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An empirical model was developed to infer soil moisture and surface roughness from radar data. The accuracy of the inversion technique is assessed by comparing soil moisture obtained with the inversion technique to in situ measurements. The effect of vegetation on the inversion is studied and a method to eliminate the areas where vegetation impairs the algorithm is described.
A series of surface-modified clays containing nanophase (np) iron/oxyhydroxides of extremely small particle sizes, with total iron contents as high as found in Mars soil, were prepared by iron deposition on the clay surface from ferrous chloride solution. Comprehensive studies of the iron mineralogy in these 'Mars-soil analogs' were conducted using chemical extractions, solubility analyses, pH and redox, x ray and electron diffractometry, electron microscopic imaging specific surface area and particle size determinations, differential thermal analyses, magnetic properties characterization, spectral reflectance, and Viking biology simulation experiments. The clay matrix and the procedure used for synthesis produced nanophase iron oxides containing a certain proportion of divalent iron, which slowly converts to more stable, fully oxidized iron minerals. The noncrystalline nature of the iron compounds precipitated on the surface of the clay was verified by their complete extractability in oxalate. Lepidocrocite (gamma-FeOOH) was detected by selected area electron diffraction. It is formed from a double iron Fe(II)/Fe(III) hydroxyl mineral such as 'green rust', or ferrosic hydroxide. Magnetic measurements suggested that lepidocrocite converted to the more stable meaghemite (gamma-Fe203) by mild heat treatment and then to nanophase hematite (aplha-Fe203) by extensive heat treatment. Their chemical reactivity offers a plausible mechanism for the somewhat puzzling observations of the Viking biology experiments. Their unique chemical reactivities are attributed to the combined catalytic effects of the iron oxide/oxyhydroxide and silicate phase surfaces. The mode of formation of these (nanophase) iron oxides on Mars is still unknown.
This study outlines a method for the estimation of regional patterns of surface moisture availability (M(sub 0)) and fractional vegetation (Fr) in the presence of spatially variable vegetation cover. The method requires relating variations in satellite-derived (NOAA, Advanced Very High Resolution Radiometer (AVHRR)) surface radiant temperature to a vegetation index (computed from satellite visible and near-infrared data) while coupling this association to an inverse modeling scheme. More than merely furnishing surface soil moisture values, the method constitues a new conceptual and practical approach for combining thermal infrared and vegetation index measurements for incorporating the derived values of M(sub 0) into hydrologic and atmospheric prediction models. Application of the technique is demonstrated for a region in and around the city of Newcastle upon Tyne situated in the northeast of England. A regional estimate of M(sub 0) is derived and is probabbly good for fractional vegetation cover up to 80% before errors in the estimated soil water content become unacceptably large. Moreover, a normalization scheme is suggested from which a nomogram, `universal triangle,' is constructed and is seen to fit the observed data well. The universal triangle also simplifies the inclusion of remotely derived M(sub 0) in hydrology and meteorological models and is perhaps a practicable step toward integrating derived data from satellite measurements in weather forecasting.
The thermal emision of two palagonitic soils, common visible and near infrared spectral analogs for bright soils on Mars, was measured over the wavelength range of 5 to 25 micrometers (2000 to 400/cm) for several partical size separates. All spectra exhibit emissivity features due to vibrations associated with H2O and SiO. The maximum variability of emissivity is approximately 20% in the short wavelength region (5 to 6.5 mirometers, 2000 to 1500/cm), and is more subdued, less than 4%, at longer wavelengths. The strengths of features present in the infrared spectra of Mars cannot be solely provided by emissivity variations of palagonite; some other material or mechanism must provide additional absorptions(s).
Analytical transmission electron microscope (TEM) observations reveal that ilmenite grains sampled from the sub-10 micron size fraction of Apollo 11 (10084) and Apollo 16 (61221, 67701) soils have rims 10-300 nm thick that are chemically and microstructurally distinct from the host ilmenite. The rims have a thin outer sublayer 10-50 nm thick that contains the ilmenite-incompatible elements Si, Al, Ca and S. This overlies a relatively thicker (50-250 nm) inner sublayer of nanocrystalline Ti-oxide precipitates in a matrix of single-crystal ilmenite that is structurally continuous with the underlying host grain. Microstructural information, as well as data from x-ray spectrometry (EDS) and electron energy loss spectrometry (EELS) analysis of the inner sublayer, suggest that both the inner and outer sublayer assemblages are reduced and that the inner layer is depleted in Fe relative to the underlying ilmenite. The chemistry of the outer sublayer suggests that it is a surface deposit of sputtered or impact-vaporized components from the bulk lunar soil. The inner sublayer is part of the original host grain that has been physically and chemically processed, but not amorphized, by solar ion irradiation and possibly some subsolidus heating. The fact that the deposited outer sublayer is consistently much thinner than the radiation-altered inner sublayer indicates that only a minor fraction of the total rim volume is a product of vapor or sputter deposition. This finding is in contrast to recent descriptions of thick deposited layers on one-third of regolith silicate grains and indicates that ilmenite and silicate rims as a group are different in the fraction of deposited material that they contain.
The objectives of the study are: (1) Analysis of SIR-C/X-SAR response to soil moisture, vegetation and surface roughness and development of an algorithm to retrieve these parameters; (2) Combination of the visible and near-infrared data and the SIR-C/X-SAR data to improve the range and accuracy of vegetation classification; (3) Testing of theoretical models for microwave propagation with SIR-C/X-SAR and microwave radiometric measurements over rough surfaces; and (4) Evaluation of a water balance model using SIR-C/X-SAR derived soil moisture values and other ancillary data. Progress, significant results and future plans are presented.
Using a sensitive high performance liquid chromatography technique, we have analyzed both the hot water extract and the acid hydrolyzed hot water extract of lunar soil collected during the Apollo 17 mission. Both free amino acids and those derived from acid labile precursors are present at a level of roughly 15 ppb. Based on the D/L amino acid ratios, the free alanine and aspartic acid observed in the hot water extract can be entirely attributed to terrestrial biogenic contamination. However, in the acid labile fraction, precursors which yield amino acids are apparently present in the lunar soil. The amino acid distribution suggests that the precursor is probably solar wind implanted HCN. We have evaluated our results with regard to the meteoritic input of intact organic compounds to the moon based on an upper limit of less than or equal to 0.3 ppb for alpha-aminoisobutyric acid, a non-protein amino acid which does not generally occur in terrestrial organisms and which is not a major amino acid produced from HCN, but which is a predominant amino acid in many carbonaceous chondrites. We find that the survival of exogenous organic compounds during lunar impact is less than or equal to 0.8%. This result represents an example of minimum organic impact survivability. This is an important first step toward a better understanding of similar processes on Earth and on Mars, and their possible contribution to the budget of prebiotic organic compounds on the primitive Earth.
The thermal emission of two palagonitic soils, common visible and near infrared spectral analogs for bright soils on Mars, was measured over the wavelength range of 5 to 25 microns (2000 to 400 cm(exp -1) for several particle size separates. All spectra exhibit emissivity features due to vibrations associated with H2O and SiO. The maximum variability of emissivity is approx. = 20% in the short wavelength region (5 to 6.5 microns, 2000 to 1500 cm(exp -1)), and is more subdued, < 4%, at longer wavelengths. The strengths of features present in infrared spectra of Mars cannot be solely provided by emissivity variations of palagonite; some other material or mechanism must provide additional absorption(s).
Landsat thematic mapper data are used to estimate instantaneous regional-scale surface water and energy fluxes in a semi-arid Great Basin desert of the western United States. Results suggest that it is possible to scale from point measurements of environmental state variables to regional estimates of water and energy exchange. This research characterizes the unifying thread in the classical climate-topography-soil-vegetation relation -the surface water and energy balance-through maps of the partitioning of energy throughout the landscape. The study was conducted in Goshute Valley of northeastern Nevada, which is characteristic of most faulted graben valleys of the Basin and Range Province of the western United States. The valley comprises a central playa and lake plain bordered by alluvial fans emanating from the surrounding mountains. The distribution of evapotranspiration (ET) is lowest in the middle reaches of the fans where the water table is deep and plants are small, resulting in low evaporation and transpiration. Highest ET occurs in the center of the valley, particularly in the playa, where limited to no vegetation occurs, but evaporation is relatively high because of a shallow water table and silty clay soil capable of large capillary movement. Intermediate values of ET are associated with large shrubs and is dominated by transpiration.
Landsat Thematic Mapper data is used to estimate instantaneous regional-scale surface water and energy fluxes in a semi-arid Great Basin desert of the western United States. Results suggest that it is possible to scale from point measurements of environmental state variables to regional estimates of water and energy exchange. This research characterizes the unifying thread in the classical climate-topography-soil-vegetation relation-the surface water and energy balance-through maps of the partitioning of energy throughout the landscape. The study was conducted in Goshute Valley of northeastern Nevada, which is characteristic of most faulted graben valleys of the Basin and Range Province of the western United States. The valley comprises a central playa and lake plain bordered by alluvial fans emanating from the surrounding mountains. The distribution of evapotranspiration (ET) is lowest in the middle reaches of the fans where the water table is deep and plants are small, resulting in low evaporation and transpiration. Highest ET occurs in the center of the valley, particularly in the playa, where limited to no vegetation occurs, but evaporation is relatively high because of a shallow water table and silty clay soil capable of large capillary movement. Intermediate values of ET are associated with large shrubs and is dominated by transpiration.
Experiments in the Mars Wind Tunnel at NASA Ames Research Center show that under Mars conditions, spacesuit materials are highly susceptible to dust contamination when exposed to windblown soil. This effect was suspected from knowledge of the interaction of electrostatically adhesive dust with solid surfaces in general. However, it is important to evaluate the respective roles of materials, meteorological and radiation effects, and the character of the soil. The tunnel permits evaluation of dust contamination and sand abrasion of space suits by simulating both pressure and wind conditions on Mars. The long-term function of space suits on Mars will be primarily threatened by dust contamination. Lunar EVA activities caused heavy contamination of space suits, but the problem was never seriously manifest because of the brief utilization of the suits, and the suits were never reused. Electrostatically adhering dust grains have various detrimental effects: (1) penetration and subsequent wear of suit fabrics, (2) viewing obscuration through visors and scratching/pitting of visor surfaces, (3) penetration, wear, and subsequent seizing-up of mechanical suit joints, (4) changes in albedo and therefore of radiation properties of external heat-exchanger systems, (5) changes in electrical conductivity of suit surfaces which may affect tribocharging of suits and create spurious discharge effects detrimental to suit electronics/radio systems. Additional information is contained in the original.
The effect of vegetation on passive microwave remote sensing of soil moisture is studied. The radiative transfer modeling work of Njoku and Kong is applied to a stratified medium of which the upper layer is treated as a layer of vegetation. An effective dielectric constant for this vegetation layer is computed using estimates of the dielectric constant of individual components of the vegetation layer. The horizontally-polarized brightness temperature is then computed as a function of the incidence angle. Model predictions are used to compare with the data obtained in the Huntsville '96, remote sensing of soil moisture experiment, and with predictions obtained using a correction procedure of Jackson and Schmugge.
Spectral measurements of loose and cemented mixtures of palagonitic soil and sulfates were made to determine whether cemented soils could be identified on Mars. Cemented MgSO4 mixtures exhibit an enhanced 9 micron sulfate fundamental compared to gypsum mixtures due to more diffuse and pervasive cementing.
Plant growth is enhanced by the presence of symbiotic soil microbes. In order to better understand how plants might prosper on Mars, we set up an experiment to test whether symbiotic microbes function to enhance plant growth in a Martian soil simulant.
Correspondence and Least Squares Mixing Analysis techniques are applied to the chemical composition of Viking 1 soils and Pathfinder rocks and soils. Implications for the parent composition of local and global materials are discussed.
Results of a new grain size analysis of 0.99 g of the submillimeter fraction of the soil 10084, using the JSC methodology, are: 4.28 phi =(51 micrometers) and 2.23 phi (=213 micrometers). A significant fraction (14.2%) of the soil is less than 10 micrometers in size.
The Boreal Ecosystem-Atmosphere Study (BOREAS) Hydrology (HYD)-6 team collected several data sets related to the moisture content of soil and overlying humus layers. This data set contains percent soil moisture (by weight) (and/or water content if there is a moss/humus layer) measured from aircraft using a terrestrial gamma ray instrument. There are also data that indicate the location of the aircraft at the time it collected the terrestrial gamma ray data for the various flight lines and bins. The location information contains a list of coordinates that indicate the path of the aircraft for each bin. The data were collected during four time periods from September 1993 to September 1994 over the southern study area (SSA) and two time periods from February to August 1994 over the northern study area (NSA). The data are available in tabular ASCII files. The data files are available on a CD-ROM (see document number 20010000884) or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).
The Boreal Ecosystem-Atmosphere Study (BOREAS) Hydrology (HYD)-1 team made measurements of volumetric soil moisture at the Southern Study Area (SSA) and Northern Study Area (NSA) tower flux sites in 1994 and at selected tower flux sites in 1995-97. Different methods were used to collect these measurements, including neutron probe and manual and automated Time Domain Reflectometry (TDR). In 1994, the measurements were made every other day at the NSA-OJP (Old Jack Pine), NSA-YJP (Young Jack Pine), NSA-OBS (Old Black Spruce), NSA-Fen, SSA-OJP, SSA-YJP, SSA-Fen, SSA-YA (Young Aspen), and SSA-OBS sites. In 1995-97, when automated equipment was deployed at NSA-OJP, NSA-YJP, NSA-OBS, SSA-OBS, and SSA-OA (Old Aspen), the measurements were made as often as every hour. The data are stored in tabular ASCII files. The volumetric soil moisture data are available from the Earth Observing System Data and Information System (EOSDIS) Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). The data files are available on a CD-ROM (see document number 20010000884).