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At least 1,477 records · Page 82

Degradation and Reliability Advancements in Tubular SOFC (Final Report)

The objective of this project is to improve the degradation and reliability of tubular SOFC and develop technologies applicable to stacks scalable to sub-MW system. The Phase II project scope encompasses the cell level technology development listed here and also bundle level degradation verification; 1. Incorporation of an inexpensive on-cell contamination gettering element in each cell to provide protection for cathode against Cr and S; 2. Enhance the electrical contact between Ag current collector and the lanthanum chromite based interconnection layer; 3. Improve the electrolyte layer sintering recipe to reduce the defect density and related anode oxidation problem

03 NATURAL GAS↗

Degradation and Reliability Advancements in Tubular SOFC (Final Report)

The objective of this project is to improve the degradation and reliability of tubular SOFC and develop technologies applicable to stacks scalable to sub-MW system. The Phase II project scope encompasses the cell level technology development listed below and also bundle level degradation verification. (1) Incorporation of an inexpensive on-cell contamination gettering element in each cell to provide protection for cathode against Cr and S. (2) Enhance the electrical contact between Ag current collector and the lanthanum chromite based interconnection layer. (3) Improve the electrolyte layer sintering recipe to reduce the defect density and related anode oxidation problem.

03 NATURAL GAS↗

Improving Coal-Fired Plant Performance Through Integrated Predictive and Condition-Based Monitoring Tools

The project demonstrated the ability to improve boiler performance and reliability through the integrated use of condition-based monitoring (CBM) and predictions of the impacts of coal quality on boiler operations at a full-scale coal-fired power plant. The advanced tool developed actively monitors and manages coal quality and overall boiler conditions that maximizes availability and maintains generating capacity while reducing cost. The tool is used to forecast and alert plant operators and engineers about poor boiler conditions which may occur as a result of incoming coal and/or current power plant operating conditions. The Combustion System Performance Indices (CSPI) and CoalTracker (CT) programs predicts fireside performance of the plant including slagging, fouling, erosion, slag flow, strength development (sintering/densification), and slag layer thickness based on the composition of delivered coal. CT program is tailored for each plant and is used to track the coal from the point of delivery to the burner. The most successful application of the CSPI-CT has been at plants where the coal composition is determined through the use of a full stream elemental analyzers based on prompt gamma neutron analysis (PGNAA). The CSPI-CT program information is used by coal procurement, coal mining and plant operations personnel to select and blend coal properties for the best plant performance.

01 COAL, LIGNITE, AND PEAT↗

Comparison of Commercial, State-of-the-Art, Fossil-Based Hydrogen Production Technologies

This report presents an independent assessment of the cost and performance of select hydrogen production plants utilizing fossil fuel resources as the primary feedstocks – specifically, natural gas (NG), steam methane reforming (SMR), NG autothermal reforming (ATR), coal gasification, and coal/biomass co-gasification – using a systematic, transparent technical and economic approach. Study cases were selected to reflect the capabilities of current, commercial technologies within plant configurations, and at scales, representative of next commercial offerings facing no fundamental research and development (R&D) obstacles. Additionally, several areas of R&D are identified as potential pathways for performance improvements and cost reductions.

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Hydrogen Storage for Load-Following and Clean Power: Duct-firing of Hydrogen to Improve the Capacity Factor of NGCC Plants (Final Report, Phase I Conceptual Study)

The 12-month Feasibility study in Phase I study was completed and confirmed the system is feasible and the proposed system is an improvement over alternate low carbon dispatchable power options. Our demonstration will include 54 MWh of hydrogen storage. CO 2 capture inherent to the CHG process can capture 90% of the CO 2 (with upgrades to >98%) in a commercial system (~300 MWth) for sequestration or other uses. The hydrogen will be utilized in a duct burner in a Heat Recovery Steam Generator (HRSG) integrated with the existing Southern Company fossil asset. Here, the firing rate of the duct burner is varied to let the plant respond to fluctuations of electrical load. However, H 2 production is relatively constant by storing H 2 , and revenues are improved by arbitrage between use of low-cost off-peak variable electricity generation or use of stored H 2 under peak demand. The study enabled the fidelity of the concept to be improved and allowed identification of the requirements for the system. Defining the individual system and component requirements was performed via system requirements review with the whole team. These requirements were then incorporated into/iterated with our Heat & Mass Balance models and process flow diagrams were generated to reflect the overall system. This information was then used to complete the TEA and show economic feasibility. Our system generates power at 17.4% lower cost than other low carbon approaches for the H 2 generation, H 2 compression and storage, carbon sequestration, and HRSG added electricity production for a large-scale duct-fired system. Our team recommends completing the Phase II Pre-FEED study for the proposed system as the next step for the project and its tasks will achieve the overall objective and be ready to launch the FEED. The Pre-FEED tasks include updating the requirements, Concept of Operations, plant scope/process description, component modeling, system modeling, performance estimates, emission estimates, block flow diagrams, fluid/process conditions (PFD), utility usage, and facility sizing/definition. The approach will be to complete these updates in a greater level of detail for the selected site. The approach for developing the EIV is to use the updated results, including model outputs, for carbon dioxide and waste streams.

03 NATURAL GAS↗

Analyses of Model-Based Predictive Control for a S-CO 2 Brayton Cycle Power Converter

The supercritical carbon dioxide (S-CO 2 ) Brayton cycle is a promising alternative to steam cycles as an energy converter for advanced nuclear reactors as well as fossil-fired and concentrated solar power plants. For advanced reactors, such as Sodium-cooled Fast Reactors (SFRs), the S-CO 2 cycle offers the benefits of high cycle efficiency, very compact turbomachinery, and elimination of sodium-water reactions, all of which may enable improved economics. The efficiency gains calculated for the S-CO 2 cycle are particularly significant if advantage can be taken of the sharp changes in the carbon dioxide thermo-physical properties near the critical point. On the other hand, the same property variations give rise to challenges in the cycle design, analysis, and control. The onset of two-phase flow (where the minimum cycle temperature and pressure drop drop below the critical value) can degrade compressor performance and potentially cause damage to the compressor blades. In previous work, the feasibility of the Model-based Predictive Control (MPC) approach was assessed for improving regulation of the precooler outlet temperature. A linear reduced-order model for the precooler was generated and for this simplified standalone system operating with an MPC controller the response of outlet temperature was evaluated through simulations. These evaluations included the presence of temperature measurement time delay representing a degraded sensor. It was demonstrated that the MPC controller maintained stable precooler temperature for those delay cases where a proportional-integral controller became unstable. In the present work the simulations have been extended to evaluate the MPC controller operating under more realistic conditions, namely in the split-flow recompression cycle non-linear plant. This compares with the previous standalone reduced-order linear system described above. In the present work the MPC-based control scheme was implemented in a GPASS 1-D systems code representation of the split-flow recompression cycle. The performance of the controller was again investigated for degraded sensor conditions and compared to that of a proportional-integral controller. The results were qualitatively similar to the previous results with the MPC controller and again providing superior stability characteristics. This work provides a sound starting point for the development of model-based control systems. In particular, the MPC control approach applied to Multiple Input Multiple Output systems can be used to synchronize the operation of the different system components to improve control system dynamic performance.

20 FOSSIL-FUELED POWER PLANTS↗

Pilot Scale Testing of the Hydrophobic-Hydrophilic Separation Process to Produce Value-Added Products from Waste Coal

The primary objective of this project was to demonstrate the technical and economic feasibility of using the hydrophobic-hydrophilic separation (HHS) process to produce high-purity, value-added clean coal that could serve as feedstock for specialty carbon products from waste coal. An existing one-skid (i.e., the entire unit fits on a single tractor-trailer) HHS pilot-scale facility was used to process bituminous and anthracite waste coals to produce: 1) a clean coal containing less than 5% ash (super-clean) and 2) another containing less than 1.5% ash (ultra-clean), all of which contain single-digit moistures. Sufficient quantities of these products were to be generated to permit detailed evaluations by potential customers producing or developing new, high-value market applications. In addition, the project included the evaluation of several process improvements to reduce the capital and operating costs for a commercial HHS plant. A final objective was to complete an economic analysis, market-penetration analysis, and technology-gap analysis of the HHS technology and its products.

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Blockchain Empowered Provenance Framework for Sensor Identity Management and Data Flow Security in Fossil-based Power Plants

The overall goals of this project are divided into 3 important phases. First, a peer-to-peer SCADA network is to be established where identity profile of sensors from fossil-power plants will be stored in an immutable manner in order to verify data flow integrity in real time. Second, it is aimed to develop a Blockchain-based provenance platform to audit equipment operations along with data and process integrity violations. In this phase, various operational rules will be incorporated in the ledger on behalf of the operating sensor so its abnormal use can be easily detected. In addition, it is aimed to achieve provenance when the rate of transactions is exceedingly high, thus enabling to design a scalable provenance scheme that can work in real time when number of data collecting points or sensor units increase in fossil-based power plants. Finally, a working testbed will be developed to integrate the Blockchain platform with sensor-based fossil power plant comprising of Remote Terminal Units (RTU) and SCADA devices. Using multiple Raspberry-PIs mimicking the role of RTUs that are interfaced with multiple sensors devices will be deployed to serve as a critical component of fossil power plant and the performance metrics such as throughput, latency, bootstrapping time, etc., will be evaluated on the testbed.

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U.S. Incentives to Capture and Store CO 2

Fact sheet on the 45Q tax credit. 45Q was created in 2008 as a tax credit to incentivize the development of carbon capture, utilization, and storage (CCUS) projects.

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Permitting Commercial Geologic CO 2 Storage Projects

Conference presentation at 2023 Rocky Mountain Section-American Association of Petroleum Geologists (RMS-AAPG) Annual Meeting, Bismarck, ND, June 4–6, 2023. Successful Carbon Capture, Utilization, and Storage (CCUS) projects depend on clear and applicable regulatory requirements that are thoroughly understood by project developers. It is evident that states are best positioned to regulate CO 2 storage through comprehensive regulations and permitting efficiencies. Further, tax incentives and an emphasis on low-carbon fuels compound to make CCUS more attractive to investors and states alike.

20 FOSSIL-FUELED POWER PLANTS↗

Second generation non-aqueous solvents (gen2nas) for co 2 capture from natural gas combined cycle plants

This final technical report submitted to DOE/NETL presents all the research activities performed during the Cooperative Agreement DE-FE0032218 entitled Second Generation Non-Aqueous Solvents (GEN2NAS) for CO 2 Capture from Natural Gas Combined Cycle Plants, which spanned from April 2023 through March 2025. In this project, Research Triangle Institute (RTI) International has developed the second-generation of its non-aqueous solvent (NAS), herein referred to as GEN2NAS, to remove carbon dioxide (CO 2 ) from natural-gas combined cycle (NGCC) flue gas. The technology aims to substantially reduce the cost of CO 2 capture while minimizing the environmental impacts through lower secondary emissions and wastewater generated from the CO 2 capture plant.

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lllinois Storage Corridor CarbonSAFE Phase III: Pre-drilling Site Assessment: Prairie State Generating Company

The Illinois Storage Corridor project will drill a stratigraphic test well as part of the Illinois Storage Corridor CarbonSAFE Phase 3 project near the Prairie State Generating Company coal-fired power plant near Marissa, Illinois. The pre-drilling site evaluation has considered the primary target reservoirs, the Potosi Dolomite and St. Peter Sandstone, and primary seal, the Maquoketa Group. Data to be collected from the well include core, fluid samples, in situ well tests, geophysical logs intended to provide information on lithologic, geomechanical, and geophysical characteristics to determine the feasibility for the geologic sequestration of 50 million metric tons or more of injected carbon dioxide. The planned drilling site has been evaluated using available subsurface geologic data and analyses from the Illinois Basin. These data provide lithologic and structural information, shallow groundwater resource distribution, location of known nearby wellbores, and regional drilling characteristics. The data were used to generate geologic structure and isopach maps for the target reservoir and caprock strata and for prognosing the tops of major lithologic units to aid drilling and coring procedures. The regional analyses indicate that no known structural features are expected to negatively impact the target storage reservoir or caprock. No protected and sensitive areas, groundwater resources, or existing resource development are expected to be impacted by the proposed well drilling activities. The well is planned to be drilled to a total depth of approximately 5,600 feet (1,707 m) and terminate in the Precambrian. Cores (up to 5 intervals) will be collected from the Maquoketa Group, confining units above the St. Peter Sandstone, St. Peter Sandstone, confining units of the Potosi Dolomite and the Potosi Dolomite. Water samples will be attempted to be collected from the St. Peter Sandstone and Potosi Dolomite. Potential impact on drilling progress is a lost circulation zone in the Potosi Dolomite, which has been demonstrated to have intermittent cavernous porosity from karstification elsewhere in the Illinois Basin. This document also presents a preliminary coring and sampling program, proposed logging suite, and well testing program, all of which will be reviewed during drilling.

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PCOR Partnership: A Catalyst for Commercial CCUS Deployment

Conference presentation at Carbon Capture & Storage Summit, Minneapolis, Minnesota, June 10-12, 2024. An overview of the Plains CO 2 Reduction (PCOR) Partnership Initiative and active commercial carbon capture, utilization, and storage (CCUS) activity in the region. The presentation discusses solutions for CCUS deployment challenges.

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Implementing the First Incentive-Drive Carbon Capture and Storage Projects

Conference presentation at International Fuel and Ethanol Workshop and Expo (FEW), Omaha, Nebraska, June 13, 2023. An overview of the Plains CO 2 Reduction (PCOR) Partnership Initiative and active commercial carbon capture, utilization, and storage (CCUS) activity in the region. Includes solutions for CCUS deployment challenges.

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Permitting Commercial-Scale Carbon Dioxide Geological Storage

Conference presentation at Underground Injection Control Annual Meeting of the Groundwater Protection Council, San Antonio, Texas, February 18, 2020. An overview of the Plains CO 2 Reduction (PCOR) Partnership Initiative and carbon capture, utilization, and storage (CCUS) activity in the region. Includes permitting process for CCUS deployment in North Dakota.

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Balancing CO 2 Pipeline Infrastructure Challenges

Conference presentation at American Association of Petroleum Geologists (AAPG) Carbon Capture, Utilization, and Storage (CCUS) Conference, Houston, Texas, March 28–30, 2022. This study on the pipeline systems revealed challenges that a pipeline system will face: a) pipeline cost estimates and cost drivers, b) cost and hydraulics optimization, and c) temperature effects on the pipeline capacity and maximum injection pressure at an injection well.

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Regional Subsurface Stress Assessment for CO 2 Storage in Candidate Basal Reservoirs within the Plains CO 2 Reduction Partnership Region of North America

Conference presentation at Carbon Capture, Utilization, and Storage (CCUS) Conference 2024, Houston, Texas, March 11–13, 2024. A screening-level regional evaluation of basement and mechanical overburden stress across the geologically diverse Plains CO 2 Reduction (PCOR) Partnership Initiative region was conducted. The main objective of the project was to assess potential basement fault reactivation and better understand technical uncertainties pertaining to CO 2 storage in candidate basal reservoirs.

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