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At least 1,495 records · Page 83
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

UNIFORM ATMOSPHERIC RETRIEVAL ANALYSIS OF ULTRACOOL DWARFS. I. CHARACTERIZING BENCHMARKS, Gl 570D AND HD 3651B

Interpreting the spectra of brown dwarfs is key to determining the fundamental physical and chemical processes occurring in their atmospheres. Powerful Bayesian atmospheric retrieval tools have recently been applied to both exoplanet and brown dwarf spectra to tease out the thermal structures and molecular abundances to understand those processes. In this manuscript we develop a significantly upgraded retrieval method and apply it to the SpeX spectral library data of two benchmark late T dwarfs, Gl 570D and HD 3651B, to establish the validity of our upgraded forward model parameterization and Bayesian estimator. Our retrieved metallicities, gravities, and effective temperatures are consistent with the metallicity and presumed ages of the systems. We add the carbon-to-oxygen ratio as a new dimension to benchmark systems and find good agreement between carbon-to-oxygen ratios derived in the brown dwarfs and the host stars. Furthermore, we have for the first time unambiguously determined the presence of ammonia in the low-resolution spectra of these two late T dwarfs. We also show that the retrieved results are not significantly impacted by the possible presence of clouds, though some quantities are significantly impacted by uncertainties in photometry. This investigation represents a watershed study in establishing the utility of atmospheric retrieval approaches on brown dwarf spectra.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRSDate not supplied

Arctic Amplification: Process Drivers and Sources of Uncertainty

Arctic amplification (AA) is a coupled atmosphere-sea ice-ocean process. This understanding has evolved from the early concept of AA, as a consequence of snow ice line progressions, through more than a century of research that has clarified the relevant processes and driving mechanisms of AA. The predictions made by early modeling studies, namely the fall/winter maximum, bottom-heavy structure, the prominence of surface albedo feedback, and the importance of stable stratification have withstood the scrutiny of multi-decadal observations and more complex models. Yet, the uncertainty in Arctic climate projections is larger than in any other region of the planet, making the assessment of high-impact, near-term regional changes difficult or impossible. Reducing this large spread in Arctic climate projections requires a quantitative process understanding. This presentation synthesizes current knowledge of AA and describes a set of recommendations to guide future research. It briefly reviews the history of AA science, summarizes observed Arctic changes, discusses modeling approaches and feedback diagnostics, and assesses the current understanding of the most relevant feedbacks to AA. These sections culminate in a conceptual model of the fundamental physical mechanisms causing AA and a collection of recommendations to accelerate progress towards reduced uncertainty in Arctic climate projections. Our conceptual model highlights the need to account for local feedback and remote process interactions within the context of the annual cycle to constrain projected AA.

Patrick C Taylor↗
DOE OSTI2015

The field experiments on the HTO washout from the atmosphere

HTO (tritiated water) wash-out from the atmosphere is one of the key processes governing the HTO transport from the atmosphere into soil and plants. Experimental studies of the HTO interaction with water drops were carried out both in laboratories and in the field. In the course of experiments, the following rain characteristics were recorded: rain intensity, size distribution of drops, and falling velocities and their dependence on drop diameter. A laser optical device was designed and used to measure the distribution of the drop radius and velocities during the period of experiment. The tritium source was placed at a height of 30 m. Rainwater samples were collected in plastic bottles and their HTO activity was determined by liquid scintillation techniques. The data obtained for the experimental values of the scavenging rate are within the range from 4.12*10{sup -5} to 1.57*10{sup -4} s{sup -1} and correspond to the precipitation intensity from 0.3 to 1.26 mm/hour. These results are in sufficiently good agreement with the results of earlier papers.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1976

Resonance-line transfer with partial redistribution. VIII - Solution in the comoving frame for moving atmospheres

The effects of partial frequency redistribution in the scattering process for lines formed in moving atmospheres are analyzed using a general method that allows the transfer equation to be solved in the comoving frame of the gas. The same chromospheric and atomic model studied by Cannon and Vardavas (1974) is employed in the calculations, but a depth scale with logarithmically spaced points is adopted. It is found that in both static and moving atmospheres, the profiles obtained with complete and partial frequency redistribution are virtually identical. The large differences in profiles obtained by Cannon and Vardavas when they used complete and partial redistribution are shown to be spurious (and physically unreal) effects resulting from angle averaging in the observer's frame instead of the comoving frame.

Mihalas, D.↗
NASA NTRS1992

Atmospherically Resistant Vegetation Index (ARVI) for EOS-MODIS

ARVI, which is here proposed as a tool for the remote sensing of vegetation by the EOS MODIS sensor, takes advantage of the presence of the blue channel in MODIS, together with the red and near-IR channels composing the normalized-difference vegetation index (NDVI). Unlike the NDVI, ARVI resists atmospheric effects via a self-correction process for the effects of the atmosphere on the red channel. ARVI is presently shown to have a dynamic range similar to NDVI's, but is on average less sensitive to atmospheric effects by a factor of 4. A single combination of the blue and red channels in the ARVI may be used in all or most remote-sensing applications.

Kaufman, Yoram J.↗
NASA NTRS1992

Atmospheric correction of AVIRIS data in ocean waters

Hyperspectral data offers unique capabilities for characterizing the ocean environment. The spectral characterization of the composition of ocean waters can be organized into biological and terrigenous components. Biological photosynthetic pigments in ocean waters have unique spectral ocean color signatures which can be associated with different biological species. Additionally, suspended sediment has different scattering coefficients which result in ocean color signatures. Measuring the spatial distributions of these components in the maritime environments provides important tools for understanding and monitoring the ocean environment. These tools have significant applications in pollution, carbon cycle, current and water mass detection, location of fronts and eddies, sewage discharge and fate etc. Ocean color was used from satellite for describing the spatial variability of chlorophyll, water clarity (K(sub 490)), suspended sediment concentration, currents etc. Additionally, with improved atmospheric correction methods, ocean color results produced global products of spectral water leaving radiance (L(sub W)). Ocean color results clearly indicated strong applications for characterizing the spatial and temporal variability of bio-optical oceanography. These studies were largely the results of advanced atmospheric correction techniques applied to multispectral imagery. The atmosphere contributes approximately 80 percent - 90 percent of the satellite received radiance in the blue-green portion of the spectrum. In deep ocean waters, maximum transmission of visible radiance is achieved at 490nm. Conversely, nearly all of the light is absorbed by the water at wavelengths greater than about 650nm and thus appears black. These spectral ocean properties are exploited by algorithms developed for the atmospheric correction used in satellite ocean color processing. The objective was to apply atmospheric correction techniques that were used for procesing satellite Coastal Zone Color Scanner (CZCS) data to AVIRIS data. Quantitative measures of L(sub W) from AVIRIS are compared with ship ground truth data and input into bio-optical models.

Terrie, Gregory↗
NASA NTRS2003

The East and Southeast Asia Initiatives: Aerosol Column Measurements

Airborne dusts from northern China contribute a significant part of the air quality problem and, to some extent, regional climatic impact in Asia during spring- time. However, with the economical growth in China, increases in the emission of air pollutants generated from industrial and vehicular sources will not only impact the radiation balance, but adverse health effects to humans all year round. In addition, both of these dust and air pollution clouds can transport swiftly across the Pacific reaching North America within a few days, possessing an even larger scale effect. The Asian dust and air pollution aerosols can be detected by its colored appearance on current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and its evolution monitored by satellites and surface network. Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3,Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth- atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth's radiation and water budget. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds from the soil to the atmosphere; the hydrological cycle (i.e., run off and evaporation); land surface reflectivity and emissivity; as well as ecosystem biodiversity and stability. Two new initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented and discussed their contribution to better understand the impacts of aerosols on regional-to- global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, Si-Chee↗
NASA NTRS2004

Biomass-Burning Aerosols in South East-Asia: Smoke Impact Assessment (BASE-ASIA)

Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth- atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth s radiation and water budget. Analyses from satellite measurements reveal the reflected solar (emitted thermal) radiation from clouds due to smoke aerosols can be reduced (enhanced) by 100 (20) Watts per square meter over the month of March 2000. In addition, the reduction in cloud spectral reflectance is large enough to lead to significant errors in satellite retrievals of cloud properties (e.g., optical thickness and effective radius). The fresh water distribution in this region is highly dependent on monsoon rainfall; in fact, the predictability of the tropical climate system is much reduced during the boreal spring. Therefore, to accurately assess the impact of smoke aerosols in this region requires continuous observations from satellites, aircraft, ground-based networks and dedicated field experiments. BASE-ASIA initiative has been proposed and will be discussed.

Tsay, S.-C.↗
NASA NTRSDate not supplied

The Equilibrium Response of Climate and Composition to Lightning

Climate change can affect atmospheric composition through perturbation of natural processes, leading to complex feedbacks. The primary atmospheric oxidants OH and ozone are very sensitive to emissions of nitrogen oxides (NO x ) from lightning, and therefore so are the subsequent chemical perturbations to long-lived greenhouse gases (e.g., methane) and aerosol chemistry and physics. Meanwhile, cloud electrification responds to both meteorology and composition (aerosol particles). Key to understanding the ultimate impact of lightning on air quality and climate is the long-term methane feedback. Here, we present simulations from the GISS ModelE2.1 chemistry-climate model in which we isolate the response of Earth’s radiative budget and composition to lightning NO x in the present day and at the end of this century by allowing the model to re-equilibrate following removal of the source. Whereas lightning initially contributes to surface ozone enhancements, longer-term responses amplified by the methane lifetime feedback reduce surface ozone on multi-decadal time scales in the northern midlatitudes. Lightning consequently contributes a strong negative radiative effect in the present day (-0.5 W m -2 ), stronger than that estimated for the anthropogenic NOx source. In addition to influencing tropospheric composition, we find significant changes in stratospheric dynamics and composition. We test the sensitivity of our results to multiple parameterizations for global lightning activity.

Lightning↗
DOE OSTI2019

Process-oriented evaluation using ARM observations to improve clouds and radiation in a global atmospheric model

The goal of the research is to improve understanding of cloud, radiation and precipitation processes and their representation in numerical models for weather and climate using observations from the ARM/ASR program. Global models need to represent all cloud types across different weather regimes from the tropics to the poles and ARM provides long-term observations at different geographical sites that cover these different regimes. Combined with satellite data to give a global context, the observations are used to evaluate the systematic errors in a global model for predictions of cloud, radiation and precipitation. The focus is on understanding the links to underlying physical processes to pinpoint the sources of error and improve the model representation of these processes. The research covers boundary layer cloud over the continental U.S., marine stratocumulus and shallow cumulus in the subtropics, mixed-phase clouds over the Arctic and Southern Ocean, and high-altitude cirrus ice clouds in the tropics. The model used is the operational global weather prediction system at the European Centre for Medium-range Weather Forecasts (ECMWF). The research has led to numerous developments, several of which have been implemented operationally leading to improvements in everyday forecasts. Many of the systematic errors are common across different modelling systems and the wider implications from the research for other weather and climate models are highlighted.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2019

Summary and Highlights of the SPARC-Reanalysis Intercomparison Project

The climate research community uses global atmospheric reanalysis data sets to understand a wide range of processes and variability in the atmosphere; they are a particularly powerful tool for studying phenomena that cannot be directly observed. Different reanalyses may give very different results for the same diagnostics. The Stratosphere troposphere Processes And their Role in Climate (SPARC) Reanalysis Intercomparison Project (S-RIP) is a coordinated activity to compare key diagnostics that are important for stratospheric processes and their tropospheric connections among available reanalyses. S-RIP has been identifying differences among reanalyses and their underlying causes, providing guidance on appropriate usage of reanalysis products in scientific studies (particularly those of relevance to SPARC), and contributing to future improvements in the reanalysis products by establishing collaborative links between reanalysis centres and data users. S-RIP emphasizes diagnostics of the upper troposphere, stratosphere, and lower mesosphere. The draft S-RIP final report is expected to be completed in 2018. This poster gives a summary of the S-RIP project and presents highlights including results on the Brewer-Dobson circulation, stratosphere/troposphere dynamical coupling, the extra-tropical upper troposphere / lower stratosphere, the tropical tropopause layer, the quasi-biennial oscillation, lower stratospheric polar processing, and the upper stratosphere/lower mesosphere.

Fujiwara, M.↗
DOE OSTI2025

Rapid scalable plasma processing of thin-film Li–La–Zr–O solid-state electrolytes

Solid-state electrolytes, such as lithium lanthanum zirconium oxide (LLZO), show promise as technologies for next-generation high-energy-density batteries, but commercial development has been hindered by a lack of scalable processing methods. Current fabrication methods are costly or require long annealing steps to create dense films. We report an atmospheric pressure blown-arc nitrogen plasma jet process to rapidly form sub-micrometer-thick, dense amorphous LLZO (a-LLZO) films from sol-gel precursors. Films are processed in less than 2 min, an order of magnitude faster than what has previously been reported. We demonstrate 500-nm-thick a-LLZO films processed at 350°C with an ionic conductivity of 2 × 10 −6 S/cm at 30°C and 2 × 10 −3 S/cm at 100°C and a conductance of 19 S at 100°C, the highest conductance of any LLZO phase to date. Here, the films exhibit outstanding smooth surface morphology with low defectivity, advancing atmospheric plasma processing as a scalable processing method for solid-state electrolytes.

25 ENERGY STORAGE↗
DOE OSTI2022

All-atmospheric fabrication of Ag–Cu core–shell nanowire transparent electrodes with Haacke figure of merit >600 × 10–3 Ω−1

Abstract Transparent conducting electrodes (TCEs) are essential components in devices such as touch screens, smart windows, and photovoltaics. Metal nanowire networks are promising next-generation TCEs, but best-performing examples rely on expensive metal catalysts (palladium or platinum), vacuum processing, or transfer processes that cannot be scaled. This work demonstrates a metal nanowire TCE fabrication process that focuses on high performance and simple fabrication. Here we combined direct and plating metallization processes on electrospun nanowires. We first directly metallize silver nanowires using reactive silver ink. The silver catalyzes subsequent copper plating to produce Ag–Cu core–shell nanowires and eliminates nanowire junction resistances. The process allows for tunable transmission and sheet resistance properties by adjusting electrospinning and plating time. We demonstrate state-of-the-art, low-haze TCEs using an all-atmospheric process with sheet resistances of 0.33 Ω sq −1 and visible light transmittances of 86% (including the substrate), leading to a Haacke figure of merit of 652 × 10 –3 Ω −1 . The core–shell nanowire electrode also demonstrates high chemical and bending durability.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Safety-Enclosure System For MOCVD Process Chamber

Safety-enclosure system filled with nitrogen surrounds reaction chamber in which metallo-organic chemical vapor deposition (MOCVD) performed. Designed to protect against explosions and/or escaping toxic gases and particulates. Gas-purification subsystem ensures during loading and unloading of process materials, interior of MOCVD chamber exposed to less than 1 ppm of oxygen and less than 5 ppm of water in nitrogen atmosphere. Toxic byproducts of MOCVD process collected within inert atmosphere. Enclosure strong enough to contain any fragments in unlikely event of explosion.

Singletery, James, Jr.↗
DOE OSTI2022

Uptake and speciation of trace metal inputs to Wetland Soils from Illinois and South Carolina and Stream Sediments from Tennessee

Metals occur in all ecosystems, although their concentrations vary depending on their natural geologic conditions and surrounding human activities. In addition to metals intrinsically present from the geology of a particular system, metals can enter environmental systems from a wide variety of natural and anthropogenic sources, such as sediment re-suspension, mining operations, industrial processes, agricultural activities, and atmospheric deposition. While metals can be toxic at high concentrations, some metals serve as essential micronutrients for biogeochemical processes. Metal transport and availability in engineered and natural water systems depend on processes of adsorption/desorption, oxidation/reduction, dissolution/precipitation, and ligand complexation. Insights into the speciation of metals and their bioavailability will also help advance understanding of the roles of metals in the biogeochemical cycling of nutrients. We conducted batch experiments under anoxic conditions on soils and sediments collected from three different natural aquatic systems to understand their response to influxes of dissolved Cu, Ni and Zn. While soils and sediments from all sites could strongly bind added trace metals, there were substantial differences in trace metal uptake trends between different sites, especially for Cu. There was no distinct correlation between trace metal uptake and the total organic matter, iron, and sulfur content present in the samples. X-ray absorption spectroscopy indicated that the speciation of the freshly added metals taken up by the solids differs substantially from the speciation of the metals originally present in unamended samples. Cu sulfides dominated speciation at low loadings (1 µmol/g), whereas complexation to thiol groups and formation of metallic Cu governed speciation at high loadings (10 µmol/g). For Ni and Zn, adsorption to mineral surfaces and organic matter governed their speciation in materials from most sites. This study suggests that the background speciation of metals in natural aquatic systems is a poor predictor of the speciation and lability of metals introduced to terrestrial aquatic systems from anthropogenic or natural processes. Our findings imply that geochemical processes controlling trace metal speciation may vary considerably with metal loading in different natural systems. Data are provided for marsh wetland soils at Argonne National Laboratory (Marsh 1 and Marsh 2), riparian wetland soils (Riparian 1 and Riparian 2) in the Tims Branch watershed at Savannah River National Laboratory, and stream bed sediments (Stream 1 and Stream 2) from East Fork Poplar Creek near Oak Ridge National Laboratory. Data package includes the results of trace metal uptake experiments conducted on the selected sites for determining their capacity to immobilize metals under different loadings. XANES spectra for Cu, Ni, ad Zn at different loadings are included in the package. The abundance of different trace metal species obtained using linear combination fitting in ATHENA are also included in the data.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1975

Interactive image processing for meteorological applications at NASA/Goddard Space Flight Center

The meteorological data processing program at the space center is centered on the analysis of geostationary satellite data. Its objectives are to detect and predict severe storms, to improve short range and long range global numerical weather forecasting models, and to develop improved satellite systems. The Image Display and Manipulation System (IDAMS) for earth resources satellite data processing is described, as is the special purpose software package, METPAK, for performing meteorology operations on IDAMS. The Atmospheric and Oceanographic Information Processing System (AOIPS), a dual terminal multiprocessor is also described.

Billingsley, J. B.↗
NASA NTRS1976

Mars - Chemical weathering as a massive volatile sink

The amounts of volatiles incorporated in the Martian regolith by photostimulated oxidation weathering of Fe(2+)-bearing minerals are estimated. The process of photostimulated oxidation weathering is described, and it is noted that all the necessary constituents for this process are present on Mars. The rates at which oxygen and hydrogen are irreversibly removed from the Martian atmosphere by the present process are determined, irreversible and reversible water losses are considered, and the loss of CO2 by carbonate formation is shown to be irreversible. The results suggest that photostimulated oxidation weathering has irreversibly consumed 100 to 100,000 g/sq cm of H2O and 10 to 10,000 g/sq cm of CO2, assuming a uniform rate over geologic time. It is concluded that if the amounts of H2O and CO2 actually removed by photostimulated oxidation are close to the upper limits of the present estimates, then that process may have had a major effect in limiting the amount of H2O and CO2 trapped in the regolith and polar caps.

Huguenin, R. L.↗
NASA NTRS1981

The structure of chromospheres around late-type giants and supergiants

Observations alpha Tau (K5III) and beta Gru (M2II) made at high resolution are used to confirm line identifications of features blended at low resolution. The high resolution spectra allow selected pairs of lines to be used to find the electron density and the opacity. Methods for determining these factors and the usual emission measure are presented. The electron density and opacity can be used together with the emission measure to place constraints on the structure of the atmosphere. The line formation processes are briefly discussed. Photo-excitation by strong lines appears to be important in these late type atmospheres.

Brown, A.↗