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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,495 records · Page 83
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Toward More Efficient Organic Solar Cells: A Detailed Study of Loss Pathway and Its Impact on Overall Device Performance in Low‐Offset Organic Solar Cells

Abstract Low‐offset organic solar cell systems have attracted great interest since nonfullerene acceptors came into the picture. While numerous studies have focused on the charge generation process in these low‐offset systems, only a few studies have focused on the details of each loss channel in the charge generation process and their impact on the overall device performance. Here, several nonfullerene acceptors are blended with the same polymer donor to form a series of low‐offset organic solar cell systems where significant variation in device performance is observed. Through detailed analyses of loss pathways, it is found that: i) the donor:acceptor interfaces of PM6:Y6 and PM6:TPT10 are close to the optimum energetic condition, ii) energetics at the donor:acceptor interface are the most important factor to the overall device performance, iii) exciton dissociation yield can be field‐dependent owing to the sufficiently small energetic offset at the donor:acceptor interface, and iv) the change in substituents in the terminal group of Y‐series acceptors in this work mainly affects energetics at the donor:acceptor interface instead of the interface density in the active layer. In general, this work presents a path toward more efficient organic solar cells.

14 SOLAR ENERGY↗
DOE OSTI2021

Acceleration of Oxygen Ions in Dipolarization Events: 1. CPS Distributions

Abstract Using an MHD simulation of near tail reconnection associated with a flow burst and the collapse (dipolarization) of the inner tail in combination with test particle tracing we study the acceleration and flux increases of energetic oxygen ions (O + ). The characteristic orbits, distributions, and acceleration mechanisms are governed by the dimensionless parameter σ = ω ci t n , where ω ci is the ion gyro frequency and t n a characteristic Alfvén time of the MHD simulation. For σ < 1, central plasma sheet (CPS) populations after the passage of the dipolarization front are found to resemble half‐shells in velocity space oriented toward dusk. They originate from within the CPS and are energized typically by a single encounter of the region of enhanced cross‐tail electric field associated with the flow burst. For larger σ values ( σ > 1) the O + distributions resemble more closely those of protons, consisting of two counter‐streaming field‐aligned beams and an, albeit more tenuous and irregular, ring population perpendicular to the magnetic field. The existence of the beams, however, depends on suitable earthward moving source populations in the plasma sheet boundary layer or the adjacent lobes. The acceleration to higher energies is found to indicate a charge dependence, consistent with a dominance of more highly charged ions at energies of a few hundred keV. As in earlier simulations, the simulated fluxes show large anisotropies and nongyrotropic effects, phase bunching, and spatially and temporally localized beams.

Birn, J.↗
NASA NTRS1998

An Analysis of Thrust Normalization of Ground Flowfield Pressures, Temperatures, and Velocities, for an AV-8B -408 Harrier During Hover

An external environment test for an AV-8B Harrier during hover and vertical operations was conducted at NAWCAD at Patuxent River, Maryland in July 1997. Four boundary layer rakes were instrumented with static and total pressures, and thermocouples for measuring temperatures. These rakes were installed at 30, 50, 75, and 100 foot from the hover center. The 50 ft and 100 ft rakes were offset 20 deg from the other two to minimize interference effects. In order to measure a complete flowfield footprint, it was necessary to have the Harrier change its heading relative to the rakes from 0 to 180 deg. A 20 deg increment in azimuth was used. This permitted the four rakes to measure the flowfield at 72 locations relative to the aircraft. However, as the Harrier burns fuel, the hover thrust must be reduced by the pilot in order to maintain a constant height above ground. The typical test procedure employed was: (1) vertical takeoff at an initial heading; (2) 20 second hover dwell at that heading; (3) pedal turn to a second heading, followed by a 20 second dwell hover; (4) pedal turn to a third heading, followed by a 20 second dwell hover; and (5) vertical landing at the third heading. Additional information is contained in the original extended abstract.

Naumowicz, Tim↗
DOE OSTI2021

Effects of Al:Si and (Al+Na):Si ratios on the static corrosion of sodium‐boroaluminosilicate glasses

Abstract Understanding alteration mechanisms of borosilicate glasses in aqueous media is essential to nuclear waste performance assessments to ensure radioisotopes are contained for extended durations. Aluminum is typically added to glass compositions to reduce the extent of alteration. However, previous work on 7‐day durability tests has suggested that Al has a nonlinear relationship with extent of alteration. The effects of Al:Si and (Al+Na):Si substitutions on glass durability were evaluated using series of glasses based on the International Simple Glass corroded in static conditions up to 13 months in deionized water at 90°C. The alteration behavior was determined by measurement of element release in solution. The ⁓7‐day alteration trends across the series were consistent with predicted trends. The 13‐month results indicated overall alteration decreased as Al:Si ratios increased and was unaffected by changes in (Al+Na):Si except for the glass with the highest (Al+Na):Si ratio (ISG‐A23N), which completely altered within 14 days. Frequent sampling and in situ Raman measurements of solutions revealed ISG‐A23N experienced several distinguishable alteration rate regimes within 7 days, forming a ⁓100 µm alteration layer and a NaSiAlO 4 zeolite.

Reiser, Joelle T.↗
DOE OSTI2024

Operando Investigation of the Molecular Origins of Dipole Switching in P(VDF‐TrFE‐CFE) Terpolymer for Large Adiabatic Temperature Change

Abstract Relaxor ferroelectric polymers exhibiting a giant electrocaloric effect (ECE) can potentially be used to create next‐generation solid‐state coolers. Under an electric field, poly(vinylidene fluoride‐trifluoroethylene‐chlorofluoroethylene) terpolymer goes through a large dipolar entropy change producing a high adiabatic temperature change (Δ T ECE ). This work resolves the molecular origins of the large entropy change behind the electric field‐induced dipole switching. A Fourier transform infrared spectroscopy equipped with a high voltage source is used to operandoly observe the characteristic molecular vibrational modes. A short‐range trans (T) conformation of the CF 2 ‐CH 2 dyads interrupted by a gauche (G) conformation, e.g., TTTG in the terpolymer chain, undergoes a dynamic transformation that leads to a corresponding Δ T ECE whenever an electric field is applied. The molecular dynamics simulation also proves that the energy barrier that the transformation from TTTGs into a long T sequence overcomes is smaller than that for all other conformations. A mixed solvent system is used to obtain T3G‐enriched terpolymer films exhibiting a 4.02 K Δ T ECE at 60 MV m −1 and these films are employed to manufacture a 2‐layer‐cascaded cooling device that achieves a 6.7 K temperature lift, the highest reported value for a 2‐layer cascaded device made of fluoropolymers.

Zhu, Yuan↗
NASA NTRS1995

(abstract) Variations in Polarimetric Backscatter of Saline Ice Grown Under Diurnal Thermal Cycling Condition

An experiment was carried out in January 1994 at the Geophysical Research Facility in the Cold Regions Research and Engineering Laboratory. To investigate effects on polarimetric scattering signatures of sea ice growth under diurnal temperature variations, an ice sheet was grown for 2.5 days for the thickness of 10 cm and a polarimetric radar operating at C-band was used to obtain backscattering data in conjunction with ice-characterization measurements. The ice sheet was grown in the late morning of January 19, 1994. The initial growth rate was slow due to high insolation and temperature. As the air temperature dropped during the night, the growth rate increased significantly. The air temperature changed drastically from about -10(deg)C to -35(deg)C between day and night. The temperature cycle was repeated during the next day and the growth rate varied in the same manner. The surface of the ice was partially covered by frost flowers and the areal coverage increased as the ice became thicker. Throughout the ice growth duration of 2.5 days, polarimetric backscatter data were collected at roughly every centimeter of ice growth. For each set of radar measurements of saline ice, a set of calibration measurements was carried out with trihedrial corner reflectors and a metallic sphere. Measured polarimetric backscattering coefficients of the ice sheet reveal a strong correlation between radar data and temperature variations. As the temperature increased (decreased), the backscatter increased (decreased) correspondingly. From the ice-characterization data, temperatures of the air, at the ice-air interface, and in the ice layer had the same variation trend. Another interesting experimental observation is that the salinity measured as a function of ice depth from a sample of 10-cm thich ice indicated that the salinity variations had a similar cycle as the temperature; i.e., the salinity profile recorded the history of the temperature variations. Characterization data of the ice sheet are used in a theoretical model for scattering from saline ice with frost cover to explain the observed polarimetric signatures.

characterization polarimetric radar salinity tempe↗
DOE OSTI2021

Electrolytes Polymerization‐Induced Cathode‐Electrolyte‐Interphase for High Voltage Lithium‐Ion Batteries

Abstract Lithium‐ion batteries (LIBs) based on LiNi x Co y Mn 1‐x‐y O 2 (NCM) cathode materials have been widely commercialized, because of their high energy density, favorable rate performance, and relatively low cost. However, with increased Ni content to further increase their energy density, their cycling stability deteriorates dramatically and thus fails to meet the commercial application requirements. The artificial cathode‐electrolyte‐interphase (CEI) is a promising approach to solve this problem. Here, a robust CEI is fabricated through in situ polymerization of ethylene carbonate induced by aluminum isopropoxide (AIP). By adding 1 wt.% AIP in a commercial electrolyte, the capacity retention of LiNi 0.8 Co 0.1 Mn 0.1 O 2 ||Li cell at 1 C rate has been significantly increased from 80.8% to 97.8% with a highly reversible capacity of 176 mA h g −1 after 200 cycles. AIP can be also used as an additive during the slurry‐making process, enabling a reversible capacity of 170 mA h g −1 for LiCoO 2 after 200 cycles even at a high charge cut‐off voltage of 4.6 V. It is confirmed that the in situ formed CEI layer can prevent the cathodes from cracking and reduce the irreversible phase transformation.

Yang, Jixiang↗
DOE OSTI2021

Assimilation of a Coordinated Fleet of Uncrewed Aircraft System Observations in Complex Terrain: EnKF System Design and Preliminary Assessment

Abstract Uncrewed aircraft system (UAS) observations collected during the 2018 Lower Atmospheric Process Studies at Elevation—a Remotely Piloted Aircraft Team Experiment (LAPSE-RATE) field campaign were assimilated into a high-resolution configuration of the Weather Research and Forecasting Model using an ensemble Kalman filter. The benefit of UAS observations was assessed for a terrain-driven (drainage and upvalley) flow event that occurred within Colorado’s San Luis Valley (SLV) using independent observations. The analysis and prediction of the strength, depth, and horizontal extent of drainage flow from the Saguache Canyon and the subsequent transition to upvalley and up-canyon flow were improved relative to that obtained both without data assimilation (benchmark) and when only surface observations were assimilated. Assimilation of UAS observations greatly improved the analyses of vertical variations in temperature, relative humidity, and winds at multiple locations in the northern portion of the SLV, with reductions in both bias and the root-mean-square error of roughly 40% for each variable relative to the benchmark run. Despite these noted improvements, some biases remain that were tied to measurement error and/or the impact of the boundary layer parameterization on vertically spreading the observations, both of which require further exploration. The results presented here highlight how observations obtained with a fleet of profiling UAS improve limited-area, high-resolution analyses and short-term forecasts in complex terrain.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Towards a Unified Setup to Simulate Mid‐Latitude and Tropical Mesoscale Convective Systems at Kilometer‐Scales

Abstract Mesoscale convective systems (MCSs) are the main source of precipitation in the tropics and parts of the mid‐latitudes and are responsible for high‐impact weather worldwide. Studies showed that deficiencies in simulating mid‐latitude MCSs in state‐of‐the‐art climate models can be alleviated by kilometer‐scale models. However, whether these models can also improve tropical MCSs and whether we can find model settings that perform well in both regions is understudied. We take advantage of high‐quality MCS observations collected over the Atmospheric Radiation Measurement (ARM) facilities in the US Southern Great Plains (SGP) and the Amazon basin near Manaus (MAO) to evaluate a perturbed physics ensemble of simulated MCSs with 4 km horizontal grid spacing. A new model evaluation method is developed that enables to distinguish biases stemming from spatiotemporal displacements of MCSs from biases in their reflectivity and cloud shield. Amazon MCSs are similarly well simulated across these evaluation metrics than SGP MCSs despite the challenges anticipated from weaker large‐scale forcing in the tropics. Generally, SGP MCSs are more sensitive to the choice of model microphysics, while Amazon cases are more sensitive to the planetary boundary layer (PBL) scheme. Although our tested model physics combinations had strengths and weaknesses, combinations that performed well for SGP simulations result in worse results in the Amazon basin and vice versa. However, we identified model settings that perform well at both locations, which include the Thompson and Morrison microphysics coupled with the Yonsei University (YSU) PBL scheme and the Thompson scheme coupled with the Mellor‐Yamada‐Janjic PBL scheme.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Highly Stable and Conductive 1,3‐Dioxolane/Hydrocarbon Based Electrolyte Solvent for Advanced Lithium‐Sulfur Batteries

Abstract Developing effective electrolytes is crucial for boosting the performance of Lithium‐Sulfur (LiS) rechargeable battery. Recent improvements in electrolyte formulations have enhanced cyclability by increasing electrochemical stability at the electrode interfaces. However, achieving both high ionic conductivity (σ) and stability at these interfaces simultaneously remains a significant challenge. In this study, we utilized a strategy to suppress polysulfide dissolution by employing a mixture of 1,3‐dioxolane (DOL) and hydrocarbon solvents with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) electrolyte salt. Compared to the conventional electrolyte solution, which is 1 M LiTFSI salt in a 50/50 vol % mixture of DOL and dimethoxy ethane (DME), the LiTFSI electrolyte with DOL/hydrocarbon solvents demonstrate better cycling stability, compatibility with the Li‐metal anode, and a high specific discharge capacity (Csp). Among the various DOL/hydrocarbon and LiTFSI electrolyte salts, the combination of DOL and n‐hexane, a linear hydrocarbon, with LiTFSI electrolyte salt, (DnH40LiTFSI) exhibits remarkable σ (6.5×10 −3 S/cm at 30 °C), compatibility with the Li‐metal anode, an initial Csp of ca. 1264 mAh/g, cycling stability (Csp and Coulombic efficiency are 811 mAh/g and 98.09 % after 120 cycles) at 0.1 C by forming a good protective layer on the Li‐metal surface and preventing polysulfide dissolution.

Ahmed, Faiz↗
DOE OSTI2023

Inference of main ion particle transport coefficients with experimentally constrained neutral ionization during edge localized mode recovery on DIII-D

Abstract The plasma and neutral density dynamics after an edge localized mode are investigated and utilized to infer the plasma transport coefficients for the density pedestal. The Lyman-Alpha Measurement Apparatus (LLAMA) diagnostic provides sub-millisecond profile measurements of the ionization and neutral density and shows significant poloidal asymmetries in both. Exploiting the absolute calibration of the LLAMA diagnostic allows quantitative comparison to the electron and main ion density profiles determined by charge-exchange recombination, Thomson scattering and interferometry. Separation of diffusion and convection contributions to the density pedestal transport are investigated through flux gradient methods and time-dependent forward modeling with Bayesian inference by adaptation of the Aurora transport code and IMPRAD framework to main ion particle transport. Both methods suggest time-dependent transport coefficients and are consistent with an inward particle pinch on the order of 1 m s −1 and diffusion coefficient of 0.05 m 2 s −1 in the steep density gradient region of the pedestal. While it is possible to recreate the experimentally observed phenomena with no pinch in the pedestal, low diffusion in the core and high outward convection in the near scrape-off layer are required without an inward pedestal pinch.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Shallow Cumulus Entrainment Dynamics in a Sheared Environment

Abstract Vertical wind shear has long been known to tilt convective towers and reduce thermal ascent rates. The purpose of this study is to better understand the physical mechanisms responsible for reduced ascent rates in shallow convection. In particular, the study focuses on cloud-edge mass flux to assess how shear impacts mass-flux profiles of both the ensemble and individual clouds of various depths. A compositing algorithm is used to distill large-eddy simulation (LES) output to focus on up- and down-shear cloud edges that are not influenced by complex cloud geometry or nearby clouds. A direct entrainment algorithm is used to estimate the mass flux through the cloud surface. We find that the dynamics on the up- and down-shear sides are fundamentally different, with the entrainment of environmental momentum and dilution of buoyancy being primarily responsible for the reduced down-shear ascent rates. Direct estimates of fluid flow through the cloud interface indicate a counter-shear organized flow pattern that entrains on the down-shear side and detrains on the up-shear side, resulting from the subcloud shear being lifted into the cloud layer by the updraft. In spite of organized regions of entrainment and detrainment, the overall net lateral mass flux remains unchanged with respect to the no shear run, with weak detrainment present throughout cloud depth.

Meteorology & Atmospheric Sciences↗
DOE OSTI2021

Technical note: Uncertainties in eddy covariance CO 2 fluxes in a semiarid sagebrush ecosystem caused by gap-filling approaches

Abstract. Gap-filling eddy covariance CO2 fluxes is challenging at dryland sites due to small CO2 fluxes. Here, four machine learning (ML) algorithms including artificial neural network (ANN), k-nearest neighbors (KNNs), random forest (RF), and support vector machine (SVM) are employed and evaluated for gap-filling CO2 fluxes over a semiarid sagebrush ecosystem with different lengths of artificial gaps. The ANN and RF algorithms outperform the KNN and SVM in filling gaps ranging from hours to days, with the RF being more time efficient than the ANN. Performances of the ANN and RF are largely degraded for extremely long gaps of 2 months. In addition, our results suggest that there is no need to fill the daytime and nighttime net ecosystem exchange (NEE) gaps separately when using the ANN and RF. With the ANN and RF, the gap-filling-induced uncertainties in the annual NEE at this site are estimated to be within 16 g C m−2, whereas the uncertainties by the KNN and SVM can be as large as 27 g C m−2. To better fill extremely long gaps of a few months, we test a two-layer gap-filling framework based on the RF. With this framework, the model performance is improved significantly, especially for the nighttime data. Therefore, this approach provides an alternative in filling extremely long gaps to characterize annual carbon budgets and interannual variability in dryland ecosystems.

Yao, Jingyu↗
DOE OSTI2023

Linewidth narrowing in self-injection-locked on-chip lasers

Abstract Stable laser emission with narrow linewidth is of critical importance in many applications, including coherent communications, LIDAR, and remote sensing. In this work, the physics underlying spectral narrowing of self-injection-locked on-chip lasers to Hz-level lasing linewidth is investigated using a composite-cavity structure. Heterogeneously integrated III–V/SiN lasers operating with quantum-dot and quantum-well active regions are analyzed with a focus on the effects of carrier quantum confinement. The intrinsic differences are associated with gain saturation and carrier-induced refractive index, which are directly connected with 0- and 2-dimensional carrier densities of states. Results from parametric studies are presented for tradeoffs involved with tailoring the linewidth, output power, and injection current for different device configurations. Though both quantum-well and quantum-dot devices show similar linewidth-narrowing capabilities, the former emits at a higher optical power in the self-injection-locked state, while the latter is more energy-efficient. Lastly, a multi-objective optimization analysis is provided to optimize the operation and design parameters. For the quantum-well laser, minimizing the number of quantum-well layers is found to decrease the threshold current without significantly reducing the output power. For the quantum-dot laser, increasing the quantum-dot layers or density in each layer increases the output power without significantly increasing the threshold current. These findings serve to guide more detailed parametric studies to produce timely results for engineering design.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Search for extended Lyman-α emission around 9k quasars at z = 2–3

ABSTRACT Enormous Lyα nebulae (ELANe) around quasars have provided unique insights into the formation of massive galaxies and their associations with super-massive black holes since their discovery. However, their detection remains highly limited. This paper introduces a systematic search for extended Lyα emission around 8683 quasars at z = 2.34–3.00 using a simple but very effective broad-band gri selection based on the Third Public Data Release of the Hyper Suprime-Cam Subaru Strategic Program. Although the broad-band selection detects only bright Lyα emission (≳ 1 × 10−17 erg s−1cm−2 arcsec−2) compared with narrow-band imaging and integral field spectroscopy, we can apply this method to far more sources than such common approaches. We first generated continuum g-band images without contributions from Lyα emission for host and satellite galaxies using r- and i-bands. Then, we established Lyα maps by subtracting them from observed g-band images with Lyα emissions. Consequently, we discovered extended Lyα emission (with masked area >40 arcsec2) for 7 and 32 out of 366 and 8317 quasars in the Deep and Ultra-deep (35 deg2) and Wide (890 deg2) layers, parts of which may be potential candidates of ELANe. However, none of them seem to be equivalent to the largest ELANe ever found. We detected higher fractions of quasars with large nebulae around more luminous or radio-loud quasars, supporting previous results. Future applications to the forthcoming big data from the Vera C. Rubin Observatory will help us detect more promising candidates. The source catalogue and obtained Lyα properties for all the quasar targets are accessible as online material.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Reaction between Hydrogen and Ferrous/Ferric Oxides at High Pressures and High Temperatures—Implications for Sub-Neptunes and Super-Earths

Abstract Sub-Neptune exoplanets may have thick hydrogen envelopes and therefore develop a high-pressure interface between hydrogen and the underlying silicates/metals. Some sub-Neptunes may convert to super-Earths via massive gas loss. If hydrogen chemically reacts with oxides and metals at high pressures and temperatures ( P − T ), it could impact the structure and composition of the cores and atmospheres of sub-Neptunes and super-Earths. While H 2 gas is a strong reducing agent at low pressures, the behavior of hydrogen is unknown at the P − T expected for sub-Neptunes’ interiors, where hydrogen is a dense supercritical fluid. Here we report experimental results of reactions between ferrous/ferric oxides and hydrogen at 20–40 GPa and 1000–4000 K utilizing the pulsed laser-heated diamond-anvil cell combined with synchrotron X-ray diffraction. Under these conditions, hydrogen spontaneously strips iron off the oxides, forming Fe-H alloys and releasing oxygen to the hydrogen medium. In a planetary context where this reaction may occur, the Fe-H alloy may sink to the metallic part of the core, while released oxygen may stabilize as water in the silicate layer, providing a mechanism to ingas hydrogen to the deep interiors of sub-Neptunes. Water produced from the redox reaction can also partition to the atmosphere of sub-Neptunes, which has important implications for understanding the composition of their atmospheres. In addition, super-Earths converted from sub-Neptunes may contain a large amount of hydrogen and water in their interiors (at least a few wt% H 2 O). This is distinct from smaller rocky planets, which were formed relatively dry (likely a few hundredths wt% H 2 O).

58 GEOSCIENCES↗
DOE OSTI2024

Cloud water adjustments to aerosol perturbations are buffered by solar heating in non-precipitating marine stratocumuli

Abstract. Marine low-level clouds are key to the Earth's energy budget due to their expansive coverage over global oceans and their high reflectance of incoming solar radiation. Their responses to anthropogenic aerosol perturbations remain the largest source of uncertainty in estimating the anthropogenic radiative forcing of climate. A major challenge is the quantification of the cloud water response to aerosol perturbations. In particular, the presence of feedbacks through microphysical, dynamical, and thermodynamical pathways at various spatial and temporal scales could augment or weaken the response. Central to this problem is the temporal evolution in cloud adjustment, governed by entangled feedback mechanisms. We apply an innovative conditional Monte Carlo subsampling approach to a large ensemble of diurnal large-eddy simulation of non-precipitating marine stratocumulus to study the role of solar heating in governing the evolution in the relationship between droplet number and cloud water. We find a persistent negative trend in this relationship at night, confirming that the role of microphysically enhanced cloud-top entrainment. After sunrise, the evolution in this relationship appears buffered and converges to ∼-0.2 in the late afternoon. This buffering effect is attributed to a strong dependence of cloud-layer shortwave absorption on cloud liquid water path. These diurnal cycle characteristics further demonstrate a tight connection between cloud brightening potential and the relationship between cloud water and droplet number at sunrise, which has implications for the impact of the timing of advertent aerosol perturbations.

Zhang, Jianhao (ORCID:0000000169882935)↗