble Space Telescope

During the Hubble Space Telescope (HST) Second Servicing Mission, 6.8 years after the telescope was deployed in low Earth orbit, degradation of unsupported Teflon FEP (DuPont; fluorinated ethylene propylene), used as the outer layer of the multilayer insulation (MLI) blankets, was evident as large cracks on the telescope light shield. A sample of the degraded outer layer (see the photograph) was retrieved during the second servicing mission and returned to Earth for ground testing and evaluation. Also retrieved was a Teflon FEP radiator surface from a cryogen vent cover that was exposed to the space environment on the aft bulkhead of the HST. NASA Goddard Space Flight Center directed the efforts of the Hubble Space Telescope MLI Failure Review Board, whose goals included determining the FEP degradation mechanisms. As part of the investigations into the degradation mechanisms, specimens retrieved from the first and second HST servicing missions, 3.6 and 6.8 years after launch, respectively, were characterized through exhaustive mechanical, optical, and chemical testing. Testing led by Goddard included scanning electron microscopy, optical microscopy, tensile testing, solar absorptance measurements, time-of-flight secondary ion mass spectroscopy (TOF-SIMS), Fourier transform infrared microscopy (m-FTIR), attenuated total reflectance infrared microscopy (ATR/FTIR), and x-ray diffraction (XRD). The NASA Lewis Research Center contributed significantly to the analysis of the retrieved HST materials by leading efforts and providing results of bend testing, surface microhardness measurements, x-ray photoelectron spectroscopy, solid-state nuclear magnetic resonance spectroscopy, and density measurements. Other testing was conducted by Nano Instruments, Inc., and the University of Akron.

Dever, Joyce A.↗
NASA NTRS1999

Scanning Mode Shock Position Sensor Invented and Demonstrated

A flow-visualizing system with a scanning optical beam offers greater advantages than the conventional approaches. In addition to a higher signal-to-noise ratio and lower source power, the scanning permits visualization of weak phenomena such as the scattering and diffraction of light on shocks. Scanning beam flow-visualization techniques were evaluated at the NASA Lewis Research Center for shock position sensing. In an effort to eliminate moving parts, a spectral scanning technique was invented and demonstrated.

Adamovsky, Grigory↗
NASA NTRS2012

Arrayed Micro-Ring Spectrometer System and Method of Use

A spectrometer system includes an array of micro-zone plates (MZP) each having coaxially-aligned ring gratings, a sample plate for supporting and illuminating a sample, and an array of photon detectors for measuring a spectral characteristic of the predetermined wavelength. The sample plate emits an evanescent wave in response to incident light, which excites molecules of the sample to thereby cause an emission of secondary photons. A method of detecting the intensity of a selected wavelength of incident light includes directing the incident light onto an array of MZP, diffracting a selected wavelength of the incident light onto a target focal point using the array of MZP, and detecting the intensity of the selected portion using an array of photon detectors. An electro-optic layer positioned adjacent to the array of MZP may be excited via an applied voltage to select the wavelength of the incident light.

Choi, Sang H.↗
NASA NTRS2017

Precision Projector Laboratory: Detector Characterization with an Astronomical Emulation Testbed

As astronomical observations benefit from improved sensitivity, the effectiveness of scientific programs is becoming limited by systematics that often originate in poorly understood image sensor behavior. Traditional, bottom-up detector characterization methods provide one way to model underlying detector physics, and generate ever more faithful numerical simulations, but this approach is vulnerable to preconceptions and over-simplification. The alternative top-down approach is laboratory emulation, which enables observation, calibration, and analysis scenarios to be tested without relying on a complete understanding of the underlying physics. This complements detector characterization and simulation efforts by testing their validity. We describe a laboratory facility and experimental testbed that supports the emulation of a wide range of mission concepts such as gravitational weak lensing measurements by WFIRST and high precision spectrophotometry of transiting exoplanets by JWST. An Offner relay projects readily customizable "scenes" (e.g. stars, galaxies, spectra) with very low optical aberration over the full area of a typical optical or near infrared image sensor. f/8 and slower focal ratios may be selected, spanning those of most proposed space missions and approximating the point spread function (PSF) size of seeing limited ground based surveys. Diffraction limited PSFs are projected over a wide field of view and wavelength range to deliver highly predictable image patterns down to sub-pixel scales with stable intensity and fine motion control. The testbed enables realistic validation of detector performance on science-like images, which aids mission design and survey strategy, as well as targeted investigations of various detector effects.

Seshadri, Suresh↗
NASA NTRS2022

ORCAS - Keck Instrument Development - ORKID

A new breed of space-ground hybrid observatory, the Orbiting Configurable Artificial Star (ORCAS) mission is working with the W. M. Keck Observatory (WMKO) to demonstrate the viability of diffraction-limited visible imaging from large ground telescopes. To support that, we have built and delivered ORKID (The ORCAS Keck Instrument Demonstrator) as an early visible-wavelength performance demonstration with the Keck II Adaptive Optics (AO) system. By enabling AO and flux calibration observations, the low-cost ORCAS/ORKID mission will deliver highly detailed images to support many scientific advances. A community driven observation plan will provide Great Observatory quality capabilities open to all US observers. These observations will result in unique science for the mission, while also complementing and extending space-borne science.

Eliad Peretz↗
DOE OSTI2019

In situ and operando investigation of the dynamic morphological and phase changes of a selenium-doped germanium electrode during (de)lithiation processes

To understand the effect of selenium doping on the good cycling performance and rate capability of a Ge 0.9 Se 0.1 electrode, the dynamic morphological and phase changes of the Ge 0.9 Se 0.1 electrode were investigated by synchrotron-based operando transmission X-ray microscopy (TXM) imaging, X-ray diffraction (XRD), and X-ray absorption spectroscopy (XAS). The TXM results show that the Ge 0.9 Se 0.1 particle retains its original shape after a large volume change induced by (de)lithiation and undergoes a more sudden morphological and optical density change than pure Ge. The difference between Ge 0.9 Se 0.1 and Ge is attributed to a super-ionically conductive Li–Se–Ge network formed inside Ge 0.9 Se 0.1 particles, which contributes to fast Li-ion pathways into the particle and nano-structuring of Ge as well as buffering the volume change of Ge. The XRD and XAS results confirm the formation of a Li–Se–Ge network and reveal that the Li–Se–Ge phase forms during the early stages of lithiation and is an inactive phase. The Li–Se–Ge network also can suppress the formation of the crystalline Li 15 Ge 4 phase. Finally, these in situ and operando results reveal the effect of the in situ formed, super-ionically conductive, and inactive network on the cycling performance of Li-ion batteries and shed light on the design of high capacity electrode materials.

25 ENERGY STORAGE↗
DOE OSTI2022

Structural Characterization of Uranium Tetrafluoride Hydrate (UF 4 ·2.5H 2 O)

Uranium tetrafluoride is an important intermediate in the nuclear fuel cycle. Facile synthesis of its hydrate, uranium tetrafluoride hydrate (UF 4 ·2.5H 2 O), has recently been reported. The hydrate forms by contacting anhydrous UF 4 with neat H 2 O at room temperature for 24 h or by exposing anhydrous UF 4 to high relative humidity (>90%) conditions for several weeks. These pathways are of clear environmental relevance. Further understanding of the structure and optical spectra of UF 4 ·2.5H 2 O, especially of the water molecules, is therefore necessary. Herein, the structure of UF 4 ·2.5H 2 O was probed using time-of-flight neutron powder diffraction to improve understanding of the crystalline water environments in the structure. The complete structure was elucidated and compared to a previously reported partial structure for UF 4 ·2.5H 2 O and a predicted complete structure from density functional theory. The crystalline structure exhibits three distinct water environments: two of the three water sites are bound to uranium, and the third water is unbound or “free”. Furthermore, the completed structure reveals an extensive hydrogen bonding network involving water–fluorine and water–water interactions. One bound water site participates in hydrogen bonding with nearby fluoride ligands (O–H···F–U), and the second bound water site participates in hydrogen bonding with the unbound water (O–H···O) and a nearby fluoride ligand (O–H···F–U); the unbound water participates in hydrogen bonding with bound water (O–H···O–U). Low-temperature experiments and thermal analysis indicate UF 4 ·2.5H 2 O is thermally stable from 10 to 358 K, undergoes dehydration at higher temperatures, and is nearly dehydrated at 473 K. Structural measurements provide foundational understanding and will inform future investigations of the thermal and environmental stability of UF 4 ·2.5H 2 O.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Spin-orbital correlations from complex orbital order in MgV 2⁢ O 4

MgV 2 ⁢O 4 is a spinel based on magnetic V 3+ ions, which host both spin (𝑆 = 1) and orbital (𝑙 eff = 1) moments. Owing to the underlying pyrochlore coordination of the magnetic sites, the spins in MgV 2 ⁢O 4 only antiferromagnetically order once the frustrating interactions imposed by the 𝐹⁡𝑑⁢$\overline{3}$⁢𝑚 lattice are broken through an orbitally-driven structural distortion at T 𝑆 ≃ ⁢60 K. Consequently, a Néel transition occurs at T 𝑁 ≃ ⁢40 K. Low-temperature spatial ordering of the electronic orbitals is fundamental to both the structural and magnetic properties; however, considerable discussion on whether it can be described by complex or real orbital ordering is ambiguous. We apply neutron spectroscopy to resolve the nature of the orbital ground state and characterize hysteretic spin-orbital correlations using x-ray and neutron diffraction. Neutron spectroscopy finds multiple excitation bands and we parametrize these in terms of a multilevel (or excitonic) theory based on the orbitally degenerate ground state. Meaningful for the orbital ground state, we report an “optical-like” mode at high energies that we attribute to a crystal-field-like excitation from the spin-orbital 𝑗 eff = 2 ground-state manifold to an excited 𝑗 eff =1 energy level. We parametrize the magnetic excitations in terms of a Hamiltonian with spin-orbit coupling and local crystalline electric field distortions resulting from deviations from perfect octahedra surrounding the V 3+ ions. We suggest that this provides compelling evidence for complex orbital order in MgV 2⁢ O 4 . We then apply the consequences of this model to understand hysteretic effects in the magnetic diffuse scattering where we propose that MgV 2⁢ O 4 displays a high-temperature orbital memory of the low-temperature spin order.

Frustrated magnetism↗
DOE OSTI2020

An automated platform for in situ serial crystallography at room temperature

Direct observation of functional motions in protein structures is highly desirable for understanding how these nanomachineries of life operate at the molecular level. Because cryogenic temperatures are non-physiological and may prohibit or even alter protein structural dynamics, it is necessary to develop robust X-ray diffraction methods that enable routine data collection at room temperature. We recently reported a crystal-on-crystal device to facilitate in situ diffraction of protein crystals at room temperature devoid of any sample manipulation. Here an automated serial crystallography platform based on this crystal-on-crystal technology is presented. A hardware and software prototype has been implemented, and protocols have been established that allow users to image, recognize and rank hundreds to thousands of protein crystals grown on a chip in optical scanning mode prior to serial introduction of these crystals to an X-ray beam in a programmable and high-throughput manner. This platform has been tested extensively using fragile protein crystals. We demonstrate that with affordable sample consumption, this in situ serial crystallography technology could give rise to room-temperature protein structures of higher resolution and superior map quality for those protein crystals that encounter difficulties during freezing. This serial data collection platform is compatible with both monochromatic oscillation and Laue methods for X-ray diffraction and presents a widely applicable approach for static and dynamic crystallographic studies at room temperature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Hidden phonon highways promote photoinduced interlayer energy transfer in twisted transition metal dichalcogenide heterostructures

Vertically stacked van der Waals (vdW) heterostructures exhibit unique electronic, optical, and thermal properties that can be manipulated by twist-angle engineering. However, the weak phononic coupling at a bilayer interface imposes a fundamental thermal bottleneck for future two-dimensional devices. Using ultrafast electron diffraction, we directly investigated photoinduced nonequilibrium phonon dynamics in MoS 2 /WS 2 at 4° twist angle and WSe 2 /MoSe 2 heterobilayers with twist angles of 7°, 16°, and 25°. We identified an interlayer heat transfer channel with a characteristic timescale of ~20 picoseconds, about one order of magnitude faster than molecular dynamics simulations assuming initial intralayer thermalization. Atomistic calculations involving phonon-phonon scattering suggest that this process originates from the nonthermal phonon population following the initial interlayer charge transfer and scattering. Our findings present an avenue for thermal management in vdW heterostructures by tailoring nonequilibrium phonon populations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1972

Optimum detection of an optical image on a photoelectric surface

The detection of an optical image in the presence of uniform background light is based on a likelihood ratio formed of the numbers of photoelectrons emitted from small elements of a photoelectric surface onto which the image is focused. When diffraction is negligible and the surface has unit quantum efficiency, this detector is equipollent with the optimum detector of the image forming light. Its performance is compared with that of the threshold detector and that of a detector basing its decisions on the total number of photoelectrons from a finite area of the image. The illuminance of the image is postulated to have a Gaussian spatial distribution. All three detectors exhibit nearly the same reliability.

Helstrom, C. W.↗
NASA NTRS1975

Solar rejection for an orbiting telescope

The present work discusses some of the constraints that the optical designer must deal with in optimizing spaceborne sensors that must look at or near the sun. Analytical techniques are described for predicting the effects of stray radiation from sources such as mirror scatter, baffle scatter, diffraction, and ghost images. In addition, the paper describes a sensor design that has been flown on the Apollo Telescope Mount (Skylab) to aid astronauts in locating solar flares. In addition to keeping stray radiation to a minimum, the design had to be nondegradable by the direct solar heat load.

Rehnberg, J. D.↗
NASA NTRS1993

Pinhole Calibrator For Particle-Sizing Instrument

Rotating-pinhole calibrator designed for use in calibrating and testing optical instrument measuring sizes of cloud droplets, dust particles, and other small particles suspended in flowing air. Easily attachable to particle-size-measuring instrument and suitable for both quick verification of calibration in field and detailed calibration studies in laboratory. Calibrator used to determine such operating parameters of instrument as optical collection angles, depth of field, profile of laser beam used to measure particles, and response to trajectory of particle. Also used to align instrument. Pinhole reused any number of times without risk of variation in diffraction pattern. Furthermore, size of pinhole chosen precisely and at will.

Hovenac, Edward↗
NASA NTRS1993

Figures of merit for laser beam quality

It was shown how full-width at half maximum (FWHM), full-width at 1/e(sup 2) (FW1/e(sup 2)), Strehl ratio, and encircled energy figures of merit vary with different types of aberration and measurement methods. The array sampling method and the slit-scan method are examined in detail. Our irradiance in the exit pupil of the optical system is a simple gaussian. It was found that in general the slit-scan method and the array method do not yield the same result. The width measurements for the central lobe of the diffraction pattern are very insensitive to aberration.

Milster, T. D.↗
NASA NTRS2003

Nanocrystalline Chalcopyrite Materials (CuInS2 and CuInSe2) via Low-Temperature Pyrolysis of Molecular Single-Source Precursors

Nanometer sized particles of the chalcopyrite compounds CuInS2 and CuInSe2 were synthesized by thermal decomposition of molecular single-source precursors (PPh3)2CuIn(SEt)4 and (PPh3)2CuIn(SePh)4, respectively, in the non-coordinating solvent dioctyl phthalate at temperatures between 200 and 300 C. The nanoparticles range in size from 3 - 30 nm and are aggregated to form roughly spherical clusters of about 500 nm in diameter. X-ray diffraction of the nanoparticle powders shows greatly broadened lines indicative of very small particle sizes, which is confirmed by TEM. Peaks present in the XRD can be indexed to reference patterns for the respective chalcopyrite compounds. Optical spectroscopy and elemental analysis by energy dispersive spectroscopy support the identification of the nanoparticles as chalcopyrites.

Castro, Stephanie L.↗