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DOE OSTI2020

Exploratory Efforts to Constrain Geologic Material Properties from Remote Sensing Data: Joint Study (FY2020 Final Report)

Identification and characterization of underground events from surface or remote data requires a thorough understanding of the rock material properties. However, material properties usually come from borehole data, which is expensive and not always available. A potential alternative is to use topographic characteristics to approximate the strength, but this has never been done before quantitatively. Here we present the results from the first steps towards this goal. We have found that there are strong correlations between compressive and tensile strengths and slopes, but these correlations vary depending on data analysis details. Rugosity may be better correlated to strength than slope values. More comprehensive analyses are needed to fully understand the best method of predicting strength from topography for this area. We also found that misalignment of multiple GIS datasets can have a large influence on the ability to make interpretations. Lastly, these results will require further study in a variety of climatic conditions before being applicable to other sites.

58 GEOSCIENCES↗

DOE OSTI2021

Characterization of Tank 9H Dissolution Batches in Support of Tank Closure Cesium Removal (TCCR) 1A Batch 1 Preparations

Savannah River Remediation (SRR) is currently preparing the first batch of material to be processed through the Tank Closure Cesium Removal (TCCR) 1A system. The feed for TCCR 1A will consist of dissolved saltcake from Tank 9H. Two batches of salt (Batch 1A and Batch 1B) have been dissolved in Tank 9H and subsequently transferred to Tank 10H to prepare Batch 1 for TCCR 1A. Savannah River National Laboratory (SRNL) received samples from each batch of dissolved salt prior to transfer for characterization. SRNL received both a surface and a variable depth sample from Batches 1A and 1B. In both cases no solids were observed in the surface sample, but were observed in the depth sample. For Batch 1A the variable depth sample was only slightly cloudy, while for Batch 1B the variable depth sample contained a significant amount (10.14 wt%) of solids. The solids were determined to be primarily aluminum containing phases, with only a small fraction (0.22 wt%) being sludge solids. In general, the samples from Batch 1A were more concentrated salt solutions than Batch 1B, with sodium concentrations of 8.53 and 8.57 M for the surface and filtered depth samples in Batch 1A, respectively. The sodium concentrations in Batch 1B samples ranged from 4.27 M for the surface sample to 7.57 M for the depth sample filtrate, indicating some stratification within the tank. The 137 Cs activity as well as the total Cs concentration in the filtered Batch 1A depth sample were approximately double the activity and concentration measured in the filtrate from the Batch 1B depth sample. The total Cs concentration in the Batch 1A depth sample filtrate was 22.4 mg/L, while for the Batch 1B depth sample filtrate the total Cs concentration was calculated to be 12.0 mg/L. These Cs concentrations are significantly higher than was measured in Batches 1-3 from Tank 10H dissolved saltcake which was previously processed through the original TCCR unit.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Exploratory Efforts to Constrain Geologic Material Properties from Remote Sensing Data: A Joint Study

42 ENGINEERING↗

DOE OSTI2022

Cassio Simulations of X-ray Flow Over Lumps (XFOL) Experiments [Slides]

Homogeneous media is not a good approximation for stochastic media with large clump sizes and therefore not valid for our experiments. The media created for these experiments is not Markovian distributed. Stochastic media transport methods don’t work well with non-Markovian mixtures. Sphere at various axial locations in the dmain encounter very different radflow characteristics and therefore result in different spectroscopic signatures. Ongoing analysis of tally surfaces will allow for better characterization of the radiation flow in radiation hydrodynamics simulations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2024

Functionalization of nitrogen vacancy-containing nanodiamonds with a metal-organic framework for quantum sensing applications

Nitrogen vacancy (NV)-containing nanodiamonds (NDs) are an important material in applications such as biological imaging, catalysis, and, in particular, quantum sensing. Careful manipulation of the surface coating on NV NDs is essential for both enhancing quantum sensor performance and for tuning selectivity towards specific sensing targets. Here, we demonstrate a simple synthetic approach for functionalizing NV NDs with the zeolitic imidazole framework-8 (ZIF-8) metal–organic framework (MOF), providing a well-ordered, porous scaffold for immobilizing target analytes near the NV ND surface. The composites were structurally characterized by x-ray diffraction, electron microscopy, and X-ray photoelectron spectroscopy, and these results were all consistent with NV NDs fully encapsulated by ZIF-8. Critically, the luminescent properties of the NV NDs, which are vital for quantum sensing experiments such as optically detected magnetic resonance (ODMR), are unchanged by the MOF coating. Moreover, spin relaxometry experiments indicate that the ZIF-8 coating significantly enhances the NV ND spin longitudinal relaxation time T1, a critical quantum parameter for sensing applications. Given the tremendous structural diversity of MOFs, the NV ND@MOF composites are an exciting material class with exciting implications for the development of high-performance quantum sensors.

Crawford, Scott↗

DOE OSTI2021

Azimuthal Anchoring Strength in Photopatterned Alignment of a Nematic

Spatially-varying director fields have become an important part of research and development in liquid crystals. Characterization of the anchoring strength associated with a spatially-varying director is difficult, since the methods developed for a uniform alignment are seldom applicable. Here we characterize the strength of azimuthal surface anchoring produced by the photoalignment technique based on plasmonic metamsaks. The measurements used photopatterned arrays of topological point defects of strength +1 and −1 in thin layers of a nematic liquid crystal. The integer-strength defects split into pairs of half-integer defects with lower elastic energy. The separation distance between the split pair is limited by the azimuthal surface anchoring, which allows one to determine the strength of the latter. The strength of the azimuthal anchoring is proportional to the UV exposure time during the photoalignment of the azobenzene layer.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Manufacturing Bulk Nanocrystalline Al-3Mg Components Using Cryomilling and Spark Plasma Sintering

In the current study, pure aluminum (Al) powders were cryomilled with and without 3 wt.% pure magnesium (Mg) dopant for varying durations followed by spark plasma sintering (SPS) of powders to prepare bulk components with superior mechanical properties. The crystallite sizes were determined for powders and the bulk components by analyzing the X-ray diffraction (XRD) spectrum. The calculations indicated a reduction in crystallite size with the increase in the cryomilling duration. The results also showed a more significant decrease in the crystallite sizes for Al-3Mg samples than that of pure Al. The changes in the surface morphology of powders were characterized using scanning electron microscopy (SEM). The elemental mapping analysis at nanoscale was carried out using Energy-dispersive X-ray spectroscopy (EDX) in Scanning transmission electron microscopy (STEM). The mechanical properties of the bulk components were assessed using a Vickers Microhardness tester. The test results demonstrated an improvement in the hardness of Mg-doped components. Higher hardness values were also reported with an increase in the cryomilling duration. This article discusses the mechanisms for the reduction in crystallite size for pure Al and Al-3Mg and its subsequent impact on improving mechanical properties.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Acid Dissolution Behavior of Ferritic FeCrAl Tubes Candidates for Nuclear Fuel Cladding

The international materials community is engaged in finding safer alternatives to zirconium alloys for the cladding of fuel in light water reactors. One solution is to replace the zirconium cladding using ferritic iron-chromium-aluminum (FeCrAl) alloys, which offer extraordinary resistance to high-temperature reaction with air or steam due to the formation of a protective alumina layer on the external surface. It is important to characterize the behavior of FeCrAl not only during accident conditions but in the entire fuel cycle, which may include reprocessing of the used fuel after it is removed from the power reactors. The reprocessing may involve the dissolution of the fuel rods in mineral acids. Little or nothing is known on the dissolution of FeCrAl alloys in common mineral acids, therefore the objective of this research was to study the dissolution of typical cladding tubing having two compositions of FeCrAl (APMT and C26M) in three acids (H 2 SO 4 , HNO 3 , and HCl) as a function of the temperature using both standard ASTM immersion tests as well as electrochemical tests. The dissolution behavior of the FeCrAl alloys is compared to the dissolution capability of other traditional nuclear materials such as austenitic stainless steels (304SS and 316SS) and austenitic nickel alloys (Alloy 600 and Hastelloy C-276). Results show that both C26M and APMT have a higher dissolution capability in the studied mineral acids, which will be beneficial for reprocessing procedures.

36 MATERIALS SCIENCE↗

NASA NTRS1974

Design of mechanical components for long-term performance

Review of the results of a NASA program designed to study advanced techniques for determining the long-term performance of rocket engine components. Aging and operational degradation mechanisms of metal valve seats are identified. Characterization of metal valve seat surfaces by optical signature analysis is described. The results of the development of a long-life 'zero leakage' metal valve seal designed to avoid failure by contamination, stress/strain, fatigue, and the deterioration of the surface by wear is reported. An analysis of a specific seat design showed that material strain prevention along all axes would prevent these failures. The design provided for refurbishment of the sealing surfaces during each valve cycle, thereby preventing cumulative surface damage.

Salvinski, R. J.↗

NASA NTRS1976

Device for installing rocket engines

A device for installing rocket engines is reported that is supported at a cant relative to vertical by an axially extensible, tiltable pedestal. A lifting platform supports the rocket engine at its thrust chamber exit, including a mount having a concentric base characterized by a concave bearing surface, a plurality of uniformly spaced legs extended radially from the base, and an annular receiver coaxially aligned with the base and affixed to the distal ends of said legs for receiving the thrust chamber exit. The lifting platform rests on a seat concentrically related to the pedestal and affixed to an extended end portion thereof having a convex bearing surface mated in sliding engagement with the concave bearing surface of the annular base for accommodating a rocking motion of the platform.

George, T. R., Jr.↗

NASA NTRS1981

Topology of three-dimensional separated flows

Based on the hypothesis that patterns of skin-friction lines and external streamlines reflect the properties of continuous vector fields, topology rules define a small number of singular points (nodes, saddle points, and foci) that characterize the patterns on the surface and on particular projections of the flow (e.g., the crossflow plane). The restricted number of singular points and the rules that they obey are considered as an organizing principle whose finite number of elements can be combined in various ways to connect together the properties common to all steady three dimensional viscous flows. Introduction of a distinction between local and global properties of the flow resolves an ambiguity in the proper definition of a three dimensional separated flow. Adoption of the notions of topological structure, structural stability, and bifurcation provides a framework to describe how three dimensional separated flows originate and succeed each other as the relevant parameters of the problem are varied.

Tobak, M.↗

NASA NTRS1981

The crustal structure and tectonics of South America

A preliminary crustal structure map and a bibliography of crustal and upper mantle studies for South America are given. Work on the surface wave analysis and tectonic characterizations continues.

Keller, G. R.↗

NASA NTRS1983

Short-term planetary-scale interactions over the tropics and midlatitudes. II - Winter-MONEX period

The FGGE/winter-Monex wind data from 850 and 200 mb are used to analyze the short-term teleconnections over the tropical and midlatitude Pacific and monsoonal surges in the winter of 1978-79. The data were taken twice a day, and included the total wind field, the computed rotational and divergent winds, the velocity potential, and the streamfunction. Cold surges were identified from shipboard data over the South China Sea and characterized an increase in the surface northerly wind and a surface pressure differential between Hong Kong and 30 deg N, 115 deg E. Midlatitude baroclinic disturbances triggered the cold surges, which displayed intensities dependent on the strength of the midlatitude anticyclogenesis and the intensity of the East Asia local Hadley cell. Fluctuations in the 200 mb jet streak over Japan indicated changes in eddy behavior over the North Pacific and the intensity of the East Asia local Hadley cell circulation and tropical convection. It was concluded that midlatitude synoptic systems could force equatorial convection that produces remote midlatitude responses.

Lau, K.-M.↗

NASA NTRS1985

The NO-NO2 system at laboratory surfaces

Experiments on formation and excitation of NO2 and NO molecules at (and near) laboratory surfaces of varying degrees of characterization are reviewed. On some transition metals NO is desorbed in the B sub 2 pi state, from which it radiates the familiar beta (B yields x) bands. In contrast while an ONO intermediate is inferred from isotope interchange measurements on platinum, neither ground state nor excited NO2 has been found to be desorbed under the relatively limited number of laboratory conditions so far investigated.

Barrett, J. L.↗

NASA NTRS1987

One-dimensional wave propagation in rods of variable cross section: A WKBJ solution

As an important step in the characterization of a particular dynamic surface displacement transducer (IQI Model 501), a one-dimensional wave propagation in isotropic nonpiezoelectric and piezoelectric rods of variable cross section are presented. With the use of the Wentzel-Kramers-Brillouin-Jeffreys (WKBJ) approximate solution technique, an approximate formula, which relates the ratio of the amplitudes of a propagating wave observed at any two locations along the rod to the ratio of the cross sectional radii at these respective locations, is derived. The domains of frequency for which the approximate solution is valid are discussed for piezoelectric and nonpiezoelectric materials.

Ochi, Simeon C. U.↗

NASA NTRS1986

Sputtering of sodium on the planet Mercury

It is shown here that ion sputtering cannot account for the observed neutral sodium vapor column density on Mercury, but that it is an important loss mechanism for Na. Photons are likely to be the dominant stimulus, both directly through photodesorption and indirectly through thermal desorption of absorbed Na. It is concluded that the atmosphere produced is characterized by the planet's surface temperature, with the ion-sputtered Na contributing to a lesser, but more extended, component of the atmosphere.

Mcgrath, M. A.↗

NASA NTRS1989

The Tsarev meteorite - Petrology and bidirectional reflectance spectra of a shock-blackened L chondrite

The Tsarev meteorite is a highly shocked black L5 ordinary chondrite. Meteorites of this class may have been subjected to regolith processes on or near the surface of ordinary chondrite bodies. The study of their optical alteration can provide valuable support in the spectral search for ordinary chondrite parent bodies. Although Tsarev is very dark in a cut-surface hand sample, it is characterized by subtle variations in apparent darkness, called in this work grey and black areas. Both areas are substantially optically altered from normal ordinary chondrites and are characterized by a much lower albedo and strongly suppressed absorption features. Although both areas are altered, they show differences in albedo and the strength of absorption features. Particulate samples from the black area have a slightly higher albedo and stronger absorption features, while the particulate samples from the grey area show a systematic suppression of spectral features and albedo. Chemical, mineralogical, and spectral analyses suggest that the spectral differences can be the result of one or a combination of several factors, including shock effects on the crystallographic structure of the minerals and differences in the size, distribution, and amount of metal and troilite grains.

Britt, D. T.↗

NASA NTRS1992

The Mars Observer laser altimeter investigation

The primary objective of the Mars Observer laser altimeter (MOLA) investigation is to determine globally the topography of Mars at a level suitable for addressing problems in geology and geophysics. Secondary objectives are to characterize the 1064-nm wavelength surface reflectivity of Mars to contribute to analyses of global surface mineralogy and seasonal albedo changes, to assist in addressing problems in atmospheric circulation, and to provide geodetic control and topographic context for the assessment of possible future Mars landing sites. The principal components of MOLA are a diode-pumped, neodymium-doped yttrium aluminum garnet laser transmitter that emits 1064-nm wavelength laser pulses, a 0.5-m-diameter telescope, a silicon avalanche photodiode detector, and a time interval unit with 10-ns resolution. MOLA will provide measurements of the topography of Mars within approximately 160-m footprints and a center-to-center along-track foot print spacing of 300 m along the Mars Observer subspacecraft ground track. The elevation measurements will be quantized with 1.5 m vertical resolution before correction for orbit- and pointing induced errors. MOLA profiles will be assembled into a global 0.2 deg x 0.2 deg grid that will be referenced to Mars' center of mass with an absolute accuracy of approximately 30 m. Other data products will include a global grid of topographic gradients, corrected individual profiles, and a global 0.2 deg x 0.2 deg grid of 1064-nm surface reflectivity.

Zuber, M. T.↗