Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Splitting”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,495 records · Page 83
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Strongly vs. weakly coupled in-medium showers: energy stopping in large-Nf QED

Abstract Inside a medium, showers originating from a very high-energy particle may develop via medium-induced splitting processes such as hard bremsstrahlung or pair production. During shower development, two consecutive splittings sometimes overlap quantum mechanically, so that they cannot be treated independently. Some of these effects can be absorbed into an effective value of a medium parameter known as$$ \hat{q} $$ q ̂ . Previous calculations (with certain simplifying assumptions) have found that, after adjusting the value of$$ \hat{q} $$ q ̂ , the leftover effect of overlapping splittings is quite small for purely gluonic large-N c showers but is very much larger for large-N f QED showers, at comparable values ofNα. Those works did not quite make for apples-to-apples comparisons: the gluon shower work investigated energy deposition from a gluon-initiated shower, whereas the QED work investigated charge-deposition from an electron-initiated shower. As a first step to tighten up the comparison, this paper investigates energy deposition in the QED case. Along the way, we develop a framework that should be useful in the future to explore whether the very small effect of overlapping splitting in purely gluonic showers is an artifact of having ignored quarks.

Physics↗
DOE OSTI2020

The LPM effect in sequential bremsstrahlung: nearly complete results for QCD

The splitting processes of bremsstrahlung and pair production in a medium are coherent over large distances in the very high energy limit, which leads to a suppression known as the Landau-Pomeranchuk-Migdal (LPM) effect. We continue study of the case when the coherence lengths of two consecutive splitting processes overlap (which is important for understanding corrections to standard treatments of the LPM effect in QCD), avoiding soft-emission approximations. Previous work has computed overlap effects for double splitting g → gg → ggg. To make use of those results, one also needs calculations of related virtual loop corrections to single splitting g → gg in order to cancel severe (power-law) infrared (IR) divergences. This paper provides calculations of nearly all such processes involving gluons and discusses how to organize the results to demonstrate the cancellation. In the soft emission limit, our results reproduce the known double-log behavior of earlier authors who worked in leading-log approximation. We also present a first (albeit numerical and not yet analytic) investigation of sub-leading, single IR logarithms. Ultraviolet divergences appearing in our calculations correctly renormalize the coupling αs in the usual LPM result for leading-order g → gg.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2018

γ-Taxilin temporally regulates centrosome disjunction in a Nek2A-dependent manner

Highlights: • γ-Taxilin co-localizes with Nek2A at the centrosome during interphase. • γ-Taxilin interacts with Nek2A in yeast two-hybrid and pull-down assays. • γ-Taxilin protein expression levels decrease at the onset of mitosis. • γ-Taxilin depletion induces immature splitting of centrosomes. • The immature splitting of centrosomes induced by γ-taxilin depletion depends on Nek2A. Never in mitosis A-related kinase 2A (Nek2A), a centrosomal serine/threonine kinase, is involved in mitotic progression by regulating the centrosome cycle. Particularly, Nek2A is necessary for dissolution of the intercentriole linkage between the duplicated centrosomes prior to mitosis. Nek2A activity roughly parallels its cell cycle-dependent expression levels, but the precise mechanism regulating its activity remains unclear. In this study, we found that γ-taxilin co-localized with Nek2A at the centrosome during interphase and interacted with Nek2A in yeast two-hybrid and pull-down assays and that γ-taxilin regulated centrosome disjunction in a Nek2A-dependent manner. γ-Taxilin depletion increased the number of cells with striking splitting of centrosomes. The precocious splitting of centrosomes induced by γ-taxilin depletion was attenuated by Nek2A depletion, suggesting that γ-taxilin depletion induces the Nek2A-mediated dissolution of the intercentriole linkage between the duplicated centrosomes nevertheless mitosis does not yet begin. Taken together with the result that γ-taxilin protein expression levels were decreased at the onset of mitosis, we propose that γ-taxilin participates in Nek2A-mediated centrosome disjunction as a negative regulator through its interaction with Nek2A.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2020

The geometric theory of charge conservation in particle-in-cell simulations

In recent years, several gauge-symmetric particle-in-cell (PIC) methods have been developed whose simulations of particles and electromagnetic fields exactly conserve charge. While it is rightly observed that these methods’ gauge symmetry gives rise to their charge conservation, this causal relationship has generally been asserted via ad hoc derivations of the associated conservation laws. In this work, we develop a comprehensive theoretical grounding for charge conservation in gauge-symmetric Lagrangian and Hamiltonian PIC algorithms. For Lagrangian variational PIC methods, we apply Noether’s second theorem to demonstrate that gauge symmetry gives rise to a local charge conservation law as an off-shell identity. For Hamiltonian splitting methods, we show that the momentum map establishes their charge conservation laws. We define a new class of algorithms – gauge-compatible splitting methods – that exactly preserve the momentum map associated with a Hamiltonian system’s gauge symmetry – even after time discretization. This class of algorithms affords splitting schemes a decided advantage over alternative Hamiltonian integrators. We apply this general technique to design a novel, explicit, symplectic, gauge-compatible splitting PIC method, whose momentum map yields an exact local charge conservation law. Finally, our study clarifies the appropriate initial conditions for such schemes and examines their symplectic reduction.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Fast wide-field upconversion luminescence lifetime thermometry enabled by single-shot compressed ultrahigh-speed imaging

Photoluminescence lifetime imaging of upconverting nanoparticles is increasingly featured in recent progress in optical thermometry. Despite remarkable advances in photoluminescent temperature indicators, existing optical instruments lack the ability of wide-field photoluminescence lifetime imaging in real time, thus falling short in dynamic temperature mapping. Here, we report video-rate upconversion temperature sensing in wide field using single-shot photoluminescence lifetime imaging thermometry (SPLIT). Developed from a compressed-sensing ultrahigh-speed imaging paradigm, SPLIT first records wide-field luminescence intensity decay compressively in two views in a single exposure. Then, an algorithm, built upon the plug-and-play alternating direction method of multipliers, is used to reconstruct the video, from which the extracted lifetime distribution is converted to a temperature map. Using the core/shell NaGdF 4 :Er 3+ ,Yb 3+ /NaGdF 4 upconverting nanoparticles as the lifetime-based temperature indicators, we apply SPLIT in longitudinal wide-field temperature monitoring beneath a thin scattering medium. SPLIT also enables video-rate temperature mapping of a moving biological sample at single-cell resolution.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Magneto-transport evidence for strong topological insulator phase in ZrTe5

Abstract The identification of a non-trivial band topology usually relies on directly probing the protected surface/edge states. But, it is difficult to achieve electronically in narrow-gap topological materials due to the small (meV) energy scales. Here, we demonstrate that band inversion, a crucial ingredient of the non-trivial band topology, can serve as an alternative, experimentally accessible indicator. We show that an inverted band can lead to a four-fold splitting of the non-zero Landau levels, contrasting the two-fold splitting (spin splitting only) in the normal band. We confirm our predictions in magneto-transport experiments on a narrow-gap strong topological insulator, zirconium pentatelluride (ZrTe 5 ), with the observation of additional splittings in the quantum oscillations and also an anomalous peak in the extreme quantum limit. Our work establishes an effective strategy for identifying the band inversion as well as the associated topological phases for future topological materials research.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Mechanism for spontaneous oxygen and hydrogen evolution reactions on CoO nanoparticles

Overall photocatalytic water splitting with a high efficiency of ~5% has recently been observed for CoO nanoparticle suspensions in the absence of an applied bias or co-catalyst. Although experimental measurements indicate that the overall photocatalytic water splitting is caused by optimal band edge alignments with respect to the redox potentials of water, the mechanism by which H 2 and O 2 simultaneously evolve on these nanoparticles is unknown. Here, we used first-principles density functional theory (DFT) calculations to elucidate the mechanisms for the charge separation and H 2 and O 2 evolution on CoO nanoparticles under illumination in aqueous solution. We demonstrated that electrons are driven to the CoO(100) facet and holes are driven to the hydroxylated CoO(111) facet (OH*–CoO(111)) as a result of the built-in potential arising from the difference in the band edge positions on the two facets. Furthermore, based on a set of criteria, depending on if the photoexcited electrons and holes have sufficient energy to overcome the kinetic barrier along the H 2 and O 2 evolution reaction pathways, respectively, on the relevant surface facet, we show that H 2 evolution preferentially occurs on the CoO(100) facet, while O 2 evolution occurs on the OH*–CoO(111) surface. Our understanding of the overall water splitting mechanism on CoO nanoparticles provides a general explanation for the experimentally observed overall water splitting phenomena on a variety of self-standing photocatalysts, including γ-Ga 2 O 3 , Cu 2 O, and KTaO 3 , without an external driving potential or co-catalyst. In addition, we provide a new strategy for designing novel photocatalysts with high efficiency by controlling their surface configurations and morphologies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

A test of the standard cosmological model with geometry and growth

We perform a general test of the ΛCDM and wCDM cosmological models by comparing constraints on the geometry of the expansion history to those on the growth of structure. Specifically, we split the total matter energy density, Ω M , and (for wCDM) dark energy equation of state, w, into two parameters each: one that captures the geometry, and another that captures the growth. We constrain our split models using current cosmological data, including type Ia supernovae, baryon acoustic oscillations, redshift space distortions, gravitational lensing, and cosmic microwave background (CMB) anisotropies. We focus on two tasks: (i) constraining deviations from the standard model, captured by the parameters ΔΩ M ≡ Ω M grow -Ω M geom and Δw ≡ w grow -w geom , and (ii) investigating whether the S 8 tension between the CMB and weak lensing can be translated into a tension between geometry and growth, i.e. ΔΩ M ≠ 0, Δw ≠ 0. In both the split ΛCDM and wCDM cases, our results from combining all data are consistent with ΔΩ M = 0 and Δ w = 0. If we omit BAO/RSD data and constrain the split wCDM cosmology, we find the data prefers Δw < 0 at 3.6σ significance and ΔΩ M > 0 at 4.2σ evidence. We also find that for both CMB and weak lensing, ΔΩ M and S 8 are correlated, with CMB showing a slightly stronger correlation. Furthermore, the general broadening of the contours in our extended model does alleviate the S 8 tension, but the allowed nonzero values of ΔΩ M do not encompass the S 8 values that would point toward a mismatch between geometry and growth as the origin of the tension.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Shear Alfvén wave continuum spectrum with bifurcated helical core equilibria

Here, the radial structure of the continuum spectrum of shear Alfvén and Alfvén-acoustic waves in the beta-induced Alfvén eigenmode (BAE) frequency range is modeled for tokamak plasmas in the presence of 3D effects obtained from the bifurcated MHD equilibrium reconstruction. Plasma compressibility and geodesic curvature effects responsible for the low-frequency continuum spectrum calculations are invoked. In the equilibrium calculations we find that the helically distorted MHD equilibria may exist even for the axisymmetric devices if q = 1 rational surfaces are present. The continuum calculations with the bifurcated equilibria lead to a frequency splitting between the highest frequency branch and the lowest frequency branch continua at the frequency accumulation point. Radially localised shifting of modes happens via coupling of the adjacent n – 1 continuum around an accumulation point. Our modelling (including 3D effects) correctly reproduces the phenomenon of continuum frequency splitting and provides a possible solution for the differences of few kHz in frequency splitting, which remained unexplained with the 2D kinetic calculations. The pressure scaling confirms the increase of helical excursion of the magnetic axis in equilibrium reconstruction and hence the range of continuum frequency splitting. In our calculations, the existence of low-frequency continua is in agreement with the experimentally observed low-frequency modes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Mitigation of birefringence in cavity-based quantum networks using frequency-encoded photons

Atom-cavity systems offer unique advantages for building large-scale distributed quantum computers by providing strong atom-photon coupling while allowing for high-fidelity local operations of atomic qubits. However, in prevalent schemes where the photonic state is encoded in polarization, cavity birefringence introduces an energy splitting of the cavity eigenmodes and alters the polarization states, thus limiting the fidelity of remote entanglement generation. To address this challenge, we propose a scheme that encodes the photonic qubit in the frequency degree-of-freedom. The scheme relies on resonant coupling of multiple transverse cavity modes to different atomic transitions that are well-separated in frequency. We numerically investigate the temporal properties of the photonic wavepacket, two-photon interference visibility, and atom-atom entanglement fidelity under various cavity polarization-mode splittings and find that our scheme is less affected by cavity birefringence. Finally, we propose practical implementations in two trapped ion systems, using the fine structure splitting in the metastable D state of 40 Ca + , and the hyperfine splitting in the ground state of 225 Ra + . Furthermore, our study presents an alternative approach for cavity-based quantum networks that is less sensitive to birefringent effects, and is applicable to a variety of atomic and solid-state emitter-cavity interfaces.

Cavity quantum electrodynamics↗
DOE OSTI2021

Chemically and electrically tunable spin polarization in ferroelectric Cd-based hybrid organic-inorganic perovskites

Density functional theory computations are used to predict the electronic structure of Cd-based hybrid organic-inorganic high-T C ferroelectric perovskites with TMCM-CdCl 3 being one representative. Here we report Rashba-Dresselhaus spin splitting in the valence band of these nonmagnetic compounds. Interestingly, we find in computations that the splitting is not necessarily sensitive to the polarization of the material but to the organic molecule itself which opens a way to its chemical tunability through the choice of the molecule. Further chemical tunability of spin splitting is shown to be possible through a substitution of Cl in the CdCl 3 chains as the valence band was found to originate from Cl-Cl weekly bonding orbitals. For example, the substitution of Cl with Br in TMCM-CdCl 3 resulted in a ten times increase of spin splitting. Furthermore, the spin polarization in these materials gives origin to persistent spin textures which are coupled to the polarization direction, and, therefore, can be controlled by the electric field. This is promising for spintronics applications.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Ultrafast optical snapshots of hybrid perovskites reveal the origin of multiband electronic transitions

In this paper, connecting the complex electronic excitations of hybrid perovskites to their intricate organic-inorganic lattice structure has critical implications for energy conversion and optoelectronic technologies. Here we detail the multiband, multivalley electronic structure of a halide hybrid perovskite by measuring the absorption transients of a millimeter-scale-grain thin film as it undergoes a thermally controlled reversible tetragonal-to-orthogonal phase transition. Probing nearly single grains of this hybrid perovskite, we observe an unreported energy splitting (degeneracy lifting) of the high-energy 2.6 eV band in the tetragonal phase that further splits as the rotational degrees of freedom of the disordered CH 3 NH 3 + molecules are reduced when the sample is cooled. This energy splitting drastically increases during an extended phase-transition coexistence region that persists from 160 to 120 K, becoming more pronounced in the orthorhombic phase. By tracking the temperature-dependent optical transition energies and using symmetry analysis that describes the evolution of electronic states from the tetragonal phase to the orthorhombic phase, we assign this energy splitting to the nearly degenerate transitions in the tetragonal phase from both the R - and M -point-derived states. Importantly, these assignments explain how momentum conservation effects lead to long hot-carrier lifetimes in the room-temperature tetragonal phase, with faster hot-carrier relaxation when the hybrid perovskite structurally transitions to the orthorhombic phase due to enhanced scattering at the Γ point.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Time-resolved study of nonlinear three-magnon processes in yttrium iron garnet films

In this work, the temporal aspects of two nonlinear spin-wave processes, i.e., three-magnon splitting and confluence, were investigated in a yttrium iron garnet film. Three-magnon splitting involves the conversion of a magnon at the microwave pumping frequency f p into two magnons, each with a frequency near f p /2, while confluence refers to the subsequent combination of two of the split magnons into one with frequency f c < f p . Time-resolved Brillouin scattering measurements confirm that these processes occur close to the driving antenna (<1.7mm away), which is expected. Here, the data indicate, however, that magnons with larger group velocities are more likely to undergo confluence, which is not predicted by existing theory. Understanding the details of the splitting and confluence processes may have important implications for the use of short-wavelength spin waves for spintronic devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Insulating titanium oxynitride for visible light photocatalysis

We propose insulating titanium oxynitrides Ti n N 2 O 2 n -3 as promising water-splitting photocatalytic materials in the visible light range. Using first-principles many-body perturbation theory based on the GW approximation, we show that corundum-type Ti 2 N 2 O (an example Ti n N 2 O 2 n -3 compound with n =2) has a smaller band gap of about 2.5 eV, which is more suitable to absorb visible light, compared to other Ti-based oxides such as TiO 2 and SrTiO 3 with a band gap of more than 3 eV. Band-gap reduction in Ti 2 N 2 O is caused by an upward shift of the valence band (negative shift to the oxidation potential of H 2 O to O 2 ) due to the presence of nitrogen 2 p states. The conduction band is dominated by Ti 3 d states and the conduction-band minimum is nearly unchanged. As a result, the band-edge potentials of Ti 2 N 2 O are better aligned to the water reduction and oxidation levels. Our theoretical predictions provide useful insights for the discovery of efficient visible-light-driven photocatalysts for water splitting.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Computational analysis of interface-driven spin-orbit coupling in molecular adsorbates on transition metal dichalcogenides

Spin-orbit coupling (SOC) lifts molecular orbital degeneracy, enabling bilevel electronic platforms suitable for next-generation digital devices. However, common light-atom molecular feedstocks exhibit weak SOC due to the absence of heavy elements. To enhance SOC without synthesizing new materials, we leverage interfacial interactions between molecules and transition-element-based solid-state materials. This computational study investigates SOC splitting in metal-phthalocyanine adsorbed on transition metal dichalcogenides (TMDs) using density functional theory (DFT). The enhanced SOC splitting is attributed to strong orbital hybridization at the molecule-substrate interface. Specifically, Zn-phthalocyanine (ZnPC) on monolayer Mo⁢S 2 achieves a notable SOC splitting of ∼8 meV. Furthermore, when ZnPC forms self-assembled chains on Mo⁢S 2 , the splitting increases to ∼20 meV, driven by the formation of hybrid bands modulated by molecular periodicity. Furthermore, these findings highlight the role of interfacial and intermolecular interactions in inducing and enhancing SOC in surface-adsorbed molecules, providing a new strategy for molecular spintronic materials without complex synthetic efforts.

2-dimensional systems↗
DOE OSTI2017

Novel Histogram Based Unsupervised Classification Technique to Determine Natural Classes From Biophysically Relevant Fit Parameters to Hyperspectral Data

Hyperspectral image analysis has benefited from an array of methods that take advantage of the increased spectral depth compared to multispectral sensors; however, the focus of these developments has been on supervised classification methods. Lack of a priori knowledge regarding land cover characteristics can make unsupervised classification methods preferable under certain circumstances. An unsupervised classification technique is presented in this paper that utilizes physically relevant basis functions to model the reflectance spectra. These fit parameters used to generate the basis functions allow clustering based on spectral characteristics rather than spectral channels and provide both noise and data reduction. Histogram splitting of the fit parameters is then used as a means of producing an unsupervised classification. Unlike current unsupervised classification techniques that rely primarily on Euclidian distance measures to determine similarity, the unsupervised classification technique uses the natural splitting of the fit parameters associated with the basis functions creating clusters that are similar in terms of physical parameters. The data set used in this work utilizes the publicly available data collected at Indian Pines, Indiana. This data set provides reference data allowing for comparisons of the efficacy of different unsupervised data analysis. The unsupervised histogram splitting technique presented in this paper is shown to be better than the standard unsupervised ISODATA clustering technique with an overall accuracy of 34.3/19.0% before merging and 40.9/39.2% after merging. Finally, this improvement is also seen as an improvement of kappa before/after merging of 24.8/30.5 for the histogram splitting technique compared to 15.8/28.5 for ISODATA.

58 GEOSCIENCES↗
DOE OSTI2023

Protecting Customer Privacy Through Distributed Energy Resource Anonymization

Due to their stochastic nature, the increase of Renewable Energy Resources (RERs) as a primary source of energy for power grids creates challenges regarding the reliability and resilience of the system. In order to combat these obstacles, expansion of Distributed Energy Resources (DERs) and their participation in Demand Response (DR) programs is necessary. Widespread participation requires prioritizing customer privacy and addressing concerns that may arise regarding communication between DERs and the Grid Service Provider (GSP). This paper discusses the use of flow reservation resources to split the operating cycles of DER load profiles into unique phases. The splitting of phases increases anonymization of the DERs by making it more difficult to determine the individual characteristics of the device. We discuss an example of this using simulated DER load profile data and examine the resulting effectiveness by using a machine learning algorithm for classification, called Support Vector Machine (SVM).

Distributed Energy Resource, Anonymization, Renewa↗