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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,495 records · Page 83
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Quenching in the Right Place at the Right Time: Tracing the Shared History of Starbursts, Active Galactic Nuclei, and Poststarburst Galaxies Using Their Structures and Multiscale Environments

This work uses multiscale environments and the structures of galaxies in the Sloan Digital Sky Survey as consistency checks on the evolution from starburst to quiescence at redshift z < 0.2. The environmental indicators include fixed-aperture mass overdensities (δ xMpc , x ϵ {0.5, 1, 2, 4, 8} h –1 Mpc), k-nearest neighbor distances, the tidal parameter, halo mass (M h ), and satellite/central classification. The residuals of the specific star formation rates (Δ SSFRs) are used to select starbursts (ΔSSFR > 0.6 dex, N ≈ 8600). Quenched poststarbursts (QPSBs) are selected using Hα < 3 Å emission and Hδ A > 4 Å absorption (N ≈ 750). The environments of starbursts and QPSBs are compared with those of active galactic nuclei (AGNs) and inactive galaxies of varying ΔSSFR. The environments of starbursts, AGNs, and QPSBs are unlike the environments of most quiescent galaxies (QGs). About 70%–90% of starbursts, AGNs with Hδ A > 4 Å, and QPSBs are centrals; ~80%–90% have M h < 10 13 M ⊙ , and only ~2%–4% have M h > 10 14 M ⊙ or live in clusters. Their M h and satellite fractions are also different from those of QGs. All QPSBs are matched to some SFGs, starbursts, AGNs, and QGs of similar M $\star$ , environments, concentration indices, and velocity dispersions. A significant fraction (~20%–30%) of starbursts cannot be matched to QPSBs or QGs. The implications are that: (1) some starbursts do not quench rapidly; (2) the satellite-quenching mechanisms operating in high-density environments cannot account for most QPSBs; (3) the evolution from starbursts to QPSBs to QGs is not the dominant path at z < 0.2; and (4) starbursts are not mainly triggered by tidal interactions.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1978

Prediction of solar energetic particle event histories using real-time particle and solar wind measurements

The comparatively well-ordered magnetic structure in the solar corona during the decline of Solar Cycle 20 revealed a characteristic dependence of solar energetic particle injection upon heliographic longitude. When analyzed using solar wind mapping of the large scale interplanetary magnetic field line connection from the corona to the Earth, particle fluxes display an approximately exponential dependence on heliographic longitude. Since variations in the solar wind velocity (and hence the coronal connection longitude) can severely distort the simple coronal injection profile, the use of real-time solar wind velocity measurements can be of great aid in predicting the decay of solar particle events. Although such exponential injection profiles are commonplace during 1973-1975, they have also been identified earlier in Solar Cycle 20, and hence this structure may be present during the rise and maximum of the cycle, but somewhat obscured by greater temporal variations in particle injection.

Roelof, E. C.↗
DOE OSTI2015

Simulation of multi-photon emission isotopes using time-resolved SimSET multiple photon history generator

Abstract-Multiple-photon emitters, such as In-111 or Se-75, have enormous potential in the field of nuclear medicine imaging. For example, Se-75 can be used to investigate the bile acid malabsorption and measure the bile acid pool loss. The simulation system for emission tomography (SimSET) is a well-known Monte Carlo simulation (MCS) code in nuclear medicine for its high computational efficiency. However, current SimSET cannot simulate these isotopes due to the lack of modeling of complex decay scheme and the time-dependent decay process. To extend the versatility of SimSET for simulation of those multi-photon emission isotopes, a time-resolved multiple photon history generator based on SimSET codes is developed in present study. For developing the time-resolved SimSET (trSimSET) with radionuclide decay process, the new MCS model introduce new features, including decay time information and photon time-of-flight information, into this new code. The half-life of energy states were tabulated from the Evaluated Nuclear Structure Data File (ENSDF) database. The MCS results indicate that the overall percent difference is less than 8.5% for all simulation trials as compared to GATE. To sum up, we demonstrated that time-resolved SimSET multiple photon history generator can have comparable accuracy with GATE and keeping better computational efficiency. The new MCS code is very useful to study the multi-photon imaging of novel isotopes that needs the simulation of lifetime and the time-of-fight measurements. (authors)

07 ISOTOPE AND RADIATION SOURCES↗
NASA NTRS1993

Computer program for analysis of high speed, single row, angular contact, spherical roller bearing, SASHBEAN. Volume 1: User's guide

The computer program SASHBEAN (Sikorsky Aircraft Spherical Roller High Speed Bearing Analysis) analyzes and predicts the operating characteristics of a Single Row, Angular Contact, Spherical Roller Bearing (SRACSRB). The program runs on an IBM or IBM compatible personal computer, and for a given set of input data analyzes the bearing design for it's ring deflections (axial and radial), roller deflections, contact areas and stresses, induced axial thrust, rolling element and cage rotation speeds, lubrication parameters, fatigue lives, and amount of heat generated in the bearing. The dynamic loading of rollers due to centrifugal forces and gyroscopic moments, which becomes quite significant at high speeds, is fully considered in this analysis. For a known application and it's parameters, the program is also capable of performing steady-state and time-transient thermal analyses of the bearing system. The steady-state analysis capability allows the user to estimate the expected steady-state temperature map in and around the bearing under normal operating conditions. On the other hand, the transient analysis feature provides the user a means to simulate the 'lost lubricant' condition and predict a time-temperature history of various critical points in the system. The bearing's 'time-to-failure' estimate may also be made from this (transient) analysis by considering the bearing as failed when a certain temperature limit is reached in the bearing components. The program is fully interactive and allows the user to get started and access most of its features with a minimal of training. For the most part, the program is menu driven, and adequate help messages were provided to guide a new user through various menu options and data input screens. All input data, both for mechanical and thermal analyses, are read through graphical input screens, thereby eliminating any need of a separate text editor/word processor to edit/create data files. Provision is also available to select and view the contents of output files on the monitor screen if no paper printouts are required. A separate volume (Volume-2) of this documentation describes, in detail, the underlying mathematical formulations, assumptions, and solution algorithms of this program.

Aggarwal, Arun K.↗
DOE OSTI2017

Electron Captures on {sup 14}N as a Trigger for Helium Shell Detonations

White dwarfs (WDs) that accrete helium at rates ∼10{sup −8} M{sub ⊙} yr{sup −1}, such as those in close binaries with sdB stars, can accumulate large (≳0.1 M{sub ⊙}) helium envelopes, which are likely to detonate. We perform binary stellar evolution calculations of sdB+WD binary systems with MESA, incorporating the important reaction chain {sup 14}N(e{sup −},ν){sup 14}C(α,γ){sup 18}O (NCO), including a recent measurement for the {sup 14}C(α,γ){sup 18}O rate. In large accreted helium shells, the NCO reaction chain leads to ignitions at the dense base of the freshly accreted envelope, in contrast to 3α ignitions, which occur away from the base of the shell. In addition, at these accretion rates, the shells accumulate on a timescale comparable to their thermal time, leading to an enhanced sensitivity of the outcome on the accretion rate history. Hence, time dependent accretion rates from binary stellar evolution are necessary to determine the helium layer mass at ignition. We model the observed sdB+WD system CD −30{sup ∘}11223 and find that the inclusion of these effects predicts ignition of a 0.153 M{sub ⊙} helium shell, nearly a factor of two larger than previous predictions. A shell with this mass will ignite dynamically, a necessary condition for a helium shell detonation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

The Physics of g-2

At any time in history, a few scientific measurements disagreed with the best theoretical predictions of the time. Currently, one such discrepancy involves the measurement of the strength of the magnetic field of a subatomic particle called a muon. In this video, Fermilab’s Dr. Don Lincoln explains this mystery and sketches ongoing efforts to determine if this disagreement signifies a discovery. If it does, this measurement will mean that we will have to rewrite the textbooks.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Layer Time Control for Large Scale Additive Manufacturing Using High Performance Computing

This work proposes to optimize an additive manufacturing AM process to reduce energy and printing cost. The polymer AM process is inherently dependent on the time-temperature history of each layer to maintain geometric tolerances and mechanical integrity. Our preliminary study shows that regression-based layer time control model using thermal images could result in up to 30% build time reduction for simple geometries. This proposed work would use high-performance computing (HPC) to couple the data-driven model with thermal simulation for better predicting layer temperature profiles, improving throughput of large-scale additive manufacturing, and reducing its energy cost. We have developed a method to optimize a layer deposition time (a.k.a. layer time) for large-scale AM via physics-based simulations. A long layer time leads to an over-cooled surface on which a new layer is deposited, and therefore, it may result in a weak bonding or debonding between layers, cracking, or warping. A short layer time leads to a high temperature of the structure due to insufficient cooling, and therefore, the structure may not be stiff enough and may collapse during manufacturing. Therefore, it is important to estimate the optimal layer time in additive manufacturing for a high-quality product. The temperature of a top layer right before deposition is recommended to be slightly higher than the glass temperature of the material. A temperature cooling was approximated to an exponential function of time, and the optimized layer time was obtained based on a target temperature while maintaining a minimal printing time. The material used is carbon fiber-reinforced polycarbonate (CF/PC), and the large-scale deposition system used is LSAM TM from Thermwood Corporation. Three different layer time cases were used for experiments, and a series of thermal images were obtained via an infra-red (IR) camera during the entire AM processes. AM process simulations were performed using a finite element method and the temperature profiles from the simulation were in good agreements with those from experiments. The layer time optimization was performed based on the temperature profiles from the simulations. A layer temperature with the optimal layer time was confirmed as the target temperature through simulation. In addition to the development of a layer time optimization method, we have developed a numerical framework for AM simulation with element activations in sync with toolpath, based on an open source finite element framework, DEAL.II. A major portion of this work was presented at SAMPE 2022 Conference and Exhibition on May 2022, and published in Proceedings of SAMPE 2022.

42 ENGINEERING↗
NASA NTRS2001

Continued Investigations of the Accretion History of Extraterrestrial Matter over Geologic Time

This grant supported our ongoing project to characterize the accretion rate of interplanetary dust particles (IDPs) to Earth over geologic time using He-3 as a tracer. IDPs are derived from collisions in the asteroid belt and from disaggregation of active comets. Owing to their small size (few to few hundred micrometers diameter) these particles spiral into the sun under Poynting-Robertson drag typically in less than a few tens of kyrs. Thus IDPs must be continually resupplied to the zodiacal cloud, and because the processes of IDP production are likely to be sporadic, time variation in the IDP accretion rate to Earth is likely to be time-varying. For example, major asteroidal collisions and comet showers should greatly enhance the IDP accretion rate. Our ultimate objective (still ongoing) is to document this time variance so as to better understand the history of the solar system, the source of IDPs accreting to Earth, and the details of the mechanism by which particles are captured by Earth. To document variations in IDP accretion rate through time we use He-3 as a tracer. This isotope is in extremely low abundance in terrestrial matter, but IDPs have very high concentrations of He-3 from implantation of solar wind ions. By measuring He-3 in seafloor sediments, we can estimate the IDP accretion rate for at least the last few hundred Myrs. Under an earlier NASA grant we identified the existence of a large increase in He-3 flux in the Late Eocene (35 Myr ago), coincident with the two largest impact craters of the Cenozoic Era. The simplest interpretation of this observation is the occurrence of a shower of long period comets at that time, simultaneously increasing the impact cratering probability and accretion rate of IDPs to Earth (Farley et al., 1998). Comet showers produced by stellar perturbation of the Oort cloud should be fairly common in the geologic record, so this is not an unreasonable interpretation of our observations.

Farley, Kenneth↗
NASA NTRS1992

Distribution in magnetotail of O(+) ions from cusp/cleft ionosphere - A possible substorm trigger

The transport of O(+) ions from the cusp/cleft ionosphere to the magnetotail during highly disturbed times was determined by computing the guiding-center trajectories of the ions to a distance of 6 R(E) from the ionosphere and the full-motion trajectories at later times. Case histories were tallied in six planes perpendicular to the X(GSM) axis, three planes perpendicular to the Y(GSM) axis, and in the center plane of the tail. At various times relative to the enhancement of the convection electric field, the following ion properties were constructed from the case histories: number density, mean energy, energy and pitch angle distributions of the flux, and ion pressure components parallel and perpendicular to the magnetic field. It was found that, after about 1.7 hours, the ion flux in the near-earth magnetotail increased dramatically and the spectrum hardened, much as observed during periods just preceding substorms. This increase is attributed to (1) the increase in the O(+) outflux from the ionosphere, (2) the increased energization of the ions by the convection electric field, and (3) ion trapping, which generally occurs because the ion magnetic moments generally increase after the ions first cross the geomagnetotail center plane.

Cladis, J. B.↗
NASA NTRS1984

Postprocessing for the UCLA climate model

Postprocessing programs written to analyze the results of a general circulation model are described. The model history data is interpolated to pressure surfaces, converted from 64-bit Cyber words to 32 bit IBM words, and transferred to tape for further analysis. The time average program reads the interpolation output tape and produces 15-day time averages. The model outputs a very detailed record for selected grid points. This data is sent to a tape in Cyber full words. The conversion program changes the format of the tape from 64 bit Cyber words to 32 bit IBM words, processing a month of data at a time. The grid-point history sorting program inputs the converted grid point history tape and sorts it by time. The end product is a tape with a time history of each field for every point. After the PBP data has been stored, it can be plotted. The plotting package is flexible, and allows the choice of fields and grid points. The one-dimensional fields are plotted as functions of time, and a daily summary is also produced. For the two-dimensional fields, time-height cross sections and daily summaries are produced. The model plotting package produces plots for all fields on the time average and pressure tapes. These plots include world maps, polar projections, zonal means, vectors, streamlines, and latitude-height plots.

Abeles, J.↗
DOE OSTI2020

Time of flight and supernova progenitor effects on the neutrino halo

We argue that the neutrino halo, a population of neutrinos that have undergone direction-changing scattering in the stellar envelope of a core-collapse supernova (CCSNe), is sensitive to neutrino emission history through time of flight. In this work, we show that the constant time approximation, commonly used in calculating the neutrino halo, does not capture the spatiotemporal evolution of the halo neutrino population and that correcting for time of flight can produce conditions which may trigger fast neutrino flavor conversion. We also find that there exists a window of time early in all CCSNe where the neutrino halo population is sufficiently small that it may be negligible. This suggests that collective neutrino oscillation calculations which neglect the halo may be well founded at sufficiently early times.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2017

The Effects of Vegetative Type, Edges, Fire History, Rainfall and Management in Fire-Maintained Ecosystems

The combined effects of repeated fires, climate, and landscape features (e.g., edges) need greater focus in fire ecology studies, which usually emphasize characteristics of the most recent fire and not fire history. Florida scrub-jays are an imperiled, territorial species that prefer medium (1.2-1.7 m) shrub heights. We measured short, medium, and tall habitat quality states annually within 10 ha grid cells that represented potential territories because frequent fires and vegetative recovery cause annual variation in habitat quality. We used multistate models and model selection to test competing hypotheses about how transition probabilities between states varied annually as functions of environmental covariates. Covariates included vegetative type, edges, precipitation, openings (gaps between shrubs), mechanical cutting, and fire characteristics. Fire characteristics not only included an annual presenceabsence of fire covariate, but also fire history covariates: time since the previous fire, the maximum fire-free interval, and the number of repeated fires. Statistical models with support included many covariates for each transition probability, often including fire history, interactions and nonlinear relationships. Tall territories resulted from 28 years of fire suppression and habitat fragmentation that reduced the spread of fires across landscapes. Despite 35 years of habitat restoration and prescribed fires, half the territories remained tall suggesting a regime shift to a less desirable habitat condition. Measuring territory quality states and environmental covariates each year combined with multistate modeling provided a useful empirical approach to quantify the effects of repeated fire in combinations with environmental variables on transition probabilities that drive management strategies and ecosystem change.

Breininger, David R.↗
NASA NTRS2018

The Effects of Vegetative Type, Edges, Fire History, Rainfall and Management in Fire-Maintained Habitat

The combined effects of fire history, climate, and landscape features (e.g., edges) on habitat specialists need greater focus in fire ecology studies, which usually only emphasize characteristics of the most recent fire. Florida scrub-jays are an imperiled, territorial species that prefer medium (1.2-1.7 m) shrub heights, which are dynamic because of frequent fires. We measured short, medium, and tall habitat quality states annually within 10 ha grid cells (that represented potential territories) because fires and vegetative recovery cause annual variation in habitat quality. We used multistate models and model selection to test competing hypotheses about how transition probabilities vary between states as functions of environmental covariates. Covariates included vegetative type, edges (e.g., roads, forests), precipitation, openings (gaps between shrubs), mechanical cutting, and fire characteristics. Fire characteristics not only included an annual presence/absence of fire covariate, but also fire history covariates: time since the previous fire, the longest fire-free interval, and the number of repeated fires. Statistical models with support included many covariates for each transition probability, often including fire history, interactions and nonlinear relationships. Tall territories resulted from 28 years of fire suppression and habitat fragmentation that reduced the spread of fires across landscapes. Despite 35 years of habitat restoration and prescribed fires, half the territories remained tall suggesting a regime shift to a less desirable habitat condition. Edges reduced the effectiveness of fires in setting degraded scrub and flatwoods into earlier successional states making mechanical cutting an important tool to compliment frequent prescribed fires.

Breininger, David R.↗
DOE OSTI2015

Complex rheological behaviors of loach (Misgurnus anguillicaudatus) skin mucus

The functions and structures of biological mucus are closely linked to rheology. In this article, the skin mucus of loach (Misgurnus anguillicaudatus) was proved to be a weak hydrogel susceptible to shear rate, time, and history, exhibiting: (i) Two-region breakdown of its gel structure during oscillatory strain sweep; (ii) rate-dependent thickening followed by three-region thinning with increased shear rate, and straight thinning with decreased shear rate; and (iii) time-dependent rheopexy at low shear rates, and thixotropy at high shear rates. An interesting correlation between the shear rate- and time-dependent rheological behaviors was also revealed, i.e., the rheopexy-thixotropy transition coincided with the first-second shear thinning region transition. Apart from rheology, a structure of colloidal network was observed in loach skin mucus using transmission electron microscopy. The complex rheology was speculated to result from inter- and intracolloid structural alterations. The unique rheology associated with the colloidal network structure, which has never been previously reported in vertebrate mucus, may play a key role in the functions (e.g., flow, reannealing, lubrication, and barrier) of the mucus.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1984

Constitutive modeling for isotropic materials (HOST)

The results of the first year of work on a program to validate unified constitutive models for isotropic materials utilized in high temperature regions of gas turbine engines and to demonstrate their usefulness in computing stress-strain-time-temperature histories in complex three-dimensional structural components. The unified theories combine all inelastic strain-rate components in a single term avoiding, for example, treating plasticity and creep as separate response phenomena. An extensive review of existing unified theories is given and numerical methods for integrating these stiff time-temperature-dependent constitutive equations are discussed. Two particular models, those developed by Bodner and Partom and by Walker, were selected for more detailed development and evaluation against experimental tensile, creep and cyclic strain tests on specimens of a cast nickel base alloy, B19000+Hf. Initial results comparing computed and test results for tensile and cyclic straining for temperature from ambient to 982 C and strain rates from 10(exp-7) 10(exp-3) s(exp-1) are given. Some preliminary date correlations are presented also for highly non-proportional biaxial loading which demonstrate an increase in biaxial cyclic hardening rate over uniaxial or proportional loading conditions. Initial work has begun on the implementation of both constitutive models in the MARC finite element computer code.

Lindholm, Ulric S.↗
DOE OSTI2014

Transient x-ray diffraction with simultaneous imaging under high strain-rate loading

Real time, in situ, multiframe, diffraction, and imaging measurements on bulk samples under high and ultrahigh strain-rate loading are highly desirable for micro- and mesoscale sciences. We present an experimental demonstration of multiframe transient x-ray diffraction (TXD) along with simultaneous imaging under high strain-rate loading at the Advanced Photon Source beamline 32ID. The feasibility study utilizes high strain-rate Hopkinson bar loading on a Mg alloy. The exposure time in TXD is 2–3 μs, and the frame interval is 26.7–62.5 μs. Various dynamic deformation mechanisms are revealed by TXD, including lattice expansion or compression, crystal plasticity, grain or lattice rotation, and likely grain refinement, as well as considerable anisotropy in deformation. Dynamic strain fields are mapped via x-ray digital image correlation, and are consistent with the diffraction measurements and loading histories.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

FORCE Update 2024

The Framework for Optimization of Resources and Economics (FORCE) tool suite is the U.S. Department of Energy’s Nuclear Integrated Energy Systems (IES) Program flagship tool suite for technoeconomic IES analysis of IES. This tool suite is useful for analysis designed to evaluate and improve the technoeconomics of energy production systems, particularly for systems including nuclear technology. In this report, we document the development activity for the FORCE tool suite to extend its capabilities as performed during fiscal year 2024. In addition to reliability and accessibility, capability is one of the three standards guiding the development of the FORCE tool suite and the software codes that are its constituent parts. Extending the capabilities of the FORCE tool suite allows analysis both within the IES program as well as industry, university, and laboratory partners to perform analysis with more accuracy, insight, and impactful narrative. Four areas of capability development were the focus of activity this year: economic parameter uncertainty quantification, multiresolution analysis, components-to-optimization workflow automation, and statespace construction workflows for real-time optimal control. In economic parameter uncertainty quantification, the ability of HERON to capture risk due to scenarios (weather and energy demand uncertainty) was expanded to also include uncertainties in financial parameters such as capital cost or operation and maintenance costs. By including these sources of uncertainty, which are sometimes very large compared with scenario uncertainty, HERON is better able to capture the risk posed by investment in various IES technology. Because of this, analysts can also consider the reduction in risks that can be realized by choice of some technologies. In multiresolution analysis, development activity extended on work completed previously. In fiscal year 2023, methods for decomposing time series signals, such as demand, solar and wind availability, and price profiles, were analyzed and down-selected to those most effective at splitting signals into different resolutions. These resolutions allow considering the influence of different energy demand and supply behaviors across different time scales. For example, energy demand might be divided into seasonal, weekly, and hourly profiles. In fiscal year 2024, this preliminary work was extended and implemented within the Risk Analysis Virtual Environment (RAVEN) risk and uncertainty analysis platform, which is used throughout the FORCE framework. This development of the “multi-resolution time series analysis” (MR-TSA) module in RAVEN allows training synthetic history generators on complex time series. These synthetic history generators can then be used in HERON for generating scenarios that represent possible market and weather scenarios that can be analyzed on different time scales. We envision completing this work in the future, implementing multiresolution dispatch optimization strategies that can make the most beneficial use of these stratified time histories. In components-to-optimization workflow development, workflows for translating user inputs of components into algorithms for algebraic optimization were selected and implemented. Similar algorithms within the Holistic Energy Resource Optimization Network (HERON) were separated from the main code base of HERON and gathered with the components-to-optimization workflows in the new Dispatch Optimization Variable Engine (DOVE) software library. This modularization allows FORCE users to analyze dispatch optimization and energy system duty cycles independently of HERON, which previously was a burdensome task. Additionally, these dispatch optimization algorithms, set up in an independent library, can now be used across all software applications within FORCE, especially including the real-time optimal control software Optimization of Real-time Capacity Allocation (ORCA). Allowing FORCE software to share dispatch optimization algorithms within a single library allows for improved software maintenance and reliability. In statespace characterization workflow development, alternative workflows for optimizing dispatch with additional technical accuracy was the focus, particularly to improve the real-time optimization decision making in ORCA. Using algorithms and workflows initially developed for the Feasible Actuator Range Modifier (FARM), workflows for determining the statespace representation of IES were identified and demonstrated. The resulting dispatch optimization required a more robust optimization algorithm than that originally used in HERON (and moved to DOVE), which required adding an alternate workflow to DOVE that can more accurately match the behavior of physical systems using a partial differential equation representation. In conclusion, capability developments in the FORCE tool suite in fiscal year 2024 have improved the ability of the FORCE tool suite to perform

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Rheo-Structural Spectroscopy: Fingerprinting the In Situ Response of Fluids to Arbitrary Flow Fields

The objectives of this project were to develop new sample environments, measurement methodologies and associated modeling tools for characterizing the structural response to arbitrarily complex processing flows using small angle scattering, and to apply these new tools for understanding the fundamental physics governing the structuring of anisotropic particulate and polymeric materials under flow histories and conditions relevant to industrial processing flows. The research resulted in the development and implementation of a new sample environment, the fluidic four roll mill (FFoRM), for in situ small angle neutron and X-ray scattering (SANS/SAXS) measurements. These measurements are capable of generating large data sets that “fingerprint” how a complex fluid responds to a wide range of flow histories involving time variations in deformation type and rate. New modeling tools were developed to extract detailed microstructural information from such data sets, including orientation distribution functions and interparticle correlation functions, as well as reduced-order parametric descriptors of these high-dimensional functions that can be used to readily map, visualize and interpret a fluid’s structural response to its flow history. These new tools were applied to a range of model materials involving elongated particle suspensions in order to provide new insights into the physics of how flow couples with orientational and structural order in complex flows, particularly under non-dilute conditions for which no accurate theories currently exist. Using these investigations, we elucidated a number of new insights into the fundamental phenomena driving such process-structure-property relationships. These findings provide guidance for the further development of rheological models, and ultimately can inform the rational and model-based design of flow processes to achieve optimized orientational ordering that is key to the properties and function of a wide range of energy-relevant materials.

36 MATERIALS SCIENCE↗