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DOE OSTI2020

The Influence of Disorder in the Synthesis, Characterization and Applications of a Modifiable Two-Dimensional Covalent Organic Framework

Two-dimensional covalent organic frameworks (2D-COFs) have been of increasing interest in the past decade due to their porous structures that ideally can be highly ordered. One of the most common routes to these polymers relies on Schiff-base chemistry, i.e., the condensation reaction between a carbonyl and an amine. In this report, we elaborate on the condensation of 3,6-dibromobenzene-1,2,4,5-tetraamine with hexaketocyclohexane (HKH) and the subsequent carbonylation of the resulting COF, along with the possibility that the condensation reaction on HKH can result in a trans configuration resulting in the formation of a disordered 2D-COF. This strategy enables modification of COFs via bromine substitution reactions to place functional groups within the pores of the materials. Ion-sieving measurements using membranes from this COF, reaction of small molecules with unreacted keto groups along with modeling studies indicate disorder in the COF polymerization process. We also present a Monte Carlo simulation that demonstrates the influence of even small amounts of disorder upon both the 2D and 3D structure of the resulting COF.

carboxylated pores↗

NASA NTRS1973

Public science policy and administration

Science, the overwhelming concern of our time, is no longer a matter of private research and development but one of public policy and administration, in which government, industry, foundations, and educational institutions must all work together as never before. Few other single tasks are of such decisive importance to the collective and individual welfare of American citizens as the formulation of public science policy and the administration of scientific programs. Eleven national authorities of varied background in science, education, and government administration contribute their experience and their judgment in an effort to deal with the major aspects of the subject. Their focus is on the meeting of actual problems; they consider the decision making process in both public and public-private organizations. Topics are grouped in three general categories: personnel needs and resources, organizational problems and techniques, and the administrative role in policy leadership.

Rosenthal, A. H.↗

NASA NTRS1973

Interplanetary orbit determination

The logistical aspects of orbit determination (OD) in the interplanetary phase of the Mariner Mars 1971 mission are described and the working arrangements for the OD personnel, both within the Navigation Team and with outside groups are given. Various types of data used in the OD process are presented along with sources of the data. Functional descriptions of the individual elements of the OD software and brief sketches of their modes of operation are provided.

Zielenbach, J. W.↗

NASA NTRS1974

Switched electrical networks and bilinear equations

An investigation is conducted concerning the state equations which arise in the description of power processing systems. Attention is given to the role played by Lie groups and Lie algebras in the characterization of the dynamical features of the systems. The bilinear equations used for the representation of the network characteristics are discussed along with the nature of the solutions for the equations. The application of the described approaches is illustrated with the aid of a number of network examples.

Wood, J. R.↗

NASA NTRS1975

Study for identification of Beneficial Uses of Space (BUS). Volume 2: Technical report. Book 5: Study methods and trade studies

A glossary of terms, a work breakdown structure, and work element descriptions, resource needs, and costs are introduced. The generic work breakdown structure was utilized to organize specific structures for each product under study; each structure containing both space and ground elements arrived at via mutual interaction. Concept definition and assessment, provided the study team and the participants visibility of the limits, and the organization of the efforts provided by both groups spelling out where such efforts fit into the generation of processing concepts.

Source record↗

NASA NTRS1982

Three sensor hot wire/film technique for three dimensional mean and turbulence flow field measurement

Methods of measuring the three dimensional flow field using a three-sensor, hot-wire probe is described in this paper, with emphasis on the techniques developed by the author's group at The Pennsylvania State University. The hot wire equations, data processing procedure, calibration techniques, and a discussion of various errors in the measurement are included. Some typical data acquired by this probe is also included.

Lakshminarayana, B.↗

NASA NTRS1984

LANDSAT-4 MSS and TM Spectral Class Comparison and Coherent Noise Analysis

A detailed spectral analysis is conducted of thematic mapper and MSS data for an area near Des Moines, Iowa. Data are utilized from 7 blocks distributed throughout the area which included agricultural, forest, suburan, urban, and water scene types. The blocks are processed using a clustering algorithm to produce up to 18 cluster groupings for each block. Each cluster class is then identified with a ground-cover class using aerial photography and maps of the area. The clusters from each of the 7 blocks are inspected with regard to separability, mean, and variances. The separability measure used in the transformed divergence function or processor measures the statistical distance between classes based on class means and covariance matrices. The measure has a maximum value of 2,000 and the minimum of 0. Spectrally, very close classes will typically have values as low as 50 to 500.

Anuta, P. E.↗

NASA NTRS1988

Highly labile elements

Certain elements of high lability are very responsive to thermal processes, being either highly volatile during primary nebular condensation or highly mobile by postaccretionary metamorphic or shock heating. Data for highly labile elements indicate that different thermal processes were important in the genesis of each of the chondritic groups and a discussion of each is given. Contents of highly labile elements in a given group of contemporary falls differ from those of the same group that fell in Antarctica more than 0.1 Myr ago. This difference is due either to a time-dependent change in meteorite sources or, less likely, orbital variation of the meteorite flux to Earth.

Lipschutz, Michael E.↗

NASA NTRS1991

Decomposing Systems Into Subsystems For Design

Interactions among systems displayed in concise format. DeMAID (Design Manager's Aide for Intelligent Decomposition) is knowledge based software system for automating sequencing of subprocesses in design process and identifying possible multilevel structure for synthesis problem. Reorders and groups modules of equipment being designed on basis of links among modules, helping design manager make design decisions early in design cycle. Written in FORTRAN 77.

Rogers, James L., Jr.↗

NASA NTRS1992

Results from testing and analysis of solar cells flown on LDEF

A brief discussion of the solar cell experiments flown on the Long Duration Exposure Facility (LDEF) is provided. The information presented is a collation of results published by the various experimenters. This process of collation and documentation is an ongoing Systems Special Investigation Group (SIG) effort. There are four LEO environments, operating individually and/or synergistically, that cause performance loss in solar cells: meteoroid and space debris, atomic oxygen, ultraviolet radiation, and charged particle radiation. In addition, the effects of contamination caused by outgassing of materials used on the specific spacecraft play a role in decreasing the light being transmitted through the coverglass and adhesive to the solar cell. From the results presented on the solar cells aboard LDEF, the most extensive degradation of the solar cells came from impacts and the resulting cratering. The extent of the damage to the solar cells was largely dependent upon the size and energy of the meteoroids or space debris. The other cause of degradation was reduced light reaching the solar cell. This was caused by contamination, UV degradation of coverglass adhesive, and/or atomic oxygen/UV degradation of antireflection coatings.

Dursch, Harry↗

NASA NTRS1993

Quality metrics for sensor images

Methods are needed for evaluating the quality of augmented visual displays (AVID). Computational quality metrics will help summarize, interpolate, and extrapolate the results of human performance tests with displays. The FLM Vision group at NASA Ames has been developing computational models of visual processing and using them to develop computational metrics for similar problems. For example, display modeling systems use metrics for comparing proposed displays, halftoning optimizing methods use metrics to evaluate the difference between the halftone and the original, and image compression methods minimize the predicted visibility of compression artifacts. The visual discrimination models take as input two arbitrary images A and B and compute an estimate of the probability that a human observer will report that A is different from B. If A is an image that one desires to display and B is the actual displayed image, such an estimate can be regarded as an image quality metric reflecting how well B approximates A. There are additional complexities associated with the problem of evaluating the quality of radar and IR enhanced displays for AVID tasks. One important problem is the question of whether intruding obstacles are detectable in such displays. Although the discrimination model can handle detection situations by making B the original image A plus the intrusion, this detection model makes the inappropriate assumption that the observer knows where the intrusion will be. Effects of signal uncertainty need to be added to our models. A pilot needs to make decisions rapidly. The models need to predict not just the probability of a correct decision, but the probability of a correct decision by the time the decision needs to be made. That is, the models need to predict latency as well as accuracy. Luce and Green have generated models for auditory detection latencies. Similar models are needed for visual detection. Most image quality models are designed for static imagery. Watson has been developing a general spatial-temporal vision model to optimize video compression techniques. These models need to be adapted and calibrated for AVID applications.

Ahumada, AL↗

NASA NTRS1994

Low-freqency instabilities and the resulting velocity distributions of pickup ions at comet Halley

The interaction between the solar wind and newborn cometary ions is studied using a new analytical theory as well as one- and two-dimensional hybrid simulations. Using the observed parameters upstream of the comet Halley, a detailed study of wave excitation and the resulting particle distributions is presentd. Linear theory as well as simulations show that a variety of modes such as the fast magnetosonic mode, high frequency whistlers and obliquely propagating Alfven ion cyclotron waves can be excited. However, parallel propagating waves are found to be dominant in the wave spectrum and to control the scattering of the pickup ions. Several features of the observed distributions of pickup protons are explained. In particular, it is shown that the observed asymmetric pitch distribution for the pickup protons is due to the small saturation amplitude of the waves for the given parameters. Water group associated waves can lead to energy diffusion and further pitch angle scattering of protons. This effect is most likely to be important in the vicinity of the bow shock of comet Halley where the density of water group ions becomes comparable to that of protons. It is shown that the observed increase in the radius of the proton velocity shell just outside the bow shock can be due to water group waves. The nearby isotropic proton pitch angle distribution observed by Neugebauer et al. (1989) just outside the bow shock may, however, be related to the presence of a rotational discontinuity which has been identified in the magnetic field data. Just outside the bow shock, simulations show that parallel propagating water group waves can steepen with attached whistler wave packets. The steepening process at parallel propagation is a transient effect, in an important contrast to the case of steepening at oblique angles. The smaller beam densitites at comet Halley appears to be the main reason not only why waves at comet Halley have smaller amplitudes but also why oblique, steepening magnetosonic waves have not been detected at comet Halley, whereas they have been seen at comet Giacobini-Zinner. Halley, whereas they have been seen at comet Giacobini-Zinner.

Karimabadi, H.↗

NASA NTRS2002

Phenylethynyl Containing Reactive Additives

Phenylethynyl containing reactive additives were prepared from aromatic diamines containing phenylethynyl groups and various ratios of phthalic anhydride and 4-phenylethynylphthalic anhydride in glacial acetic acid to form the imide in one step or in N-methyl-2-pyrrolidinone to form the amide acid intermediate. The reactive additives were mixed in various amounts (10% to 90%) with oligomers containing either terminal or pendent phenylethynyl groups (or both) to reduce the melt viscosity and thereby enhance processability. Upon thermal cure, the additives react and become chemically incorporated into the matrix and effect an increase in crosslink density relative to that of the host resin. This resultant increase in crosslink density has advantageous consequences on the cured resin properties such as higher glass transition temperature and higher modulus as compared to that of the host resin.

John W Connell↗

NASA NTRS2002

Phenylethynyl Containing Reactive Additives

Phenylethynyl containing reactive additives were prepared from aromatic diamine, containing phenylethvnvl groups and various ratios of phthalic anhydride and 4-phenylethynviphthalic anhydride in glacial acetic acid to form the imide in one step or in N-methyl-2-pvrrolidinone to form the amide acid intermediate. The reactive additives were mixed in various amounts (10% to 90%) with oligomers containing either terminal or pendent phenylethynyl groups (or both) to reduce the melt viscosity and thereby enhance processability. Upon thermal cure, the additives react and become chemically incorporated into the matrix and effect an increase in crosslink density relative to that of the host resin. This resultant increase in crosslink density has advantageous consequences on the cured resin properties such as higher glass transition temperature and higher modulus as compared to that of the host resin.

Connell, John W.↗

NASA NTRS2003

Nanophase, Low-Ni Metal Grains in Fine-grained Rims in the Murchison CM2 Chondrite: Insights into the Survival of Metal Grains During Aqueous Alteration

Aqueous alteration has played a significant role in the geological evolution of almost all the chondrite groups and attests to the importance of water during the earliest history of the solar system. Among the chondrites that show evidence of aqueous alteration the CM chondrites, in particular, have received considerable attention, because of their primitive composition and the fact that they preserve a record of incomplete hydration. Petrologic studies of this group of meteorites have helped provide important insights into aqueous alteration processes and the nature of the alteration products. However, due to the complex history of these chondrites, important details of the alteration remain enigmatic. Among the major problems to be resolved are the location and timing of aqueous alteration as well as the relationship between alteration and brecciation. Although many authors favor aqueous alteration within a parent body environment, there is also evidence that some of the components of CM chondrites may have experienced aqueous alteration prior to accretion. One of the key lines of evidence for alteration in a pre-accretionary environment is the presence of unaltered metal grains associated with hydrated phases. Low-Ni metal (kamacite) is typically one of the first phases in CM chondrites that alters in the presence of water. However, in some CM chondrites, such as Yamato 791198, micron-sized metal grains are present within the hydrated fine-grained rim material around chondrules. In addition, nanometer-sized grains that have been interpreted as being unaltered metal particles have been reported in the relatively heavily altered CM chondrite, ALH 81002. In most cases, these occurrences have been interpreted as being the result of mixing of anhydrous and hydrous materials prior to accretion. According to this hypothesis, the metal grains remain unaltered because little or no post-accretionary alteration took place. Whilst such a scenario is plausible, no alternative explanations such as the presence of submicron protective layers or a minor element chemistry that might inhibit oxidation have been investigated in detail. During a study of the distribution of carbonaceous material in fine-grained rims on chondrules in Murchison, previously unidentified, nanometer-sized metal grains were observed. These grains were characterized in detail using high resolution TEM and energy filtered TEM (EFTEM) and provide important insights into how metal grains in CM chondrites may survive aqueous alteration.

Brearley, Adrian J.↗

NASA NTRS1992

On the nature of global classification

Molecular sequencing technology has brought biology into the era of global (universal) classification. Methodologically and philosophically, global classification differs significantly from traditional, local classification. The need for uniformity requires that higher level taxa be defined on the molecular level in terms of universally homologous functions. A global classification should reflect both principal dimensions of the evolutionary process: genealogical relationship and quality and extent of divergence within a group. The ultimate purpose of a global classification is not simply information storage and retrieval; such a system should also function as an heuristic representation of the evolutionary paradigm that exerts a directing influence on the course of biology. The global system envisioned allows paraphyletic taxa. To retain maximal phylogenetic information in these cases, minor notational amendments in existing taxonomic conventions should be adopted.

NASA Program Exobiology↗

NASA NTRS2004

Global Land Ice Measurements from Space

The NSIDC at the University of Colorado has successfully completed the tasks outlined in its proposal 0999.08.1216B, the 'Global Land Ice Measurements from Space' grant funded by NASA under NAG5-9722. The Global Land Ice Measurements from Space (GLIMS) grant reported on here is one of the first completed elements of the overall GLIMS project that continues with separate funding from NASA, the United States Geological Survey (USGS), and internationally by many national agencies and universities. The primary goals of GLIMS are to survey significant numbers of the world's 160,000 glaciers with data collected by the ASTER (Advanced Spaceborne Thermal Emission and reflection Radiometer) instrument aboard the EOS Terra spacecraft, and Landsat ETM+ (Enhanced Thematic Mapper Plus) and to make these data available to users in a common and easily usable format. GLIMS participants include: NSIDC as developer of the GLIMS database, USGS Flagstaff as the GLIMS Coordination Center, USGS EROS Data Center (EDC) as the archive for satellite imagery used in GLIMS analyses (NASA funding for GLIMS also includes the Flagstaff group and EDC through the related ASTER Science Team and Land Processes Distributed Active Archive Center [LP DAAC] activities), and approximately twenty two Regional Centers (RCs). RCs are funded by the national agencies of participating countries to analyze satellite imagery for a specified set of glaciological parameters and provide the results to NSIDC for archive and distribution to the public.

Scharfen, Gregory R.↗

NASA NTRS2005

A PdMn Based High Resolution Thermometer for the Temperature Range of 0.7-1 K

Experiments Along the Coexistence near Tricriticality (EXACT) will test exact predictions made by Renormalization Group theory by mapping the phase diagram of liquid He-3 and He-4 mixtures at the tricritical point, Tcp=0.867 K. A PdMn based High Resolution Thermometer (HRT) will be utilized by EXACT to make accurate measurements with a resolution that has never been attained for the temperature range 0.7-1 K. The basic design of this mini high resolution thermometer comprises a sensing element whose magnetic susceptibility changes with temperature, a thermal connector, magnetic shielding, and some permanent magnets to apply a constant magnetic field. In this study, we will quantitatively determine the resolution of possible sensing element candidates of 0.15%, 0.20%, and 0.25% ppm Mn and compare them with an annealed group of PdMn with the corresponding concentrations to see how this processing technique affects sensitivity.

Koo, Peter K.↗