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At least 1,495 records · Page 83

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NASA NTRS1975

Ancient meteoritic component in Apollo 17 boulders

The reported investigation is concerned with the resolution of a number of questions related to the ancient meteoritic component in Apollo 17 boulders. Numerical taxonomic methods have been adopted to objectively group the components. Only the nonvolatile siderophile elements have been used for the classification. Efforts were made to obtain data on the metal composition of breccias analyzed for trace elements, to determine if metal homogeneity was reflected in siderophile ratios. Thirty-one samples were analyzed of which twenty-eight have significant siderophile contents. It is concluded that highland breccias are largely the product of large basin-forming impacts. Highland soils are then produced by comminution of the breccias by small local impacts and micrometeorite bombardment. The long-lived component of bulk soils considered by Baedecker et al. (1974) is thought to contain a substantial micrometeorite contribution, plus assorted debris.

Higuchi, H.↗

NASA NTRS1979

Ion-beam analysis of meteoritic and lunar samples

Charged particle-induced nuclear reactions were used in the following problems: the determination of elemental abundances of boron and fluorine in carbonaceous chondritic meteorites; the identification of products of lunar vulcanism; and the study of solar wind-implanted atoms in lunar materials. The technique was seen as an important supplement to other methods of elemental and isotopic analysis. This was especially true for cases involving light elements at very low concentrations or where high resolution depth distribution information was needed in non-destructive analysis.

Tombrello, T. A.↗

NASA NTRS1978

Meteorites - Relics from the early solar system

Data on meteorite mineralogy, texture, and composition are reviewed and analyzed in order to obtain constraints on the temperatures, pressures, time-spans, and chemical environments that existed in the early solar system. It emerges that the temperature in the nebula was above 1400 K. Accretion into small bodies appears to have begun just below this temperature, when the major condensates, metal and silicate, appeared. Pressures inferred are about 0.000001 to 0.001 atm, suggesting a massive nebula with low accretion efficiency.

Larimer, J. W.↗

NASA NTRS1978

Thermal metamorphism of primitive meteorites. VII - Mineralogy-petrology of heated Murchison /C2/ and alteration of C30 and other chondrites

Alterations caused by week-long heating of Murchison in a low-pressure environment at 400-1400 C are of two types: thermodynamically favored kinetically controlled or thermodynamically controlled rapid processes. Kinetically controlled changes pertinent to chondritic evolution and which vary progressively with temperature in heated Murchison include: chondrule blurring; matrix coarsening; increasing mean Fa and Fs contents of ferromagnesian silicates; equilibration of olivine; increasing Mg/Si, Ca/Si, Al/Si, and Cr/Si and decreasing Fe/Si, Ni/Si, and S/Si in matrix; Cr loss from kamacite; and homogenization and Ni-zoning in taenite at high temperatures. Low-temperature thermodynamically controlled changes include: transformation of high-Ni troilite to low-Ni and formation of Ni- and Co-rich metal from pentlandite. High-temperature changes include formation of Cr-rich magnetite and formation of a Ni-rich sulfide similar to that found in highly altered chondrites. Trends resulting from processes of both kinds in Murchison are consistent with characteristics of a postulated C30 metamorphic suite, while those changes caused by reactions of the second kind are similar to those in heavily shock-heated ordinary chondrites and the heavily metamorphosed C5-6 chondrite, Mulga West. Either the simulations support the metamorphic origin of the C30 suite and other thermally induced changes or the natural alterations support the utility of laboratory simulations in studying meteoritic evolution.

Matza, S. D.↗

NASA NTRS1979

Trace elements in shergottite meteorites - Implications for the origins of planets

The average concentrations of 19 siderophile and volatile elements in shergottite meteorites differ from those in terrestrial basalts by less than a factor of ten. This observation undermines claims that the abundances of siderophile and volatile elements in the Earth's upper mantle are uniquely terrestrial. Claims that similarities in the Moon's siderophile element pattern imply a terrestrial origin for the Moon are also weakened. The implication that basalt source regions on the asteroidal parent body of the shergottites resembled the terrestrial upper mantle constrains models of planetary formation and evolution. Heterogeneous accretion models may explain many of the similarities between these planets. Alternatively, separation of sulfide from basaltic magmas or their source regions on the Earth and the shergottite parent body may explain some of these similarities.

Stolper, E.↗

NASA NTRS1979

The Shaw meteorite - History of a chondrite consisting of impact-melted and metamorphic lithologies

Three intermingled lithologies are identified in the Shaw L-group chondrite: a light-colored lithology with a poikilitic texture, consisting of olivine and augite crystals surrounded by larger orthopyroxene grains; a dark-colored lithology containing remnant chondrules and exhibiting a microgranular texture; and a gray lithology which appears to be intermediate between the other two. Contrary to published opinions, the Shaw meteorite contains normal L-group chondrite abundances of metal and troilite, though these phases are irregularly distributed. The lithological analyses suggest that 4.52 Byr ago an impact took place on the L-group chondrite parent object of Shaw.

Taylor, G. J.↗

NASA NTRS1979

Magnesium isotopic variations in hibonite from the Murchison meteorite - An ion microprobe study

Ion microprobe measurements show that some hibonite crystals from refractory-rich inclusions in Murchison contain isotopically anomalous Mg. The observed effects include: (1) the largest mass fractionation ever observed in nature for this element, about 10% per mass unit; (2) small Mg-26 excesses; (3) isotopic variability on a scale of microns or less in individual grains. These observations are corroborative evidence for the primitiveness of the Murchison inclusions. More importantly, they indicate that the types of Mg isotopic anomalies previously observed in Allende and Leoville inclusions are not confined to CV meteorites.

Macdougall, J. D.↗

NASA NTRS1979

Iron-nickel sulfides in the Murchison meteorite and their relationship to phase Q1

Pentlandite from the Murchison meteorite survives HF-HCl attack and dissolves in HNO3 at room temperature, thus satisfying the operational definition of phase Q1, the proposed major carrier of carbonaceous chondrite fission xenon. However, identification of pentlandite with that phase is problematical in view of apparently differing thermal stabilities.

Kerridge, J. F.↗

NASA NTRS1979

The magnetic effects of brecciation and shock in meteorites. II - The ureilites and evidence for strong nebular magnetic fields. III - The achondrites

Magnetic studies were conducted on samples of the ureilitic meteorites Goalpara, Havero, Novo Urei, and Kenna. Measurements included bulk magnetic susceptibility, natural remanent magnetization (NRM), saturation remanence, and the demagnetization behavior of NRM and saturation remanence. An approximate 'fossil' magnetic field intensity was determined by analysis of coercivity spectra of NRM and saturation remanence after reheating. It was found that the magnetic susceptibility of ureilites increased with severity of shock, and the NRM intensity decreases while its coercivity spectrum generally hardens with increasing shock. Goalpara and Kenna are distinguished by unexpectedly homogeneous, strong, stable, and directionally clustered NRM, indicative of a unique original magnetizing event. The results support the assertion that both ureilites and carbonaceous chondrites have formed from related nebular material and provide further evidence for a strong external magnetic field during the accretional stages and throughout an early bombardment stage.

Brecher, A.↗

NASA NTRS1979

The origin of metal clasts in the Bencubbin meteoritic breccia

The Bencubbin meteorite is a shock-welded breccia consisting of a diverse collection of metal and silicate clasts. Several types of evidence suggest that the metal clasts in Bencubbin retain chemical abundances that were established during condensation. The Cr, Ni, P and trace element abundances are consistent with condensation calculations and are much closer to the predicted compositions of metal condensates than the CM metal particles. In addition, petrographic and chemical evidence strongly suggest that the breccia components were incorporated as solid clasts within the breccia prior to a shock heating event of very short duration, which did not produce significant metamorphic effects.

Newsom, H. E.↗

NASA NTRS1978

Fractional crystallization of iron meteorites, an experimental study

Measurements of the distribution coefficients of various elements (Ni, Co, P, Pt, Ir, Ge, Cr, and Au) between solid and liquid phases were made for FeNi alloys. A high thermal gradient crystal growing furnace was employed in order to promote plane front solidification, rapid mixing in the liquid and a minimum of diffusion in the solid. Eight measurements of the nickel distribution coefficient gave an average value of 0.91 plus or minus 0.03 and this value was independent of the Ni concentration in the range 5.5 to 8.75 wt. % Ni. Equilibrium distribution coefficients were also calculated by correcting for the diffusion boundary layer present in the liquid. These values are within 20% of the measured distribution coefficient values. Except for Co and Ni, all the measured distribution coefficient values are closer to 1.0 than those calculated by Scott (1972) for the IIIAB irons. Using the experimental values and the calculated equilibrium values for ternary additions to FeNi melts, it appears that fractional crystallization processes will not explain the observed chemical variations in the major iron meteorite groups. Alternative explanations are suggested which also recognize the fact that cooling rates vary widely in several chemical groups.

Goldstein, J. I.↗

NASA NTRS1979

Trace elements in the Allende meteorite. IV - Amoeboid olivine aggregates

INAA data for Ca, Sc, Hf, La, Ce, Sm, Eu, Tb, Yb, Lu, Os, Ir, Ru, Na, Cl, Br, Fe, Mn, Cr, Co, Au, As, and Sb are presented for ten amoeboid aggregates from the Allende meteorite. Only one lacks olivine. Seven of the remainder, as a group, have cosmic proportions of refractory lithophile and siderophile elements and appear to have formed when coarse-grained Allende inclusion material underwent partial reaction with a low-temperature nebular gas and mixture with FeO-rich olivine. The other two have highly fractionated abundances of refractory elements relative to one another compared to Cl chondrites, including Group II REE patterns, and probably formed by the mixing of fine-grained Allende inclusion material with FeO-rich olivine. Non-refractory siderophile components are also different in composition in each type of amoeboid olivine aggregate.

Grossman, L.↗

NASA NTRS1979

The distribution of zirconium and hafnium in terrestrial rocks, meteorites and the moon

It is shown that Zr and Hf are not always fractionated in terrestrial igneous differentiation or regional metamorphism. Data do support a Zr-Hf fractionation in the differentiation of the alkali olivine magma at St. Helena Island. A strong Zr-Hf fractionation exists among lunar rocks and minerals. Ilmenite is an excellent concentrator of Zr and Hf and always exhibits high Zr/Hf ratios. Chondritic meteorites exhibit rather uniform Zr abundances and Zr/Hf ratios but a distinct Zr-Hf fractionation is observed among the eucrite and diogenite achondrites.

Ehmann, W. D.↗

NASA NTRS1979

The reaction Mg/n, alpha/Ne at 14.1 and 14.7 MeV - Cross sections and implications for meteorites

Mass spectroscopic analysis of neutron-irradiated targets of natural magnesium yields cross sections of 59 + or - 14, 160 + or - 8, and 11.0 + or - 3.3 mb for Ne-20, Ne-21 and Ne-22, respectively, at 14.1 MeV and of 94 + or - 8, 152 or - 12, and 13.0 + or - 2.0 mb at 14.7 Mev. Using these cross sections, calculations modeling cosmic ray interactions in stony meteoroids of radii 20 and 26 cm predict that between the surface and the center the Ne-22/Ne-21 ratio falls more than 10% while the Ne-21 production rate rises about 30%. Calculations are compared with published neon measurements for the Keyes and St. Severin meteorites.

Reedy, R. C.↗

NASA NTRS1979

Isotopic anomalies of noble gases in meteorites and their origins. III - LL-chondrites

Nine LL-chondrites were studied by selective etching to characterize the noble gas components in three mineral fractions: HF-HCl-solubles, chromite and carbon. The Ne-20/Ar-36 ratio is considered, noting that chondrites of different petrologic types cannot all be derived from the same volatile rich ancestor, but must have formed over a range of temperatures, with correspondingly different volatile contents. Variations in the carbonaceous chondrite fission (CCFXe) component in LL3, LL5, and LL6 chondrites are discussed, noting that if CCFXe comes from a supernova, then its distribution in LL-chondrites requires three presolar carrier minerals of the right solubility properties, containing three different xenon components. However, if CCFXe comes from fission of a volatile superheavy element, then its decrease from LL3 to LL6 can be attributed to less complete condensation from the solar nebula. Finally, the three types of primordial xenon components which occur in different minerals of the same meteorite are described.

Alaerts, L.↗

NASA NTRS1979

Solubility of noble gases in serpentine - Implications for meteoritic noble gas abundances

An investigation of the solubilities of the noble gases from synthesis and solubility studies of the sheet silicate mineral serpentine in carbonaceous chondrites is presented. Hydrothermal synthesis and exchange experiments were made at 340C and 1 kbar with noble gas partial pressures from 2 times 10 to the -8th power to 0.1 atm. The measured distribution coefficients for noble gases are not sufficiently high to account for the trapped noble gases in carbonaceous chondrites by exchange in solar nebula if meteoritic minerals have comparable distribution coefficients. Also, serpentine gains and loses noble gases to approach equilibrium values with the terrestrial atmosphere, indicating that this exposure may have influenced the noble gas abundances in phyllosilicate minerals of these chondrites. The dispersion of K-Ar ages of carbonaceous chondrites could be the result of phyllosilicates approaching equilibrium solubility of atmospheric Ar-40.

Zaikowski, A.↗

NASA NTRS1980

Primordial refractory metal particles in the Allende meteorite

Refractory metal particles containing Os, Re, W, Mo, Ir, and Ru were observed in a Ca-Al-rich inclusion in the Allende meteorite. These particles are the closest to unaltered primordial metal condensates from a nebula yet reported, and appear to have been isolated from the nebula before the condensation of refractories was complete. Computer calculations of condensation indicate that the temperature of isolation appears to be close to the calculated temperature of first formation of oxides (about 1620 K at 0.0001 atm) indicating that isolation may have been effected by coating of the particles by oxides.

Blander, M.↗

NASA NTRS1979

74001 drive tube - Siderophile elements match II B iron meteorite pattern

Eight siderophile elements, seven volatile elements, and U were determined in three samples from 74001 by radiochemical neutron activation analysis. The siderophile pattern closely corresponds to the addition of approximately 0.1% of II B iron meteorites, and the enrichment of nonsiderophile volatile elements seems to be derived from lunar sources with variation generally following Se content. In addition, in 74001 (predominantly black glass), moderately volatile elements (Ag, Zn) are more abundant than In, Cd, and particularly Bi, while in 74220 (mainly orange glass), Ag, Zn, In, and Cd are almost equally abundant, but Bi is as low as in 74001.

Morgan, J. W.↗