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At least 1,495 records · Page 83

Study of a Solar X-Ray Telescope

The highly structured nature of the outer solar atmosphere seems to be intimately linked to the presence, at the solar surface, of magnetic fields that have been generated inside the Sun and have emerged to the surface. The corona is brightest (and also hottest) at just those locations where the magnetic field has emerged from inside the Sun. Dynamo theory predicts that strong magnetic fields will be generated deep in the solar interior and that bundles or 'ropes' of magnetic flux will float to the surface. When this happens, a magnetically bipolar region will become visible, extending above the surface in a three-dimensional structure. The field lines penetrate through the surface, showing two magnetic poles, and also exhibit a three-dimensional structure above the surface. The structure created by the field emergence is rooted in the (relatively) cool photosphere and extends through the chromosphere and transition region to the corona. Thus, the magnetic field creates a region, called an active region, which contains portions at temperatures from less than 10(exp 4) K to greater than 10(exp 6) K, and is therefore visible at wavelengths from the infrared through x-rays. The locations where the magnetic field leaves and reenters the visible surface are called the 'footpoints' of the coronal structures associated with the magnetic field. The magnetic fields themselves are not directly visible. However, the hot coronal plasma is, for the most part, constrained to follow the direction of the magnetic field lines in the atmosphere. Now, 100 years after the discovery of x-rays by Wilhelm Roentgen in 1896, we can routinely make observations of the solar corona from outside the Earth's atmosphere in this region of the electromagnetic spectrum. As shown by comparing x-ray images with magnetograms, the bright corona over these bipolar magnetic regions consists of closed structures that seem to follow the orientation of the magnetic field. Although we can see down to the photosphere at x-ray wavelengths when observing the disk of the Sun, this part of the solar atmosphere emits so little that far from the peak of its Planck curve it appears dark in x-ray images. This impression of hot plasma following the magnetic field direction is further strengthened by quantitative studies that calculate coronal magnetic field strength and direction based on photospheric measurements and compare them with the observed brightness and location of the x-ray emitting structures. Such comparisons make it clear that, for the most part, the hot plasma conforms to the geometry of the magnetic field and that the coronal brightness is strongly linked to the strength of the magnetic fields which have erupted to the solar surface from the interior. It is also the case that the larger-scale, fainter corona, as well as coronal holes, are strongly influenced by the large-scale solar magnetic field. We may get a small hint of the reason that the coronal plasma outlines the direction of B by examining the thermal conductivity of a hot plasma in the presence of a magnetic field. This quantity has enormously different values in the directions parallel and perpendicular to the field for a coronal temperature of 10(exp 6) K, a particle density of 10(exp 9)/cu cm and a magnetic field strength of 100 G, the conductivity along the field is approximately 13 orders of magnitude greater than that perpendicular to the field. It is therefore not surprising that a parcel of plasma which is locally heated would conduct that heat preferentially in the direction of the field. We also note that the thermal conductivity parallel to the magnetic field increases with temperature T, while the perpendicular conductivity decreases. To the extent that the loop aspect ratio, i.e., the ratio of loop length to loop width, is determined by the thermal conductivity, we would expect that higher temperature loops are longer and thinner than cooler ones. However, if the loop width becomes smaller than the spatial resolution of the observing instrument, this effect will not be directly observable. For organizational purposes, we provide a listing of some scientific objectives for a Solar-B x-ray telescope, arranged in terms of identifiable features in the corona.

Golub, Leon↗

SPHERICAL HARMONIC ANALYSES OF INTENSITY MAPPING POWER SPECTRA

Intensity mapping is a promising technique for surveying the large-scale structure of our universe from z = 0 to z ∼ 150, using the brightness temperature field of spectral lines to directly observe previously unexplored portions of our cosmic timeline. Examples of targeted lines include the 21 cm hyperfine transition of neutral hydrogen, rotational lines of carbon monoxide, and fine-structure lines of singly ionized carbon. Recent efforts have focused on detections of the power spectrum of spatial fluctuations, but have been hindered by systematics such as foreground contamination. This has motivated the decomposition of data into Fourier modes perpendicular and parallel to the line of sight, which has been shown to be a particularly powerful way to diagnose systematics. However, such a method is well-defined only in the limit of a narrow-field, flat-sky approximation. This limits the sensitivity of intensity mapping experiments, as it means that wide surveys must be separately analyzed as a patchwork of smaller fields. In this paper, we develop a framework for analyzing intensity mapping data in a spherical Fourier–Bessel basis, which incorporates curved sky effects without difficulty. We use our framework to generalize a number of techniques in intensity mapping data analysis from the flat sky to the curved sky. These include visibility-based estimators for the power spectrum, treatments of interloper lines, and the “foreground wedge” signature of spectrally smooth foregrounds.

79 ASTRONOMY AND ASTROPHYSICS↗

Extending a 10‐node composite tetrahedral finite element for solid mechanics

Abstract We propose to extend the composite tetrahedral finite element first introduced by Thoutireddy et al. (2002) and recently reformulated by Ostien et al. (2016). We generalize the gradient operator and mass matrix to curved domains through analytical expressions weighted by subtetrahedra Jacobians. Optimal integration weights are constructed to increase the accuracy of Gaussian quadrature. We preserve the variational structure of the formulation through a new five‐field functional with additional, independent fields for the Jacobian and the pressure. This approach not only obviates volumetric locking but also yields symmetry. A deleterious soft mode, common to both the quadratic and composite tetrahedral element with constant pressure formulations is effectively stabilized through a novel convex energy penalty function. Numerous numerical examples spanning a patch test to the impact of a Taylor bar demonstrate the accuracy, robustness, and convergence of the extended composite tetrahedral element for application to structural metals.

Foulk III, James W.↗

The Plasma Simulation Code: A modern particle-in-cell code with patch-based load-balancing

This work describes the Plasma Simulation Code (psc), an explicit, electromagnetic particle-in-cell code with support for different order particle shape functions. We review the basic components of the particle-in-cell method as well as the computational architecture of the psc code that allows support for modular algorithms and data structure in the code. We then describe and analyze in detail a distinguishing feature of psc: patch-based load balancing using space-filling curves which is shown to lead to major efficiency gains over unbalanced methods and a previously used simpler balancing method.

Computer Science↗

Near-infrared and blue cooperative Yb3+ luminescence in Lu3Sc2Ga3O12 nano-garnets

Highlights: • Lu{sub 3}Sc{sub 2}Ga{sub 3}O{sub 12} nano-garnets doped with Yb{sup 3+} ions were synthesized by sol-gel method. • Concentration dependent structural and luminescence properties were investigated. • Variation of blue cooperative luminescence as a function of laser pump power has been studied. • Mechanism of blue cooperative luminescence of Yb{sup 3+} ions in these nano-garnets has been described. - Abstract: Nanocrystalline Lu{sub 3}Sc{sub 2}Ga{sub 3}O{sub 12} garnet powders doped with different concentrations of trivalent ytterbium (Yb{sup 3+}) ions have been prepared by sol-gel method. These garnet nano-powders have been characterized for their structural and luminescence properties using X-ray diffraction, diffuse reflectance and luminescence spectra. Near-infrared and blue cooperative upconversion luminescence spectra and decay curves of Yb{sup 3+} ions in these nano-garnets have been measured as a function of the optically active ion concentration. Quenching of near-infrared and cooperative luminescence intensity beyond 5.0 mol% of Yb{sup 3+} ion concentration have been observed. Variation of blue cooperative luminescence intensity with pump power has also been discussed.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Molecular Mass Growth Processes to Polycyclic Aromatic Hydrocarbons through Radical–Radical Reactions Exploiting Photoionization Reflectron Time-of-Flight Mass Spectrometry

Polycyclic aromatic hydrocarbons (PAHs) represent critical building blocks in molecular mass growth processes to carbonaceous nanoparticles, referred to as interstellar and circumstellar grains along with soot particles in astrophysical environments and combustion systems, respectively. Recent advancements on elucidating elementary steps to PAHs have utilized reactions of aromatic radicals, resonantly stabilized free radicals, and aliphatic radicals with closed shell hydrocarbons. However, the role of radical–radical reactions (RRRs) leading to PAHs has remained largely unexplored on the molecular level due to preceding experimental challenges in producing sufficiently high number densities of radical reactants for isomer-selective detection of products from bimolecular and termolecular reactions. This Account offers the latest developments in our knowledge on the mechanisms and pathways to PAHs via RRRs probed in a chemical microreactor at temperatures as high as 1600 K. Product preservation in a molecular beam coupled with synchrotron vacuum ultraviolet photoionization reflectron time-of-flight mass spectrometry and photoelectron photoion coincidence spectroscopy enabled isomer-selective detection of PAHs of up to three rings by their photoionization efficiency curves, which were fit with a linear combination of reference curves for identification. Experiments were combined with computational fluid dynamics modeling of the physicochemical processes in the microreactor, as well as high-level electronic structure calculations to reveal the reaction pathways of each system. Six distinct reaction mechanisms were discovered in this work: propargyl addition─benzannulation (PABA), methyl addition─ring expansion (MARE), cyclopentadienyl addition─naphthylization (CPAN), fulvenallenyl addition─cyclization─aromatization (FACA), benzyl addition─aromatization (BAA), and phenyl addition─pentacyclization (PAP). By systematically varying the number of carbon atoms in the radical reactants, molecular mass growth processes involving reactions between radicals with odd numbers of carbon atoms access aromatics carrying one, two, or three six-membered rings, whereas reactions between even- and odd-carbon-numbered radicals produce aromatics combining five- and six-membered rings. Our investigations reveal unconventional cycloadditions on excited state triplet surfaces, additions of radicals to low spin density carbon-centered radicals, spiroaromatic and fulvene-type intermediates, and highly strained bicyclic reaction intermediates, challenging current perceptions of PAH molecular mass growth processes. All of the listed mechanisms, except for FACA, feature endoergic reactions or barriers which lie above the separated reactants and therefore might be central to circumstellar environments of carbon-rich stars and planetary nebulae as their descendants, but they play no role in the gas phase of cold molecular clouds where temperatures as low as 10 K dominate. Altogether, this work provides detailed reaction mechanisms of PAH growth processes, advancing our knowledge of the chemistry of carbonaceous matter in the universe.

Addition reactions↗

First-Principles Study of the Voltage Profile and Mobility of Mg Intercalation in a Chromium Oxide Spinel

The development of Mg batteries, which can potentially achieve higher energy densities than Li-ion systems, is in need of cathodes that can reversibly intercalate Mg 2+ and exhibit a higher energy density than the state-of-the-art Chevrel and thio-spinel cathodes. Recent theoretical and experimental studies indicate that the oxide spinel family presents a set of promising Mg cathodes. Here specifically, in this work, we investigate Mg intercalation into the spinel-MgxCr 2 O 4 system. Using first-principles calculations in combination with a cluster expansion model and the nudged elastic band theory, we calculate the voltage curve for Mg insertion at room temperature and the activation barriers for Mg diffusion, respectively, at different Mg concentrations in the Cr 2 O 4 structure. Our results identify a potential limitation to Mg intercalation in the form of stable Mg-vacancy orderings in the Cr 2 O 4 lattice, which exhibit high migration barriers for Mg diffusion in addition to a steep voltage change. Additionally, we propose cation substitution as a potential mechanism that can be used to suppress the formation of the stable Mg-vacancy ordering, which can eventually enable the practical usage of Cr 2 O 4 as a Mg-cathode.

25 ENERGY STORAGE↗

Direct Observations of Solute Dispersion in Rocks With Distinct Degree of Sub‐Micron Porosity

Abstract The transport of chemical species in rocks is affected by their structural heterogeneity to yield a wide spectrum of local solute concentrations. To quantify such imperfect mixing, advanced methodologies are needed that augment the traditional breakthrough curve analysis by probing solute concentration within the fluids locally. Here, we demonstrate the application of asynchronous, multimodality imaging by X‐ray computed tomography (XCT) and positron emission tomography (PET) to the study of passive tracer experiments in laboratory rock cores. The four‐dimensional concentration maps measured by PET reveal specific signatures of the transport process, which we have quantified using fundamental measures of mixing and spreading. We observe that the extent of solute spreading correlate strongly with the strength of subcore‐scale porosity heterogeneity measured by XCT, while dilution is enhanced in rocks containing substantial sub‐micron porosity. We observe that the analysis of different metrics is necessary, as they can differ in their sensitivity to the strength and forms of heterogeneity. The multimodality imaging approach is uniquely suited to probe the fundamental difference between spreading and mixing in heterogeneous media. We propose that when multi‐dimensional data is available, mixing and spreading can be independently quantified using the same metric. We also demonstrate that one‐dimensional transport models have limited predictive ability toward the internal evolution of the solute concentration, when the model is solely calibrated against the effluent breakthrough curves. The data set generated in this study can be used to build realistic digital rock models and to benchmark transport simulations that account deterministically for rock property heterogeneity.

Kurotori, Takeshi [Department of Chemical Engineer↗

Leveraging public AI tools to explore systems biology resources in mathematical modeling

Predictive mathematical modeling is an essential part of systems biology and is interconnected with information management. Systems biology information is often stored in specialized formats to facilitate data storage and analysis. These formats are not designed for easy human readability and thus require specialized software to visualize and interpret results. Therefore, comprehending modeling and underlying networks and pathways is contingent on mastering systems biology tools, which is particularly challenging for users with no or little background in data science or system biology. To address this challenge, we investigated the usage of public Artificial Intelligence (AI) tools in exploring systems biology resources in mathematical modeling. We tested public AI’s understanding of mathematics in models, related systems biology data, and the complexity of model structures. Our approach can enhance the accessibility of systems biology for non-system biologists and help them understand systems biology without a deep learning curve.

59 BASIC BIOLOGICAL SCIENCES↗

Condensations of single DNA molecules induced by heptaplatin and its chiral isomer

Heptaplatin is a third-generation platinum antitumor drug. It has a chiral isomer. We studied the interactions between the two isomers and DNA by using magnetic tweezers and atomic force microscopy (AFM) to investigate the effect of chiralities of the isomers on the interactions. We found that the extension curves and average condensation rates of DNA molecules incubated with heptaplatin were nearly the same as those incubated with its chiral isomer. In addition, the structures of DNA molecules incubated with heptaplatin were also similar to those incubated with its chiral isomer. These results indicate the difference in chirality of the two isomers does not induce different interactions of the isomers with DNA. Our study may facilitate the understanding of interactions of platinum complexes with DNA and the design of new antitumor platinum complexes.

36 MATERIALS SCIENCE↗

GRB 130427A AND SN 2013cq: A MULTI-WAVELENGTH ANALYSIS OF AN INDUCED GRAVITATIONAL COLLAPSE EVENT

We performed a data analysis of the observations by the Swift, NuStar, and Fermi satellites in order to probe the induced gravitational collapse (IGC) paradigm for gamma-ray bursts (GRBs) associated with supernovae (SNe) in the terra incognita of GRB 130427A. We compare our data analysis with those in the literature. We have verified that GRB 130427A conforms to the IGC paradigm by examining the power law behavior of the luminosity in the early 10{sup 4} s of the XRT observations. This has led to the identification of the four different episodes of the binary driven hypernovae (BdHNe) and to the prediction, on 2013 May 2, of the occurrence of SN 2013cq, which was also observed in the optical band on 2013 May 13. The exceptional quality of the data has allowed the identification of novel features in Episode 3 including: (1) the confirmation and the extension of the existence of the recently discovered nested structure in the late X-ray luminosity in GRB 130427A, as well as the identification of a spiky structure at 10{sup 2} s in the cosmological rest-frame of the source; (2) a power law emission of the GeV luminosity light curve and its onset at the end of Episode 2; and (3) different Lorentz Γ factors for the emitting regions of the X-ray and GeV emissions in this Episode 3. These results make it possible to test the details of the physical and astrophysical regimes at work in the BdHNe: (1) a newly born neutron star and the supernova ejecta, originating in Episode 1; (2) a newly formed black hole originating in Episode 2; and (3) the possible interaction among these components, observable in the standard features of Episode 3.

79 ASTRONOMY AND ASTROPHYSICS↗

Netload Range Cost Curves for Coordinated Transmission-Distribution Planning Under DER Growth Uncertainty

The increasing penetration of distributed energy resources (DERs) requires better coordination between transmission and distribution (T&D) planning to ensure system security and cost efficiency. However, misaligned planning horizons, computational burdens, and privacy concerns hinder effective coordination, leading to either underutilized resources caused by overinvestments or reliability risks due to underinvestment. To address this challenge, we introduce netload range cost curves (NRCCs), a novel approach for managing long-term DER growth uncertainty through T&D coordination, while preserving existing data-sharing and regulatory structures. NRCCs provide pairs of (i) peak substation netload guarantees and (ii) corresponding distribution upgrade options and costs, enabling their seamless integration into transmission planning workflows. To compute NRCCs efficiently, we develop a transmission-aware distribution network planning (TADNP), which is subsequently integrated to an iterative computation procedure. These NRCCs are then embedded into an NRCC-informed transmission planning model to enable resource-efficient coordination. We illustrate our proposed approach with a case study based on realistic distribution and transmission systems in the San Francisco Bay Area, California. Our results indicate the possibility of dramatic savings in transmission investments by incorporating the proposed NRCC-integrated T&D coordination framework.

Li, Yujia↗

Toroidal Nuclear Matter Distributions of Superheavy Nuclei from Constrained Skyrme-HFB Calculations

Using the Hartree Fock Bogoliubov (HFB) self-consistent mean-field theory with the SkM* Skyrme energy-density functional, we study nuclear structure properties of even even superheavy nuclei (SHN) of Z = 120 isotopes and N = 184 isotones. The shape of the nucleus along the lowest energy curve as a function of the quadrupole moment Q20 makes a sud- den transition from the oblate spheroids (biconcave discs) to the toroidal shapes, in the region of large oblate quadrupole moments.

Hatree-Fock-Bogoiiubov Calculations↗

A parametric study of self-similar blast waves.

Comprehensive examination of self-similar blast waves with respect to two parameters, one describing the front velocity and the other the variation of the ambient density immediately ahead of the front. All possible front trajectories are taken into account, including limiting cases of the exponential and logarithmic form. The structure of the waves is analyzed by means of a phase plane defined in terms of two reduced coordinates. Loci of extrema of the integral curves in the phase plane are traced, and loci of singularities are determined on the basis of their intersections. Boundary conditons are introduced for the case where the medium into which the waves propagate is at rest. Representative solutions, pertaining to all the possible cases of blast waves bounded by shock fronts propagating into an atmosphere of uniform density, are obtained by evaluating the integral curves and determining the corresponding profiles of the gasdynamic parameters. Particular examples of integral curves for waves bounded by detonations are given, and all the degenerate solutions corresponding to cases where the integral curve is reduced to a point are delineated.

Oppenheim, A. K.↗

Methane absorption in the Jovian atmosphere. I - The Lorentz half-width in the 3nu/sub 3/ band at 1.1 micron.

The Lorentz half-width alpha (L), of the fine-structure components of the methane 3nu/sub 3/ R-branch in the Jovian spectrum has been measured from photoelectric observations of the singlet R(1). Curves of growth for the 3nu/sub 3/ R-branch manifolds have been calculated, using the measured value of alpha (L) and assuming a reflecting-layer atmosphere. The Walker-Hayes (1967) equivalent widths have been reanalyzed for rotational temperature and methane abundance. The half-width derived here is significantly different from a similar measurement made by Farmer (1969). The source of the discrepancy remains obscure.

Bergstralh, J. T.↗

On the upper atmosphere of Neptune

We have reanalyzed the Mount Stromlo observations of the occultation of BD 17 4388 by Neptune and find that the upper atmosphere is not isothermal as suggested by Freeman and Lynga. For a pure hydrogen atmosphere, our results give a temperature of 135 K at a number density of 1000 trillion per cu cm. Above this level, the possibility of a small overall positive temperature gradient is suggested by the data. The temperature structure is complicated in detail, with local 5 to 10 K fluctuations some 10 km in extent associated with the numerous spikes in the light curve. Concentrations of helium greater than 50 per cent can probably be ruled out.

Veverka, J.↗

The upper atmosphere of Uranus - A critical test of isotropic turbulence models

Observations of the August 15, 1980, Uranus occultation of KM 12, obtained from Cerro Tololo InterAmerican Observatory, European Southern Observatory, and Cerro Las Campanas Observatory, are used to compare the atmospheric structure at points separated by approximately 140 km along the planetary limb. The results reveal striking, but by no means perfect correlation of the light curves, ruling out isotropic turbulence as the cause of the light curve spikes. The atmosphere is strongly layered, and any acceptable turbulence model must accommodate the axial ratios of greater than about 60 which are observed. The mean temperature of the atmosphere is 150 plus or minus 15 K for the region near number density 10 to the 14th per cu cm. Derived temperature variations of vertical scale approximately 130 km and amplitude plus or minus 5 K are in agreement for all stations, and correlated spikes correspond to low-amplitude temperature variations with a vertical scale of several kilometers.

French, R. G.↗

Crashworthiness of light aircraft fuselage structures: A numerical and experimental investigation

The dynamic behavior of aircraft fuselage structures subject to various impact conditions was investigated. An analytical model was developed based on a self-consistent finite element (CFE) formulation utilizing shell, curved beam, and stringer type elements. Equations of motion were formulated and linearized (i.e., for small displacements), although material nonlinearity was retained to treat local plastic deformation. The equations were solved using the implicit Newmark-Beta method with a frontal solver routine. Stiffened aluminum fuselage models were also tested in free flight using the UTIAS pendulum crash test facility. Data were obtained on dynamic strains, g-loads, and transient deformations (using high speed photography in the latter case) during the impact process. Correlations between tests and predicted results are presented, together with computer graphics, based on the CFE model. These results include level and oblique angle impacts as well as the free-flight crash test. Comparisons with a hybrid, lumped mass finite element computer model demonstrate that the CFE formulation provides the test overall agreement with impact test data for comparable computing costs.

Nanyaro, A. P.↗