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At least 1,495 records · Page 83

ELECTRON AND PROTON ACCELERATION DURING THE FIRST GROUND LEVEL ENHANCEMENT EVENT OF SOLAR CYCLE 24

High-energy particles were recorded by near-Earth spacecraft and ground-based neutron monitors (NMs) on 2012 May 17. This event was the first ground level enhancement (GLE) of solar cycle 24. In this study, we try to identify the acceleration source(s) of solar energetic particles by combining in situ particle measurements from the WIND/3DP, GOES 13, and solar cosmic rays registered by several NMs, as well as remote-sensing solar observations from SDO/AIA, SOHO/LASCO, and RHESSI. We derive the interplanetary magnetic field (IMF) path length (1.25 {+-} 0.05 AU) and solar particle release time (01:29 {+-} 00:01 UT) of the first arriving electrons by using their velocity dispersion and taking into account contamination effects. We found that the electron impulsive injection phase, indicated by the dramatic change in the spectral index, is consistent with flare non-thermal emission and type III radio bursts. Based on the potential field source surface concept, modeling of the open-field lines rooted in the active region has been performed to provide escape channels for flare-accelerated electrons. Meanwhile, relativistic protons are found to be released {approx}10 minutes later than the electrons, assuming their scatter-free travel along the same IMF path length. Combining multi-wavelength imaging data of the prominence eruption and coronal mass ejection (CME), we obtain evidence that GLE protons, with an estimated kinetic energy of {approx}1.12 GeV, are probably accelerated by the CME-driven shock when it travels to {approx}3.07 solar radii. The time-of-maximum spectrum of protons is typical for shock wave acceleration.

79 ASTRONOMY AND ASTROPHYSICS↗

Structural and magnetic characterization of as-prepared and annealed FeCoCu nanowire arrays in ordered anodic aluminum oxide templates

Herein, we report on the preparation, structure, and magnetic characterization of FeCoCu nanowire arrays grown by DC electrodeposition inside self-assembled ordered nanopores of anodic aluminum oxide templates. A systematic study of their structure has been performed both in as-prepared samples and after annealing in the temperature range up to 800 °C, although particular attention has been paid to annealing at 700 °C after which maximum magnetic hardening is achieved. The obtained nanowires have a diameter of 40 nm and their Fe{sub 0.28}Co{sub 0.67}Cu{sub 0.05} composition was confirmed by energy dispersive X-ray spectroscopy (EDS). Focused ion-beam lamellas of two samples (as-prepared and annealed at 700 °C) were prepared for their imaging in the high-resolution transmission electron microscopy (HRTEM) perpendicularly to the electron beam, where the obtained EDS compositional mappings show a homogeneous distribution of the elements. X-ray diffraction analysis, and selected area electron diffraction (SAED) patterns confirm that nanowires exhibit a bcc cubic structure (space group Im-3m). In addition, bright-dark field images show that the nanowires have a polycrystalline structure that remains essentially the same after annealing, but some modifications were observed: (i) an overall increase and sharpening of recrystallized grains, and (ii) an apparent shrinkage of the nanowires diameter. Obtained SAED patterns also show strong textured components with determined <111> and <112> crystalline directions parallel to the wires growth direction. The presence of both directions was also confirmed in the HRTEM images doing Fourier transform analyses. Magnetic measurements show strong magnetic anisotropy with magnetization easy axis parallel to the nanowires in as-prepared and annealed samples. The magnetic properties are tuned by suitable thermal treatments so that, maximum enhanced coercivity (∼2.7 kOe) and normalized remanence (∼0.91 Ms) values are achieved after annealing at temperature of 700 °C. The contribution of the changes in the crystalline structure, induced by the heat treatment, to the magnetic hardening of the FeCoCu nanowires is discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Magnetically induced optical activity and dichroism of gadolinium oxide nanoparticle-based ferrofluids

The present work reports on magnetically induced optical activity (such as Faraday rotation and linear dichroism) of pristine and gamma-irradiated gadolinium oxide (Gd{sub 2}O{sub 3}) nanoparticle-based ferrofluids. The ferrofluids were produced by dispersing N-cetyl-N,N,N-trimethyl ammonium bromide (CTAB)-coated {approx}9-nm-sized Gd{sub 2}O{sub 3} particles in a carrier fluid of ethanol. The ferrofluids were then irradiated with 1.25 MeV energetic gamma rays (dose: 868 Gy and 2.635 kGy). Irradiation-led formation of a number of point defects was revealed through high resolution electron microscopy. The interaction of light with the ionized point defects is believed to have caused substantial improvement in the magneto-optic response of irradiated magnetic fluids.

36 MATERIALS SCIENCE↗

A microstructural analysis of isoprenol ether-based polycarboxylates and the impact of structural motifs on the dispersing effectiveness

Generally, polycarboxylate superplasticizers (PCEs) are synthesized via aqueous free radical copolymerization. The conditions during copolymerization such as relative reactivity and feeding mode and ratio of monomers can cause different monomer sequences in the final product. In this study, the sequence of monomers in PCE polymers synthesized from acrylic acid and isoprenyloxy polyethylene glycol (IPEG) macromonomer was characterized by {sup 13}C nuclear magnetic resonance (NMR) spectroscopy. Three different triads of monomer sequences (EAE, AAE and AAA; E = ether, A = acid monomer) were detected. It was found that IPEG PCEs predominantly contain the structural motifs of AAE and EAE, and less of AAA. Higher additions of acrylic acid do not incorporate into the structure of PCE, but convert to HMW polyacrylate as by-product instead. A PCE with optimal dispersing effectiveness was achieved at high contents of IPEG macromonomer, a molecular weight (M{sub w}) around 40,000 Da and narrow molecular weight distribution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Structural and Magnetic Properties of Co{sub 100−x}Pd{sub x} Thin Films Evaporated on Si (100) Substrate

The structural and magnetic properties of Co{sub 100−x}Pd{sub x} thin films grown under vacuum by physical vapor deposition (PVD) on Si (100) are reported. The thicknesses of the samples were measured with a DEKTAK 150 profilometer; chemical composition was analyzed by energy dispersive X-ray analyses (EDX). Microscopic characterizations of the films were done with X-ray diffraction (XRD) and we conclude that all the samples were polycristalline with an hcp structure. The hysteresis loops are performed by means of vibrating sample magnetometer (VSM) and we point up that all the samples present a planar ferromagnetic anisotropy. The saturation magnetization decreases as the palladium content increases and high values of the squareness up to 0.62 were measured. All these results are analyzed and correlated.

36 MATERIALS SCIENCE↗

Room temperature ferroelectric and magnetic investigations and detailed phase analysis of Aurivillius phase Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} thin films

Aurivillius phase Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} (BTF7C3O) thin films on {alpha}-quartz substrates were fabricated by a chemical solution deposition method and the room temperature ferroelectric and magnetic properties of this candidate multiferroic were compared with those of thin films of Mn{sup 3+} substituted, Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Mn{sub 0.3}O{sub 15} (BTF7M3O). Vertical and lateral piezoresponse force microscopy (PFM) measurements of the films conclusively demonstrate that BTF7C3O and BTF7M3O thin films are piezoelectric and ferroelectric at room temperature, with the major polarization vector in the lateral plane of the films. No net magnetization was observed for the in-plane superconducting quantum interference device (SQUID) magnetometry measurements of BTF7M3O thin films. In contrast, SQUID measurements of the BTF7C3O films clearly demonstrated ferromagnetic behavior, with a remanent magnetization, B{sub r}, of 6.37 emu/cm{sup 3} (or 804 memu/g), remanent moment = 4.99 Multiplication-Sign 10{sup -5} emu. The BTF7C3O films were scrutinized by x-ray diffraction, high resolution transmission electron microscopy, scanning transmission electron microscopy, and energy dispersive x-ray analysis mapping to assess the prospect of the observed multiferroic properties being intrinsic to the main phase. The results of extensive micro-structural phase analysis demonstrated that the BTF7C3O films comprised of a 3.95% Fe/Co-rich spinel phase, likely CoFe{sub 2-x}Ti{sub x}O{sub 4}, which would account for the observed magnetic moment in the films. Additionally, x-ray magnetic circular dichroism photoemission electron microscopy (XMCD-PEEM) imaging confirmed that the majority of magnetic response arises from the Fe sites of Fe/Co-rich spinel phase inclusions. While the magnetic contribution from the main phase could not be determined by the XMCD-PEEM images, these data however imply that the Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} thin films are likely not single phase multiferroics at room temperature. The PFM results presented demonstrate that the naturally 2D nanostructured Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} phase is a novel ferroelectric and has potential commercial applications in high temperature piezoelectric and ferroelectric memory technologies. The implications for the conclusive demonstration of ferroelectric and ferromagnetic properties in single-phase materials of this type are discussed.

36 MATERIALS SCIENCE↗

Magnetic excitation linking quasi-one-dimensional Chevrel-type selenide and arsenide superconductors

The quasi-one-dimensional Chevrel phases, A 2 M o6 Se 6 (A=Tl, In, K, Rb, Cs), are of interest due to their atypical electronic properties. The Tl and In analogs undergo a superconducting transition whereas the alkali metal analogs show charge gapping of another, not well understood type. Here we report the results of inelastic neutron scattering on polycrystalline In 2 Mo 6 Se 6 (T c =2.85 K) and Rb 2 Mo 6 Se 6 (nonsuperconducting) samples, which reveal a column of intensity with linear dispersion from [0 0 1/2] to [0 0 1] in both compounds. The observed temperature and |Q| independence together suggest the presence of unconventional carriers with a spin contribution to the excitation. This is contrary to the prevailing model for these materials, which is that they are nonmagnetic. The excitation has similar dispersion and S(Q,E,T) behavior as one observed in the structurally related superconducting compounds A 2 Cr 3 As 3 and A 2 Mo 3 As 3 (A=K, Rb, Cs), which has been interpreted as magnetic in origin and related to Fermi surface nesting. The connection is unexpected because the calculated Fermi surface of the arsenides differs substantially from the A 2 Mo 6 Se 6 compounds, and many consider them distinct classes of materials. This observation suggests a hidden link in the physics between both classes of superconductors, perhaps originating from their quasi-low-dimensional character.

1-dimensional systems↗

Global Hall-MHD simulations of magnetorotational instability in a plasma Couette flow experiment

Global MHD and Hall-MHD numerical simulations relevant to the Madison plasma Couette flow experiment (MPCX) have been performed using the extended MHD code NIMROD. The MPCX has been constructed to study the magnetorotational instability (MRI) in a plasma. The two-fluid Hall effect, which is relevant to some astrophysical situations such as protostellar disks, is also expected to be important in the MPCX. Here, we first derive the local Hall dispersion relation including viscosity, extending earlier work by Balbus and Terquem [Astrophys. J. 552, 235 (2001)]. The predictions of the local analysis are then compared with nonlocal calculations of linear stability of the MRI for a parameter range relevant to the MPCX. It is found that the MHD stability limit and mode structure are altered by the Hall term, and nonlocal analysis is necessary to obtain quantitatively reliable predictions for MPCX. Two-fluid physics also significantly changes the nonlinear evolution and saturation of the axisymmetric MRI. Both the Reynolds and Maxwell stresses contribute significantly to momentum transport. In the Hall regime, when the magnetic field is parallel to the rotation axis, the Maxwell stress is larger than the Reynolds stress (similar to the MHD regime). However, when the magnetic field is antiparallel to the rotation axis in the Hall regime, the Reynolds stress is much larger than the Maxwell stress. To further study the role of non-axisymmetric modes, we have also carried out fully nonlinear MHD computations. Non-axisymmetric modes play an increasingly important role as the magnetic Reynolds number increases and grow to large amplitudes in a saturated turbulent state.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Enhanced Catalytic Performance of a Ce/V Oxo Cluster through Confinement in Mesoporous SBA-15

To increase catalytic efficiency, mesoporous supports have been widely applied to immobilize well-defined metal oxide clusters due to their ability to stabilize highly dispersed clusters. Here, for this study, a redox-active heterometallic Ce 12 V 6 -oxo cluster (CeV) was first presynthesized and then incorporated into mesoporous silica, SBA-15, via a straightforward impregnation method. Scanning transmission electron microscopy (STEM) and Fourier transform infrared spectroscopy (FTIR), in concert with scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM-EDS), verified the successful introduction of the CeV cluster inside the pore of SBA-15. The 51 V magic angle spinning solid-state nuclear magnetic resonance ( 51 V MAS NMR) spectroscopy and differential pair distribution function (dPDF) analysis confirmed the structural integrity of the CeV cluster inside the SBA-15. The composite was then benchmarked for liquid-phase oxidation of 2-chloroethyl ethyl sulfide (CEES) under mild conditions and gas-phase oxidative dehydrogenation (ODH) of propane under high temperatures (up to 550 °C). The catalytic reactivity results demonstrated 8- and 14-fold increase in turnover frequency (TOF) values of the composite (CeV@10SBA-2) than the bulk CeV cluster under the same conditions for CEES oxidation and ODH, respectively. These results highlight the improved reactivity of the catalytically active CeV cluster as attributed to the higher dispersion of the discrete cluster upon immobilization within the SBA-15 support.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spatial structure and temporal evolution of energetic particle injections in the inner magnetosphere during the 14 July 2013 substorm event

Recent results by the Van Allen Probes mission showed that the occurrence of energetic ion injections inside geosynchronous orbit could be very frequent throughout the main phase of a geomagnetic storm. Understanding, therefore, the formation and evolution of energetic particle injections is critical in order to quantify their effect in the inner magnetosphere. We present a case study of a substorm event that occurred during a weak storm (Dst ~ –40 nT) on 14 July 2013. Van Allen Probe B, inside geosynchronous orbit, observed two energetic proton injections within 10 min, with different dipolarization signatures and duration. The first one is a dispersionless, short-timescale injection pulse accompanied by a sharp dipolarization signature, while the second one is a dispersed, longer-timescale injection pulse accompanied by a gradual dipolarization signature. We combined ground magnetometer data from various stations and in situ particle and magnetic field data from multiple satellites in the inner magnetosphere and near-Earth plasma sheet to determine the spatial extent of these injections, their temporal evolution, and their effects in the inner magnetosphere. Our results indicate that there are different spatial and temporal scales at which injections can occur in the inner magnetosphere and depict the necessity of multipoint observations of both particle and magnetic field data in order to determine these scales.

58 GEOSCIENCES↗

Anisotropic positive linear and sub-linear magnetoresistivity in the cubic type-II Dirac metal Pd 3 In 7

We report a transport study on Pd 3 In 7 which displays multiple Dirac type-II nodes in its electronic dispersion. Pd 3 In 7 is characterized by low residual resistivities and high mobilities, which are consistent with Dirac-like quasiparticles. For an applied magnetic field (μ 0 H) having a non-zero component along the electrical current, we find a large, positive, and linear in μ 0 H longitudinal magnetoresistivity (LMR). The sign of the LMR and its linear dependence deviate from the behavior reported for the chiral-anomaly-driven LMR in Weyl semimetals. Interestingly, such anomalous LMR is consistent with predictions for the role of the anomaly in type-II Weyl semimetals. In contrast, the transverse or conventional magnetoresistivity (CMR for electric fields E⊥μ 0 H) is large and positive, increasing by 10 3 –10 4 % as a function of μ 0 H while following an anomalous, angle-dependent power law ρ xx α (μ 0 H) n with n(θ) ≤ 1. The order of magnitude of the CMR, and its anomalous power-law, is explained in terms of uncompensated electron and hole-like Fermi surfaces characterized by anisotropic carrier scattering likely due to the lack of Lorentz invariance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effect of the electronic charge gap on LO bond-stretching phonons in undoped La 2 CuO 4 calculated using LDA + U

Typical density-functional theory calculations that wrongly predict undoped cuprates to be metallic also predict Cu-O half- and full-breathing phonon energies that are significantly softer than observed, presumably because of weak on-site Coulomb repulsion on the Cu 3d orbitals. We used DFT+U calculations with antiferromagnetic supercells of La 2 CuO 4 to establish correlation between the on-site repulsion strength, tuned via adjusting the value of U, and phonon dispersions. Here, we find that breathing and half-breathing phonons reach experimental values when U is tuned to obtain the correct optical gap and magnetic moments. We demonstrate that using distorted supercells within DFT+U is a promising framework to model phonons in undoped cuprates and other perovskite oxides with complex, interrelated structural and electronic degrees of freedom.

36 MATERIALS SCIENCE↗

Characterization of the structure and tectonic of South America

Geologic studies of the South American plate were undertaken. The Guayana shield is reasonably well studied, and although data are sparce, the central Brazilian shield appears similar. Both the Amazon and Parnaiba basins seem to be related to an aulocogen structure. The collection of crustal structure information and the generation of measurement of surface wave dispersion in the shield areascontinues. Long period seismograms are digitized and analyzed. Exisiting crusted and upper mantle studies were indexed. Both MAGSAT scaler and vector magnetic anomaly data were used with regional gravity anomaly data to investigate the regional tectonic features of the South American plate.

Keller, G. R.↗

Directivity of Bremsstrahlung radiation from relativistic beams and the Gamma-Rays from solar flares

It has been observed that flares with greater than 10 Mev gamma-ray emission are concentrated around the solar limb with a dispersion of 10 to 20 degrees. It is shown that the bremsstrahlung by relativistic electrons is responsible for such gamma-rays and that the expected relativistic beaming cannot explain this dispersion. It is argued that this dispersion is predominately a reflection of the pitch angle distribution of the electrons. Then it is shown that this requires a small variation of the magnetic field from the point where the electrons are injected to the photosphere and a nearly isotropic (in the downward direction) pitch angle distribution at the injection. The influence of other effects on the observed distribution is also discussed.

Petrosian, V.↗

Directivity of bremsstrahlung radiation from relativistic beams and the gamma rays from solar flares

It has been observed that flares with greater than 10 MeV gamma-ray emission are concentrated around the solar limb with a dispersion of 10 to 20 degrees. It is shown that the bremsstrahlung by relativistic electrons is responsible for such gamma-rays and that the expected relativistic beaming cannot explain this dispersion. It is argued that this dispersion is predominately a reflection of the pitch angle distribution of the electrons. Then it is shown that this requires a small variation of the magnetic field from the point where the electrons are injected to the photosphere and a nearly isotropic (in the downward direction) pitch angle distribution at the injection. The influence of other effects on the observed distribution is also discussed.

Petrosian, V.↗

The stability of a compressible stratified shear layer

The stability of a shear layer under the effect of gravity is investigated using the compressible magnetohydrodynamic (MHD) equations, including an effective gravity term to represent the curvature effects of the flow and magnetic field line geometry. A general eigenmode equation is derived for a two-dimensional MHD fluid, and an energy-principle analysis to explain the effect of compressibility on the critical Richardson number is presented. For the case of a hyperbolic tangent shear flow and exponential density profile, it was found that, in the Boussinesq approximation, the compressibility raises the critical Richardson number from 1/4 to as much as 1/2, with the exact value depending on the value of the magnetic field at infinity. Under approximation of a strong asymptotic magnetic field, without invoking the Boussinesq approximation, it is shown both analytically and numerically that the density gradient terms cause the shear instability to be dispersive. The long-wavelength stability boundary for the Richardson number J = 0 is characterized by a normalized phase velocity c =

Wang, Z.↗

Ion anisotropy instabilities in the magnetosheath

Recent observations in Earth's magnetosheath have delineated several different kinds of magnetic fluctuation spectra below the proton cyclotron frequency. This paper provides a theoretical interpretation for some of these observations describing solutions of the linear Vlasov dispersion equation for fully electromagnetic instabilities for particle distributions which model those observed in the magnetosheath. This model yields three growing modes: the proton cyclotron anisotropy the helium cyclotron anisotropy, and the mirror instabilities. The results show very good agreement with the observations of mirror-like and proton-cyclotron-like events. This agreement with observations implies that the transition between cyclotron and mirror fluctuation dominance is consistent with linear theory.

Gary, S. P.↗

Impulsive ion injections in the morning auroral region

Low altitude (less than 1000 km) measurements of ions precipitating into the morning auroral region are presented and analyzed. The ion fluxes exhibited time-energy signatures consistent with impulsive injection onto high-altitude field lines, followed by time-of-flight dispersion. The origin of these ions is investigated through the detailed examination of these signatures in conjunction with simultaneous measurements of precipitating electrons and a magnetic field model. A model is developed which indicates that the source for these particles was located in or near the magnetopause boundary layer, with the position deduced to be in the midlatitude flank region about 20-30 R(sub E) tailward of the Earth. The model explains the existence of multiple injections on a given field line as due to a quasi-periodic source, with the periodicity being about 100-200 s at the source. Several mechanisms are examined in an attempt to explain the injections, with a mechanism related to the propagation of waves on the surface of the boundary layer found to be the most plausible. The observations and results are compared to those of similar experiments and some unifying ideas are discussed.

Clemmons, J. H.↗