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At least 1,477 records · Page 82

Chemically Stable Styrenic Electrospun Membranes with Tailorable Surface Chemistry

Membranes with tailorable surface chemistry have applications in a wide range of industries. Synthesizing membranes from poly(chloromethyl styrene) directly incorporates an alkyl halide surface-bound initiator which can be used to install functional groups via SN2 chemistry or graft polymerization techniques. In this work, poly(chloromethyl styrene) membranes were synthesized through electrospinning. After fabrication, membranes were crosslinked with a diamine, and the chemical resistance of the membranes was evaluated by exposure to 10 M nitric acid, ethanol, or tetrahydrofuran for 24 h. The resulting membranes had diameters on the order of 2–5 microns, porosities of >80%, and permeance on the order of 10,000 L/m2/h/bar. Crosslinking the membranes generally increased the chemical stability. The degree of crosslinking was approximated using elemental analysis for nitrogen and ranged from 0.5 to 0.9 N%. The poly(chloromethyl styrene) membrane with the highest degree of crosslinking did not dissolve in THF after 24 h and retained its high permeance after solvent exposure. The presented chemically resistant membranes can serve as a platform technology due to their versatile surface chemistry and can be used in membrane manufacturing techniques that require the membrane to be contacted with organic solvents or monomers. They can also serve as a platform for separations that are performed in strong acids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Beyond Pristine Metal–Organic Frameworks: Preparation of Hollow MOFs and Their Composites for Catalysis, Sensing, and Adsorption Removal Applications

Metal–organic frameworks (MOFs) have been broadly applied to numerous domains with a substantial surface area, tunable pore size, and multiple unsaturated metal sites. Recently, hollow MOFs have greatly attracted the scientific community due to their internal cavities and gradient pore structures. Hollow MOFs have a higher tunability, faster mass-transfer rates, and more accessible active sites when compared to traditional, solid MOFs. Hollow MOFs are also considered to be candidates for some functional material carriers. For example, composite materials such as hollow MOFs and metal nanoparticles, metal oxides, and enzymes have been prepared. These composite materials integrate the characteristics of hollow MOFs with functional materials and are broadly used in many aspects. This review describes the preparation strategies of hollow MOFs and their composites as well as their applications in organic catalysis, electrochemical sensing, and adsorption separation. Finally, we hope that this review provides meaningful knowledge about hollow-MOF composites and their derivatives and offers many valuable references to develop hollow-MOF-based applied materials.

36 MATERIALS SCIENCE↗

Statistical imprints of wave-like dark matter on multiply-imaged galaxies in strong cluster lenses from JWST

Wave-like dark matter ($ψ$DM) is an elusive dark matter (DM) candidate. The model, often also called fuzzy or ultralight DM, proposes that DM is an extremely light ($m\sim10^{-22}$ eV) boson and thereby has a kpc-scale de Broglie wavelength. Hence, interference of DM gives rise to sub-galactic density fluctuations that can be studied with strong gravitational lensing. In this paper, we use the residual power spectrum, $\mathrm{P}_δ(k)$, as a probe of $ψ$DM, which quantifies deviations from smooth lensing predictions, measured from multiply-imaged galaxies in strong cluster lenses. The key idea is that imprinted in these deviations are lensing distortions from DM substructure, which can be harnessed statistically to distinguish among DM theories. We simulate JWST-quality mock observations of strong gravitational lensing in galaxy clusters, modeling line-of-sight DM substructure within $ψ$DM and the standard cold dark matter (CDM) paradigms. Using mock deep observations ($\sim$ 20 hours), we find that $\mathrm{P}_δ(k)$ is sensitive to both $ψ$DM particle mass and fluctuation amplitude, and can distinguish $ψ$DM fluctuations from CDM subhalos. We demonstrate that $\mathrm{P}_δ(k)$ can be measured directly from data by modeling the smooth lensing with a local Curved Arc Basis formalism. With realistic modeling systematics, we find a statistically significant separation between $ψ$DM and CDM across $1 \lesssim k \lesssim 11\,\mathrm{kpc}^{-1}$ -- offering an independent probe of the wave-like nature of DM complementary to existing constraints.

Cosmology and Nongalactic Astrophysics (astro-ph.C↗

Co-Investigator Proposal for Enstrophy - - Filamentation of Auroral Currents

Cornell University provided three instruments for the Enstrophy experiment: an electric field meter, a plasma wave receiver, and a magnetometer for measuring FAC. The electric field meter consisted of a 6 m Weitzmann boom system with analog signal processing and 12 bit ADC, which yielded one electric field component instantaneously and a two dimensional electric field every half spin. The plasma wave receiver used the same sensing system with the addition of pre-amplifiers in the spheres to sense plasma waves up to and including the electron Langmuir frequency. Signal processing employed a variety of continuous and snap shot techniques depending on the frequency range and band width. The science magnetometer provided by Cornell University was a Billingsly design fluxgate previously used on spacecraft missions but without radiation hardening. The magnetometer was mounted on a one meter, stiff aluminum "flop-down" boom. The Enstrophy payload was launched on february 11, 1999. Because of a design flaw in the event timers, the magnetometer boom was deployed before the payload despun. As a result the magnetometer separated mechanically from the boom but maintained electrical connection. This was confirmed by the calculation of the scalar magnetic field from all three vector components of the magnetic field. However, the individual vector values had no scientific value. The electric field and plasma wave instrumentation worked as designed. The data from these instruments was provided to the University of New Hampshire and to the Principal Investigator, as proposed.

Kintner, Paul M.↗

Sea Ice Kinematics and Thickness from RGPS: Observations and Theory

The RADARSAT Geophysical Processor System (RGPS) has produced a wealth of data on Arctic sea ice motion, deformation, and thickness with broad geographical coverage and good temporal resolution. These data provide unprecedented spatial detail of the structure and evolution of the sea ice cover. The broad purpose of this study was to take advantage of the strengths of the RGPS data set to investigate sea ice kinematics and thickness, which affect the climate through their influence on ice production, ridging, and transport (i.e. mass balance); heat flux to the atmosphere; and structure of the upper ocean mixed layer. The objectives of this study were to: (1) Explain the relationship between the discontinuous motion of the ice cover and the large-scale, smooth wind field that drives the ice; (2) Characterize the sea ice deformation in the Arctic at different temporal and spatial scales, and compare it with deformation predicted by a state-of-theart ice/ocean model; and (3) Compare RGPS-derived sea ice thickness with other data, and investigate the thinning of the Arctic sea ice cover as seen in ULS data obtained by U.S. Navy submarines. We briefly review the results of our work below, separated into the topics of sea ice deformation and sea ice thickness. This is followed by a list of publications, meetings and presentations, and other activities supported under this grant. We are attaching to this report copies of all the listed publications. Finally, we would like to point out our community service to NASA through our involvement with the ASF User Working Group and the RGPS Science Working Group, as evidenced in the list of meetings and presentations below.

Stern, Harry↗

Trajectory Design and Orbit Determination for the Lunar CRater Observation and Sensing Satellite (LCROSS)

The Lunar CRater Observation and Sensing Satellite (LCROSS) was competitively selected by the National Aeronautical and Space Administration (NASA) Exploration Systems Mission Directorate (ESMD) as a low-cost (< $80M) 1000 kg secondary payload to be launched with the Lunar Reconnaissance Orbiter (LRO) in October of 2008. LCROSS is a lunar impactor mission that will investigate the presence or absence of water in a permanently shadowed crater. Following launch, trans-lunar injection (TLI) and separation from LRO, LCROSS will remain attached to the launch vehicle's approximately 2300 kg spent Earth Departure Upper Stage (EDUS) and will guide it toward an impact of a permanently shadowed crater at the lunar South Pole. Hours prior to impact, LCROSS will separate from the EDUS and perform a braking maneuver that will allow the spacecraft to take measurements of the resulting EDUS impact ejecta cloud for several minutes, before impacting the crater as well. As a cost-capped secondary mission that must accommodate specific LRO launch dates, LCROSS faces unique challenges and constraints that must be carefully reconciled in order to satisfy an ambitious set of science observation requirements. This paper examines driving mission requirements and constraints and describes the trajectory design and navigation strategy that shape the LCROSS mission.

Galal, Ken↗

NASA Bioculture System: From Experiment Definition to Flight Payload

Starting in 2015, the NASA Bioculture System will be available to the science community to conduct cell biology and microbiology experiments on ISS. The Bioculture System carries ten environmentally independent Cassettes, which house the experiments. The closed loop fluids flow path subsystem in each Cassette provides a perfusion-based method for maintain specimen cultures in a shear-free environment by using a biochamber based on porous hollow fiber bioreactor technology. Each Cassette contains an incubator and separate insulated refrigerator compartment for storage of media, samples, nutrients and additives. The hardware is capable of fully automated or manual specimen culturing and processing, including in-flight experiment initiation, sampling and fixation, up to BSL-2 specimen culturing, and the ability to up to 10 independent cultures in parallel for statistical analysis. The incubation and culturing of specimens in the Bioculture System is a departure from standard laboratory culturing methods. Therefore, it is critical that the PI has an understanding the pre-flight test required for successfully using the Bioculture System to conduct an on-orbit experiment. Overall, the PI will conduct a series of ground tests to define flight experiment and on-orbit implementation requirements, verify biocompatibility, and determine base bioreactor conditions. The ground test processes for the utilization of the Bioculture System, from experiment selection to flight, will be reviewed. Also, pre-flight test schedules and use of COTS ground test equipment (CellMax and FiberCell systems) and the Bioculture System will be discussed.

Bioculture System↗

femto-PIXAR: a self-supervised neural network method for reconstructing femtosecond X-ray free electron laser pulses

X-ray Free Electron Lasers (X-FELs) operate in a wide range of lasing configurations for a broad variety of scientific applications at ultrafast time-scales such as structural biology, materials science, and atomic and molecular physics. Shot-by-shot characterization of the X-FEL pulses is crucial for analysis of many experiments as well as tuning the X-FEL performance. However, for the weak pulses found in advanced configurations, e.g. those needed for coherent, two-pulse studies of quantum materials, there is no current method for reliably resolving pulse profiles. Here we show that a physics-based U-net model can reconstruct the individual pulse power profiles for sub-picosecond pulse separation without the need for simulations. Using experimental data from weak X-FEL pulse pairs, we demonstrate we can learn the pulse characteristics on a shot-by-shot basis when conventional methods fail.

43 PARTICLE ACCELERATORS↗

The Dragonfly Entry and Descent System

Dragonfly is a proposed New Frontiers class mission that will send a nuclear powered octocopter to the surface of Titan for an extended science mission. This presentation will provide an overview of the Entry and Descent system that is under development to ensure the save delivery of this unique "relocatable lander" to Titan. Titan's dense atmosphere, large atmospheric scale height, and low gravity allows for a slow-paced entry and descent sequence that lasts more than 100 minutes, as opposed to the "7 minutes of terror" that is charac-teristic of landed Mars missions. This slow pace al-lows for sufficient temporal separation between critical events of the EDL sequence to minimize overall risk.The Dragonfly entry and descent system is composed of high-heritage components, minimizing overall risk. The aeroshell will be a scaled Genesis Sample Return capsule with a diameter of 3.75 meters, built by Lock-heed Martin. The thermal protection system (TPS) is made up of Phenolic Impregnated Carbon Ablator-Domestic (PICA-D) on the heatshield, SLA-561V on the backshell, and SLA-220M on the aft cover and low gain antenna. Each material has extensive heritage for the chosen application. The spacecraft will enter Titan at a velocity of 7.3 km/s, resulting in a predicted fully margined stagnation point heating environment of 254 W/cm2 heat rate and 13 kJ/cm2 heat load, well within the tested limits of the chosen materials. The aeroheat-ing environments, including the significant contribu-tion of shock layer radiation from CN on both the heatshield and backshell, are evaluated using state of the art models and codes that have been validated with appropriate ground testing.Once the deceleration pulse is complete, a disk-gap-band (DGB) drogue parachute will be deployed at ap-proximately Mach 1.5 to stabilize and further deceler-ate the spacecraft. Due to the dense atmosphere, the spacecraft will spend more than 80 minutes on this parachute, until reaching an appropriate altitude to de-ploy the subsonic main parachute. The lander is re-leased after approximately 17 minutes on the main chute before releasing and transitioning to powered flight in order to navigate to its first landing site. The release of the lander from the backshell effectively ends the entry and descent portion of the mission.The full presentation will provide additional details about the design of the EDL system hardware, engi-neering design, and overall con-ops. Preliminary aero-thermal and TPS sizing analyses will be presented, and the parachute system will be described in greater detail. In addition, the Dragonfly spacecraft will carry an En-gineering Science Investigation (ESI) package designed to obtain engineering data during EDL that will be used to validate the design methodology for future missions. An overview of the proposed ESI package will also be presented.

EDL↗

Reliable Transport over SpaceWire for James Webb Space Telescope (JWST) Focal Plane Electronics (FPE) Network

NASA's James Webb Space Telescope (JWST) faces difficult technical and budgetary challenges to overcome before it is scheduled launch in 2010. The Integrated Science Instrument Module (ISIM), shares these challenges. The major challenge addressed in this paper is the data network used to collect, process, compresses and store Infrared data. A total of 114 Mbps of raw information must be collected from 19 sources and delivered to the two redundant data processing units across a twenty meter deployed thermally restricted interface. Further data must be transferred to the solid-state recorder and the spacecraft. The JWST detectors are kept at cryogenic temperatures to obtain the sensitivity necessary to measure faint energy sources. The Focal Plane Electronics (FPE) that sample the detector, generate packets from the samples, and transmit these packets to the processing electronics must dissipate little power in order to help keep the detectors at these cold temperatures. Separating the low powered front-end electronics from the higher-powered processing electronics, and using a simple high-speed protocol to transmit the detector data minimize the power dissipation near the detectors. Low Voltage Differential Signaling (LVDS) drivers were considered an obvious choice for physical layer because of their high speed and low power. The mechanical restriction on the number cables across the thermal interface force the Image packets to be concentrated upon two high-speed links. These links connect the many image packet sources, Focal Plane Electronics (FPE), located near the cryogenic detectors to the processing electronics on the spacecraft structure. From 12 to 10,000 seconds of raw data are processed to make up an image, various algorithms integrate the pixel data Loss of commands to configure the detectors as well as the loss of science data itself may cause inefficiency in the use of the telescope that are unacceptable given the high cost of the observatory. This combination of requirements necessitates a redundant, fault tolerant, high- speed, low mass, low power network with a low Bit error Rate(1E-9- 1E-12). The ISIM systems team performed many studies of the various network architectures that meeting these requirements. The architecture selected uses the Spacewire protocol, with the addition of a new transport and network layer added to implement end-to-end reliable transport. The network and reliable transport mechanism must be implemented in hardware because of the high average information rate and the restriction on the ability of the detectors to buffer data due to power and size restrictions. This network and transport mechanism was designed to be compatible with existing Spacewire links and routers so that existing equipment and designs may be leveraged upon. The transport layer specification is being coordinated with European Space Agency (ESA), Spacewire Working Group and the Consultative Committee for Space Data System (CCSDS) PlK Standard Onboard Interface (SOIF) panel, with the intent of developing a standard for reliable transport for Spacewire. Changes to the protocol presented are likely since negotiations are ongoing with these groups. A block of RTL VHDL that implements a multi-port Spacewire router with an external user interface will be developed and integrated with an existing Spacewire Link design. The external user interface will be the local interface that sources and sinks packets onto and off of the network (Figure 3). The external user interface implements the network and transport layer and handles acknowledgements and re-tries of packets for reliable transport over the network. Because the design is written in RTL, it may be ported to any technology but will initially be targeted to the new Actel Accelerator series (AX) part. Each link will run at 160 Mbps and the power will be about 0.165 Watt per link worst case in the Actel AX.

Rakow, Glenn↗

Launch Pad Closeout Operations for the Mars Science Laboratory's Heat Rejection System

The Mars Science Laboratory (MSL) rover was launched on an Atlas V on November 26, 2011. Preparations were carried out prior to launch in order to closeout the spacecraft's complex heat rejection system (HRS), which consists of two mechanically pumped CFC-11 fluid loops. The first HRS loop, onboard the Curiosity rover, was fully integrated, filled with CFC-11, and successfully operated prior to launch pad operations; however, the second thermal loop, called the cruise HRS loop, required final mechanical and thermal integration activities to occur while on the launch pad in order to accommodate the last minute installation of the rover's Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) power source. In order to prevent overheating of propellant tanks and critical avionics equipment buried deep within the spacecraft's aeroshell, the MMRTG needed to be pre-cooled using a separate non-flight mechanically pumped fluid loop prior to and during the final closeout and subsequent startup of the flight loop. This paper outlines the various steps that took place to safely install the MMRTG while carefully transitioning from the pre-cooling operation to the final startup and operation of the flight cruise HRS loop. Temperature data of the launch pad thermal transition from the ground support loop activity to the final flight loop operation is presented. Some background development of the ground support loop and lessons learned are also discussed. This successful launch pad integration activity required a close-knit coordination between NASA KSC, JPL, the Department of Energy, Idaho National Labs, Pratt and Whitney Rocketdyne Inc., Teledyne Technologies Inc., ULA, and Advanced Thermal Sciences Corp.

thermal↗

Earth observation photography: Looking back 20 years after Skylab

A committee of trained classroom teachers, backed by a volunteer team of technical experts and academic advisors has developed a program for earth science based on photographs obtained from low earth orbit. In selecting targeting objectives, immediate note was made of the fact nearly one generation (20 years) has passed since the United States' ambitious SKYLAB program was conducted. A critical part of those missions was the acquisition of earth photography using a six camera, multi-spectral camera system. This objective was systematically furthered through the term of three separate crew visits to the Space Station. Not merely an exercise in randomly photographing the Earth below, the purpose of the Earth Resource Experiment Package (EREP) was to determine what kind, and how much, photographic data could be acquired of the broad variety of Earth features witnessed on the mission's ground track. The collection of 35,000 photos produced by EREP represents the most complete coverage of Earth. However, it remains under used. GAS 324 intends to revisit, and to add a tier of relevancy to this inventory. The photography of GAS 324 should allow a direct examination and comparison of the changes in the globe in the last 20 years. format in both coverage and quality. The photogra phy acquired by CAN DO should allow a direct examination and comparison of the changes that have occured to the Globe in the last twenty years.

Nicholson, James H.↗

Summary Report of Mission Acceleration Measurements for STS-89: Launched January 22, 1998

Support of microgravity research on the 89th flight of the Space Transportation System (STS-89) and a continued effort to characterize the acceleration environment of the Space Shuttle Orbiter and the Mir Space Station form the basis for this report. For the STS-89 mission, the Space Shuttle Endeavour was equipped with a Space Acceleration Measurement System (SAMS) unit, which collected more than a week's worth of data. During docked operations with Mir, a second SAMS unit collected approximately a day's worth of data yielding the only set of acceleration measurements recorded simultaneously on the two spacecraft. Based on the data acquired by these SAMS units, this report serves to characterize a number of acceleration events and quantify their impact on the local nature of the accelerations experienced at the Mechanics of Granular Materials (MGM) experiment location. Crew activity was shown to nearly double the median root-mean-square (RMS) acceleration level calculated below 10 Hz, while the Enhanced Orbiter Refrigerator/Freezer operating at about 22 Hz was a strong acceleration source in the vicinity of the MGM location. The MGM science requirement that the acceleration not exceed q I mg was violated numerous times during their experiment runs; however, no correlation with sample instability has been found to this point. Synchronization between the SAMS data from Endeavour and from Mir was shown to be close much of the time, but caution with respect to exact timing should be exercised when comparing these data. When orbiting as a separate vehicle prior to docking, Endeavour had prominent structural modes above 3 Hz, while Mir exhibited a cluster of modes around 1 Hz. When mated, a transition to common modes was apparent in the two SAMS data sets. This report is not a comprehensive analysis of the acceleration data, so those interested in further details should contact the Principal Investigator Microgravity Services team at the National Aeronautics and Space Administration's John H. Glenn Research Center.

Hrovat, Kenneth↗

K2-288Bb: A Small Temperate Planet in a Low-Mass Binary System Discovered by Citizen Scientists

Observations from the Kepler and K2 missions have provided the astronomical community with unprecedented amounts of data to search for transiting exoplanets and other astrophysical phenomena. Here, we present K2-288, a low-mass binary system (M2.0 ± 1.0; M3.0 ± 1.0) hosting a small (Rp=1.9 R), temperate (Teq=226K) planet observed in K2 Campaign 4. The candidate was first identified by citizen scientists using Exoplanet Explorers hosted on the Zooniverse platform. Follow-up observations and detailed analysesvalidate the planet and indicate that it likely orbits the secondary star on a 31.39-day period. This orbit places K2-288Bb in or near the habitable zone of its low-mass host star. K2-288Bb resides in a system with a uniquearchitecture, as it orbits at >0.1 au from one component in a moderate separation binary (a(proj)~55 au), andfurther follow-up may provide insight into its formation and evolution. Additionally, its estimated size straddlesthe observed gap in the planet radius distribution. Planets of this size occur less frequently and may be in atransient phase of radius evolution. K2-288 is the third transiting planet system identified by the ExoplanetExplorers program and its discovery exemplifies the value of citizen science in the era of Kepler, K2, and theTransiting Exoplanet Survey Satellite.

Kepler and K2 missions↗

Revision of Paschen's Law Relating to the ESD of Aerospace Vehicle Surfaces

The purpose of this work is to develop a form of Paschen's law that takes into account the flow of gas past electrode surfaces. This work was performed under a NASA Science Innovation Fund (SIF) project at the Kennedy Space Center in collaboration with the University of Central Florida. In 2010 the Electrostatics and Surface Physics Laboratory (ESPL) at the Kennedy Space Center performed an electrostatic safety analysis on the flight termination system (FTS) antenna for the Ares I rocket. Paschen's law, derived by Friedrich Paschen in 1889 to relate sparking voltage to gas pressure and electrode separation, does not take into account the effect of flowing gas between the electrodes. The safety of the FTS housing to triboelectric charging was shown only after extensive laboratory testing. Potential benefits are of a form of Paschen's law that considers gas velocity. This work is applicable to current and planned rockets and aerospace vehicles and could lead to possible relaxation of electrostatic launch criteria. Launch aborts can cost up to about a million US dollars depending on the vehicle. [ElectroStatic Discharge (ESD)]

Paschen↗

Move to Talk, Talk to Move: Tightly Integrated Communication and Control for Coordinated Swarms of Small Spacecraft

The Move to Talk, Talk to Move: Tightly Integrated Communication and Control for Coordinated Swarms of Small Spacecraft project will build on existing research on collaborative autonomy of multi-agent systems and design techniques that will enable coordinated communication and control of spacecraft. The success of many space exploration and science missions hinges on real-time monitoring of time-varying and/or geographically distributed phenomena. This monitoring can be achieved using a swarm of small spacecraft, which collect data about the environment and share information within the swarm of spacecraft. Current space exploration missions typically issue commands to control each spacecraft individually from Earth, and the data gathered by each spacecraft is also transmitted to Earth separately via X-band communication over the Deep Space Network (DSN). This approach is expensive, slow, and unreliable. Many coordinated tasks amongst a swarm of autonomous agents (or, specifically, small spacecraft) rely on communication. Existing control, estimation, and decision algorithms often assume that mostly reliable communications are available; however, this is often not the case in actual environments and thus is a barrier to operating swarms of small spacecraft.

Qi Han↗

Magnetic Field and Plasma Density Observations of a Pressure Front by Voyager 1during 2020 in the Very Local Interstellar Medium

Voyager 1 has been moving through the very local interstellar medium (VLISM) from the time that it crossed the heliopause on 2012/DOY 238 to 2020/DOY 292. Three notable objects in the magnetic field of the VLISM have been observed: two shocks and one pressure front. This paper reports the observation of a fourth object observed near 2020/DOY 147. There were no upstream electron plasma oscillations of the type often observed ahead of shocks, abrupt increases in energetic particles, or fluctuations in the 48 s increments of the magnetic field associated with this feature, suggesting that it was probably not a shock. This feature was associated with a relatively large increase in the magnetic field strength(B2/B1=1.35)and in the electron density determined by the Plasma Wave Science experiment (N2/N1=1.36) using a new method described in this paper. This feature appears to be a pressure front associated with a compressive wave in the VLISM. The two shocks and the two pressure fronts were associated with the four largest maxima observed in B (t) between 2012/DOY 238 and 2020/DOY 292. Each feature was associated with a jump–ramp structure. The jump–ramp structures were separated by long relatively undisturbed quiet intervals.

Interstellar magnetic fields↗