NASA NTRS1979
The annual variations of ozone near the tropopause are derived from aircraft exhibit year-to-year differences which are not explicitly accounted for by the simple, classical ozone transport theory. Phenomena such as tropopause lifting, interannual variations in the rates of stratospheric-tropospheric exchange and meridional mixing, contribute differently to the distribution of ozone in this altitude region. Ozone encounter climatologies have been represented by global maps which show the probabilities of exceeding ambient ozone levels of 200, 300, and 400 ppbV along flight routes during the year. Continuous ozone records obtained from the GASP system revealed the presence of gravity waves whose wavelength is of the order 20 km. The GASP data cannot, however, be utilized for the evaluation of horizontal fluxes of such quantities as ozone, sensible heat, and zonal momentum; the data are too sparsely and irregularly distributed for the computation of stable correlations. Multiple species data from the unique circumglobal flight of a Pan American airliner on 28-30 October 1977 are discussed with particular regard to the apparent interhemispheric differences in tropospheric species concentrations, variation between the Arctic and Antarctic stratospheres, to possible covariations between species, and to potential source regions for various constituents.