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At least 1,495 records · Page 83

Development of Cross Section Library and Application Programming Interface (API)

The goal of NEAMS neutronics is to develop a high-fidelity deterministic neutron transport code termed PROTEUS for use on all reactor types of interest, but focused primarily on sodium-cooled fast reactors. While PROTEUS-SN has demonstrated good accuracy for homogeneous fast reactor problems and partially heterogeneous fast reactor problems, the simulation results were not satisfactory when applied on fully heterogeneous thermal problems like the Advanced Test Reactor (ATR). This is mainly attributed to the quality of cross section data for heterogeneous geometries since the conventional cross section generation approach does not work accurately for such irregular and complex geometries. Therefore, one of the NEAMS neutronics tasks since FY12 has been the development of a procedure to generate appropriate cross sections for a heterogeneous geometry core.

97 MATHEMATICS AND COMPUTING↗

Carbon Capture (Annual Report)

The following report describes the research conducted under the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), Regional University Alliance (RUA) Carbon Capture Field Work Proposal (FWP) in FY13. The goal of the Carbon Capture FWP is to support the program by developing technologies which decrease the cost of carbon dioxide (CO 2 ) capture from coal-based power generation below $40/tonne. This goal is accomplished by examining a portfolio of transformative technologies to determine which might be applicable to CO 2 capture and advancing the most promising technologies through successive levels of development, including ideal performance testing, realistic performance testing, and field testing in the presence of actual flue or fuel gas with the final objective of technology transfer and commercialization. Fourteen potentially transformative technologies were evaluated in FY13, and five were selected for continued development in FY14. Nine more advanced technologies were developed toward commercialization. Of these, five made significant progress and will be further developed in FY14, and research on four has been discontinued.

20 FOSSIL-FUELED POWER PLANTS↗

LDRD FY2013 Annual Report

The Department of Energy (DOE) and the SLAC National Accelerator Laboratory (SLAC) encourage innovation, creativity, originality and quality to maintain the Laboratory’s research activities and staff at the forefront of science and technology. To further advance the Laboratory’s scientific research capabilities, the Laboratory allocates a portion of its funds for the Laboratory Directed Research and Development (LDRD) program. With DOE guidance, the LDRD program enables SLAC scientists to make rapid and significant contributions to seeding new strategies for solving important national science and technology problems. The LDRD program is conducted using existing research facilities.

ACCPHY↗

Somerset County Renewable Energy Initiative

The County of Somerset, New Jersey, through the Somerset County Improvement Authority (SCIA), applied Federal funding through the U.S. Department of Energy to will apply project funds to buy-down the capital costs of equipment associated with the installation of solar photovoltaic (PV) systems at two sites owned by the County. This Renewable Energy Initiative allows the County to take advantage of clean renewable energy, without any adverse debt impacts, and at a price that results in operating budget savings beyond what is presently available in the marketplace. This project addressed the objectives of the Office of Energy Efficiency and Renewable Energy by making the acquisition of renewable energy more affordable for the County, thereby, encouraging other counties and local units to develop similar programs and increase the deployment of solar energy technologies. The two sites that were funded by the DOE grant are part of a much larger, ambitious, and unique renewable energy project, described in the next section.

14 SOLAR ENERGY↗

Design, Fabrication, and Testing of an Acid-Dissolution Front-End Process for Current Mo-99 Recovery Processes: Optimization for Full-Scale Demonstration in Hot-Cell Facility

The National Nuclear Security Administration’s Global Threat Reduction Initiative Conversion Program (GTRI) develops technology necessary for converting civilian nuclear facilities that use high enriched uranium (HEU) to low enriched uranium (LEU) fuels and targets. The conversion of conventional HEU targets to LEU for the production of Mo-99 for medical use requires approximately five times the amount of uranium per target to maintain current Mo-99 yields. Under GTRI, Argonne National Laboratory (Argonne) is developing two frontend options for the current Mo-99 recovery processes to allow the use of LEU-foil targets: (1) an ambient pressure, nitric acid dissolution process; and (2) an electrochemical, basic dissolution process. The goal in developing both frontend options is to produce a product that will be compatible with current purification operations and that will, with the same number of targets irradiated, provide the same or a higher yield of Mo-99 at the end of processing. This work was done under the Mo-99 International Production Support, FY 2012 work package: 21.2.94.2.6 LEU Target – Foreign Production Development, ANL Activity 1.

Jerden, James↗

In-situ Study of Dynamic Phenomena at Metal Nanosolder Interfaces Using Aberration Corrected Scanning Transmission Electron Microcopy.

Controlling metallic nanoparticle (NP) interactions plays a vital role in the development of new joining techniques (nanosolder) that bond at lower processing temperatures but remain viable at higher temperatures. The pr imary objective of this project is t o develop a fundamental understanding of the actual reaction processes, associated atomic mechanisms, and the resulting microstructure that occur during thermally - driven bond formation concerning metal - metal nano - scale (%3C50nm) interfaces. In this LDRD pr oject, we have studied metallic NPs interaction at the elevated temperatures by combining in - situ transmission electron microscopy (TEM ) using an aberration - corrected scanning transmission electron microscope (AC - STEM) and atomic - scale modeling such as m olecular dynamic (MD) simulations. Various metallic NPs such as Ag, Cu and Au are synthesized by chemical routines. Numerous in - situ e xperiments were carried out with focus of the research on study of Ag - Cu system. For the first time, using in - situ STEM he ating experiments , we directly observed t he formation of a 3 - dimensional (3 - D) epitaxial Cu - Ag core - shell nanoparticle during the thermal interaction of Cu and Ag NPs at elevated temperatures (150 - 300 o C). The reaction takes place at temperatures as low as 150 o C and was only observed when care was taken to circumvent the effects of electron beam irradiation during STEM imaging. Atomic - scale modeling verified that the Cu - Ag core - shell structure is energetically favored, and indicated that this phenomenon is a nano - scale effect related to the large surface - to - volume ratio of the NPs. The observation potentially can be used for developing new nanosolder technology that uses Ag shell as the "glue" that stic ks the particles of Cu together. The LDRD has led to several journal publications and numerous conference presentations, and a TA. In addition, we have developed new TEM characterization techniques and phase - field modeling tools that can be used for future materials research at Sandia. Acknowledgeme nts This work was supported by the Laboratory Directed Research and Development (LDRD) program of Sandia National Laboratories. Sandia National Laboratories is a multi - program laboratory managed and operated by Sandia Corporation, a wholly owned subsidia ry of Lockheed Martin Corporation, for the US Department of Energy's National Nuclear Security Administration under contract DE - AC04 - 94AL85000.

Lu, Ping↗

Geological Sequestration Training and Research Program in Capture and Transport: Development of the Most Economical Separation Method for CO2 Capture

The project provided hands-on training and networking opportunities to undergraduate students in the area of carbon dioxide (CO2) capture and transport, through fundamental research study focused on advanced separation methods that can be applied to the capture of CO2 resulting from the combustion of fossil-fuels for power generation . The project team’s approach to achieve its objectives was to leverage existing Carbon Capture and Storage (CCS) course materials and teaching methods to create and implement an annual CCS short course for the Tuskegee University community; conduct a survey of CO2 separation and capture methods; utilize data to verify and develop computer models for CO2 capture and build CCS networks and hands-on training experiences. The objectives accomplished as a result of this project were: (1) A comprehensive survey of CO2 capture methods was conducted and mathematical models were developed to compare the potential economics of the different methods based on the total cost per year per unit of CO2 avoidance; and (2) Training was provided to introduce the latest CO2 capture technologies and deployment issues to the university community.

Vahdat, Nader↗

Status report on assessment of environmentally assisted fatigue for LWR extended service conditions

This report provides an update on an earlier assessment of environmentally assisted fatigue for light water reactor (LWR) materials under extended service conditions. This report is a deliverable in September 2013, under the work package for environmentally assisted fatigue in the Light Water Reactor Sustainability (LWRS) program. The overall objective of this LWRS project is to assess the degradation by environmentally assisted cracking/fatigue of LWR materials, such as various alloy base metals and their welds used in reactor coolant system piping. This effort is to support the U.S. Department of Energy LWRS program for developing tools to predict the aging/failure mechanism and to correspondingly predict the remaining life of LWR components for anticipated 60-80 year operation.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Environmental Effect on Evolutionary Cyclic Plasticity Material Parameters of 316 Stainless Steel: An Experimental & Material Modeling Approach

This report provides an update on an earlier assessment of environmentally assisted fatigue for light water reactor (LWR) materials under extended service conditions. This report is a deliverable under the work package for environmentally assisted fatigue in the Light Water Reactor Sustainability (LWRS) program. The overall objective of this LWRS project is to assess the degradation by environmentally assisted cracking/fatigue of LWR materials such as various alloy base metals and their welds used in reactor coolant system piping. This effort is to support the Department of Energy LWRS program for developing tools to understand the aging/failure mechanism and to predict the remaining life of LWR components for anticipated 60-80 year operation.

36 MATERIALS SCIENCE↗

Light Water Reactor Sustainability Program: Computer-Based Procedures for Field Activities: Results from Three Evaluations at Nuclear Power Plants

The Computer-Based Procedure (CBP) research effort is a part of the Light-Water Reactor Sustainability (LWRS) Program, which is a research and development (R&D) program sponsored by Department of Energy (DOE) and performed in close collaboration with industry R&D programs that provides the technical foundations for licensing and managing the long-term, safe, and economical operation of current nuclear power plants. One of the primary missions of the LWRS program is to help the U.S. nuclear industry adopt new technologies and engineering solutions that facilitate the continued safe operation of the plants and extension of the current operating licenses. One area that could yield tremendous savings in increased efficiency and safety is in improving procedure use. Nearly all activities in the nuclear power industry are guided by procedures, which today are printed and executed on paper. This paper-based procedure process has proven to ensure safety; however, there are improvements to be gained. Due to its inherent dynamic nature, a CBP provides the opportunity to incorporate context driven job aids, such as drawings, photos, and just-in-time training. Compared to the static state of paper-based procedures (PBPs), the presentation of information in CBPs can be much more flexible and tailored to the task, actual plant condition, and operation mode. The dynamic presentation of the procedure will guide the user down the path of relevant steps, thus minimizing time spent by the field worker to evaluate plant conditions and decisions related to the applicability of each step. This dynamic presentation of the procedure also minimizes the risk of conducting steps out of order and/or incorrectly assessed applicability of steps.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Resources for National Water Savings for Outdoor Water Use

In support of efforts by the U.S. Environmental Agency's (EPA's) WaterSense program to develop a spreadsheet model for calculating the national water and financial savings attributable to WaterSense certification and labeling of weather-based irrigation controllers, Lawrence Berkeley National Laboratory reviewed reports, technical data, and other information related to outdoor water use and irrigation controllers. In this document we categorize and describe the reviewed references, highlighting pertinent data. We relied on these references when developing model parameters and calculating controller savings. We grouped resources into three major categories: landscapes (section 1); irrigation devices (section 2); and analytical and modeling efforts (section 3). Each category is subdivided further as described in its section. References are listed in order of date of publication, most recent first.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Geomechanical Testing of Bayou Choctaw 102B Core for SPR Analysis

A laboratory testing program was developed to examine the short-term mechanical and time-dependent (creep) behavior of salt from the Bayou Choctaw Salt Dome. This report documents the test methodologies, and constitutive properties inferred from tests performed. These are used to extend our understanding of the mechanical behavior of the Bayou Choctaw domal salt and provide a data set for numerical analyses. The resulting information will be used to support numerical analyses of the current state of the Bayou Choctaw Dome as it relates to its crude oil storage function as part of the US Strategic Petroleum Reserve. Core obtained from Drill Hole BC-102B was tested under creep and quasi-static constant mean stress axisymmetric compression, and constant mean stress axisymmetric extension conditions. Creep tests were performed at 100 degrees Fahrenheit, and the axisymmetric tests were performed at ambient temperatures (72-78 degrees Fahrenheit). The testing performed indicates that the dilation criterion is pressure and stress state dependent. It was found that as the mean stress increases, the shear stress required to cause dilation increases. The results for this salt are reasonably consistent with those observed for other domal salts. Also it was observed that tests performed under extensile conditions required consistently lower shear stress to cause dilation for the same mean stress, which is consistent with other domal salts. Young's moduli ranged from 3.95 x 10 6 to 8.51 x 10 6 psi with an average of 6.44 x 10 6 psi, with Poisson's ratios ranging from 0.10 to 0.43 with an average of 0.30. Creep testing indicates that the BC salt is intermediate in creep resistance when compared with other bedded and domal salt steady-state behavior.

58 GEOSCIENCES↗

Supplemental Immobilization of Hanford Low-Activity Waste: Cast Stone Augmented Formulation Matrix Tests

More than 56 million gallons of radioactive and hazardous waste are stored in 177 underground storage tanks at the U.S. Department of Energy’s (DOE’s) Hanford Site in Washington State. The HLW will be vitrified in the HLW facility for ultimate disposal at an offsite federal repository. A portion (~35%) of the LAW will be vitrified in the LAW vitrification facility for disposal onsite at the Integrated Disposal Facility (IDF). The pretreatment and HLW vitrification facilities will have the capacity to treat and immobilize all of the wastes destined for those facilities. However, a second facility will be needed for the expected volume of LAW requiring immobilization. Cast Stone, a cementitious waste form, is being considered to provide the required additional LAW immobilization capacity. The Cast Stone waste form must be acceptable for disposal in the IDF. The Cast Stone waste form and immobilization process must be tested to demonstrate that the final Cast Stone waste form can comply with the waste acceptance criteria for the disposal facility and that the immobilization processes can be controlled to consistently provide an acceptable waste form product. A testing program was developed in fiscal year (FY) 2012 describing in detail the work needed to develop and qualify Cast Stone as a waste form for the solidification of Hanford LAW. A statistically designed test matrix was used to evaluate the effects of key parameters on the properties of the Cast Stone as it is initially prepared and after curing. For the processing properties, the water-to-dry-blend mix ratio was the most significant parameter in affecting the range of values observed for each property. The single shell tank (SST) Blend simulant also showed differences in measured properties compared to the other three simulants tested. A review of the testing matrix and results indicated that an additional set of tests would be beneficial to improve the understanding of the impacts noted in the Screening Matrix tests. A set of Cast Stone formulations were devised to augment the original screening test matrix and focus on the range of the test conditions. Fly ash and blast furnace slag were limited to either northwest or southeast and the salt solutions were narrowed to the Average and the SST Blend at the 7.8M Na concentration. To fill in the matrix, a mix ratio of 0.5 was added. In addition, two admixtures, Xypex Admix C-500 and Rheomac SF100 (silica fume), were added as an additional dry material binder in select compositions. As in the Screening Matrix, both fresh and cured properties were evaluated for the formulations. In this study, properties that were influenced by the W/DM ratio in the Screening Matrix; flow diameter, plastic viscosity, density, and compressive strength, showed consistent behavior with respect to W/DM. The leach index for highly soluble components, sodium and nitrate, were not influenced by changes in formulation or the admixtures. The leach index for both iodine and Tc-99 show an influence from the addition of the admixture, Xypex Admix C-500. Additional testing should be performed to further evaluate the influence of Xypex Admix C-500 on the leach index over a range of admixture concentrations, Cast Stone formulations, and curing and storage conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Energy Storage and Generation for Extreme Temperature and Pressure and Directional Measurement While Drilling Applications

FastCAP Systems Corporation has successfully completed all milestones defined by the award DE-EE0005503. Under this program, FastCAP developed three critical subassemblies to TRL3 demonstrating proof of concept of a geothermal MWD power source. This power source includes an energy harvester, electronics and a novel high temperature ultracapacitor (“ultracap”) rechargeable energy storage device suitable for geothermal exploration applications. FastCAP’s ruggedized ultracapacitor (ultracap) technology has been proven and commercialized in oil and gas exploration operating to rated temperatures of 150°C. Characteristics of this technology are that it is rechargeable and relatively high power. This technology was the basis for the advancements in rechargeable energy storage under this project. The ultracap performs reliably at 250°C and beyond and operates over a wide operating temperature range: -5°C to 250°C. The ultracap has significantly higher power density than lithium thionyl chloride batteries, a non-rechargeable incumbent used in oil and gas drilling today. Several hermetically sealed, prototype devices were tested in our laboratories at constant temperatures of 250°C showing no significant degradation over 2000 hours of operation. Other prototypes were tested at Sandia National Lab in the month of April, 2015 for a third party performance validation. These devices showed outstanding performance over 1000 hours of operation at three rated temperatures, 200°C, 225°C and 250°C, with negligible capacitance degradation and minimal equivalent series resistance (ESR) increase. Similarly, FastCAP’s ruggedized electronics have been proven and commercialized in oil and gas exploration operating to rated temperatures of 150°C. This technology was the basis for the advancements in downhole electronics under this project. Principal contributions here focused on design for manufacture innovations that have reduced the prototype build cycle time by a factor of 10x. The electronics have demonstrated a substantially reduced design cycle time by way of process and material selection innovations and have been qualified for 250°C / 10 Grms for at least 200 hours. FastCAP has also invented a rotary inertial energy generator (RIEG) to harvest various mechanical energy sources that exist downhole. This device is flow-independent and has been demonstrated as a proof of concept to survive geothermal well temperatures under this project. The herein energy harvester has been developed to provide operational power by harvesting rotational mechanical energy that exists downhole in geothermal drilling. The energy harvester has been tested at 250°C / 10 Grms for 200 hours. Deployment of these technologies in geothermal drilling and exploration applications could have an immediate and significant impact on the effectiveness and efficiency of drilling processes, particularly with regard to use of advanced logging and monitoring techniques. The ultimate goal of this work is to reduce drilling risk to make geothermal energy more attractive and viable to the customer. Generally speaking, we aim to support the transfer of MWD techniques from oil and gas to geothermal exploration with considerations toward the practical differences between the two. One of the most significant obstacles to the deployment of advanced drilling and production techniques in the geothermal context are limitations related to the maximum operating temperatures of downhole batteries used to provide power for downhole sensors, steering tools, telemetry equipment and other MWD/LWD technologies. FastCAP’s higher temperature ultracapacitor technology will provide power solutions for similar advanced drilling and production techniques, even in the harsher environments associated with geothermal energy production. This ultracapacitor will enable downhole power solutions for the geothermal industry capable of the same reliable and safe operation our team has demonstrated in the oil and gas context. Without batteries, geothermal MWD is left without a downhole power source. Some very high temperature turbines exist but provide unsteady, intermittent power and no power when the flow is off. In high loss formations common to geothermal exploration, it will be auspicious to support air drilling in which case there is no flow to power a turbine at all. In the best case, rechargeable energy storage will help to buffer unsteady power from non-battery power sources and in the worst case it will be needed to store energy from highly intermittent sources to provide a continuously operable power source to the tool.

15 GEOTHERMAL ENERGY↗

From Idea to Innovation: The Role of LDRD Investments in Sandia's Recent Successful B61 Experiments.

The Laboratory Directed Research and Development (LDRD) program, authorized by U.S. Congress in 1991, enables Department of Energy (DOE) laboratories to devote a small portion of their research funding to high-risk and potentially high-payoff research. Because it is high-risk, LDRD-supported research may not lead to immediate mission impacts; however, many successes at DOE labs can be traced back to investments in LDRD. LDRD investments have a history of enabling significant payoffs for long-running DOE and NNSA missions and for providing anticipatory new technologies that ultimately become critical to future missions. Many of Sandia National Laboratories’ successes can be traced back to investments in LDRD. Capabilities from three LDRDs were critical to recent tests of the B61-12 gravity bomb—tests that would previously have only been performed experimentally.

Arrowsmith, Marie Danielle↗

Development and Implementation of Degree Programs in Electric Drive Vehicle Technology

The Electric-drive Vehicle Engineering (EVE) MS degree and graduate certificate programs have been continuing to make good progress, thanks to the funding and the guidance from DOE grant management group, the support from our University and College administrations, and to valuable inputs and feedback from our Industrial Advisory Board as well as our project partners Macomb Community College and NextEnergy. Table 1 below lists originally proposed Statement of Project Objectives (SOPO), which have all been completed successfully. Our program and course enrollments continue to be good and increasing, as shown in later sections. Our graduating students continue to get good job offers from local EV-related companies. Following the top recommendation from our Industrial Advisory Board, we were fortunate enough to be accepted into the prestigious EcoCAR2 (http://www.ecocar2.org/) North America university design competition, and have been having some modest success with the competition. But most importantly, EcoCAR2 offers the most holistic educational environment for integrating real-world engineering and design with our EVE graduate curriculum. Such integrations include true real-world hands-on course projects based on EcoCAR2 related tasks for the students, and faculty curricular and course improvements based on lessons and best practices learned from EcoCAR2. We are in the third and last year of EcoCAR2, and we have already formed a core group of students in pursuit of EcoCAR”3”, for which the proposal is due in early December.

33 ADVANCED PROPULSION SYSTEMS↗

Controlling Energy Performance on the Big Stage - The New York Times Company

The Times partnered with the U.S. Department of Energy (DOE) as part of DOE’s Commercial Building Partnerships (CBP) Program to develop a post-occupancy evaluation (POE) of three EEMs that were implemented during the construction of The Times building between 2004-2006. With aggressive goals to reduce energy use and carbon emissions at a national level, one strategy of the US Department of Energy is looking to exemplary buildings that have already invested in new approaches to achieving the energy performance goals that are now needed at scale. The Times building incorporated a number of innovative technologies, systems and processes that make their project a model for widespread replication in new and existing buildings. The measured results from the post occupancy evaluation study, the tools and processes developed, and continuous improvements in the performance and cost of the systems studied suggest that these savings are scalable and replicable in a wide range of commercial buildings nationwide.

99 GENERAL AND MISCELLANEOUS↗