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At least 1,495 records · Page 83
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Phase Diagram of Superfluid {sup 3}He in a Nematic Aerogel in a Strong Magnetic Field

The simultaneous effect of a nematic aerogel and a strong magnetic field on the phase diagram of superfluid {sup 3}He is considered. Using the Ginzburg–Landau theory, the domains of existence of new phases, viz., β phase (P{sub 1}), distorted β phase (P{sub 2}), distorted A phase (A{sub 4}{sup (I)}), and distorted planar phase (A{sub 4}{sup (II)}), are determined. It is shown that order parameter components of the β phase have the maximal transition temperature. The conditions for the existence of the second-order transition from the distorted β phase to the distorted planar phase is formulated.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2023

Role of spin-orbit coupling on crystal-field splitting and phase-stability of rare-earth based layered intermetallic

Layered and incommensurate heterostructures have attracted much attention for the occurrence of superconductivity and charge density waves with the possibility of intercalating foreign atoms. However, lanthanide-based heterostructures where (Eu x Sm 1-x )S and TaS 2 are alternatively stacked have been scarcely investigated. In this work, we performed phase stability, bonding behavior and electronic-structure analysis of (Eu x Sm 1-x )TaS 3 using first-principles density-functional theory methods. Our phase stability analysis suggests 50 at.% solubility of Eu in (Eu x Sm 1-x )TaS 3 compared to Eu solubility in all proportions in cubic SmS. The instability of Eu beyond 50 at.% in (Eu x Sm 1-x )TaS 3 was attributed to higher density of Eu-4f states at the Fermi-level. Based on band position calculated from spin-orbit coupling effect, we constructed a qualitative schematic of possible crystal-field analysis. The local change in bond-length and bond-angle around Eu-S in (Eu x Sm 1-x )TaS 3 correlate well with our crystal-field analysis. We believe that quantum mechanical insights provided in this work will be useful to understand other complex heterostructures.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Generative Physics-Informed Neural Network Solving Multi-Scale and Multi-Phase Plasma Chemical Flow Field

Low-temperature plasmas (LTPs) are non-equilibrium systems with near-room-temperature gas and highly energetic electrons. This makes them ideal for delicate applications in biomedicine and semiconductor manufacturing, enabling processes like wound healing, sterilization, etching, and plasma-enhanced chemical vapor deposition without thermal damage. However, LTPs involve complex chemistries, with hundreds of species and thousands of reactions, complicating their diagnosis, prediction, and control. Conventional diagnostics, such as Fourier-transform infrared spectroscopy (FTIR), laser-induced fluorescence (LIF), and optical emission spectroscopy (OES), offer limited species detection, while mass spectrometry (MS) struggles with low-sensitivity species. Additionally, LTP simulations face multi-scale challenges, as macroscopic fluid dynamics and microscopic particle collisions operate on vastly different timescales. To address these issues, we developed an artificial intelligence (AI) based diagnostic system: a generative physics-informed neural network (PINN-Gen) that can predict spatially resolved species concentrations and temperatures in LTPs by integrating experimental data from planar LIF with microscopic plasma chemical kinetics and macroscopic fluid mechanics, including plasma-liquid interactions at the interface between two phases. PINN-Gen solves no equations but checks the errors of physical laws by substituting the output from neural network, and the comparison with the experimental results. Thus, it naturally avoids the multi-scale difficulty of numerical simulations and predicts the results of conventionally unsolvable multi-scale and multi-phase problems. The real-time prediction will be robust due to the physical information used in the training of such a neural network, and only very limited input of condition required due to its generative feature.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Grand potential sintering simulations of doped UO 2 accident-tolerant fuel concepts

Chromium-doped UO is a widely-studied near-term deployable accident-tolerant fuel concept because it results in a dense, large-grain structure that increases the fuel resistance to densification, swelling, and fission gas release. A new charged-interstitial mechanism was recently proposed to describe the behavior of dopants like chromium in sintered UO 2 . Based on that mechanism, manganese was suggested as an even stronger dopant than chromium. In the current work we use mesoscale sintering simulations in an effort to validate the new mechanism. We compare the relative behavior of Cr-doped and undoped UO 2 against experimental data in the literature. We also make predictions of the relative behavior of Mn-doped UO 2 . Simulations are done using the phase field-based grand potential sintering model. Dopants have two effects on sintered UO 2 . They marginally increase the densification rate and greatly increase the average grain size. Both of these effects are individually tested in small-scale simulations. Then large 3D sintering simulations are used to test the combined behavior of both effects. The results for the densification rate simulations are consistent with experiments for Cr-doped fuels. However, we note the grain growth rates are lower than what is found in the literature for Cr-doped fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1983

Far-field distributions of semiconductor phase-locked arrays with multiple contacts

Experimental results on far-field patterns of semiconductor laser arrays with multiple contacts are reported. It is found that, by tailoring the distribution of the currents through the array elements, narrow single-lobe patterns, which are more useful in most applications, can be obtained from arrays that usually operate in a double-lobe mode. A diffraction-limited 1.8 deg-wide far field pattern was obtained from a three-element array.

Katz, J.↗
DOE OSTI2015

Phase transition studies of BiMnO{sub 3}: Mean field theory approximations

We studied the phase transition and magneto-electric coupling effect of BiMnO{sub 3} by employing mean field theory approximations. To capture the ferromagnetic and ferroelectric transitions of BiMnO{sub 3}, we construct an extended Ising model in a 2D square lattice, wherein, the magnetic (electric) interactions are described in terms of the direct interactions between the localized magnetic (electric dipole) moments of Mn ions with their nearest neighbors. To evaluate our model, we obtain magnetization, magnetic susceptibility and electric polarization using mean field approximation calculations. Our results reproduce both the ferromagnetic and the ferroelectric transitions, matching very well with the experimental reports. Furthermore, consistent with experimental observations, our mean field results suggest that there is indeed a coupling between the magnetic and electric ordering in BiMnO{sub 3}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Field-induced spin density wave and spiral phases in a layered antiferromagnet

Here we determine the low-field ordered magnetic phases of the S=1 dimerized antiferromagnet Ba 3 Mn 2 O 8 using single crystal neutron diffraction. We find that for magnetic fields between μ 0 H=8.80 T and 10.56 T applied along the $1\bar{1}0$ direction the system exhibits spin density wave order with incommensurate wave vectors of type (η,η,ε). For μ 0 H > 10.56 T, the magnetic order changes to a spiral phase with incommensurate wave vectors only along the [hh0] direction. For both field induced ordered phases, the magnetic moments are lying in the plane perpendicular to the field direction. Finally, the nature of these two transitions is fundamentally different: the low-field transition is a second order transition to a spin-density wave ground state, while the one at higher field, toward the spiral phase, is of first order.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Electronic phase separation and magnetic-field-induced phenomena in molecular multiferroic ( ND 4 ) 2 FeCl 5 · D 2 O

Electronic phase separation has been increasingly recognized as an important phenomenon in understanding many of the intriguing properties displayed in transition metal oxides. It is believed to produce fascinating functional properties in otherwise chemically homogenous electronic systems, e.g., colossal magnetoresistance manganites and high- T c cuprates. While many well-known electronically phase-separated systems are oxides, it has been argued that the same phenomenon should occur in other electronic systems with strong competing interactions. Here we report the observation of electronic phase separation in molecular (ND 4 ) 2 FeCl 5 • D 2 O, a type-II multiferroic. We show that two magnetic phases, one of which is commensurate and the other of which is incommensurate, coexist in this material. Here, their evolution under applied magnetic field produces emergent properties. In particular, our measurements reveal a field-induced exotic state linked to a direct transition from a paraelectric/paramagnetic phase to a ferroelectric/antiferromagnetic phase, a collective phenomenon that hasn't been seen in other magnetic multiferroics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Magnetic structures and excitations in a multiferroic Y-type hexaferrite BaSrCo 2 Fe 11 AlO 22

Here, we have investigated magnetic orders and excitations in a Y-type hexaferrite BaSrCo 2 Fe 11 AlO 22 (BSCoFAO), which was reported to exhibit spin-driven ferroelectricity at room temperature. By means of magnetization, electric polarization, and neutron-diffraction measurements using single-crystal samples, we establish a H-T magnetic phase diagram for magnetic field perpendicular to the c axis (H ⟂c ). This system exhibits an alternating longitudinal conical (ALC) magnetic structure in the ground state, and it turns into a non-co-planar commensurate magnetic order with spin-driven ferroelectricity under H ⟂c . The field-induced ferroelectric phase remains as a metastable state after removing magnetic field below 250 K. This metastability is the key to understanding of magnetic field reversal of the spin-driven electric polarization in this system. Inelastic polarized neutron-scattering measurements in the ALC phase reveal a magnetic excitation at around 7.5 meV, which is attributed to spin components oscillating in a plane perpendicular to the cone axis. This phasonlike excitation is expected to be an electric-field active magnon, i.e., electromagnon excitation, in terms of the magnetostriction mechanism.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Magnetic Structure and Exchange Interactions in Quasi-One-Dimensional MnCl 2 (urea) 2

MnCl 2 (urea) 2 is a new linear chain coordination polymer that exhibits slightly counter-rotated Mn 2 Cl 2 rhomboids along the chain-axis. The material crystallizes in the noncentrosymmetric orthorhombic space group Iba2, with each Mn(II) ion equatorially surrounded by four Cl – that lead to bibridged ribbons. Additionally, urea ligands coordinate via O atoms in the axial positions. Hydrogen bonds of the Cl···H–N and O···H–N type link the chains into a quasi-3D network. Magnetic susceptibility data reveal a broad maximum at 9 K that is consistent with short-range magnetic order. Pulsed-field magnetization measurements conducted at 0.6 K show that a fully polarized magnetic state is achieved at B sat = 19.6 T with another field-induced phase transition occurring at 2.8 T. Zero-field neutron diffraction studies made on a powdered sample of MnCl 2 (urea) 2 reveal that long-range magnetic order occurs below T N = 3.2(1) K. Additional Bragg peaks due to antiferromagnetic (AFM) ordering can be indexed according to the Ib'a2' magnetic space group and propagation vector τ = [0, 0, 0]. Rietveld profile analysis of these data revealed a Néel-type collinear ordering of Mn(II) ions with an ordered magnetic moment of 4.06(6) μ B (5 μ B is expected for isotropic S = 5/2) oriented along the b-axis, i.e., perpendicular to the chain-axis that runs along the c-direction. Owing to the potential for spatial exchange anisotropy and the pitfalls in modeling bulk magnetic data, we analyzed inelastic neutron scattering data to retrieve the exchange constants: J c = 2.22 K (intrachain), J a = -0.10 K (interchain), and D = -0.14 K with J > 0 assigned to AFM coupling. Lastly, this J configuration is most unusual and contrasts the more commonly observed AFM interchain coupling of 1D chains.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1994

Use of KC-135 parabolic flights to determine if brief changes in the gravity field can influence the phase and/or period of the circadian clock

In February 1994 a total of 10 hampsters flew on two separate KC-135 flights. On one flight, 25 animals experienced 31 parabolas, thus going through 31 cycles of hypergravity (up to about 1.8 G). On the other flight, the animals were exposed to 43 parabolas. fifty additional animals served as ground based controls and were treated in the same fashion as the experimental animals. The profiles of plasma GH, corisol and coricosterone from representative parabolic flight and ground control animals during pre-flight, in-flight, and post-flight conditions are depicted.

Turek, Fred W.↗
NASA NTRS1996

Optimal Signal Filtration in Optical Sensors with Natural Squeezing of Vacuum Noises

The structure of optimal receiver is discussed for optical sensor measuring a small displacement of probe mass. Due to nonlinear interaction of the field and the mirror, a reflected wave is in squeezed state (natural squeezing), two quadratures of which are correlated and therefore one can increase signal-to-noise ratio and overcome the SQL. A measurement procedure realizing such correlation processing of two quadratures is clarified. The required combination of quadratures can be produced via mixing of pump field reflected from the mirror with local oscillator phase modulated field in duel-detector homodyne scheme. Such measurement procedure could be useful not only for resonant bar gravitational detector but for laser longbase interferometric detectors as well.

Gusev, A. V.↗
DOE OSTI2012

Advanced Sample Environments for in situ Neutron Diffraction Studies of Nuclear Materials

Summaries of this presentation are: (1) the author successfully developed and commissioned three sample environments and applied them to study scientific problems of nuclear materials; (2) sample changer - reliable, unattended operation, Reiche and Vogel, 2010; (3) creep furnace - 1000 C, 2.7 kN, texture, Reiche et al., 2012; (4) Zr-2.5Nb pressure tubes - deconvolute the contributions of heating, phase transformation, deformation at temperature in the {beta}-field, and phase transformation during cooling; (5) our data informs currently developed mechanical models predicting texture evolution during phase transformation and high temperature deformation (MST-8, LANL); (6) high-temperature furnace - >2200 C, texture, paper in progress; (7) UC - Bowman's NaCl-type structure correct for cubic UC{sub 2}, recent reactor safetly calculations by Chevalier and Fischer (2001) and independent work by Freyss (2010) incorrect, as fluorite structure is assumed; and (8) UC - order-disorder transition starting at 1800 C discovered which will improve current models, as these do not predict this transition (e.g. Basak, 2007), or confirm the prediction (Wen et al., 2012, T-1, LANL).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗