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At least 1,477 records · Page 82

Zirconium and hafnium abundances in some lunar materials and implications of their ratios

A new rapid and precise analytical procedure for Zr and Hf has been applied to the study of lunar materials. The results indicate that the Zr/Hf ratios in lunar materials vary in a narrow range from 36.6 to 51.3 while their respective contents vary by a factor of 40. There is a strong Zr, Hf, and major element correlation. This correlation and the Zr and Hf systematics suggest that lunar materials fall into two groups. One group characterized by high Zr and Hf contents and higher Zr/Hf ratios corresponds to materials with a high KREEP content; the other characterized by low Zr and Hf contents and lower Zr/Hf ratios corresponds to materials with high Ti, Fe, Mn, and Mg contents. We believe that the modest Zr and Hf fractionation we observe is related to the extent of stabilization of the metals in the early titanium minerals and a charge disparity under extremely reduced conditions in which Zr exists as 3+, while Hf remains as 4+.

Chyi, L. L.↗

Major and trace element abundances in samples from the lunar highlands

Analyses for major elements, REE, Co, Cr, Cs, Ga, Hf, Ni, Rb, Sc, and Zn have been done on samples of Apollo 16 rocks 60025, 60335, 64455, 65015, 67075, and 67629 and on fines 60601, 61221, 61241, 64501, 65701, 67601, and 69941. FeO, Na2O, REE, Co, Cr, Hf, and Sc have been determined in four 4-5 mg chips from 65015 and 20 individual, 2.5-9.5 mg fragments from 65702. It appears that trace element characteristics of small fragments are similar to those of larger rocks. No simple mixing relationship was found among KREEP basalts, VHA basalts, anorthosites, fines, and meteorites. Balances could not be simultaneously achieved for Al2O3 and LIL elements, using analyzed samples as end members for mixing models. Most samples analyzed have negative Eu anomalies, in contrast to the positive anomalies expected for plagioclase cumulates. Most samples may be derived from LIL-rich liquids that flowed into highland valleys.

Haskin, L. A.↗

Trace element abundances and petrology of separates from Apollo 15 soils

Nine petrographically distinct separates from Apollo 15 coarse soils were characterized by electron microprobe and analyzed by neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Rb, Re, Sb, Se, Te, Tl, U, and Zn. Like some alkali-poor anorthosites from Apollo 16, 15102 anorthosite is low in meteoritic siderophiles but enriched in Tl, perhaps by volcanic processes. Norites from 15102 and troctolites from 15302 are lower in KREEP than are Apollo 12 or 14 norites. A possible progenitor of KREEP-rich norite breccias has been found: a mesostasis-rich basalt from 15272 high in KREEP-related elements, but very low in the siderophiles Ir, Re, Au, Sb, and Ge, and hence lacking the ancient meteoritic component that occurs in all lunar norites. At least two varieties of ancient meteoritic component are present in the soil separates from this site, consistent with the complex impact history of the Pre-Imbrian surface.

Morgan, J. W.↗

Elemental abundances of Apollo 16 samples

Results are presented for the multielement analysis of samples of lunar soil (60501 and 64501), igneous rock (60315), and the light portion of breccia 60017. A mixing model for soil compositions has been proposed consisting of linear combinations of the KREEP basalt 60315 and the anorthositic gabbroic sample 60017. A comparison of trace elements in lunar soils from different missions indicates the marked depletion of the LIL elements in the Apollo 16 samples.

Morrison, G. H.↗

Measurement of the abundance of several natural stratospheric trace constituents from high altitude aircraft

A summary report of the initial results obtained from near-infrared observations of the stratosphere from the Anglo-French SST Concorde is presented, together with the most recent results from previous flights aboard an Air Force NC-135. The measurements were made with a fast Fourier interferometer spectrometer operating in the 1.2- to 7.5-micron range of the infrared with a spectral resolution of 0.25 per cm. For the Concorde experiments, flight times and trajectories were selected which allowed the sun to be viewed near the horizon with the relative solar elevation angle held constant throughout the measurements. Results reported include the identification of features due to N2O, NO, NO2, CO, CO2, CH4, H2O and indications of their latitudinal variations.

Farmer, C. B.↗

Chemical abundances of cosmic rays greater than 4.5 GV measured with a large area proportional counter-scintillation counter stack

A 6500 sq cm-ster cosmic-ray detector consisting of 12 gas counter trays sandwiched between two large-area circular scintillation counters was flown from Palestine, Texas in November 1972 to study the composition of primary particles greater than 1.5 GeV/nucleon in the charge range from 3 to 30. For each analyzed event, the particle trajectory was recorded, using four 20-wire proportional counter trays. Also recorded were the energy loss in each of the solid counters and the dE/dx losses in each of the 12 gas counters. The large dynamic range of the detector is established by operating six of the gas counters in the ionization mode. A description of the instrument and some preliminary results are given.

Lheureux, J.↗

A new limit on the interstellar abundance of boron

Report of a new upper limit on interstellar boron in the direction of zeta Oph, obtained by making 25 scans across the B II resonance line at 1362.461 A with the Copernicus satellite. A B/H of about 7.6 times 10 to the negative 11th power or less was found, implying that boron in the interstellar gas is depleted by a factor of about 60 relative to boron in carbonaceous chondrites. These results are related to theories of the formation of grains, and the flux of cosmic rays.-

Morton, D. C.↗

Carbon, nitrogen and sulfur in lunar fines 15012 and 15013 - Abundances, distributions and isotopic compositions

Lunar fines 15012,16 and 15013,3 were analyzed by stepwise pyrolysis and acid hydrolysis as well as complete combustion in oxygen to determine carbon, nitrogen and sulfur. In addition, hydrogen was analysed during pyrolysis as well as during hydrolysis. By comparison of the distribution frequencies of C, N, S, H2 and Fe with He-4, considered to have arisen from solar wind contribution, it is concluded that nitrogen and hydrogen have largely a solar origin. Carbon has a significant solar contribution, and metallic iron may have resulted from solar wind interaction with ferrous minerals on the lunar surface. Sulfur probably has a predominantly lunar origin. There is no direct evidence for meteorotic contribution to these samples. Solar wind interaction also has a marked effect on the stable isotope distribution of C-13/C-12, N-15/N-14, and S-34/S-32. In all cases, the heavy isotope was most enriched in the smallest grain-size fraction.

Chang, S.↗

Oscillator strengths for neutral sodium and the interstellar sodium abundance in zeta Ophiuchi

Use of the high-frequency deflection technique to measure radiative lifetimes for the 4p and 5p upper states in Na I, along with relative populations of a number of ns and nd states. These data have been used to obtain f-values for the corresponding resonance transitions in Na I, which proved to be in reasonable agreement with previous oscillator strengths. From the theoretical curve of growth for pure Doppler broadening, revised line ratios for D1/3303 are given and are compared with observations of Na I in zeta Oph.

Erman, P.↗

Relative abundances of positrons and antiprotons in the primary cosmic ray flux

Observations on the ratio of positrons to the electron-positron sum made in the 5 to 50 GeV range by Buffington et al. (1974) are used to put an upper limit on the ratio of antiprotons to protons at various energies. The calculation of the latter ratio is based on detailed measurements of the cross section of antiproton production up to intersecting storage ring energies.

Badhwar, G. D.↗