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All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Techno-economic analysis and life-cycle greenhouse gas mitigation cost of five routes to bio-jet fuel blendstocks

Decarbonizing the air transportation sector remains one of the most challenging hurdles to mitigating climate change. Lignocellulosic biomass-derived jet fuel blendstocks can contribute to the shift toward renewable, low-carbon energy sources for aircrafts. Producing these renewable jet fuel molecules from biomass requires advanced pathways with the potential for efficient and affordable conversion routes. Here, this paper presents a detailed techno-economic analysis and sensitivity analysis, including estimated minimum selling price (MSP), and life-cycle greenhouse gas (GHG) mitigation costs for five routes to four potential bio-jet fuel molecules – limonane via limonene, limonane via 1,8-cineole, tetrahydromethylcyclopentadiene dimer (RJ-4), bisabolane, and epi-isozizaane. The simulated biorefineries utilize biomass sorghum and an integrated high-gravity ionic liquid-based biomass deconstruction process. We present results reflecting the current state of the technology and potential future scenarios with improved yields. Among the conversion pathways and the fuel molecules evaluated in this study, limonane, bisabolane, and epi-isozizaane could reach an MSP of 0.73–0.91 dollars per L-Jet A (2.75–3.45 dollars per gal-Jet A) in optimized future cases, without a hypothetical lignin-derived co-product. RJ-4 requires a more costly upgrading process and catalysts, resulting in a comparatively higher MSP (1.33 dollars per L-Jet A or 5.04 dollars per gal-jet A). Based on the GHG footprints of each fuel, the minimum achievable carbon mitigation cost relative to conventional Jet-A is 29 dollars per metric ton CO 2e , which is just under double the current cap-and-trade market price in California. In the absence of any policy support, the economics could be improved through high-value uses for lignin. To reach a target selling price of 0.66 dollars per L-Jet A (2.50 dollars per gal), lignin-derived products would need to be sold for at least 1.9 dollars per kg. However, the higher energy density of these bio-based blendstocks offers valuable improvements in aircraft efficiency/range; we find that commercial airlines may be willing to pay a 4–14 cent per L premium for these bio-jet fuels. In conclusion, our results highlight the need for improvements beyond currently-reported yields for the biologically produced intermediates, identification of ideal microbial hosts, selection of metabolic pathways to achieve competitive production costs, and a focus on fuels with attractive properties that increase their value.

09 BIOMASS FUELS↗
DOE OSTI2019

Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis (FRD-17-002 Progress Report)

In the month of December, we planned to have the Site License Agreement with SPI from them for final signatures, make further progress on the market assessment for the Wood-to-Bio-oil Market Report, and continue moving towards getting the subcontracts in place with Iowa State University and Frontline BioEnergy, LLC. The hope was to be able to get the finalized Site License Agreement back from SPI/Gary Blanc this month. Unfortunately, since we were in the immediate aftermath of fire season in California, and Gary was still unavailable as a result, we did not. Thankfully, it does not appear that there will be any major difficulties with getting the agreement finalized and signed, once Gary is available again, as SPI is constant in their support and eagerness for this effort to go forward, so we are not concerned that this is a risk to the project at this time. During the month of December, further research was completed on understand and evaluating the availability and potential availability of fire clearing, and other, forestry residue in California. Further investigations into the negative emissions of biomass pyrolysis products and their upgrading for use in other products (such as fuels) by incorporating carbon capture, drying and compression, and sequestration systems were conducted. The cost to achieve the maximum amount of negative emissions from these biomass-pyrolysis products with carbon capture and sequestration techniques was calculated. Sensitivity analysis was employed to understand how feedstock collection cost and product selling price affects this cost. We continued with the process towards subcontracting with Iowa State University and Frontline BioEnergy. Increased emphasis was placed on getting an updated budget from Frontline BioEnergy, LLC., so it can be submitted for approval of replacing a subcontractor, as we understand this is of utmost importance to the CAM. Frontline reported being very close to an updated budget, waiting on contracted labor costs remaining.

09 BIOMASS FUELS↗
NASA NTRSDate not supplied

A Multi-Faceted Approach to Demonstrating Multi-Functional Integrated Medical Devices to Advance Earth-Independent Medical Operations

INTRODUCTION TO MIM DEVICES Multi-functional Integrated Medical (MIM) devices conveniently incorporate multiple medical system capabilities within one device. The NASA Exploration Medical Integrated Product Team (XM-IPT) sponsored a market survey and trade study which identified the Tempus ProTM and the LifeBot 10® as the MIM devices that best met the evaluation criteria of the trade study. The Tempus ProTM (Remote Diagnostic Technologies, Ltd., Philips Corp., Farnborough, UK) and LifeBot 10® (LifeBot Health, Chicago, IL) both provide vital sign measurements such as blood pressure, electrocardiograms, heart rate, end tidal CO2, respiration rate, pulse oximetry and temperature along with ultrasound imaging. A video laryngoscopy capability is unique to the Tempus ProTM, while the LifeBot 10® supports connectivity with a digital stethoscope, otoscope, eye exam camera, and dermatoscope. Both devices include procedural guidance capabilities and have various data transmission and report generation features. TECHNOLOGY DEMONSTRATIONS NASA’s exploration-class missions will have severe resource constraints, long return trip durations, significant communication delays, and limited resupply opportunities. The medical systems of these missions will need to fit within an Earth-Independent Medical Operations (EIMO) construct. Key features of an EIMO medical system include: 1) technologies that support the prevention, diagnosis, and treatment of spaceflight medical events; 2) components that meet mass, volume, power and crew time/training constraints; 3) consideration of the medical skill level of the astronaut caregiver; 4) collection, storage and analysis of medical data within a central data architecture; and 5) incorporation of appropriate guidance and support tools that allow crew autonomy. Evaluations are underway to determine if it will be beneficial to include MIM devices within exploration medical systems by conducting a series of planned technical demonstrations. Exploration Atmosphere Chamber studies are being performed to determine MIM functionality in a high oxygen concentration atmosphere. A side-by-side comparison of the Tempus ProTM and LifeBot 10® will be performed during ground-based demonstrations. Use of the MIM devices within an EIMO medical scenario simulation will be practiced during ground-based demonstrations in preparation for International Space Station (ISS) demonstrations of the MIM device. These various demonstrations are designed to gather evidence for or against the inclusion of MIM devices within an EIMO medical system. EXPECTED DEMONSTRATION OUTCOMES Information will be gained about the feasibility, benefits, and challenges of using a multifunctional, all-in-one, medical device for medical diagnosis. Information will also be collected about performance differences as available ground support decreases. Gaining this understanding will allow for further development of exploration medical system capabilities, which take the EIMO construct into consideration.

B. E. Lewandowski↗
DOE OSTI2021

Global Ethanol-Blended-Fuel Vehicle Compatibility Study

The objective of this study is to understand the impact of ethanol-blended fuel at various blending levels (10%, 15%, and 20% vol.) on "in-operation" vehicles built to differing emissions and manufacturing standards around the world. The study focuses on vehicles used in Canada, China, India, Indonesia, Japan, South Korea, and Mexico. Historical experience in the United States and Brazil informs the analysis. The primary study question is: Are vehicles in targeted countries physically and operationally compatible with ethanol blended fuel? For a fuel to be compatible with a vehicle, the fuel must perform its function as part of the integrated fuel-vehicle system, meaning: the car should start easily and drive normally, the fuel should not cause catastrophic fuel system leaks, the fuel should not cause corrosion or degradation of any engine or fuel system components (including emissions control components). The history of E10 use in the United States, beginning in 1978, was evaluated and shows no reliability or operability issues for cars dating back to pre-emissions-control times -- and likely included many cars manufactured in the 1960s. This strongly supports the contention that fuel chemistry and property differences between E0 and E10 are so small that any car made to international standards in the last 50 years will have a very high probability of being fully compatible with E10. This conclusion is supported by the experience in Brazil in the 1970s, where E10 was also introduced, and ethanol blending for conventional cars rapidly ramped up to even higher blend levels. A limited number of fuel system and component manufacturers supply the global market, including Bosch, Continental, Denso, Delphi, and Visteon. To reduce complexity, ethanol-compatible materials began to be integrated in fuel system designs globally. Fuel systems evolved over the following decades to incorporate ethanol-compatible materials with core subsystem families, such as in-tank fuel pumps used across several global vehicle original equipment manufacturers (OEMs). A similarly compelling case can be made that all cars at the Tier 1 (or equivalent) emissions-control technology level or higher are fully compatible with E15 blends, based on the data evaluated by the U.S. Environmental Protection Agency (EPA) and Ricardo in 2010. For cars at this technology level, the minor differences in fuel chemistry and properties between E10 and E15 are not significant. For E20, studies are not as extensive but are still highly significant. A long-term durability study conducted on mileage accumulation dynamometers presents convincing evidence that Tier 2 technology level cars have materials of construction and engine control authority for compatibility with E20, although this conclusion is not as strong as those drawn for E10 and E15, which are also partly based on real-world experience.

09 BIOMASS FUELS↗
DOE OSTI2020

Problems of Nuclear Technology and Radiation Safety

This work discusses ethical issues arising in the course of the development of nuclear technologies and related issues of radiation safety. Attention is paid to ethical dilemmas and proposed solutions. The author suggests a critical analysis of the relevant discussions, conducted, first of all, in the English-language literature, and muses on the specifics associated with their transfer to the Russian context. This study considers ethical problems arising in context of the depletion of uranium resources and nuclear waste management and including the inevitable risks for the present and future generations, such as inter- and intragenerational justice (Gardiner's problem) and the problem of the identity of future generations (Parfit’s problem); problems of collectivity and individuality in the assessment of permissible radiation doses for workers at nuclear enterprises and the population associated with the need to combine deontological and utilitarian approaches in the practice of radiation protection. The author demonstrates cultural differences in attitudes towards the safety of the current and future generations of the population of countries and regions and the associated ambiguities in the choice of technology for nuclear reactors, long-term disposal or processing of nuclear waste; double standards in ensuring the radiation safety of personnel of nuclear facilities and the population; ethical problems of risk compensation to workers of radiation-hazardous production facilities; issues of gender differences in sensitivity to radiation exposure, gender equality and discrimination in relation to access to the labor market in the nuclear industry. The article elucidates the importance of socio-humanitarian discussion of the ethical problems of nuclear technologies and radiation safety Such debates currently are almost absent in the Russian-language philosophical literature, despite its exceptional importance due to both the level of development of nuclear energy in Russia and the potential risks that these technologies pose to current and future generations of both employees of nuclear facilities and the population of the country, neighboring countries, and the world. The purpose of this article, thus, is to initiate such a discussion.

ethics of science and technology↗
DOE OSTI2022

Mechanical response and microstructure evolution from multiaxial stress relaxation in textured zircaloy nuclear cladding

Modern energy markets provide motivation for nuclear reactors to increase operational flexibility and load following capacity of existing reactor designs. The operational power changes result in fuel pellet expansion and contraction resulting in pellet-cladding mechanical interaction (PCMI) and high cladding stresses that are strongly related to stressed corrosion cracking (SCC) which can lead to fuel rod failure. This work aims to quantify the stress fields in cladding with a focus on multiaxial stress relaxation response from an imposed strain and the resulting microstructure changes in textured zircaloy claddings. Stress relaxation tests resulting in multiaxial stress fields are performed to measure the material response of Zircaloy-4 nuclear cladding. Multiple experiments using samples from the same piece of cladding are performed so samples with the same processing history may be removed at strategic points throughout mechanical testing for microstructure characterization. The microstructure evolution is analyzed with mechanical response to evaluate the static recovery impact on crystallographic texture and grain morphology. Experiments are performed at Idaho National Laboratory using an experimental device capable of applying internal pressure and independent axial load to commercial nuclear cladding at elevated temperatures with stress- or strain-controlled experimental capability. X-ray diffraction and electron backscatter diffraction are used for microstructure analysis. Rheological models are used to visualize the multiaxial stress-strain relationships and isolate elastic, plastic, and viscoplastic material properties for analysis.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2023

Design optimization of an ethanol heavy-duty engine using design of experiments and bayesian optimization

Diesel-fueled engines still hold a large market share in the medium and heavy-duty transportation sector. However, the increase in fossil fuel prices and the strict emission regulations are leading engine manufacturers to seek cleaner alternatives without a compromise in performance. Alcohol-based fuels, such as ethanol, offer a promising alternative to diesel fuel in meeting regulatory demands. Ethanol provides cleaner combustion and lower levels of soot due to its chemical properties, in particular its lower level of carbon content. In addition, the stoichiometric operating conditions of alcohol fueled engines enable the mitigation of NOx emissions in aftertreatment stage. With the promise of retrofitting diesel engines to run on ethanol to reduce emissions, the thermal efficiency of these engines remains the primary optimization target. In order to find the optimal ethanol-fueled engine design that maximizes the thermal efficiency, a large design space needs to be investigated using engineering tools. In this study, previous research by the authors on optimizing the design of a single-cylinder ethanol-fueled engine was extended to explore the design space for a heavy-duty multi-cylinder engine configuration. A heavy-duty engine setup with multiple operating conditions at different engine speeds and loads were considered. A design optimization analysis was performed to identify the potential designs that maximize the indicated thermal efficiency in an ethanol-fueled compression ignition engine. First, a computational fluid dynamics (CFD) model of the engine was validated using experimental data for four drive cycle points. Using a design of experiments (DoE) approach and a parameterized piston bowl geometry, the model was then exercised to explore the relationship among geometric features of the piston bowl and spray targeting angle and indicated thermal efficiency across all tested operating conditions. After evaluating 165~candidate designs, a piston bowl geometry was identified that yielded an increase between 1.3 to 2.2 percentage points in indicated thermal efficiency for all tested conditions, while satisfying the operational design constraints for peak pressure and maximum pressure rise rate. The increased performance was attributed to enhanced mixing that led to the formation of a more homogeneous distribution of in-cylinder temperature and equivalence ratio, higher combustion temperatures, and shorter combustion duration. Finally, a Bayesian optimization (BOpt) analysis was employed to find the optimal piston bowl geometry with a fixed spray injector angle for one of the operating conditions. Using BOpt, a piston candidate was identified that resulted in a 1.9~percentage point increase in thermal efficiency from the baseline design, yet only required 65\% of the design samples investigated using the DoE approach.

Tekgul, Bulut↗
DOE OSTI2021

Modular supply chain optimization considering demand uncertainty to manage risk

Supply chain under demand uncertainty has been a challenging problem due to increased competition and market volatility in modern markets. Flexibility in planning decisions makes modular manufacturing a promising way to address this problem. We report the problem of multiperiod process and supply chain network design is considered under demand uncertainty. A mixed integer two-stage stochastic programming problem is formulated with integer variables indicating the process design and continuous variables to represent the material flow in the supply chain. The problem is solved using a rolling horizon approach. Benders decomposition is used to reduce the computational complexity of the optimization problem. To promote risk-averse decisions, a downside risk measure is incorporated in the model. The results demonstrate the several advantages of modular designs in meeting product demands. A pareto-optimal curve for minimizing the objectives of expected cost and downside risk is obtained.

42 ENGINEERING↗
DOE OSTI2023

Hybrid Solar System (Final Scientific/Technical Report)

GTI Energy (GTI) teamed with the University of California at Merced (UCM) to scaleup the hybrid solar system (HSS) technology for demonstrating its performance at the US Gypsum (USG) plant in Plaster City, California. The technology integrates two-stage concentrating solar collector with matching particle thermal transport and storage (TSS) system to deliver cost-effective, and on-demand distributed high temperature industrial process heat up to 600°C with solar thermal, in this case to a gypsum kettle, to reduce its fuel use and carbon footprint. Current solar technologies, which reach these temperatures, are not distributable (towers) or cost-effective (dish). The research team developed a conceptual system design for host site retrofit, including preliminary heat balance, process flow diagram, particle to process heat exchanger and equipment placements at the site. Subsequently, parallel efforts were carried out at UCM to design, build and test a 12 m long commercial scale prototype concentrating thermal-only collector system and at GTI to design, build and test a matching 650°C capable particle TTS system. The nominal 50 kWth collector consists of a parabolic trough and three 4 m long two-stage receivers in series. Prior to on-sun testing, a 4 m long receiver was fabricated and successfully tested at 650 °C in a laboratory setting for 100 hrs of continuous operation showing less than 15% radiation loss. A 7 m wide x 17 m long parabolic trough was then installed at UCM for on-sun testing of the 12 m long receiver, and concurrently several 4 m long receivers were built. The optics of the parabolic trough were calibrated, and on-sun test were carried out on 12 m long receivers. During tests, the intense solar radiation (53x) caused the absorber tubes in the receivers to bend, reducing the overall optical efficiency. To address the bending issue, a self-consistent algorithm that includes ray tracing, thermal and deformation models was developed to perform thermal stress analysis on absorbers for parabolic solar collectors. Results obtained with this algorithm showed a dramatic rise in deformation as absorber tube length increases. A combined efficiency parameter that includes the occluded area for the mounts was developed to obtain an optimized tube length obtained. Based on the results, a length of 2.7 m for the absorber + 0.2 m for the coupler was chosen to minimize any bending and optimize optical efficiency while maintaining ease of mounting. The associated particle TTS system was designed, built and successfully tested at GTI. It includes storage, receiving and lock hoppers and piping that simulates the transfer of captured solar energy to an actual industrial furnace. Tests over 77 charge-discharge cycles demonstrated <2% particle degradation, with no problematic particle accumulations and no flow interruptions. The piping pressure drop was about 5 psi. The team also worked with Stanley Consultants (Stanley) to prepare conceptual and preliminary engineering packages to facilitate follow-on development and commercialization efforts. These include process and instrumentation diagram’s (P&ID’s), general arrangements, electrical one-line, project definitions document, equipment data sheets, schedule, and construction cost estimate for 2 MWth system. Updated HSS technology commercialization and customer engagement plans and detailed costs and evaluated market trade-offs and manufacturing.

03 NATURAL GAS↗
NASA NTRS2012

Safety and Long-Term Performance of Lithium-ion Pouch Cells

Lithium-ion batteries have the highest energy density of the batteries available in the commercial market today. Although most lithium-ion cell designs use a metal can design, this has changed significantly in recent years. Cell designs are offered in the pouch format as they offer better volumetric and gravimetric energy densities and in some cases, higher tolerance to abuse or off-nominal conditions. In the past decade, several state-of-the-art lithium-ion pouch cell designs have been tested. The pouch cell designs have become more robust in the past two years but there are still a few issues that need to be looked into for optimization. The pouch cells seem to have a tendency to swell when left in storage under ambient conditions. The cells also swell under overvoltage and undervoltage conditions. A significant issue that has been observed is the swelling of the cells under a vacuum condition which could lead to deformation of the cell pouch after this exposure. This last factor would be very critical in the use of these cell designs for space applications as vacuum exposure is used to check for cell and battery leaks before it is flown into space. In rare cases, corrosion of the aluminum layer of the pouches has been observed in stored cells. Pouch material analysis has been carried out in an effort to understand the strength of the pouches and determine if this is a factor in the corrosion as well as unsafe condition of the cells as deformation of the inner layers of the pouch could occur when the cells swell under the various conditions described above. Pouch materials are typically aluminized plastic, made up of a layer of Al sandwiched between one or more layers of polymeric material. Deformations or cell manufacturing processes could lead to a compromise of the inner polymeric layer/s of the pouch leading to the corrosion of the Al layer in the aluminized pouch material. The safety of the pouch cell designs has been determined for cells from various manufacturers. The results are varied and in some cases, unexpected. This paper presents a summary of the tests carried out on a few li-ion pouch cell designs from various cell manufacturers. The data will include performance under different conditions specifically cycling under vacuum conditions with and without restraints as well as safety test data. The presentation will also include detailed analysis of the pouch material for the cells studied.

Jeevarajan, Judith↗
NASA NTRS1992

EOS workstation

This final report summarizes the work done from mid-1989 until January 1992 to develop a prototype set of tools for the analysis of EOS-type images. Such images are characterized by great multiplicity and quantity. A single 'snapshot' of EOS-type imagery may contain several hundred component images so that on a particular pixel, one finds multiple gray values. A prototype EOS-sensor, AVIRIS, has 224 gray values at each pixel. The work focused on the ability to utilize very large images and continuously roam through those images, zoom and be able to hold more than one black and white or color image, for example for stereo viewing or for image comparisons. A second focus was the utilization of so-called 'image cubes', where multiple images need to be co-registered and then jointly analyzed, viewed, and manipulated. The target computer platform that was selected was a high-performance graphics superworkstation, Stardent 3000. This particular platform offered many particular graphics tools such as the Application Visualization System (AVS) or Dore, but it missed availability of commercial third-party software for relational data bases, image processing, etc. The project was able to cope with these limitations and a phase-3 activity is currently being negotiated to port the software and enhance it for use with a novel graphics superworkstation to be introduced into the market in the Spring of 1993.

Leberl, Franz↗
DOE OSTI2020

Pumped Storage Hydropower (PSH) FAST Commissioning Prize Technical Analysis

The US energy landscape has undergone major changes over the past 10 years and will continue to see significant changes in future decades as the power grid increases its reliance on variable renewable energy resources. Because of the inherent variability of these resources, renewable energy growth may require additional energy storage capacity to provide flexible load-following capabilities and other grid services that can quickly adjust to changes in energy demand and generation. Pumped storage hydropower (PSH)—one such energy storage technology—uses pumps to convey water from a lower reservoir to an upper reservoir for energy storage and releases water back to the lower reservoir via a powerhouse for hydropower generation. PSH facility pump and generation cycling often follows economic and energy demand conditions. Across the United States, 43 PSH facilities are in operation and 55 projects are in various permitting or licensing stages. Altogether, the 43 operational projects provide the wide majority (95%) of utility-scale electricity storage in the United States. These facilities also provide significant power and nonpower grid benefits, including large-scale electrical system reserve capacity, grid reliability support, and electricity supply-demand balancing through quick-response capabilities and operational flexibility. PSH systems can accomplish these at a scale (e.g., size) and cost that makes these systems highly attractive from a technical standpoint. Although these research concepts are still in their infancy, they demonstrate promising potential as future PSH energy storage technologies. Although PSH has many advantages, development in the United States has effectively stalled since the 1990s, partially because of the magnitude of project costs and financing interest during development and construction, the length of time from project investment until project revenue begins, permitting challenges, construction risks, competition from other storage technologies (e.g., batteries, hydrogen storage), and electricity market evolution and uncertainty. In short, the time, cost, and risk associated with modern PSH development have resulted in limited growth in the United States recently, despite the growing energy storage demand stemming from increased wind and solar power deployment. Technology innovation is needed to help reduce PSH commissioning time, cost, and risk, particularly during the post-licensing phase of project development. To address challenges facing the PSH industry and to improve PSH commissioning timelines, the US Department of Energy (DOE) Water Power Technologies Office (WPTO) initiated the PSH Furthering Advancements to Shorten Time to (FAST) Commissioning Prize project.

13 HYDRO ENERGY↗
DOE OSTI2023

Using National-Scale Data to Inform Coal Power Plant Redevelopment and Coal Community Revitalization Planning

In the United States, individual coal plants have high variation in their construction and operation. Coal plants commonly have multiple units, with different commissioning ages, operational position, and maintenance conditions – even multiple fuels. These units may be in changing states of utilization, with variation in productivity depending on economic contexts. Coal plants themselves may be temporarily offline, mothballed, retired, or decommissioned due to owner/operator portfolios or market conditions, and the current posture of the plant may be difficult to ascertain without local news sources (Tarekegne et al. 2021). Anticipated dates of plant closures are prospectively represented to regulators and to the Energy Information Administration (EIA), but may also experience uncertainty due to the engineering, environmental, economic and social complexity of closing a very large power plant. As noted in this report, closure of the first unit to the last within a single plant may span more than 20 years. Yet tracking and predicting the position of our nation’s coal fleets on a national scale is deeply important. In developing a case for federal datasets and an approach to building and curating these data, this report identified that data must have high fidelity at the plant-level to be meaningful in aggregate. Plant-scale detail is also a match for its application: national priorities in federal investment range from economic revitalization for coal plant communities to maintaining reliable electric grid operations. This document is organized into a statistical review of coal plant retirements, past and prospective, in the United States; trends in the relationship between closures and existing federal investment programs for community revitalization; and potential methods for accelerating site redevelopment through advanced geospatial analysis based on federal data.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2025

R&D Effort of Geologic Hydrogen Production at the National Renewable Energy Lab (NREL)

Geologic hydrogen (geoH2) is an emerging technology with massive current market interest and distinct potential to change the paradigm of hydrogen production. Two major subsurface processes influence the amount of geoH2 that are available for energy extraction: 1) geochemical reactions of H2O and Fe2+-bearing rocks which can produce hydrogen in the subsurface environment, where 2) various active microbial communities consume hydrogen as an energy source before the hydrogen reaches the surface. The net gain of hydrogen from these two competing processes dictates the production rate of geoH2. A recent study (Templeton et al., 2024) suggested that for most natural geoH2 systems, five orders of magnitude of production rate enhancement are needed to make geoH2 production economical in the near term. Effective enhancement of the production rate requires an in-depth understanding of the two geoH2 processes, in order to promote the H2-generating geochemical processes and suppress the H2-consuming microbial processes. However, current significant knowledge gaps in these two processes hinders the efforts to formulate strategies to enhance geoH2 production. The National Renewable Energy Laboratory (NREL) is a U.S. Department of Energy National Laboratory with the core mission of leading research, innovation, and strategic partnership to deliver solutions for a clean energy based economy. NREL's extensive research portfolio in hydrogen, bioenergy, geothermal, industrial decarbonization, and energy analysis makes us well positioned to conduct interdisciplinary research and facilitate technology deployment in the geoH2 space. In this presentation, we will discuss ongoing geoH2 research and engagement efforts at NREL, including: 1) geochemical investigation to understand the reaction mechanisms and production rate and potential of different source minerals and rocks, 2) microbiological investigation to understand methanogenesis and acetogenesis in the subsurface geoH2 environment, and identify effective inhibitors for these microbial processes, and 3) preliminary analysis for geoH2 production in the State of Minnesota, where abundant Fe-rich rocks for stimulated geoH2 production and ample opportunity to utilize geoH2 in transforming iron and steel industries are currently available.

08 HYDROGEN↗
NASA NTRS2003

The Cam Shell: An Innovative Design With Materials and Manufacturing

Most of the personal audio and video recording devices currently sold on the open market all require hands to operate. Little consideration was given to designing a hands-free unit. Such a system once designed and made available to the public could greatly benefit mobile police officers, bicyclists, adventurers, street and dirt motorcyclists, horseback riders and many others. With a few design changes water sports and skiing activities could be another large area of application. The cam shell is an innovative design in which an audio and video recording device (such as palm camcorder) is housed in a body-mounted protection system. This system is based on the concept of viewing and recording at the same time. A view cam is attached to a helmet wired to a recording unit encased in a transparent body-mounted protection system. The helmet can also be controlled by remote. The operator will have full control in recording everything. However, the recording unit will be operated completely hands-free. This project will address the design considerations and their effects on material selection and manufacturing. It will enhance the understanding of the structure of materials, and how the structure affects the behavior of the material, and the role that processing play in linking the relationship between structure and properties. A systematic approach to design feasibility study, cost analysis and problem solving will also be discussed.

Chung, W. Richard↗
DOE OSTI2023

Economic and environmental feasibility of recycling flexible plastic packaging from single stream collection

As demand for plastic increases, there is an urgent need to ramp up its collection and recycling rate. This study reports results of a pilot study in the United States to recycle flexible plastic packaging (FPP) from single stream curbside collection focusing on both the economic feasibility and carbon footprint. To explore the marketability of recycled FPP, four down-stream market pathways were studied, including roof coverboard, plastic pellets, pallets, and film. In this work, results indicated that (1) the cleaning and pelletizing process at reclaimers contributed the most to the total greenhouse gas (GHG) emissions of recycled FPP products, and (2) the GHG emissions of recycled FPP products in all four pathways are lower than the comparator products. Therefore, using a higher percentage of recycled FPP substituted in a product can result in greater GHG emission reductions. All the recycled FPP products also showed favorable economics compared to their direct competitors.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Development of a Portable In Situ Phosphorous Sensor

While phosphorus is a critical nutrient for all forms of life, runoff leads to phosphorus accumulation in surface water where it can cause a variety of health, environmental, and economic problems. The Department of Energy is interested in conducting long-term field experiments to monitor the impact of phosphorus in terrestrial and aquatic environments, and to better understand a cost vs. benefit analysis of reducing phosphorus pollution. Performing such long-term experiments requires affordable sensors capable of monitoring low-level phosphorus concentrations under challenging environmental conditions. However, such sensors are currently not available. The goal of this proposed project is to develop and demonstrate a low-cost portable phosphorus sensor suitable for in situ measurements. We will determine the technical requirements for a Raman-based sensor system, design and build a signal amplifier, integrate it with a Raman-based sensor, and demonstrate a proof-of-concept level sensor system. The expected accomplishments for Phase I include the identification of the technical requirements of a combined Raman laser/spectrometer and cavity enhancement system, building a proof-of-concept level sensor system capable of detecting orthophosphate compounds at the desired level of 0.25 mg P/L and organic P compounds, and verification of the sensor performance under laboratory and field conditions. In addition, we will identify initial hardening requirements that will need to be implemented during Phase II. While we plan to develop an integrated sensor system for monitoring phosphorus, the cavity-based enhancement system can also be used in combination with other (non-phosphorus) Raman sensors that we plan to develop or that are already commercially available. A recent market report highlights the increasing demand for such environmental monitoring applications, with the market for chemical detection anticipated to grow at a compound annual growth rate of 6.5% (2020-2025). Wide-spread monitoring of phosphorus could reduce the damage from eutrophication in freshwater, which is estimated to be $2.2 billion annually, thereby increasing biodiversity, reducing costs required for drinking water treatment, and decreasing economic losses related to recreation and angling and lake property values.

54 ENVIRONMENTAL SCIENCES↗