Metal carbide-graphite composites
Carbon sources effects on niobium carbides, and determination of high temperature flexural strength, flexural creep, and thermal expansion up to 2550 deg C for various materials
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Carbon sources effects on niobium carbides, and determination of high temperature flexural strength, flexural creep, and thermal expansion up to 2550 deg C for various materials
High temperature creep tests of niobium carbide- carbon composites, and evaluation of additives for tantalum carbide-carbon composites
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Fabrication and cold flow testing of integral spray injector for flight configuration of axially conducting rocket engine
Tungsten used in NbC-C composites as low melting densification additive to improve composite properties and lower fabrication temperatures
WC as densification aid for NbC-C composites, examining fabrication temperature, mechanical properties, solid solution composition, etc
Metallic composite prepared for utilization which remains intact without aluminum/carbon reactions, is less expensive than other structural materials, and yields a flexible composite material.
Data summary is collection of information on typical processing techniques. Mechanical properties, and physical properties of advanced composite materials which are being considered for structural applications on advanced space vehicles.
The A-type polyimide adhesive resin P11B was modified by use of mixed diamines (thio-dianiline and meta phenylene diamine) which provided the desired autoclave processability. This new resin was termed P11BA. It was shown that copolymeric blends of P11BA and Amoco AI-1137 amide-imide resin provided improved adhesive properties when autoclave processed over the properties obtained previously by press bonding with P11B based copolymeric blended adhesives. Properties of bonded assemblies are presented for long-term aging at both elevated and low temperatures, and also stress-rupture tests at elevated temperature.
A prototype all carbon triode ultrahigh vacuum gage was fabricated and tested. The gage exhibited a sensitivity of 3.7 per torr for nitrogen and an X-ray background approximately 0.1 as large as would be expected of a metal gage of the same design. The gage made from these materials, showed good sensitivity and durability. A practical technique was developed for bonding carbon components together without metal fasteners. The bond is made with a cross-linked phenolic resin which is converted to vitreous carbon by a careful pyrolysis procedure. The resulting bonds are strong, electrically conductive, and can withstand repeated excursions to 2500 K in vacuum. Measurements of adsorption and outgassing characteristics of four refractory carbons have confirmed that such materials are suitable for use in ultrahigh vacuum and that some are superior refractory metals in man respects.
Experimental studies are described in which new A-type polyimide prepolymer chemical modifications were investigated with the aim of increasing the melt phase duration and temperature range permitting autoclave processing, yet retaining the addition-type cure mechanism required for low-void content composites. Several modification candidates were examined, and one specific formulation was selected for detailed investigation. This A-type polyimide prepolymer formulation is shown to possess the desired characteristics.
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Research and development are reported on phenolic resin binders, coke flour, binder soaking, hot molding glass-like carbons, and particle packing.
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The results of development of an advanced composite door landing-gear assembly are summarized. The development program consisted of design, analysis, fabrication, and structural testing of a door sector assembly designed to the operating loads expected for the Phase B Space Shuttle orbiter.
Four 71-cm-diameter rocket motor chambers were designed and fabricated with advanced composite materials. The first three chambers were filament wound from boron/epoxy tape, and the fourth from graphite/epoxy tape. The first boron/epoxy chamber was 74 cm in length and was successfully hydroburst tested. The other three chambers were 57.6 cm in length for a smaller propellant load. The first shortened boron/epoxy chamber failed in proof test as a result of fabrication deficiencies. The last boron/epoxy and the graphite/epoxy chambers were successfully proof tested.
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