SEARCH · Engineering Papers

Results for “Principal Component Analysis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,477 records · Page 82

All sources NASA NTRS DOE OSTI

NASA NTRS2023

ChIPPS: Charged Information-storage Polymer Preparation System

Technological advances are required to support principal science objectives of missions to the solar system’s icy worlds to seek biosignatures of past/extant life. Sensitivity and reliability are key concerns due to small sample sizes (µL – mL) and the extraordinary import of the results. The preparation and processing of small samples can constrain limits of detection (LoDs); therefore, the Charged Information-storage Polymer Preparation System (ChIPPS) project is advancing the technologies of autonomous sample preparation and processing to add a new class of reliably detectable biosignatures: charged polymers and particles, which can be the information storage-and-transmission means for life. Specifically, we are developing an integrated microfluidic sample-processing unit to prepare icy-world samples to support complementary solid-state nanopore-based analyses: 1) charged-polymer analysis, to characterize variations in polymer chain size, shape, and charge vs. position along the chain; 2) polymer and nanoparticle sizing-and-counting, to characterize the relative abundance of polymer chains, as well as small (virus-sized) particles, by their dimensions and charge. Although no such autonomous system presently exists, such measurements can reveal the nature and abundance of charged polymers that could be used by biological systems to store and transfer information—as DNA and RNA are used terrestrially—without limitation to terrestrial nucleic acids, given that life elsewhere may utilize different information store-and-transfer moieties. Key system components include (a) a lysis unit for mechanical sample disruption; b) an ion-exchange column for charged macromolecule/nanoparticle purification; c) dialyzer to remove excess salt; d) concentrator to enhance signal; e) supporting pumps, valves, bubble traps, connectors, filters, etc.; f) interface to nanopore detection instruments.

Space Biology↗

DOE OSTI2018

Content Addition and Testing for 2017 NRC Amendment for the Versa-Pac Type A Fissile Packaging - 18120

The Versa-Pac is a certified Type A, fissile packaging (USA NRC Certificate no. USA/9342/AF-96), often used as a waste package for one time use. Continuous content additions have improved the versatility of the package resulting in expanded uses for the nuclear industry. Principal design of the Versa-Pac packaging maintains the use of an inner liner positioned inside a 55-gallon (VP-55) or 110-gallon drum (VP-110), as used for decades in the transport and disposal of Type A fissile materials. The Versa-Pac is used directly or in conjunction with pails, pipe containers, poly bottles, and a variety of smaller containers, inserts and vessels. The Versa-Pac content developments assist the industry with site shutdown, decommissioning, and cleanup operations, allowing for removal, transport, and storage options for the residual waste materials. A 2017 NRC license amendment application adds new capabilities to the Versa-Pac that include a low 1.25 wt% {sup 235}U enriched uranium loading, small quantities of UF{sub 6} in the form of 1S and 2S cylinders, and a payload mass increase from 250 to 350 pounds for the Versa-Pac 55-gallon version (VP-55). The lower uranium enrichment loading of 1.25 wt% {sup 235}U allows for a higher uranium mass limit. The inclusion of 1S and 2S UF{sub 6} cylinders fills an industry need to remove and dispose of long-stored material during site cleanup activities. The content payload mass limit is increased for low contaminated or radioactive heavy metal contents, such as cut plant components and ingots. Regulatory certification of new contents is demonstrated by test, analysis, and a combination of these techniques to show that the design function of the Versa-Pac as a Type A fissile package remains unchanged. Specific UF{sub 6} criticality and thermal analysis upgrades are added to the design documentation to accommodate 1S and 2S UF{sub 6} cylinders. The parameters for criticality analyses are simplified, ensuring no credit for cylinder containment is required for HAC thus reducing the reliance on a single specific shoring device. An upgrade of the Versa-Pac thermal analysis demonstrates compliance with ANSI N14.1 UF{sub 6} cylinder thermal limits. A new drop test sequence for the VP-55 was performed, documenting the addition of the 350-pound payload and demonstrating the VP-55 maintains structural integrity during the NCT and HAC drop, crush and puncture events as defined by 10 CFR 71. The testing and analyses show no loss of the material occurs and the package maintains the material in a subcritical state. This paper traces the engineering and licensing efforts involved in expanding the Versa-Pac's versatility for the 2017 NRC amendment application; summarizing the new testing and results for the payload increase, the content addition criticality and thermal evaluations, and content description for the Versa-Pac Safety Analysis Report. The NRC license amendment is scheduled for Winter 2017. Testing and supporting analyses reported in the Versa-Pac Safety Analysis Report demonstrates the content developments met the performance requirements of 10 CFR 71 for a Type A fissile package. A revision of the NRC Certificate of Compliance is expected in Spring 2018. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2017

Instrumental Response Model and Detrending for the Dark Energy Camera

We describe the model for mapping from sky brightness to the digital output of the Dark Energy Camera (DECam) and the algorithms adopted by the Dark Energy Survey (DES) for inverting this model to obtain photometric measures of celestial objects from the raw camera output. This calibration aims for fluxes that are uniform across the camera field of view and across the full angular and temporal span of the DES observations, approaching the accuracy limits set by shot noise for the full dynamic range of DES observations. The DES pipeline incorporates several substantive advances over standard detrending techniques, including principal-components-based sky and fringe subtraction; correction of the "brighter-fatter" nonlinearity; use of internal consistency in on-sky observations to disentangle the influences of quantum efficiency, pixel-size variations, and scattered light in the dome flats; and pixel-by-pixel characterization of instrument spectral response, through combination of internal-consistency constraints with auxiliary calibration data. This article provides conceptual derivations of the detrending/calibration steps, and the procedures for obtaining the necessary calibration data. Other publications will describe the implementation of these concepts for the DES operational pipeline, the detailed methods, and the validation that the techniques can bring DECam photometry and astrometry within $\approx 2$ mmag and $\approx 3$ mas, respectively, of fundamental atmospheric and statistical limits. In conclusion, the DES techniques should be broadly applicable to wide-field imagers.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2016

Combined theoretical and experimental study of the valence, Rydberg, and ionic states of chlorobenzene

New photoelectron (PE) and ultra violet (UV) and vacuum UV (VUV) spectra have been obtained for chlorobenzene by synchrotron study with higher sensitivity and resolution than previous work and are subjected to detailed analysis. In addition, we report on the mass-resolved (2 + 1) resonance enhanced multiphoton ionization (REMPI) spectra of a jet-cooled sample. Both the VUV and REMPI spectra have enabled identification of a considerable number of Rydberg states for the first time. The use of ab initio calculations, which include both multi-reference multi-root doubles and singles configuration interaction (MRD-CI) and time dependent density functional theoretical (TDDFT) methods, has led to major advances in interpretation of the vibrational structure of the ionic and electronically excited states. Franck-Condon (FC) analyses of the PE spectra, including both hot and cold bands, indicate much more complex envelopes than previously thought. The sequence of ionic states can be best interpreted by our multi-configuration self-consistent field computations and also by comparison of the calculated vibrational structure of the B and C ionic states with experiment; these conclusions suggest that the leading sequence is the same as that of iodobenzene and bromobenzene, namely: X{sup 2}B{sub 1}(3b{sub 1}{sup −1}) < A{sup 2}A{sub 2}(1a{sub 2}{sup −1}) < B{sup 2}B{sub 2}(6b{sub 2}{sup −1}) < C{sup 2}B{sub 1}(2b{sub 1}{sup −1}). The absorption onset near 4.6 eV has been investigated using MRD-CI and TDDFT calculations; the principal component of this band is {sup 1}B{sub 2} and an interpretation based on the superposition of FC and Herzberg-Teller contributions has been performed. The other low-lying absorption band near 5.8 eV is dominated by a {sup 1}A{sub 1} state, but an underlying weak {sup 1}B{sub 1} state (πσ{sup ∗}) is also found. The strongest band in the VUV spectrum near 6.7 eV is poorly resolved and is analyzed in terms of two ππ{sup ∗} states of {sup 1}A{sub 1} (higher oscillator strength) and {sup 1}B{sub 2} (lower oscillator strength) symmetries, respectively. The calculated vertical excitation energies of these two states are critically dependent upon the presence of Rydberg functions in the basis set, since both manifolds are strongly perturbed by the Rydberg states in this energy range. A number of equilibrium structures of the ionic and singlet excited states show that the molecular structure is less subject to variation than corresponding studies for iodobenzene and bromobenzene.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2014

Advanced Automotive Fuels Research, Development, and Commercialization Cluster (OH) (Final Report)

Technical aspects of producing alternative fuels that may eventually supplement or replace conventional the petroleum-derived fuels that are presently used in vehicular transportation have been investigated. The work was centered around three projects: 1) deriving butanol as a fuel additive from bacterial action on sugars produced from decomposition of aqueous suspensions of wood cellulose under elevated temperature and pressure; 2) using highly ordered, openly structured molecules known as metal-organic framework (MOF) compounds as adsorbents for gas separations in fuel processing operations; and 3) developing a photocatalytic membrane for solar-driven water decomposition to generate pure hydrogen fuel. Several departments within the STEM College at YSU contributed to the effort: Chemistry, Biology, and Chemical Engineering. In the butanol project, sawdust was blended with water at variable pH and temperature (150 – 250 °C), and heated inside a pressure vessel for specified periods of time. Analysis of the extracts showed a wide variety of compounds, including simple sugars that bacteria are known to thrive upon. Samples of the cellulose hydrolysate were fed to colonies of Clostridium beijerinckii, which are known to convert sugars to a mixture of compounds, principally butanol. While the bacteria were active toward additions of pure sugar solutions, the cellulose extract appeared to inhibit butanol production, and furthermore encouraged the Clostridium to become dormant. Proteomic analysis showed that the bacteria had changed their genetic code to where it was becoming sporulated, i.e., the bacteria were trying to go dormant. This finding may be an opportunity, as it may be possible to genetically engineer bacteria that resist the butanol-driven triggering mechanism to stop further fuel production. Another way of handling the cellulosic hydrolysates was to simply add the enzymes responsible for butanol synthesis to the hydrolytic extract ex-vivo. These enzymes are generally not available commercially, however, and those that are can be quite expensive. Accordingly, the genes responsible for enzyme synthesis were inserted into other microorganisms in order to accelerate enzyme production. This was demonstrated for two of the required enzymes in the overall series. In the MOF project, a number of new MOF compounds were synthesized and characterized, as well as some common MOFs well-known for their adsorption properties. Selectivity for specific gases such as CO 2 and H 2 was demonstrated, although it was seen that water vapor would frequently act as an interferent. This work underscored the need to test MOF compounds under real world conditions, i.e., room temperature and above instead of liquid N 2 temperature, and testing adsorption using blends of gases instead of pure components. In the solar membrane project, thin films of CdTe and WO 3 were applied to steel substrates and used as p-type and n-type semiconductors, respectively, in the production of H 2 and O 2 . Testing with 2 H and 18 O isotopically labeled water enabled substantiation of net water-splitting.

08 HYDROGEN↗

NASA NTRS1998

Extraterrestrial organic matter: a review

We review the nature of the widespread organic material present in the Milky Way Galaxy and in the Solar System. Attention is given to the links between these environments and between primitive Solar System objects and the early Earth, indicating the preservation of organic material as an interstellar cloud collapsed to form the Solar System and as the Earth accreted such material from asteroids, comets and interplanetary dust particles. In the interstellar medium of the Milky Way Galaxy more than 100 molecular species, the bulk of them organic, have been securely identified, primarily through spectroscopy at the highest radio frequencies. There is considerable evidence for significantly heavier organic molecules, particularly polycyclic aromatics, although precise identification of individual species has not yet been obtained. The so-called diffuse interstellar bands are probably important in this context. The low temperature kinetics in interstellar clouds leads to very large isotopic fractionation, particularly for hydrogen, and this signature is present in organic components preserved in carbonaceous chondritic meteorites. Outer belt asteroids are the probable parent bodies of the carbonaceous chondrites, which may contain as much as 5% organic material, including a rich variety of amino acids, purines, pyrimidines, and other species of potential prebiotic interest. Richer in volatiles and hence less thermally processed are the comets, whose organic matter is abundant and poorly characterized. Cometary volatiles, observed after sublimation into the coma, include many species also present in the interstellar medium. There is evidence that most of the Earth's volatiles may have been supplied by a 'late' bombardment of comets and carbonaceous meteorites, scattered into the inner Solar System following the formation of the giant planets. How much in the way of intact organic molecules of potential prebiotic interest survived delivery to the Earth has become an increasingly debated topic over the last several years. The principal source for such intact organics was probably accretion of interplanetary dust particles of cometary origin.

NASA Discipline Exobiology↗

DOE OSTI2017

A STUDY OF CHANGES IN DEFORMATION AND METABOLISM IN LEFT VENTRICLE AS A FUNCTION OF HYPERTROPHY IN SPONTANEOUS HYPERTENSIVE RATS USING MICROPET TECHNOLOGY

Problem: In the case of hypertrophy caused by pressure overload (hypertension) there is an increase in cardiac mass and modification cardiac metabolism. Aim: This study was designed to study the changes in glucose metabolism, ejection fraction, and deformation in the left ventricle with the progression of hypertrophy in spontaneous hypertensive rats (SHR). Methods: Dynamic PET data were acquired using the microPET II at UC Davis. Two rats were imaged at 10-week intervals for 18 months. Each time a dose of approximately 1- 1.5 mCi of F-18-FDG was injected into a normotensive Wistar Kyoto (WKY) rat and the same dose was injected into a SHR rat. Each rat was imaged using a gated dynamic acquisition for 80 minutes acquiring list mode data with cardiac gating of approximately 600-900 million total counts. For the analysis of glucose of metabolism, the list mode data were histogrammed into a dynamic sequence (42 frames over 80 mins). For each time frame, projection data of 1203 140x210 sinograms of 0.582 mm bins were formed by summing the last three gates before and one after the R-wave trigger to correspond to the diastolic phase of the cardiac cycle. Dynamic sequences of 128x128x83 matrices of 0.4x0.4x0.582 mm3 voxels in x, y, and z were reconstructed using an iterative MAP reconstruction which used a prior that penalized the high frequency components of the reconstruction using appropriate weighting between 26 nearest neighboring voxels. Time activity curves were generated from the dynamic reconstructed sequence for the blood and left ventricular tissue regions of interest which were fit to a 2-compartment model to obtain a least squares fit for the kinetic parameters. For the analysis of deformation, the list mode data were histogrammed into 8 gates of the cardiac cycle, each gate was the total sum of the later 60 mins of the 80 min acquisition. Images of 128x128x83 matrices for each gate were reconstructed using the same iterative MAP reconstruction used to reconstruct the dynamic sequence. The in-plane image dimensions were doubled to 256x256x83 in order to increase the resolution for the Warping analyses. These image data sets were then cropped to 128x128x83. The end-systolic image data sets were designated as the template images and the end-diastole image data sets were designated as the target images, thus providing an analysis of the diastolic relaxation and filling phases of the cardiac cycle. The template images were manually segmented to create surface definitions representing the epi- and endocardial surfaces. Finite element models of the left ventricles were created using the segmented surfaces and defining a transversely isotropic material with fiber angles varying from the epicardial surface to the endocardial surface. A Warping analyses was performed to obtain the LV strain tensor and fiber stretch distributions. Results: In one study, the average first principal Green-Lagrange strain, fiber stretch, ejection fraction, and metabolic rate of F-18-FDG was 0.22, 1.08, 80%, 0.1 for the WKY rat and 0.16, 1.06, 50%, 0.25 for the SHR rat, respectively. These same rats studied a year later presented with a metabolic rate of F-18-FDG of 0.11 and 0.25 for the WKY and SHR, respectively. A follow-up study the average strain (n=10) and ejection fraction (n=18) was 0.21, 72.7% for WKY and 0.17, 69.8% for the SHR, respectively. Conclusion: In the case of pressure overload there is an increased reliance on carbohydrate oxidation in an attempt to maintain contractile function.

Sitek, Arkadiusz↗

NASA NTRS2001

Variability of Antarctic Sea Ice 1979-1998

The principal characteristics of the variability of Antarctic sea ice cover as previously described from satellite passive-microwave observations are also evident in a systematically-calibrated and analyzed data set for 20.2 years (1979-1998). The total Antarctic sea ice extent (concentration > 15 %) increased by 13,440 +/- 4180 sq km/year (+1.18 +/- 0.37%/decade). The area of sea ice within the extent boundary increased by 16,960 +/- 3,840 sq km/year (+1.96 +/- 0.44%/decade). Regionally, the trends in extent are positive in the Weddell Sea (1.5 +/- 0.9%/decade), Pacific Ocean (2.4 +/- 1.4%/decade), and Ross (6.9 +/- 1.1 %/decade) sectors, slightly negative in the Indian Ocean (-1.5 +/- 1.8%/decade, and strongly negative in the Bellingshausen-Amundsen Seas sector (-9.5 +/- 1.5%/decade). For the entire ice pack, small ice increases occur in all seasons with the largest increase during autumn. On a regional basis, the trends differ season to season. During summer and fall, the trends are positive or near zero in all sectors except the Bellingshausen-Amundsen Seas sector. During winter and spring, the trends are negative or near zero in all sectors except the Ross Sea, which has positive trends in all seasons. Components of interannual variability with periods of about 3 to 5 years are regionally large, but tend to counterbalance each other in the total ice pack. The interannual variability of the annual mean sea-ice extent is only 1.6% overall, compared to 5% to 9% in each of five regional sectors. Analysis of the relation between regional sea ice extents and spatially-averaged surface temperatures over the ice pack gives an overall sensitivity between winter ice cover and temperature of -0.7% change in sea ice extent per K. For summer, some regional ice extents vary positively with temperature and others negatively. The observed increase in Antarctic sea ice cover is counter to the observed decreases in the Arctic. It is also qualitatively consistent with the counterintuitive prediction of a global atmospheric-ocean model of increasing sea ice around Antarctica with climate warming due to the stabilizing effects of increased snowfall on the Southern Ocean.

Zwally, H. Jay↗

DOE OSTI2014

Evaluation of the effect of organic pro-degradant concentration in polypropylene exposed to the natural ageing

The production and consumption of plastics in the last decade has recorded a remarkable increase in the scientific and industrial interest in environmentally degradable polymer (EDPs). Polymers wastes are deposited improperly, such as dumps, landfills, rivers and seas, causing a serious problem by the accumulation in the environment. The abiotic processes, like the photodegradation, are the most efficient occurring in the open environmental, where the polymers undergo degradation from the action of sunlight that result from direct exposure to solar radiation, however depend of the type of chemical ageing, which is the principal component of climatic ageing. The subject of this work is to study the influence of concentration of organic pro-degradant (1, 2 and 3 % w/w) in the polypropylene (PP) exposed in natural ageing. PP samples with and without the additive were processed in plates square form, obtained by thermal compression molding (TCM) using a press at 200°C under 2 tons for 5 min, and then were exposed at natural ageing during 120 days. The presence of organic additive influenced on PP degradability, this fact was assessed by changes in the thermal and morphology properties of the samples after 120 days of natural ageing. Scanning Electronic Microscopy (SEM) results of the morphological surface of the modified PP samples showed greater degradation photochemical oxidative when compared to neat PP, due to increase of rugosity and formation of microvoids. PP samples with different pro-degradant concentration under natural ageing presented a degree of crystallinity, obtained by Differential Scanning Calorimeter (DSC) increases in comparing the neat PP.

36 MATERIALS SCIENCE↗

NASA NTRS1989

The use of aircraft and satellite remote sensing of phytoplankton chlorophyll concentrations in case 2 estuarine waters of the Chesapeake Bay

Two projects using remote sensing of phytoplankton chlorophyll concentrations in the Chesapeake Bay estuary were proposed. The first project used aircraft remote sensing with a compact radiometer system developed at NASA's Goddard Space Flight Center (GSFC), the Ocean Data Acquisition System (ODAS). ODAS includes three radiometers at 460, 490, and 520 nm, an infrared temperature sensor (PRT-5), Loran-C for navigation, and a data acquisition system using a PC and mass storage device. This instrument package can be flown in light aircraft at relatively low expense, permitting regular and frequent flights. Sixteen flights with ODAS were completed using the Virginia Institute of Marine Science's De Havilland 'Beaver'. The goal was to increase spatial and temporal resolution in assaying phytoplankton pigment concentrations in the Chesapeake. At present, analysis is underway of flight data collected between March and July 1989. The second project focused on satellite data gathered with the Nimbus-7 Coastal Zone Color Scanner (CZSC) between late 1978 and mid 1986. The problem in using CZSC data for the Chesapeake Bay is that the optical characteristics of this (and many) coastal and estuarine waters are distinct from those of the open ocean for which algorithms for computing pigment concentrations were developed. The successful use of CZCS data for the estuary requires development of site-specific algorithms and analytical approaches. Of principal importance in developing site-specific procedures is the availability of in-situ data on pigment concentrations. A significant data set was acquired from EPA's Chesapeake Bay Program in Annapolis, Maryland, and clear satellite scenes are being analyzed for which same-day sea truth measurements of pigment were obtained. Both the University of Miami and GSFC Seapak systems are being used in this effort. The main finding to date is an expected one, i.e., the algorithms developed for oceanic waters are inadequate to compute pigment concentrations for the Case 2 waters of the Chesapeake Bay. One reason is the overestimation of aerosol radiances by assuming that water-leaving radiance in Band 4 of CZCS (670 nm) is zero, an assumption that is invalid for the Bay. This prompted any attempts to iterative procedures for estimating the proportion of the Band 4 radiance that is actually attributable to aerosol by estimating the water-leaving component using optical data. A cruise on the Chesapeake the week of 7 August 1989 was conducted to collect additional optical data necessary to this task.

Harding, Lawrence W., Jr.↗

NASA NTRSDate not supplied

Implementation of Two Local Correlation-Based Transition Models in OVERFLOW 2.3e

Accurate prediction of the laminar-to-turbulent boundary layer transition is highlighted as a vital component of NASA's CFD Vision 2030 Study. With an increased emphasis on greener air transports and sustainable aviation, transition modeling is anticipated to have an added significance, particularly in the applications related to laminar flow technology. However, unmanned aerial vehicles, crewed reentry vehicles, and ground-to-flight extrapolation all benefit from transition models. It is useful to incorporate a variety of models in CFD solvers because there isn't a single transition model that is ideal for the complete spectrum of applications. While the Langtry-Menter γ–Reθt model has been widely used for CFD predictions of flows with laminar, transitional, and turbulent boundary layers, it does not meet the criteria for Galilean invariance, a desirable attribute for rotorcraft applications. To help overcome that limitation, we have implemented Menter's SST-based γ transition model within NASA’s OVERFLOW Overset CFD code (version 2.3e). In addition, an SA-based implementation of the Langtry-Menter γ–Reθt transition model has also been implemented in view of the increased robustness of the SA-turbulence model for external aerodynamic applications. An initial assessment of the implemented models has been carried out using benchmark 2D test cases involving flat plates and the NLF-0416 airfoil, focusing on bypass, Tollmien-Schlichting, and laminar separation bubble-induced transition scenarios. In comparison to the Langtry-Menter γ–Reθt model, both models were found to produce increased computation efficiency, principally as a result of the decrease from four to three auxiliary transport equations. Results from the initial analysis will be presented, along with additional details pertaining to the deployment of these models.

CFD modeling↗

NASA NTRS2017

Limiting Data Friction by Reducing Data Download Using Spatiotemporally Aligned Data Organization Through STARE

Current data processing practice limits the volume and variety of relevant geoscience data that can practically be applied to important problems. File archives in centralized data centers are the principal means by which Earth Science data are accessed. This approach, however, requires laborious search, retrieval, and eventual customization/adaptation for the data to be used. Such fractionation makes it even more difficult to share outcomes, i.e. research artifacts and data products, hampering reusability and repeatability, since end users generally have their own research agenda and preferences as well as scarce resources. Thus, while finding and downloading data files from central data centers are already costly for end users working in their own field, using data products from other disciplines rapidly becomes prohibitive. This curtails scientific productivity, limits avenues of study, and endangers quality and reproducibility. The Spatio-Temporal Adaptive Resolution Encoding (STARE) is a unifying scheme that facilitates the indexing, access, and fusion of diverse Earth Science data. STARE implements an innovative encoding of geo-spatiotemporal information, originally developed for aligning datasets with diverse spatiotemporal characteristics in an array database. The spatial component of STARE recursively quadfurcates a root polyhedron, producing a hierarchical scheme for addressing geographic locations and regions. The temporal component of STARE uses conventional date-time units as an indexing hierarchy. The additional encoding of spatial and temporal resolution information in STARE enables comparisons and conditional selections across diverse datasets. Moreover, spatiotemporal set-operations, e.g. union and intersection, are mapped to efficient integer operations with STARE. Applied to existing data models (point, grid, spacecraft swath) and corresponding granules, STARE indexes provide a streamlined description usable as geo-spatiotemporal metadata. When coupled with large scale, distributed hardware and software, STARE-based data access reduces pre-analysis data preparation costs by offering a convenient means to align different datasets spatiotemporally without specialized effort in parallel computing or distributed data management.

Kuo, Kwo-Sen↗

NASA NTRS1997

Continuing Studies in Support of Ultraviolet Observations of Planetary Atmospheres

This program was a one-year extension of an earlier Planetary Atmospheres program grant, covering the period 1 August 1996 through 30 September 1997. The grant was for supporting work to complement an active program observing planetary atmospheres with Earth-orbital telescopes, principally the Hubble Space Telescope (HST). The recent concentration of this work has been on HST observations of Jupiter's upper atmosphere and aurora, but it has also included observations of Io, serendipitous observations of asteroids, and observations of the velocity structure in the interplanetary medium. The observations of Jupiter have been at vacuum ultraviolet wavelengths, including imaging and spectroscopy of the auroral and airglow emissions. The most recent HST observations have been at the same time as in situ measurements made by the Galileo orbiter instruments, as reflected in the meeting presentations listed below. Concentrated efforts have been applied in this year to the following projects: The analysis of HST WFPC 2 images of Jupiter's aurora, including the Io footprint emissions. We have performed a comparative analysis of the lo footprint locations with two magnetic field models, studied the statistical properties of the apparent dawn auroral storms on Jupiter, and found various other repeated patterns in Jupiter's aurora. Analysis and modeling of airglow and auroral Ly alpha emission line profiles from Jupiter. This has included modeling the aurora] line profiles, including the energy degradation of precipitating charged particles and radiative transfer of the emerging emissions. Jupiter's auroral emission line profile is self-absorbed, since it is produced by an internal source, and the resulting emission with a deep central absorption from the overlying atmosphere permits modeling of the depth of the emissions, plus the motion of the emitting layer with respect to the overlying atmospheric column from the observed Doppler shift of the central absorption. By contrast the airglow emission line, which is dominated by resonant scattering of solar emission, has no central absorption, but displays rapid time variations and broad wings, indicative of a superthermal component (or corona) in Jupiter's upper atmosphere. Modeling of the observed motions of the plumes produced after the impacts of the fragments of Comet S/L-9 with Jupiter in July 1994, from the HST WFPC 2 imaging series.

Clark, John↗

DOE OSTI2013

CONSTRAINTS ON PERTURBATIONS TO THE RECOMBINATION HISTORY FROM MEASUREMENTS OF THE COSMIC MICROWAVE BACKGROUND DAMPING TAIL

The primordial cosmic microwave background at small angular scales is sensitive to the ionization and expansion history of the universe around the time of recombination. This dependence has been exploited to constrain the helium abundance and the effective number of relativistic species. Here we focus on allowed ionization fraction trajectories, x {sub e}(z), by constraining low-order principal components of perturbations to the standard recombination scenario (x {sub e}-eigenmodes) in the circa 2011 South Pole Telescope (SPT), Atacama Cosmology Telescope (ACT), and Wilkinson Microwave Anisotropy Probe seven-year data (WMAP7). Although the trajectories are statistically consistent with the standard recombination, we find that there is a tension similar to that found by varying the helium fraction. As this paper was in press, final SPT and ACT datasets were released and we applied our framework to them: we find that the tension continues, with slightly higher significance, in the new 2012 SPT data, but find no tension with the standard model of recombination in the new 2012 ACT data. We find that the prior probabilities on the eigenamplitudes are substantially influenced by the requirement that x {sub e}-trajectories conserve electron number. We propose requiring a sufficient entropy decrease between posterior and prior marginalized distributions be used as an x {sub e}-mode selection criterion. We find that in the case of the 2011 SPT/ACT+WMAP7 data only two modes are constrainable, but upcoming ACTPol, Planck, and SPTPol data will be able to test more modes and more precisely address the current tension.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS2011

X-Ray Production by V1647 Ori During Optical Outbursts

The pre-main-sequence (PMS) star V1647 Ori has recently undergone two optical/near-infrared (OIR) outbursts that are associated with dramatic enhancements in the stellar accretion rate. Our intensive X-ray monitoring of this object affords the opportunity to investigate whether and how the intense X-ray emission is related to PMS accretion activity. Our analysis of all 14 Chandra X-Ray Observatory observations of V1647 Ori demonstrates that variations in the X-ray luminosity of V1647 Ori are correlated with similar changes in the OIR brightness of this source during both (2003-2005 and 2008) eruptions, strongly supporting the hypothesis that accretion is the primary generation mechanism for the X-ray outbursts. Furthermore, the Chandra monitoring demonstrates that the X-ray spectral properties of the second eruption were strikingly similar to those of the 2003 eruption. We find that X-ray spectra obtained immediately following the second outburstduring which V1647 Ori exhibited high X-ray luminosities, high hardness ratios, and strong X-ray variabilityare well modeled as a heavily absorbed (N H 4 1022cm2), single-component plasma with characteristic temperatures (kT X 2-6keV) that are consistently too high to be generated via accretion shocks but are in the range expected for plasma heated by magnetic reconnection events. We also find that the X-ray absorbing column has not changed significantly throughout the observing campaign. Since the OIR and X-ray changes are correlated, we hypothesize that these reconnection events either occur in the accretion stream connecting the circumstellar disk to the star or in accretion-enhanced protostellar coronal activity.

Teets, William↗

NASA NTRS1999

Workshop on Extraterrestrial Materials from Cold and Hot Deserts

The workshop was held July 6-8, 1999 before the Meteoritical Society meeting in Johannesburg, South Africa. The venue was Kwa Maritane Resort in the Pilanesburg Game Reserve. Conveners were Ludolf Schultz (Chair, MPI fur Chemie), Ian Franchi (Open University), Arch Reid (University of Houston), and Mike Zolensky (NASA JSC). Extended abstracts will be published as an LPI Technical Report. In the first session, Marvin discussed three African iron meteorites: Cape of Good Hope, Gibeon, and Hoba. Grady presented a statistical analysis of meteorites from hot and cold deserts. Wasson discussed types of Antarctic iron meteorites. Several presentations characterized populations of meteorites from individual desert areas: Libyan Desert (Weber et al.), Nullarbor Region (Bevan et al.), and Mojave Desert (Kring et al. and Verish et al). Pairing among EET87503-group howardites was discussed by Buchanan et al. Based on 14C terrestrial ages of Allan Hills ordinary chondrites, Bland et al. suggested that ice flow may be the principal sink for Antarctic meteorites. The effects of preterrestrial and terrestrial alteration were considered in the second session. Nakamura et al. and Lipschutz discussed asteroidal metamorphism of carbonaceous chondrites. Zolensky presented evidence for preterrestrial halide and sulfide in meteorites. Crozaz and Wadhwa described terrestrial alteration of Dar al Gani 476. Welten and Nishiizumi discussed terrestrial weathering of chondrites from Frontier Mountain, Antarctica. Most of the third session dealt with terrestrial meteorite ages. Based on 14C-10Be ages, Jull et al. discussed the exponential decay in numbers of meteorites with increased age. Nishiizumi et al. concluded that some Allan Hills meteorites have much older terrestrial ages than any meteorites from Lewis Cliffs. Welten et al. discussed terrestrial ages determined by 41Ca/36CI of metal separates from hot desert meteorites. Based on a comparison with large IDPs, Flynn et al. suggested that polar micrometeorites, lost a water-soluble sulfate phase by terrestrial alteration. Nyquist suggested that Type I cosmic spheres from deep sea sediments and polar ice were derived from carbonaceous chondrite-like asteroidal sources. The final session considered noble gases, cosmic ray effects, and thermoluminescence. Calculations presented by Reedy indicate that cosmic ray-produced nuclides are more likely to be preserved in small objects than in larger objects. Murty and Mohapatra. reported that trapped gas in Dar al Gani 476 includes a Martian atmospheric component. Wieler et al. and Scherer et al. reported noble gas abundances in different types of desert meteorites. Patzer and Schultz discussed the influence of terrestrial weathering on cosmic ray exposure ages of enstatite chondrites. Franchi et al. suggested that it is difficult to discriminate whether differences in gas release profiles of lunar meteorites from hot deserts and returned lunar samples are the result of terrestrial weathering or shock metamorphism. Benoit and Sears surveyed natural and induced thermoluminescence of Antarctic ordinary chondrites. Merchel et al. analyzed Saharan meteorites with short or complex exposure histories.

Buchanan, Paul C.↗

DOE OSTI2021

Materials Challenges and Opportunities for Energy Generation, Conversion, Delivery, and Storage (Applied Energy Tri-Laboratory Consortium Workshop Report)

This report documents the outcomes of the Tri-Laboratory Materials Workshop that was held July 31 and August 1, 2019 to begin addressing the needs, opportunities, and challenges associated with the development, fabrication, and testing of the needed materials and components for integrated hybrid energy systems (i.e., incorporating nuclear, fossil, and renewables for electric and thermal applications). This was accomplished by assembling the research program leads and principal investigators at Idaho National Laboratory (INL), National Energy Technology Laboratory (NETL), and National Renewable Energy Laboratory (NREL), who support the research and development of new technology and system integration. The team then identified and prioritized key materials development needs. This effort was intended to enhance communications and synergy among the Tri-Lab partners. Advanced functional and structural materials are central to transformative energy technologies for energy generation, conversion, delivery, and storage. With that in mind, the workshop focused on identifying and assessing the foundational materials research needs at both the basic and applied levels. Materials challenges include the ability to withstand harsh environments, such as high temperatures and pressures, corrosion, oxidation, or irradiation while maintaining flexible mission profiles and long service lifespans. Advanced energy system material challenges and needs range from materials for the capture, upgrading/concentration, storage, and delivery of low-grade heat to materials for high temperature environments that involve liquid metals, molten salt, and very high temperature gas heat delivery and storage systems. Material improvements are needed for hybrid energy systems due to accelerated corrosion and stress-fatigue failure of materials and equipment, which results from increased frequency and amplitude of thermal, mechanical, and electrical cycling of systems components. Multifunctional materials are needed for high temperature solid-oxide fuel cells, advanced electrochemical reactors, and in-process separation. Relative to materials manufacturing, application of advanced additive and subtractive methods need to be understood to develop both thin-layer homogenous materials and materials of graded composition. Materials modeling and machine learning will be critical to accelerate the design and production of power electronics, and nuclear reactor materials and fuel, as well as to gain an understanding of beneficial materials phenomena or deleterious microstructure evolution. There is also a need for standardized models, computational structures, data reporting protocols and modeling tools across the three laboratories. This would allow consistent results, analysis, and data sharing. Combining computational capabilities between the three laboratories (e.g., hardware, software) would greatly increase computational capabilities and throughput. The workshop identified the need for laboratories to anticipate and address problems that will occur during scale-up. Laboratory work must connect with industry to ensure that research focuses on processes that are scalable and marketable. Industry input and perspective are essential to guide laboratory research to meet these requirements and deploy new technology in industrial demonstrations. Another aspect of scale-up is the integration of multiple systems since new challenges often arise at the subsystem interfaces. Establishing a scale-up manufacturing demonstration/pilot plant, potentially as an industrial user facility, would be beneficial to the laboratories and industry. That modular scale-up manufacturing demonstration/pilot plant would allow researchers to find and resolve interface problems that cannot be identified by focusing only on individual parts. Communication exchanges among the organizers, attendees, and workshop survey responses indicate that the workshop was successful in achieving its goal to identify key technology gaps and research needs. Strong positive feedback was received on the sharing of ideas, capabilities, talent, and passion to move forward on the materials-related action items.

36 MATERIALS SCIENCE↗

NASA NTRS1991

Basic research in solar physics

This grant, dating back more than 20 years has supported a variety of investigations of the chromospheres and coronae of the Sun and related cool stars by the Principal Investigator, his postdocs and graduate students, and colleagues at other institutions. This work involved studies of radiative transfer and spectral line formation theory, and the application of these techniques to the analysis of spectra obtained from space and ground-based observatories in the optical, ultraviolet, x-ray and radio portions of the spectrum. Space observations have included the analysis of spectra from OSO-7, Skylab, SMM, and the HRTS rocket experiments. Recent work has concentrated on the interaction of magnetic fields, plasma and radiation in the outer atmospheres of the Sun and other magnetically active stars with different fundamental parameters. Our study of phenomena common to the Sun and stars, the 'solar-stellar connection', can elucidate the fundamental physics, because spatially-resolved observations of the Sun provide us with the 'groundtruth,' while interpretation of stellar data permit us to isolate those parameters critical to stellar activity. Recently, we have studied the differences in physical properties between solar regions of high magnetic flux density and the surrounding plasma. High-resolution CN and CO spectroheliograms have been used to model the thermal inhomogeneities driven by unstable CO cooling, and we have analyzed spatially resolved UV spectra from HRTS to model the thermal structure and energy balance of small-scale structures. The study of nonlinear relations between atmospheric radiative losses and the photospheric magnetic flux density has been continued. We have also proposed a new model for the decay of plages by random walk diffusion of magnetic flux. Our analysis of phenomena common to the Sun and stars included the application of available spectroscopic diagnostics, establishing evidence that the atmospheres of the least active stars are heated at a 'basal' rate that is also found in the centers of solar supergranules, and using the Doppler-imaging technique to measure the position, size, and brightness of stellar active regions. We are computing multi-component models for solar and stellar atmospheres, and models for coronal loops and for the transition-region down flows. The study of solar and stellar flares permits us to assess the role of turbulent energy transport, to pinpoint the mechanism behind Type I radio bursts, to determine whether plasma radiation or cyclotron maser is responsible for microwave flares on M dwarfs, and to extend our knowledge of the basic physics pertinent to cyclotron-maser processes operating on the Sun.

Linsky, Jeffrey L.↗